CN110358380A - Water paint - Google Patents
Water paint Download PDFInfo
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- CN110358380A CN110358380A CN201910331361.7A CN201910331361A CN110358380A CN 110358380 A CN110358380 A CN 110358380A CN 201910331361 A CN201910331361 A CN 201910331361A CN 110358380 A CN110358380 A CN 110358380A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2265—Oxides; Hydroxides of metals of iron
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of water paints, comprise the following components in parts by weight: 30~80 parts of polyacrylic resin lotion；10~70 parts of filler；20~200 parts of silicone resin emulsion；0.01~5 part of auxiliary agent；The silicone resin emulsion includes silane, emulsifier and water.Water paint provided by the invention, hardness >=HB, adhesive force grade are 1 or 0, and foam time is obviously reduced, while water absorption rate is obviously reduced, and water contact angle increases, and heat resistance is accordingly increased, and properties are promoted obvious.
Description
Technical field
The present invention relates to constructional ornamental material technical fields, specifically, being related to a kind of water paint.
Background technique
Color steel plate has the characteristics that light-weight, intensity is high, flexible for installation quick, is widely used in large public building, public affairs
The metope and roofing of workshop, movable plank house and integrated house altogether.
It in color steel plate manufacturing process, needs to coat water paint on the surface of color steel plate, protection dress is carried out to color steel plate
Decorations, avoid color steel plate from exposing to the sun and rain and too fast influence service life.The property such as present water paint defoaming, levelability and adhesive force
Can be all not ideal enough, cause water paint limited to the protection of color steel plate.
Summary of the invention
The purpose of the present invention is to provide a kind of water paints, and adhesive force is strong, while defoaming and flow leveling are strong.
Technical solution used by water paint disclosed by the invention is:
A kind of water paint, comprises the following components in parts by weight:
30~80 parts of polyacrylic resin lotion；
10~70 parts of filler；
20~200 parts of silicone resin emulsion；
0.01~5 part of auxiliary agent；
The silicone resin emulsion includes silane and emulsifier.
Preferably, water paint comprises the following components in parts by weight:
30~40 parts of polyacrylic resin lotion；
10~22 parts of filler；
50~100 parts of silicone resin emulsion；
0.31~0.41 part of auxiliary agent.
Preferably, the silane is methyltriethoxysilane, propyl trimethoxy silicane and octyl trimethoxy
One of base silane is a variety of.
Preferably, the silicone resin emulsion further includes PH regulator and water, the silicone resin emulsion
The parts by weight of each component are as follows:
0.1~5 part of emulsifier；
35~45 parts of water；
15~30 parts of silane.
Preferably, the parts by weight of the silicone resin emulsion each component are as follows:
0.83~4.13 part of emulsifier；
35~43 parts of water；
19~27 parts of silane.
Preferably, the emulsifier is octyl phenol polyoxyethylene ether (OP-10), sorbitan tristearate
(SPAN-60) and one of neopelex or a variety of.
Preferably, the filler is one of titanium dioxide, precipitated calcium carbonate and fumed silica or more
Kind.
Preferably, the auxiliary agent includes thickener, preservative and drier.
Preferably, the thickener is ROHM AND HAAS TT935, and the preservative is Tao Shi rocima520s, institute
Stating drier is dibutyl tin dilaurate.
Preferably, the polyacrylic resin lotion is Ahmedabad richness RS-2205.
The beneficial effect of water paint disclosed by the invention is: the poorly water-soluble of organosilicon itself is added directly into poly- third
It is only capable of being added in olefin(e) acid resin emulsion on a small quantity, amount is difficult to stable dispersion and is layered greatly, and coating is caused to be scrapped.Pass through silane elder generation
Silicone resin emulsion is made through emulsion polymerization with emulsifier, enhances the stability that silane disperses in water, keeps organosilicon newborn
Liquid can be mixed with acrylic acid arbitrary proportion, and the increase of organosilicon composition content increases active functional group content, can shape after solidification
At interpenetrating network, silane and polyacrylate generate synergistic effect, improve the performance of coating, promote the adhesive force of coating.
Meanwhile organosilicon composition can reduce the surface energy of system, improve levelling and the defoaming effect of coating.
Specific embodiment
Present invention is further elaborated in following combination specific embodiment and explanation:
Silicone resin emulsion is made using emulsion polymerization, is first mixed using emulsifier with water, then passes through PH tune
Agent is saved by the pH value adjustment of mixed liquor to 8~9；Mixed liquor is heated to 30~50 DEG C, then silane mixture is dripped in 30min
It is added in mixed liquor, then stirs 60~90min at such a temperature, silicone resin emulsion is made.
Wherein emulsifier is one in octyl phenol polyoxyethylene ether, sorbitan tristearate and neopelex
Kind is a variety of.Silane be one of methyltriethoxysilane, propyl trimethoxy silicane and octyl trimethoxy silane or
It is a variety of.PH regulator is Na2CO3.Silicone resin emulsion proportion as different such as table 1 is made:
1 silicone resin emulsion of table proportion
Embodiment 1
A kind of water paint, comprises the following components in parts by weight: 30 parts of polyacrylic resin lotion, 8 parts of titanium dioxide and
The filler that 2 parts of precipitated calcium carbonate, 0.1 part of thickener, 0.2 part of preservative and 0.01 part of drier of auxiliary agent, organic siliconresin cream
A50 parts of liquid.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, and drier is two fourth of dilaurate
Ji Xi, polyacrylic resin lotion are Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, machine resin emulsion A and auxiliary agent are placed in stirring dress
In the container set, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 2
A kind of water paint, comprises the following components in parts by weight: 30 parts of polyacrylic resin lotion, 8 parts of titanium dioxide and
The filler that 2 parts of precipitated calcium carbonate, 0.1 part of thickener, 0.2 part of preservative and 0.01 part of drier of auxiliary agent, organic siliconresin cream
B20 parts of liquid.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, and drier is two fourth of dilaurate
Ji Xi, polyacrylic resin lotion are Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, machine resin emulsion B and auxiliary agent are placed in stirring dress
In the container set, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 3
A kind of water paint, comprises the following components in parts by weight: 30 parts of polyacrylic resin lotion, 8 parts of titanium dioxide and
The filler that 2 parts of precipitated calcium carbonate, 0.1 part of thickener, 0.2 part of preservative and 0.01 part of drier of auxiliary agent, organic siliconresin cream
C100 parts of liquid.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, and drier is dilaurate two
Butyl tin, polyacrylic resin lotion are Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, machine resin emulsion C and auxiliary agent are placed in stirring dress
In the container set, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 4
A kind of water paint, comprises the following components in parts by weight: 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide,
10 parts of precipitated calcium carbonate and 2 parts of fumed silica of filler, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier
Auxiliary agent, B20 parts of silicone resin emulsion.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, is urged
Dry agent is dibutyl tin dilaurate, and polyacrylic resin lotion is Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, silicone resin emulsion B and auxiliary agent are placed in stirring
In the container of device, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 5
A kind of water paint, comprises the following components in parts by weight: 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide,
10 parts of precipitated calcium carbonate and 2 parts of fumed silica of filler, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier
Auxiliary agent, C100 parts of silicone resin emulsion.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, is urged
Dry agent is dibutyl tin dilaurate, and polyacrylic resin lotion is Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, silicone resin emulsion C and auxiliary agent are placed in stirring
In the container of device, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 6
A kind of water paint, comprises the following components in parts by weight: 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide,
10 parts of precipitated calcium carbonate and 2 parts of fumed silica of filler, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier
Auxiliary agent, D200 parts of silicone resin emulsion.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, is urged
Dry agent is dibutyl tin dilaurate, and polyacrylic resin lotion is Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, silicone resin emulsion D and auxiliary agent are placed in stirring
In the container of device, carries out mechanical stirring 1 hour, obtain water paint.
Embodiment 7
A kind of water paint, comprises the following components in parts by weight: 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide,
10 parts of precipitated calcium carbonate and 2 parts of fumed silica of filler, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier
Auxiliary agent, E80 parts of silicone resin emulsion.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, is urged
Dry agent is dibutyl tin dilaurate, and polyacrylic resin lotion is Ahmedabad richness RS-2205.
The polyacrylic resin lotion of corresponding parts by weight, filler, silicone resin emulsion E and auxiliary agent are placed in stirring
In the container of device, carries out mechanical stirring 1 hour, obtain water paint.
Comparative example 1
A kind of water paint, comprises the following components in parts by weight: 30 parts of polyacrylic resin lotion, 8 parts of titanium dioxide and
The filler that 2 parts of precipitated calcium carbonate, 0.1 part of thickener, 0.2 part of preservative and 0.01 part of drier of auxiliary agent.Wherein thickener is
ROHM AND HAAS TT935, preservative are Tao Shi rocima520s, and drier is dibutyl tin dilaurate, polyacrylic resin cream
Liquid is Ahmedabad richness RS-2205.
Polyacrylic resin lotion, filler and the auxiliary agent of corresponding parts by weight are placed in the container with agitating device, into
Row mechanical stirring 1 hour, obtain water paint.
Comparative example 2
A kind of water paint, comprises the following components in parts by weight: 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide,
10 parts of precipitated calcium carbonate and 2 parts of fumed silica of filler, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier
Auxiliary agent.Wherein thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, and drier is dilaurate dibutyl
Tin, polyacrylic resin lotion are Ahmedabad richness RS-2205.
Polyacrylic resin lotion, filler and the auxiliary agent of corresponding parts by weight are placed in the container with agitating device, into
Row mechanical stirring 1 hour, obtain water paint.
1-7 of the embodiment of the present invention and comparative example 1-2 water paint prepared is tested for the property, wherein steel
Plate adhesive force uses substrate for Baosteel TDC51D+Z heat zinc coating plate, as a result see the table below 2.
The performance of 2 1-7 of the embodiment of the present invention of table and comparative example 1-2 water paint
| Stability | Adhesive force | Foam time | Water absorption rate | Water contact angle | Thermal decomposition temperature | Hardness | |
| Embodiment 1 | 12 months | 1 | 20 seconds | 5% | 95° | 323~400 DEG C | HB |
| Embodiment 2 | 12 months | 1 | 25 seconds | 8% | 92° | 320~400 DEG C | HB |
| Embodiment 3 | 12 months | 1 | 20 seconds | 4% | 97° | 325~400 DEG C | H |
| Embodiment 4 | 12 months | 1 | 25 seconds | 8% | 92° | 320~400 DEG C | H |
| Embodiment 5 | 12 months | 1 | 20 seconds | 4% | 97° | 325~400 DEG C | H |
| Embodiment 6 | 12 months | 0 | 20 seconds | 3% | 110° | 329~400 DEG C | 2H |
| Embodiment 7 | 12 months | 0 | 20 seconds | 5% | 97° | 323~400 DEG C | H |
| Comparative example 1 | 12 months | 2 | 120 seconds | 13% | 78° | 300~400 DEG C | B |
| Comparative example 2 | 12 months | 2 | 120 seconds | 15% | 80° | 300~400 DEG C | HB |
As shown in Table 2, the water paint that 1-7 of the embodiment of the present invention is obtained, hardness >=HB, adhesive force grade are 1 or 0, are disappeared
The bubble time significantly reduces, while water absorption rate significantly reduces, and water contact angle increases, and properties are promoted obvious.Wherein, embodiment 6
For preferred embodiment, 40 parts of polyacrylic resin lotion, 10 parts of titanium dioxide, 10 parts of precipitated calcium carbonate and fumed silica 2
The filler of part, 0.1 part of thickener, 0.3 part of preservative and 0.01 part of drier of auxiliary agent, D200 parts of silicone resin emulsion.Its
Middle thickener is ROHM AND HAAS TT935, and preservative is Tao Shi rocima520s, and drier is dibutyl tin dilaurate, poly- third
Olefin(e) acid resin emulsion is Ahmedabad richness RS-2205, and adhesive force is 0 grade, and foam time was 20 seconds, than existing foam time 120 seconds
100 second time is shortened, while water absorption rate only has 3%, there is very strong hydrophobicity, and water contact angle reaches 110 °, hardness reaches
It is 2H to grade, performance indexes is all promoted obviously.
In above scheme, the poorly water-soluble of organosilicon itself is added directly into polyacrylic resin lotion and is only capable of being added
On a small quantity, amount is difficult to stable dispersion and generates layering greatly, and coating is caused to be scrapped.Organosilicon first is mixed to prepare with emulsifier by silane
Resin emulsion, active functional group content increase, and raising when adhesive force is relatively not added with resin emulsion after solidifying system enhances
The stability of dispersion in the water of silane enables organic silicon emulsion to mix with acrylic acid arbitrary proportion, enhances silane in water
Dispersion stability, so that organic silicon emulsion is mixed with acrylic acid arbitrary proportion, inierpeneirating network structure, silicon can be formed after solidification
Alkane and polyacrylate generate synergistic effect, improve the performance of coating, promote the adhesive force of coating.The addition of organosilicon composition is dropped
The surface of low system can, levelling and the defoaming effect of coating are improved, after paint solidification, with silicone resin emulsion additional amount
Increase, system solidifies front surface and can reduce with the increase of organosilicon additional amount, and foam time shortens；Meanwhile with silicone resin cream
The increase of liquid additional amount, system silicone content increase, and the inierpeneirating network structure that system is formed after solidifying is more fine and close, makes the resistance to height of system
Warm nature can improve, and water contact angle increases, and water absorption rate reduces, and thermal decomposition temperature increases, and hardness increases.
Finally it should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention, rather than the present invention is protected
The limitation of range is protected, although explaining in detail referring to preferred embodiment to the present invention, those skilled in the art are answered
Work as understanding, it can be with modification or equivalent replacement of the technical solution of the present invention are made, without departing from the reality of technical solution of the present invention
Matter and range.
Claims (10)
1. a kind of water paint, which is characterized in that comprise the following components in parts by weight:
30~80 parts of polyacrylic resin lotion；
10~70 parts of filler；
20~200 parts of silicone resin emulsion；
0.01~5 part of auxiliary agent；
The silicone resin emulsion includes silane and emulsifier.
2. water paint as described in claim 1, which is characterized in that comprise the following components in parts by weight:
30~40 parts of polyacrylic resin lotion；
10~22 parts of filler；
50~100 parts of silicone resin emulsion；
0.31~0.41 part of auxiliary agent.
3. water paint as described in claim 1, which is characterized in that the silane is methyltriethoxysilane, propyl three
One of methoxy silane and octyl trimethoxy silane are a variety of.
4. water paint as claimed in claim 3, which is characterized in that the silicone resin emulsion further include PH regulator and
Water, the parts by weight of the silicone resin emulsion each component are as follows:
0.1~5 part of emulsifier；
35~45 parts of water；
15~30 parts of silane.
5. water paint as claimed in claim 4, which is characterized in that the parts by weight of the silicone resin emulsion each component
Are as follows:
0.83~4.13 part of emulsifier；
35~43 parts of water；
19~27 parts of silane.
6. water paint as claimed in claim 4, which is characterized in that the emulsifier is octyl phenol polyoxyethylene ether (OP-
10), one of sorbitan tristearate (SPAN-60) and neopelex or a variety of.
7. water paint as claimed in any one of claims 1 to 6, which is characterized in that the filler is titanium dioxide, lightweight carbon
One of sour calcium and fumed silica are a variety of.
8. water paint as claimed in any one of claims 1 to 6, which is characterized in that the auxiliary agent includes thickener, preservative
And drier.
9. water paint as claimed in claim 8, which is characterized in that the thickener is ROHM AND HAAS TT935, the anti-corrosion
Agent is Tao Shi rocima520s, and the drier is dibutyl tin dilaurate.
10. water paint as claimed in any one of claims 1 to 6, which is characterized in that the polyacrylic resin lotion is bar
Moral richness RS-2205.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910331361.7A CN110358380A (en) | 2019-04-24 | 2019-04-24 | Water paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910331361.7A CN110358380A (en) | 2019-04-24 | 2019-04-24 | Water paint |
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| CN110358380A true CN110358380A (en) | 2019-10-22 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114702899A (en) * | 2022-03-24 | 2022-07-05 | 上海宜瓷龙新材料股份有限公司 | Water-based one-component baking type polysiloxane coating and preparation method thereof |
| CN115093759A (en) * | 2022-07-15 | 2022-09-23 | 福建升大涂料有限公司 | Water-based wood paint and preparation method and use method thereof |
| CN115109473A (en) * | 2022-08-17 | 2022-09-27 | 青岛天成卓越新型建材有限公司 | Silane resin adhesive waterproof coating |
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Application publication date: 20191022 |