CN103351768A - Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof - Google Patents
Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof Download PDFInfo
- Publication number
- CN103351768A CN103351768A CN2013103040311A CN201310304031A CN103351768A CN 103351768 A CN103351768 A CN 103351768A CN 2013103040311 A CN2013103040311 A CN 2013103040311A CN 201310304031 A CN201310304031 A CN 201310304031A CN 103351768 A CN103351768 A CN 103351768A
- Authority
- CN
- China
- Prior art keywords
- hydrophobic
- cleaning coating
- exterior wall
- self
- warming plate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a hydrophobic self-cleaning coating for a foam cement insulation board for an exterior wall and a preparation method thereof. The method comprises the following steps: 1) preparing super-hydrophobic filler: putting calcium carbonate with different grain sizes into ethyl alcohol to form a solution, placing the solution into a reaction vessel, cooling and mixing, heating, adding hydrophobic agent, adding ammonia water, mixing, distilling ethyl alcohol, and drying calcium carbonate solid to obtain super-hydrophobic calcium carbonate; 2) preparing the hydrophobic self-cleaning coating: adding deionized water, dispersant and defoamer in a container respectively, then adding pigment and super-hydrophobic filler, performing high speed dispersion, adding coalescing agent, preservative, hydrophobic emulsion and thickener under low speed mixing, and mixing to successfully obtain the hydrophobic self-cleaning coating. The hydrophobic self-cleaning coating has excellent hydrophobic performance, and can be widely applied to an exterior wall system.
Description
Technical field
The present invention relates to a kind of used for building exterior wall foamed cement warming plate exterior coating, especially a kind of water-borne coatings with hydrophobic self-cleaning function.
Background technology
The foamed cement warming plate receives much concern because having extensive prospect in the emerging building thermal insulation material, and development rapidly, uses in a lot of engineerings at present.The foamed cement warming plate has light thermal-insulation, fire prevention, the advantage such as durable, is a kind of desirable building thermal insulation material.But the water-intake rate of the foam concrete heat-preserving plate that adopts in the market is large, and the water resistance of existing common building exterior coating is not enough, causes monolithic architecture exterior-wall heat insulation performance to reduce, and after using common exterior coating, contaminated not easy to clean.
Summary of the invention
Defective or deficiency for the above-mentioned background technology exists the object of the present invention is to provide the hydrophobic self-cleaning coating of a kind of foamed cement warming plate.This hydrophobic self-cleaning coating has excellent hydrophobic performance, and used filler all passes through hydrophobic treatment, and water contact angle reaches more than 130 °.The hydrophobic self-cleaning coating production technique of this foamed cement warming plate is simple, and cost of manufacture is lower.
The objective of the invention is to realize by following technical proposals.
The hydrophobic self-cleaning coating of a kind of used for building exterior wall foamed cement warming plate comprises the raw material of following portions by weight:
Further, described pure-acrylic emulsion is one or more in ROHM AND HAAS AC-261P, Bao Lijia BLJ-961, Tao Shi R7030 or the national starch 2800.
Further, described dispersion agent is one or more among BYK190, BYK180, the high 752W of enlightening or the Nuo Puke dispersion agent SN5040.
Further, described defoamer is one or more in BYK1660, BYK023, DOW CORNING DC62, the enlightening high 810.
Further, described thickening material is one or more among ROHM AND HAAS TT935, ROHM AND HAAS ASE-60, the ROHM AND HAAS RM-8W.
Further, described pigment is one or more in Clariant 10G131-CN, Clariant FGR131-CN, Clariant RL131-CN, Clariant GG131-CN, Clariant N131-CN or the Du Pont's titanium dioxide 902.
Further, described super-hydrophobic filler is one or more in super-hydrophobic calcium carbonate, talcum powder, mica powder or the wollastonite powder.
Further, described hydrophobic lotions is DOW CORNING MEM-0349; Described film coalescence aid is TEXANOL ester alcohol-12; Described sanitas is one or more among promise moral Nordes C15 or the ROHM AND HAAS KATHON LXE.
Correspondingly, the present invention and then provided described used for building exterior wall foamed cement warming plate with the preparation method of hydrophobic self-cleaning coating may further comprise the steps:
The first step prepares super-hydrophobic filler:
Particle diameter is respectively 400 orders, 800 orders, 1250 purpose calcium carbonate, by weight for the 1:2:2 ratio joins in an amount of ethanol, be mixed with solids content and be 30%～60% solution, this solution is joined in the reactor, condensation is stirred, be warming up to 60 ℃～90 ℃, then add weight ratio and be 1% hydrophobic treatment agent, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate;
Second step prepares hydrophobic self-cleaning coating:
In container, add first 40～60 parts of deionized waters, 0.5～3 part of dispersion agent, 1～4 part of defoamer, add again 1～10 part of pigment, 20～40 parts of super-hydrophobic fillers, high speed dispersion 30～90min, add 30～50 parts of pure-acrylic emulsions, 1～3 part of sanitas, 1～10 part of hydrophobic lotions, 2～10 parts of film coalescence aid, 5～10 parts of thickening materials under the last stirring at low speed, stir 30～90min, namely get hydrophobic self-cleaning coating.
Above-mentioned hydrophobic treatment agent is 17 fluorine decyl Trimethoxy silanes, Trimethlyfluorosilane, 17 silicon fluorides, dodecyl triethoxyl silane or Union carbide A-162
With respect to existing coating, the present invention has following characteristics:
Described hydrophobic lotions is commercially available organic silicon emulsion, can improve the hydrophobic contact angle of filming after the interpolation.
1, do not have self-cleaning performance with respect to existing exterior wall latex paint, be subject to the defective of outside contamination, the self-cleaning coating that the present invention is prepared, water contact angle can reach 130 °, have self-cleaning performance when rainy, thereby have reduced the expense of cleaning metope.
2, poor to the barrier property of water with respect to existing exterior wall latex paint, water enters into the foaming cement thermal insulation plate, so that the defective of the degradation of lagging material, the self-cleaning coating of the present invention's preparation can prevent that sealing enters into thermal insulation layer, gives full play to the performance of thermal insulation layer.
3, the super-hydrophobic filler hydrophobic performance excellence of crossing through hydrophobically modified can be widely used in building external wall system.
Embodiment
Clearer in order to make the present invention get technical scheme, below in conjunction with specific embodiment technical solutions according to the invention are further detailed.
Used for building exterior wall foamed cement warming plate of the present invention may further comprise the steps with the preparation method of hydrophobic self-cleaning coating:
The first step prepares super-hydrophobic filler:
Particle diameter is respectively 400 orders, 800 orders, 1250 purpose calcium carbonate, by weight for the 1:2:2 ratio joins in the ethanol, be mixed with solids content and be 30%～60% solution, this solution is joined in the reactor, condensation is stirred, be warming up to 60 ℃～90 ℃, then add weight ratio and be 1% hydrophobic treatment agent, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate;
Above-mentioned hydrophobic treatment agent is 17 fluorine decyl Trimethoxy silanes, Trimethlyfluorosilane, 17 silicon fluorides, dodecyl triethoxyl silane or Union carbide A-162.
Second step prepares hydrophobic self-cleaning coating:
In container, add first 40～60 parts of deionized waters, 0.5～3 part of dispersion agent, 1～4 part of defoamer, add again 1～10 part of pigment, 20～40 parts of super-hydrophobic fillers, high speed dispersion 30～90min, add 30～50 parts of pure-acrylic emulsions, 1～3 part of sanitas, 1～10 part of hydrophobic lotions, 2～10 parts of film coalescence aid, 5～10 parts of thickening materials under the last stirring at low speed, stir 30～90min, namely get hydrophobic self-cleaning coating.
Above-mentioned pure-acrylic emulsion is one or more in ROHM AND HAAS AC-261P, Bao Lijia BLJ-961, Tao Shi R7030 or the national starch 2800.
Above-mentioned dispersion agent is one or more among BYK190, BYK180, the high 752W of enlightening or the Nuo Puke dispersion agent SN5040.
Above-mentioned defoamer is one or more in BYK1660, BYK023, DOW CORNING DC62, the enlightening high 810.
Above-mentioned thickening material is one or more among ROHM AND HAAS TT935, ROHM AND HAAS ASE-60, the ROHM AND HAAS RM-8W.
Above-mentioned pigment is one or more in Clariant 10G131-CN, Clariant FGR131-CN, Clariant RL131-CN, Clariant GG131-CN, Clariant N131-CN or the Du Pont's titanium dioxide 902.
Above-mentioned super-hydrophobic filler is one or more in super-hydrophobic calcium carbonate, talcum powder, mica powder or the wollastonite powder.
Above-mentioned hydrophobic lotions is DOW CORNING MEM-0349.
Above-mentioned film coalescence aid is TEXANOL ester alcohol-12.
Foregoing preservatives is one or more among promise moral Nordes C15 or the ROHM AND HAAS KATHON LXE.
The below provides specific embodiment and further specifies embodiment of the present invention.
Embodiment 1:
The first step prepares super-hydrophobic calcium carbonate:
At first in reactor, add 50 kilograms of ethanol, add again 10 kilograms in 400 order calcium carbonate, 20 kilograms in 800 order calcium carbonate, 20 kilograms in 1250 order calcium carbonate are configured to solids content and are 50% solution, join in the reactor, condensation is stirred, be warmed up to 60 ℃, add weight ratio and be 1% hydrophobic treatment agent 17 fluorine decyl Trimethoxy silanes, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate powders.
Second step prepares the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate:
At first with 50 kilograms of deionized waters, 1.1 kilograms of dispersion agents (BYK190), 1 kilogram of adding of defoamer (enlightening is high by 810) disperses to stir in the cylinder, then add 5 kilograms of pigment titanium whites (Du Pont 902), 20 kilograms of high speed dispersion of the homemade super-hydrophobic calcium carbonate of the first step 60 minutes, add pure-acrylic emulsion (ROHM AND HAAS AC～261P) 50 kilograms under the last stirring at low speed, 1 kilogram of sanitas (ROHM AND HAAS KATHON LXE), 2 kilograms of hydrophobic lotions (DOW CORNING MEM～0349), 4 kilograms of film coalescence aid (TEXANOL ester alcohol-12), thickening material ROHM AND HAAS TT93510 kilogram stirs discharging barrelling in 30 minutes.
Then long at the foamed cement warming plate is 450mm, and wide is 300mm, and thickness is the hydrophobic self-cleaning coating that is coated with 0.2mm all around of 30mm.
Embodiment 2:
The first step prepares super-hydrophobic calcium carbonate:
At first in reactor, add 70 kilograms of ethanol, add again 20 kilograms in 400 order calcium carbonate, 40 kilograms in 800 order calcium carbonate, 40 kilograms in 1250 order calcium carbonate are configured to solids content and are 58.8% solution, join in the reactor, condensation is stirred, be warmed up to 75 ℃, add weight ratio and be 1% hydrophobic treatment agent dodecyl triethoxyl silane, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate powders.
Second step prepares the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate:
At first with 60 kilograms of deionized waters, 3 kilograms of dispersion agents (the high 752W of enlightening), defoamer (BYK16602 kilogram and BYK1802 kilogram) adds and disperses to stir in the cylinder, then add pigment Clariant 10G131-CN10 kilogram, 30 kilograms of high speed dispersion of super-hydrophobic calcium carbonate of the first step preparation 90 minutes, add 40 kilograms of pure-acrylic emulsions (Bao Lijia BLJ-961) under the last stirring at low speed, 3 kilograms of sanitass (promise moral Nordes C15), 1 kilogram of hydrophobic lotions (DOW CORNING MEM～0349), 2 kilograms of film coalescence aid (TEXANOL ester alcohol-12), thickening material ROHM AND HAAS ASE-605 kilogram stirs discharging barrelling in 90 minutes.
Then long at the foamed cement warming plate is 450mm, and wide is 300mm, and thickness is the hydrophobic self-cleaning coating that is coated with 0.2mm all around of 30mm.
Embodiment 3:
The first step prepares super-hydrophobic calcium carbonate:
At first in reactor, add 85 kilograms of ethanol, add again 8 kilograms in 400 order calcium carbonate, 15 kilograms in 800 order calcium carbonate, 15 kilograms in 1250 order calcium carbonate are configured to solids content and are 30.8% solution, join in the reactor, condensation is stirred, be warmed up to 90 ℃, add weight ratio and be 1% hydrophobic treatment agent Union carbide A-162, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate powders.
Second step prepares the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate:
At first with 40 kilograms of deionized waters, 0.5 kilogram of dispersion agent (BYK180), 2 kilograms of addings of defoamer (DOW CORNING DC62) disperse to stir in the cylinder, then add pigment Clariant FGR131-CN1 kilogram, 40 kilograms of high speed dispersion of the homemade super-hydrophobic calcium carbonate of the first step 30 minutes, add 30 kilograms of pure-acrylic emulsions (Tao Shi R7030) under the last stirring at low speed, 2 kilograms of sanitass (ROHM AND HAAS KATHON LXE), 10 kilograms of hydrophobic lotions (DOW CORNING MEM～0349), 10 kilograms of film coalescence aid (TEXANOL ester alcohol-12), thickening material ROHM AND HAAS RM-8W5 part is stirred discharging barrelling in 60 minutes.
Then long at the foamed cement warming plate is 450mm, and wide is 300mm, and thickness is the hydrophobic self-cleaning coating that is coated with 0.2mm all around of 30mm.
Comparative Examples:
Long at the foamed cement warming plate is 450mm, and wide is 300mm, and thickness is the common exterior coating that is coated with 0.2mm all around of 30mm.
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative Examples |
| Water contact angle ° | 130 | 125 | 126 | 80 |
| Water-intake rate % | 0.2 | 0.5 | 0.4 | 3 |
Above content is the further description of the present invention being done in conjunction with concrete preferred implementation; can not assert that the specific embodiment of the present invention only limits to this; for the general technical staff of the technical field of the invention; without departing from the inventive concept of the premise; can also make some simple deduction or replace, all should be considered as belonging to the present invention and determine scope of patent protection by claims of submitting to.
Claims (10)
1. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate is characterized in that, comprises the raw material of following portions by weight:
2. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that, described pure-acrylic emulsion is one or more in ROHM AND HAAS AC-261P, Bao Lijia BLJ-961, Tao Shi R7030 or the national starch 2800.
3. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that, described dispersion agent is one or more among BYK190, BYK180, the high 752W of enlightening or the Nuo Puke dispersion agent SN5040.
4. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that, described defoamer is one or more in BYK1660, BYK023, DOW CORNING DC62, the enlightening high 810.
5. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that described thickening material is one or more among ROHM AND HAAS TT935, ROHM AND HAAS ASE-60, the ROHM AND HAAS RM-8W.
6. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1, it is characterized in that described pigment is one or more in Clariant 10G131-CN, Clariant FGR131-CN, Clariant RL131-CN, Clariant GG131-CN, Clariant N131-CN or the Du Pont's titanium dioxide 902.
7. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that, described super-hydrophobic filler is one or more in super-hydrophobic calcium carbonate, talcum powder, mica powder or the wollastonite powder.
8. the hydrophobic self-cleaning coating of used for building exterior wall foamed cement warming plate according to claim 1 is characterized in that described hydrophobic lotions is DOW CORNING MEM-0349;
Described film coalescence aid is TEXANOL ester alcohol-12;
Described sanitas is one or more among promise moral Nordes C15 or the ROHM AND HAAS KATHON LXE.
9. one kind based on the preparation method of used for building exterior wall foamed cement warming plate claimed in claim 1 with hydrophobic self-cleaning coating, it is characterized in that, may further comprise the steps:
The first step prepares super-hydrophobic filler:
Particle diameter is respectively 400 orders, 800 orders, 1250 purpose calcium carbonate, by weight for the 1:2:2 ratio joins in an amount of ethanol, be mixed with solids content and be 30%～60% solution, this solution is joined in the reactor, condensation is stirred, be warming up to 60 ℃～90 ℃, then add weight ratio and be 1% hydrophobic treatment agent, add again weight ratio and be 1% ammonia soln, stir after 2 hours, steam alcohol solvent, the oven dry of residue calcium carbonate solid, it is for subsequent use to get super-hydrophobic calcium carbonate;
Second step prepares hydrophobic self-cleaning coating:
In container, add first 40～60 parts of deionized waters, 0.5～3 part of dispersion agent, 1～4 part of defoamer, add again 1～10 part of pigment, 20～40 parts of super-hydrophobic fillers, high speed dispersion 30～90min, add 30～50 parts of pure-acrylic emulsions, 1～3 part of sanitas, 1～10 part of hydrophobic lotions, 2～10 parts of film coalescence aid, 5～10 parts of thickening materials under the last stirring at low speed, stir 30～90min, namely get hydrophobic self-cleaning coating.
10. used for building exterior wall foamed cement warming plate according to claim 9 is with the preparation method of hydrophobic self-cleaning coating, it is characterized in that described hydrophobic treatment agent is 17 fluorine decyl Trimethoxy silanes, Trimethlyfluorosilane, 17 silicon fluorides, dodecyl triethoxyl silane or Union carbide A-162.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103040311A CN103351768A (en) | 2013-07-18 | 2013-07-18 | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013103040311A CN103351768A (en) | 2013-07-18 | 2013-07-18 | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103351768A true CN103351768A (en) | 2013-10-16 |
Family
ID=49308187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013103040311A Pending CN103351768A (en) | 2013-07-18 | 2013-07-18 | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103351768A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031458A (en) * | 2013-12-24 | 2014-09-10 | 徐霖 | EPO foam model aqueous paint and preparation method thereof |
| CN104910779A (en) * | 2015-06-04 | 2015-09-16 | 西安交通大学 | Super-hydrophobic acrylic polyurethane coating and preparation method thereof |
| CN104962126A (en) * | 2015-06-09 | 2015-10-07 | 南宁市富诚家私有限责任公司 | Preparation method, application and use method of super-hydrophobic calcium carbonate coating assistant |
| CN105273603A (en) * | 2015-08-27 | 2016-01-27 | 浙江工商大学 | Building facade coating and preparation method thereof |
| CN107556841A (en) * | 2017-09-11 | 2018-01-09 | 深圳市嘉达高科产业发展有限公司 | Resistance patch and super-hydrophobic exterior coating and preparation method thereof |
| CN108643379A (en) * | 2018-04-27 | 2018-10-12 | 刘孟凡 | A kind of construction heat insulation wall structure |
| CN108795167A (en) * | 2018-07-04 | 2018-11-13 | 合肥帧讯低温科技有限公司 | A kind of wall coating for building |
| CN109825119A (en) * | 2017-11-23 | 2019-05-31 | 洛阳尖端技术研究院 | A kind of anti-flaming dope and its preparation method and application |
| CN109897485A (en) * | 2019-01-31 | 2019-06-18 | 苏州百联节能科技股份有限公司 | A kind of self-cleaning environmental protection coating material of novel heat-insulation |
| CN110358380A (en) * | 2019-04-24 | 2019-10-22 | 深圳市朗奥洁净科技股份有限公司 | Water paint |
| CN111663734A (en) * | 2020-06-15 | 2020-09-15 | 陈家珺 | Heat-insulating decorative plate based on polyurethane |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1355264A (en) * | 2001-12-13 | 2002-06-26 | 复旦大学 | Process for preparing self-cleaning bionic organic paint with lotus leaf function of external wall of building |
| CN1454948A (en) * | 2003-05-19 | 2003-11-12 | 复旦大学 | Superclean external wall organic coating for building and preparing method thereof |
| CN101974273A (en) * | 2010-10-09 | 2011-02-16 | 广州市枫源化工有限公司 | Exterior wall coating and preparation method thereof |
| CN102391749A (en) * | 2011-09-07 | 2012-03-28 | 雅士利涂料（苏州）有限公司 | Self-cleaning decontamination-type interior wall latex paint as well as preparation method and coating method thereof |
-
2013
- 2013-07-18 CN CN2013103040311A patent/CN103351768A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1355264A (en) * | 2001-12-13 | 2002-06-26 | 复旦大学 | Process for preparing self-cleaning bionic organic paint with lotus leaf function of external wall of building |
| CN1454948A (en) * | 2003-05-19 | 2003-11-12 | 复旦大学 | Superclean external wall organic coating for building and preparing method thereof |
| CN101974273A (en) * | 2010-10-09 | 2011-02-16 | 广州市枫源化工有限公司 | Exterior wall coating and preparation method thereof |
| CN102391749A (en) * | 2011-09-07 | 2012-03-28 | 雅士利涂料（苏州）有限公司 | Self-cleaning decontamination-type interior wall latex paint as well as preparation method and coating method thereof |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104031458A (en) * | 2013-12-24 | 2014-09-10 | 徐霖 | EPO foam model aqueous paint and preparation method thereof |
| CN104910779A (en) * | 2015-06-04 | 2015-09-16 | 西安交通大学 | Super-hydrophobic acrylic polyurethane coating and preparation method thereof |
| CN104962126A (en) * | 2015-06-09 | 2015-10-07 | 南宁市富诚家私有限责任公司 | Preparation method, application and use method of super-hydrophobic calcium carbonate coating assistant |
| CN105273603A (en) * | 2015-08-27 | 2016-01-27 | 浙江工商大学 | Building facade coating and preparation method thereof |
| CN105273603B (en) * | 2015-08-27 | 2018-02-09 | 浙江工商大学 | A kind of facade coating and preparation method thereof |
| CN107556841A (en) * | 2017-09-11 | 2018-01-09 | 深圳市嘉达高科产业发展有限公司 | Resistance patch and super-hydrophobic exterior coating and preparation method thereof |
| CN109825119A (en) * | 2017-11-23 | 2019-05-31 | 洛阳尖端技术研究院 | A kind of anti-flaming dope and its preparation method and application |
| CN108643379A (en) * | 2018-04-27 | 2018-10-12 | 刘孟凡 | A kind of construction heat insulation wall structure |
| CN108795167A (en) * | 2018-07-04 | 2018-11-13 | 合肥帧讯低温科技有限公司 | A kind of wall coating for building |
| CN109897485A (en) * | 2019-01-31 | 2019-06-18 | 苏州百联节能科技股份有限公司 | A kind of self-cleaning environmental protection coating material of novel heat-insulation |
| CN110358380A (en) * | 2019-04-24 | 2019-10-22 | 深圳市朗奥洁净科技股份有限公司 | Water paint |
| CN111663734A (en) * | 2020-06-15 | 2020-09-15 | 陈家珺 | Heat-insulating decorative plate based on polyurethane |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103351768A (en) | Hydrophobic self-cleaning coating for foam cement insulation board for exterior wall and preparation method thereof | |
| CN105086823B (en) | Room temperature silicone curing and anticorrosive coating | |
| CN105713481B (en) | A kind of graphene modified epoxy zinc rich primer and preparation method thereof | |
| CN108165151B (en) | Water-based fluorocarbon modified acrylic polyurethane finish paint and preparation method thereof | |
| CN105368236A (en) | Waterproof coating and preparation method and application thereof, and asphalt waterproof coiled material | |
| CN105238239B (en) | Mono-component organic silicone alkane modified polyether coating and preparation method thereof | |
| CN103911030A (en) | Preparation method of aerogel thermal-insulating coating | |
| CN101831221A (en) | Aqueous fluorocarbon coating and preparation process thereof | |
| CN103602220B (en) | A kind of Siloxane hybrid anticorrosive paint | |
| CN103881496B (en) | A kind of concrete transparent protecting coating | |
| CN107083185A (en) | A kind of aluminum alloy doors and windows heat-insulated protective coating and preparation method thereof | |
| CN107603358A (en) | A kind of preparation method of the fluorine carbon anticorrosive paint of composite graphite alkene | |
| CN102391736A (en) | Self-cleaning coating used for building curtain wall aluminum veneer and preparation method thereof | |
| CN106147442B (en) | Thermal insulation coatings and preparation method thereof and heat insulation coating | |
| CN104312225A (en) | High-flexibility and high-glossiness inorganic coating and preparation method | |
| CN106280897A (en) | A kind of insulation thermal reflection-type epoxy coating | |
| CN103131290B (en) | Water-based metal baking paint and preparation method thereof | |
| CN104356790B (en) | Corrosion-resistant absorbing coating of solar energy and preparation method thereof | |
| CN105238123A (en) | Flexible epoxy putty and preparation method thereof | |
| CN102618138B (en) | Room-temperature type power insulator anti-fouling flashover paint, preparation method thereof and power insulator | |
| CN104087092A (en) | Preparation method for aqueous low-solar-absorptance antistatic coating | |
| CN104559592A (en) | Fluorocarbon elastic paint and preparation method thereof | |
| CN103013335B (en) | Aqueous reaction type rubber asphalt waterproof paint and production method thereof | |
| CN105802447B (en) | A kind of aftergrowth oil modified solvent free self-leveling coating and preparation method thereof | |
| CN107793875A (en) | A kind of corrosion resistant heat-absorbing paint of solar energy and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20131016 |