CN106700755A - Coating for building external wall - Google Patents

Coating for building external wall Download PDF

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Publication number
CN106700755A
CN106700755A CN201611239208.4A CN201611239208A CN106700755A CN 106700755 A CN106700755 A CN 106700755A CN 201611239208 A CN201611239208 A CN 201611239208A CN 106700755 A CN106700755 A CN 106700755A
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CN
China
Prior art keywords
percent
coating
emulsion
exterior wall
building exterior
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201611239208.4A
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Chinese (zh)
Inventor
张璇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chengdu LVDI Technology Co Ltd
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Chengdu LVDI Technology Co Ltd
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Filing date
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Priority to CN201611239208.4A priority Critical patent/CN106700755A/en
Publication of CN106700755A publication Critical patent/CN106700755A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1606Antifouling paints; Underwater paints characterised by the anti-fouling agent
    • C09D5/1612Non-macromolecular compounds
    • C09D5/1618Non-macromolecular compounds inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24Electrically-conducting paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention relates to a coating for a building external wall. The coating is prepared from the following raw materials in percentage by weight: 15 to 20 percent of fluorocarbon emulsion, 6 to 10 percent of organic silicon modified crylic acid emulsion, 6 to 10 percent of organic fluorine modified crylic acid emulsion, 6 to 12 percent of cellular quartz powder, 25 to 36 percent of anatase nano TiO2, 5 to 10 percent of nano zinc oxide. 1 to 3 percent of a compatilizer, 1 to 3 percent of a defoaming agent, 1 to 4 percent of a dispersing agent, 2 to 6 percent of hydroxyethyl cellulose, 1 to 3 percent of a thickener, 1 to 3 percent of a PH regulator, 1 to 2 percent of an antifreezing agent and 3 to 9 percent of water. The coating is plump and fine in paint film, has a bright color, is high in leveling property, high in adhesive force, nontoxic, long-acting, antibacterial, environmentally friendly, and high in weather resistance, stain resistance and chemical stability, and can achieve long-term effective cleaning.

Description

Coating used for building exterior wall
Technical field
The present invention relates to building decoration field, and in particular to a kind of coating used for building exterior wall.
Background technology
Existing coating used for building exterior wall is mainly fluorocarbon coating, and fluorocarbon coating refers to fluororesin as main film forming substance Coating, also known as F-C paint, fluoro coatings, fluorine resin coating etc..Among various coating, fluorine resin coating is due to the fluorine unit for introducing Plain electronegativity is big, and carbon-fluorine bond can be strong, with especially advantageous properties:Weatherability, heat resistance, lower temperature resistance, chemically-resistant medicine Moral character, and with unique non-stick and low abrasiveness.Fluorocarbon coating as the multifunctional coating with super weather resisteant, in light Damp conservation rate, fade resistant, Corrosion Protection aspect, fully meet the use requirement of client, but in the long-term dicoration side of coating Face, conventional fluorocarbon coating kind could not also reach a high level, fluorocarbon coating after some time of use, meeting Produce rainprint pollution.In actual application process, fluorocarbon coating has relatively low surface relative to other coating varieties in fact For, pollution is not easily susceptible to, even if pollutant is also bonded loosely in coating surface, it is easy to be easily removed.But make for a long time The low-surface-energy of film can not well prevent the generation of rainprint under the conditions of.Conversely with the continuous accumulation of spot, film Original decorative effect can be deteriorated, and lose original gay colours, and blackening is graying, form black, the yellow spot of various strips, If do not cleaned manually, dicoration can be gradually lost.Therefore, fluorocarbon coating has property easy to clean, rather than self-cleaning property.In order to reach To self-cleaning property, the building coating for having stain resistance in current China market is added by hydrophobic of modified organic silicone resin The coating of agent.This modified organic silicone resin addition low-surface-energy small molecule is put forward the stain resistant ability of organosilicon coating Height, but this coating stain resistance over time, reduced rapidly due to the loss of low-surface-energy small molecule, or even Lose, still reach to less than effectively self-cleaning.
The content of the invention
It is an object of the present invention to provide a kind of coating used for building exterior wall, paint film is plentiful, exquisiteness, and beautiful in colour, good leveling property is attached Put forth effort strong, nontoxic, long acting antibiotic, environmental protection, high-weatherability, high dirt resistance, chemical stability is good, and reaches permanently effective Automatically cleaning.
In order to realize the above object the technical solution adopted by the present invention is:A kind of coating used for building exterior wall, according to weight hundred Dividing the raw material of ratio includes:
Fluorine carbon emulsion 15 ~ 20%,
Organosilicon-modified acrylic emulsion 6 ~ 10%,
Organic fluoride modified acrylic acid emulsion 6 ~ 10%,
Porous konilite 6 ~ 12%,
Dichloride in anatase type TiO225 ~ 36%,
Nano zine oxide 5 ~ 10%,
Compatilizer 1 ~ 3%,
Defoamer 1 ~ 3%,
Dispersant 1 ~ 4%,
Hydroxyethyl cellulose 2 ~ 6%,
Thickener 1 ~ 3%,
PH conditioning agents 1 ~ 3%,
Antifreezing agent 1 ~ 2%,
Water 3 ~ 9%.
Preferably, described coating used for building exterior wall, includes according to the raw material of percentage by weight:
Fluorine carbon emulsion 18%,
Organosilicon-modified acrylic emulsion 8%,
Organic fluoride modified acrylic acid emulsion 8%,
Porous konilite 8%,
Dichloride in anatase type TiO230%,
Nano zine oxide 7%,
Compatilizer 2%,
Defoamer 2%,
Dispersant 3%,
Hydroxyethyl cellulose 4%,
Thickener 2%,
PH conditioning agents 1%,
Antifreezing agent 1%,
Water 6%.
Further, described compatilizer is perfluor silicone resin.
Further, described thickener polyvinyl alcohol.
Further, described dispersant is polyvinylpyrrolidone.
Further, described defoamer is CF-246 defoamers.
Further, described antifreezing agent is propane diols.
Further, 5% pure acrylic latex is contained in described fluorine carbon emulsion.
The technical effects of the invention are that:The present invention is using dichloride in anatase type TiO2Material, the main machine of its polluting proofing property Reason shows two aspects:One is dichloride in anatase type TiO2The photocatalytic Degradation of itself, under light illumination nano titanium oxide Constantly decompose and be gathered in the organic matter of coating surface, the spot of absorption is lost adhesive effect with coating;Two is nano-silica Change the addition of titanium, hydrophilic surface can be produced, completely cut off oiliness pollutant, mitigate rainprint pollution.Use porous konilite be Volcanic ash sedimentary rock, its natural particle diameter is thin(0.5 μm or so), even particle distribution, specific surface area is big, with electronic microscope image See, its surface is entirely nano level mesoporous.Periporate quartz surfaces contain a number of hydroxyl(-OH)- silanol.As polarity Functional group, is favorably improved the adhesive force and caking property of coating.On the other hand, due to the presence of hydroxyl, it is easier to by coupling Agent be surface-treated, increase its crosslinking, the effect of reinforcement, that is, increase product physical and mechanical property improve again film stretching it is strong Degree and the attachment to collective, caking property.The nano zine oxide of use has high-specific surface area, high activity, specific physical property, cause Make its environment to external world(Such as temperature, light, moisture)Very sensitive, the change of external environment can rapidly cause the notable of its resistance Change, it has the characteristic of semiconductor, with electric conductivity higher, thus can play electrostatic screen, and anti-static effect is fine, This is that it is used for an advantage of the present invention.Additionally, such nano zine oxide can make coating have shielding ultraviolet rays, absorb it is red Outside line and fungus and mildew resistance are acted on.Using hydroxyethyl cellulose as a kind of surfactant of nonionic, with thickening, hang Floating, bonding, floatingization, film forming, dispersion, water conservation and offer protective coating colloid action.The coating obtained according to said ratio, paint film Plentiful, exquisiteness, beautiful in colour, good leveling property, adhesive force is strong, nontoxic, long acting antibiotic, environmental protection, high-weatherability, high dirt resistance Property, chemical stability is good.Can be under long-term conditions, it is not necessary to artificial cleaning and oneself can maintain good clean conditions requirement from Cleaning.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all Belong to the scope of protection of the invention.
Embodiment 1:A kind of coating used for building exterior wall, includes according to the raw material of percentage by weight:
Fluorine carbon emulsion 18%,
Organosilicon-modified acrylic emulsion 8%,
Organic fluoride modified acrylic acid emulsion 8%,
Porous konilite 8%,
Dichloride in anatase type TiO230%,
Nano zine oxide 7%,
Compatilizer 2%,
Defoamer 2%,
Dispersant 3%,
Hydroxyethyl cellulose 4%,
Thickener 2%,
PH conditioning agents 1%,
Antifreezing agent 1%,
Water 6%.
Further, described compatilizer is perfluor silicone resin.
Further, described thickener polyvinyl alcohol.
Further, described dispersant is polyvinylpyrrolidone.
Further, described defoamer is CF-246 defoamers.
Further, described antifreezing agent is propane diols.
Further, 5% pure acrylic latex is contained in described fluorine carbon emulsion.
The defoamer of above-mentioned score, dispersant, thickener, defoamer, antifreezing agent etc. are dispersed in water and are obtained processing and is helped Agent, then adds porous konilite, dichloride in anatase type TiO according to the above ratio2, other slurries such as fluorine carbon emulsion, in dispersion machine High-speed stirred is disperseed, and is added above-mentioned processing aid and is sufficiently stirred for, and finally adds PH conditioning agents to adjust the pH value of coating.According to The coating that said ratio is obtained, paint film is plentiful, exquisiteness, beautiful in colour, good leveling property, and adhesive force is strong, and nontoxic, long acting antibiotic is green Colour circle is protected, and high-weatherability, high dirt resistance, chemical stability is good.Can be under the long-term conditions of at least 5 years, it is not necessary to artificial clear Wash and the automatically cleaning of energy oneself the good clean conditions requirement of maintenance.
Embodiment 2:A kind of coating used for building exterior wall, includes according to the raw material of percentage by weight:
Fluorine carbon emulsion 15%,
Organosilicon-modified acrylic emulsion 7%,
Organic fluoride modified acrylic acid emulsion 8%,
Porous konilite 10%,
Dichloride in anatase type TiO235%,
Nano zine oxide 8%,
Compatilizer 1%,
Defoamer 1%,
Dispersant 2%,
Hydroxyethyl cellulose 5%,
Thickener 1%,
PH conditioning agents 1%,
Antifreezing agent 1%,
Water 5%.
Further, described compatilizer is perfluor silicone resin.
Further, described thickener polyvinyl alcohol.
Further, described dispersant is polyvinylpyrrolidone.
Further, described defoamer is CF-246 defoamers.
Further, described antifreezing agent is propane diols.
Further, 5% pure acrylic latex is contained in described fluorine carbon emulsion.
The coating obtained according to said ratio, paint film is plentiful, exquisiteness, beautiful in colour, good leveling property, and adhesive force is strong, nontoxic, Long acting antibiotic, environmental protection, high-weatherability, high dirt resistance, chemical stability is good.Can be under the long-term conditions of at least 5 years, no Need the automatically cleaning of artificial cleaning and the good clean conditions requirement of energy oneself maintenance.
Embodiment 3:A kind of coating used for building exterior wall, includes according to the raw material of percentage by weight:
Fluorine carbon emulsion 16%,
Organosilicon-modified acrylic emulsion 8%,
Organic fluoride modified acrylic acid emulsion 7%,
Porous konilite 10%,
Dichloride in anatase type TiO235%,
Nano zine oxide 8%,
Compatilizer 1%,
Defoamer 1%,
Dispersant 2%,
Hydroxyethyl cellulose 5%,
Thickener 1%,
PH conditioning agents 1%,
Antifreezing agent 1%,
Water 4%.
Further, described compatilizer is perfluor silicone resin.
Further, described thickener polyvinyl alcohol.
Further, described dispersant is polyvinylpyrrolidone.
Further, described defoamer is CF-246 defoamers.
Further, described antifreezing agent is propane diols.
Further, 5% pure acrylic latex is contained in described fluorine carbon emulsion.
The coating obtained according to said ratio, paint film is plentiful, exquisiteness, beautiful in colour, good leveling property, and adhesive force is strong, nontoxic, Long acting antibiotic, environmental protection, high-weatherability, high dirt resistance, chemical stability is good.Can be under the long-term conditions of at least 5 years, no Need the automatically cleaning of artificial cleaning and the good clean conditions requirement of energy oneself maintenance.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be in other specific forms realized.

Claims (8)

1. a kind of coating used for building exterior wall, it is characterised in that the raw material according to percentage by weight includes:
Fluorine carbon emulsion 15 ~ 20%,
Organosilicon-modified acrylic emulsion 6 ~ 10%,
Organic fluoride modified acrylic acid emulsion 6 ~ 10%,
Porous konilite 6 ~ 12%,
Dichloride in anatase type TiO225 ~ 36%,
Nano zine oxide 5 ~ 10%,
Compatilizer 1 ~ 3%,
Defoamer 1 ~ 3%,
Dispersant 1 ~ 4%,
Hydroxyethyl cellulose 2 ~ 6%,
Thickener 1 ~ 3%,
PH conditioning agents 1 ~ 3%,
Antifreezing agent 1 ~ 2%,
Water 3 ~ 9%.
2. coating used for building exterior wall according to claim 1, it is characterised in that the raw material according to percentage by weight includes:
Fluorine carbon emulsion 18%,
Organosilicon-modified acrylic emulsion 8%,
Organic fluoride modified acrylic acid emulsion 8%,
Porous konilite 8%,
Dichloride in anatase type TiO230%,
Nano zine oxide 7%,
Compatilizer 2%,
Defoamer 2%,
Dispersant 3%,
Hydroxyethyl cellulose 4%,
Thickener 2%,
PH conditioning agents 1%,
Antifreezing agent 1%,
Water 6%.
3. coating used for building exterior wall according to claim 1 and 2, it is characterised in that described compatilizer is perfluor silica Alkane resin.
4. coating used for building exterior wall according to claim 1 and 2, it is characterised in that described thickener polyvinyl alcohol.
5. coating used for building exterior wall according to claim 1 and 2, it is characterised in that described dispersant is polyethylene pyrrole Pyrrolidone.
6. coating used for building exterior wall according to claim 1 and 2, it is characterised in that described defoamer disappears for CF-246 Infusion.
7. coating used for building exterior wall according to claim 1 and 2, it is characterised in that described antifreezing agent is propane diols.
8. coating used for building exterior wall according to claim 1 and 2, it is characterised in that pure containing 5% in described fluorine carbon emulsion Acrylic emulsion.
CN201611239208.4A 2016-12-28 2016-12-28 Coating for building external wall Pending CN106700755A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611239208.4A CN106700755A (en) 2016-12-28 2016-12-28 Coating for building external wall

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611239208.4A CN106700755A (en) 2016-12-28 2016-12-28 Coating for building external wall

Publications (1)

Publication Number Publication Date
CN106700755A true CN106700755A (en) 2017-05-24

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CN201611239208.4A Pending CN106700755A (en) 2016-12-28 2016-12-28 Coating for building external wall

Country Status (1)

Country Link
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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641584A (en) * 2018-03-12 2018-10-12 苏州甫众塑胶有限公司 A kind of ageing-resistant building coating of stain resistant and preparation method thereof
CN108976855A (en) * 2018-08-03 2018-12-11 郑州合撷亨商贸有限公司 A kind of coating of environment affinity type safety and environmental protection
CN109135464A (en) * 2018-07-13 2019-01-04 芜湖多辉建设有限公司 A kind of modified interior wall coating of environment-friendly antibacterial anti-corrosion
CN113444407A (en) * 2021-03-23 2021-09-28 上海涂固安高科技有限公司 Anti-fouling and anti-virus fluorocarbon coating and preparation method thereof
CN114836097A (en) * 2022-06-07 2022-08-02 广东美涂士建材股份有限公司 Multifunctional nano building exterior wall coating and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1454948A (en) * 2003-05-19 2003-11-12 复旦大学 Superclean external wall organic coating for building and preparing method thereof
CN102627895A (en) * 2012-03-29 2012-08-08 黑龙江省玉琦装饰涂料有限公司 Multifunctional dustproof self-cleaning wall paint
CN105315817A (en) * 2015-11-23 2016-02-10 苏州盖德精细材料有限公司 Water-based acrylic resin paint and preparing method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1454948A (en) * 2003-05-19 2003-11-12 复旦大学 Superclean external wall organic coating for building and preparing method thereof
CN102627895A (en) * 2012-03-29 2012-08-08 黑龙江省玉琦装饰涂料有限公司 Multifunctional dustproof self-cleaning wall paint
CN105315817A (en) * 2015-11-23 2016-02-10 苏州盖德精细材料有限公司 Water-based acrylic resin paint and preparing method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108641584A (en) * 2018-03-12 2018-10-12 苏州甫众塑胶有限公司 A kind of ageing-resistant building coating of stain resistant and preparation method thereof
CN109135464A (en) * 2018-07-13 2019-01-04 芜湖多辉建设有限公司 A kind of modified interior wall coating of environment-friendly antibacterial anti-corrosion
CN108976855A (en) * 2018-08-03 2018-12-11 郑州合撷亨商贸有限公司 A kind of coating of environment affinity type safety and environmental protection
CN113444407A (en) * 2021-03-23 2021-09-28 上海涂固安高科技有限公司 Anti-fouling and anti-virus fluorocarbon coating and preparation method thereof
CN114836097A (en) * 2022-06-07 2022-08-02 广东美涂士建材股份有限公司 Multifunctional nano building exterior wall coating and preparation method thereof

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Address after: 230001 Anhui Province Industrial Park of Luyang District of Hefei City, Honghe road and Jinchi Road intersection Sea Industrial Park, No. 4 Building 3

Applicant after: Wisdom ultra Ocean Construction Engineering Limited by Share Ltd

Address before: 230001 Anhui Province Industrial Park of Luyang District of Hefei City, Honghe road and Jinchi Road intersection Sea Industrial Park, No. 4 Building 3

Applicant before: ANHUI CHAOYANG DECORATION ENGINEERING CO., LTD.

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Application publication date: 20170524

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