CN105462411A - Finish-coat paint for real stone paint and preparation method of finish-coat paint - Google Patents
Finish-coat paint for real stone paint and preparation method of finish-coat paint Download PDFInfo
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- CN105462411A CN105462411A CN201510961095.8A CN201510961095A CN105462411A CN 105462411 A CN105462411 A CN 105462411A CN 201510961095 A CN201510961095 A CN 201510961095A CN 105462411 A CN105462411 A CN 105462411A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to finish-coat paint for real stone paint, wherein the finish-coat paint is prepared from the following components in parts by weight: water, a germicidal and anti-corrosion agent, bentonite, an aqueous solution of 2-amino-2-methyl-1-propanol with mass concentration of 90-95%, a defoamer, a dispersant, a wetting agent, a lotus leaf hydrophobing agent, lotus-leaf-effect organosilicone hydrophobic emulsion, a coalescing agent, a cosolvent, the defoamer, a thickening agent and a rheological auxiliary. The finish-coat paint for the real stone paint overcomes the defects that the existing finish-coat paint for the real stone paint is poor in stain resisting effect and is free from self-cleaning ability, and has the advantages that excellent hydrophobicity, excellent stain resistance and a photocatalystic self-cleaning function are achieved, and the service life of the real stone paint can be prolonged.
Description
Technical field
The present invention relates to the preparation method of a kind of true mineral varnish finishing paint and preparation method thereof, be applied in architectural decoration paint field.
Background technology
True mineral varnish due to coating surface density poor, mechanical hole is large, and coating is easily stain, and pollutent easily infiltrates paint film inside, is difficult to be removed by secondary cleaning.The existing multiplex benzene emulsion of true mineral varnish is as film forming matter in addition, and paint film weatherability is poor, easy xanthochromia efflorescence after uviolizing.In order to improve the ageing resistance of true mineral varnish, generally all need to adopt finishing paint to carry out cover.Existing true mineral varnish finishing paint stain resistant poor effect, does not have self-cleaning ability yet.Therefore a kind of hydrophobicity of having had and catalytic self-cleaning function are provided, true mineral varnish finishing paint that contamination resistance is good and preparation method thereof oneself become when business urgently.
Summary of the invention
The invention provides a kind of true mineral varnish finishing paint and preparation method thereof, which overcome existing true mineral varnish finishing paint stain resistant poor effect, not there is the shortcoming of self-cleaning ability yet, there is hydrophobicity, contaminated resistance is good, and there is catalytic self-cleaning function, the advantage in true mineral varnish work-ing life can be improved.
Technical scheme of the present invention is as follows:
A kind of true mineral varnish finishing paint, it comprises the component of following weight ratio:
The water repellency that finishing paint requires, reduce wetting ability and reduce water suction, lotus leaf effect organic silicon hydrophobic emulsion energy natural imitation circle " lotus leaf " surface effect, the true mineral varnish finishing paint of the application passes through the collocation of lotus leaf effect organic silicon hydrophobic emulsion and lotus leaf hydrophobizing agent, improve finishing paint paint film contact angle, wherein there is multiple cross-linked chemical reaction between Si-OH and with-the OH-on base material when drying and forming-film, coating can be made to have extremely low surface tension, there is good hydrophobic effect and contamination resistance.Wherein, water can adopt common tap water or other clean water, its as dispersion emulsion, aggregate and various auxiliary agent dispersion, play adjusting viscosity, reduce costs, strengthen application property.Mass concentration is that the aqueous solution of the 2-amino-2-methyl-1-propanol of 90-95% is mainly used for regulating potential of hydrogen, has the effect of thickening, dispersion and stabilising system.
This true mineral varnish finishing paint also comprises the nano-TiO of 2.0-2.5 weight part
2the nano-ZnO slurry of colloidal sol and 2.0-3.0 weight part.
Nano-TiO
2colloidal sol is arranged in nano-TiO along with moisture evaporation migrates to coating surface in drying varniss process
2layer, generation free radical under the exciting of visible ray, the macromole organic pollutant on oxygenolysis paint film, reaches the object of clean coating, effectively raises the contaminated resistance of paint film.Nano-ZnO slurry has good shielding effect to ultraviolet, can assist nano-TiO
2colloidal sol improves paint film weatherability and work-ing life, effectively can suppress and kill the harmful pathogenic bacteria in environment simultaneously, protection paint film, and in reduction environment, microorganism is to the harm of human body.
Nano-TiO
2colloidal sol and nano-ZnO are starched and lotus leaf effect organic silicon hydrophobic emulsion and the acting in conjunction of lotus leaf hydrophobizing agent, as the finishing paint that true mineral varnish is supporting, the hydrophobicity had and catalytic self-cleaning function, true mineral varnish coating contamination resistance can be improved, gloss of film can also be reduced, minimizing is grown dim, and improves weathering resistance, thus extends true mineral varnish work-ing life.
This true mineral varnish finishing paint also comprises the mute powder of amorphous silica class of 2.0-3.0 weight part.
Add the mute powder of amorphous silica class and reduce finishing paint gloss, reduce true mineral varnish aberration phenomenon and the film that causes because of high gloss is uneven grows dim and light soil vestige.
This true mineral varnish finishing paint is formulated by the component of following weight ratio:
Described lotus leaf hydrophobizing agent is the Ion in Nonionic Microemulsion of ultra-high molecular weight polysiloxane and surfactant compound, improves paint film hydrophobic permeable type, improves paint film stain resistant, improve gloss retention; Described lotus leaf effect organic silicon hydrophobic emulsion is the organic siloxane modified acrylate copolymer emulsion having 120-150 ° of contact angle with glassware for drinking water, for film provides hydrophobic " lotus leaf effect ", reduces film water-absorbent, improves weathering resistance and work-ing life; Described auxiliary rheological agents is nonionic polyurethane rheology modifier or association type alkali swollen thickener, as a kind of synergistic thickening agent, improves flowing and levelling property; Described fungicidal preservative is the stable Kathon CG series bactericidal agent of divalent metal salt, has sterilization and anticorrosion effect in tank, improves stability in storage; Described wilkinite is natural montmorillonite or artificial modification's wilkinite, is used for improving stability in storage and application property; Described defoamer is the one in oil-based defoamer, silicone antifoam agent or emulsion type defoaming agent, plays froth breaking and press down bubble effect in formula system; Described dispersion agent is sodium polyacrylate dipersant or ammonium polyacrylate dipersant, provides the stable dispersion of color stuffing; Described film coalescence aid is alcohol ester 12, plays the plastic flow and elastic deformation that promote latex particle, reduces the minimum film-forming temperature of emulsion, improves the effect of paint film property; Described solubility promoter is propylene glycol, effectively can extend the open hour, improves low tempertaure storage stability; Described thickening material is hydrophobically-modified alkali swollen thickener.
Select the hydrophobically modified acrylate thickening agent of water-tolerant and nonionic polyurethane rheology modifier can improve coating storage characteristics and application property, strengthen water tolerance.
Described hydrophobically-modified alkali swollen thickener is association type acrylate copolymer thickening material, improves paint film storage characteristics and application property.
Described nano-TiO
2colloidal sol is the high dispersing Nano titanium dioxide of surface through the process of hydrogen-oxygen group, has shielding and absorbs the effects such as ultraviolet, photo-catalyst, decomposing organic pollutant; Described nano-ZnO slurry is the dispersion of nano zine oxide in water, plays the effect of sterilization and anticorrosion, shielding ultraviolet rays.
The preparation method of this true mineral varnish finishing paint comprises the step that next coming in order carry out:
(1) under 500-750r/min rotating speed stirs, in water, fungicidal preservative, wilkinite is sequentially added, stir 3-5min, continue to add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 90-95% while stirring, add rear raising rotating speed to 800-1000r/min, stir 5-10min;
(2) add defoamer, dispersion agent, wetting agent, lotus leaf hydrophobizing agent successively in the mixture made to step (1) under 500-750r/min rotating speed stirs, add rear raising rotating speed to 800-1000r/min, stir 5-10min;
(3) lotus leaf effect organic silicon hydrophobic emulsion, film coalescence aid, solubility promoter, defoamer, thickening material, auxiliary rheological agents is added successively in the mixture made to step (2) under 750-1000r/min rotating speed stirs, add rear Keep agitation 10-15min, namely obtain true mineral varnish finishing paint.
Also need sequentially to add nano-TiO in its step (2) after adding wetting agent with before adding lotus leaf hydrophobizing agent
2colloidal sol and nano-ZnO slurry.
Also need to add the mute powder of amorphous silica class in its step (2) after adding nano-ZnO slurry with before adding lotus leaf hydrophobizing agent.
The preparation technology of this true mineral varnish finishing paint is simple, is suitable for industrialization.
Compared with prior art, the present patent application has the following advantages:
1) good hydrophobicity and catalytic self-cleaning function, improve true mineral varnish coating contamination resistance, improves weathering resistance and true mineral varnish work-ing life;
2) reduce gloss of film, minimizing is grown dim;
3) preparation technology is simple, is suitable for industrialization.
Embodiment
Below in conjunction with each embodiment, technical scheme of the present invention is described in detail.
Raw material sources:
Embodiment 1
A kind of true mineral varnish finishing paint, it is formulated by the component of following weight ratio:
This true mineral varnish finishing paint, it comprises the step that next coming in order carry out:
(1) under 650r/min rotating speed stirs, in water, divalent metal salt stable Kathon CG series bactericidal agent, natural montmorillonite is sequentially added, stir 4min, continue to add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 95% while stirring, add rear raising rotating speed to 900r/min, stir 8min;
(2) Ion in Nonionic Microemulsion of defoamer, sodium polyacrylate dipersant, wetting agent, the surperficial high dispersing Nano titanium dioxide through the process of hydrogen-oxygen group in face, the dispersion of nano zine oxide in water, the mute powder of amorphous silica class, ultra-high molecular weight polysiloxane and surfactant compound is added in the mixture made to step (1) under 700r/min rotating speed stirs successively, add rear raising rotating speed to 900r/min, stir 8min;
(3) the organic siloxane modified acrylate copolymer emulsion, alcohol ester 12, propylene glycol, oil-based defoamer, association type acrylate copolymer thickening material, the association type alkali swollen thickener that have 150 ° of contact angles with glassware for drinking water is added successively in the mixture made to step (2) under 900r/min rotating speed stirs, add rear Keep agitation 12min, namely obtain true mineral varnish finishing paint.
Embodiment 2
A kind of true mineral varnish finishing paint, it is formulated by the component of following weight ratio:
This true mineral varnish finishing paint, it comprises the step that next coming in order carry out:
(1) under 500r/min rotating speed stirs, in water, fungicidal preservative, artificial modification's wilkinite is sequentially added, stir 5min, continue to add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 90% while stirring, add rear raising rotating speed to 800r/min, stir 10min;
(2) silicone antifoam agent, ammonium polyacrylate dipersant, wetting agent, nano-TiO is added successively in the mixture made to step (1) under 500r/min rotating speed stirs
2colloidal sol, nano-ZnO slurry, the mute powder of amorphous silica class, lotus leaf hydrophobizing agent, add rear raising rotating speed to 1000r/min, stirs 5-10min;
(3) the organic siloxane modified acrylate copolymer emulsion, film coalescence aid, solubility promoter, defoamer, hydrophobically-modified alkali swollen thickener, the nonionic polyurethane rheology modifier that have 120 ° of contact angles with glassware for drinking water is added successively in the mixture made to step (2) under 750r/min rotating speed stirs, add rear Keep agitation 15min, namely obtain true mineral varnish finishing paint.
Embodiment 3
A kind of true mineral varnish finishing paint, it is formulated by the component of following weight ratio:
This true mineral varnish finishing paint, it comprises the step that next coming in order carry out:
(1) under 750r/min rotating speed stirs, in water, fungicidal preservative, wilkinite is sequentially added, stir 3min, continue to add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 92% while stirring, add rear raising rotating speed to 1000r/min, stir 5min;
(2) add emulsion type defoaming agent, dispersion agent, wetting agent, lotus leaf hydrophobizing agent successively in the mixture made to step (1) under 750r/min rotating speed stirs, add rear raising rotating speed to 800r/min, stir 10min;
(3) the organic siloxane modified acrylate copolymer emulsion, film coalescence aid, solubility promoter, defoamer, thickening material, the auxiliary rheological agents that have 130 ° of contact angles with glassware for drinking water is added successively in the mixture made to step (2) under 1000r/min rotating speed stirs, add rear Keep agitation 10min, namely obtain true mineral varnish finishing paint.
Embodiment 4
The difference of itself and embodiment 1 is: it is formulated by the component of following weight ratio:
Embodiment 5
The difference of itself and embodiment 2 is: it is formulated by the component of following weight ratio:
Embodiment 6
The difference of itself and embodiment 3 is: it is formulated by the component of following weight ratio:
Experimental data
Described standard is: JG/T24-2000 " SAND SLURRY SYNTHETIC EMULSION ARCHITECTURAL COATINGS " W type, GB/T9755-2014 " exterior wall coating material of synthetic resin emulsion " finish paint premium grads and HG/T3950-2007 " antibiotic paint " I type.
As seen from the above table, the true mineral varnish finishing paint of each embodiment there is good water-fast resistant, anti-aging, water permeability is good, has excellent in sterilization cleaning capacity.Wherein, embodiment 1 is most preferred embodiment, best from sterilization cleaning capacity.
True mineral varnish finishing paint of the present invention and preparation method thereof has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (10)
1. a true mineral varnish finishing paint, is characterized in that: it comprises the component of following weight ratio,
2. true mineral varnish finishing paint according to claim 1, is characterized in that: it also comprises the nano-TiO of 2.0-2.5 weight part
2the nano-ZnO slurry of colloidal sol and 2.0-3.0 weight part.
3. true mineral varnish finishing paint according to claim 2, is characterized in that: it also comprises the mute powder of amorphous silica class of 2.0-3.0 weight part.
4. true mineral varnish finishing paint according to claim 3, is characterized in that: it is formulated by the component of following weight ratio,
5. true mineral varnish finishing paint according to claim 1, it is characterized in that: described lotus leaf hydrophobizing agent is the Ion in Nonionic Microemulsion of ultra-high molecular weight polysiloxane and surfactant compound, described lotus leaf effect organic silicon hydrophobic emulsion is the organic siloxane modified acrylate copolymer emulsion having 120-150 ° of contact angle with glassware for drinking water, described auxiliary rheological agents is nonionic polyurethane rheology modifier or association type alkali swollen thickener, described fungicidal preservative is the stable Kathon CG series bactericidal agent of divalent metal salt, described wilkinite is natural montmorillonite or artificial modification's wilkinite, described defoamer is oil-based defoamer, one in silicone antifoam agent or emulsion type defoaming agent, described dispersion agent is sodium polyacrylate dipersant or ammonium polyacrylate dipersant, described film coalescence aid is alcohol ester 12, described solubility promoter is propylene glycol, described thickening material is hydrophobically-modified alkali swollen thickener.
6. true mineral varnish finishing paint according to claim 5, is characterized in that: described hydrophobically-modified alkali swollen thickener is association type acrylate copolymer thickening material.
7. true mineral varnish finishing paint according to claim 2, is characterized in that: described nano-TiO
2colloidal sol is the high dispersing Nano titanium dioxide of surface through the process of hydrogen-oxygen group, and described nano-ZnO slurry is the dispersion of nano zine oxide in water.
8. the preparation method of the true mineral varnish finishing paint according to any one of claim 1-7, is characterized in that: it comprises the step that next coming in order carry out,
(1) under 500-750r/min rotating speed stirs, in water, fungicidal preservative, wilkinite is sequentially added, stir 3-5min, continue to add the aqueous solution that mass concentration is the 2-amino-2-methyl-1-propanol of 90-95% while stirring, add rear raising rotating speed to 800-1000r/min, stir 5-10min;
(2) add defoamer, dispersion agent, wetting agent, lotus leaf hydrophobizing agent successively in the mixture made to step (1) under 500-750r/min rotating speed stirs, add rear raising rotating speed to 800-1000r/min, stir 5-10min;
(3) lotus leaf effect organic silicon hydrophobic emulsion, film coalescence aid, solubility promoter, defoamer, thickening material, auxiliary rheological agents is added successively in the mixture made to step (2) under 750-1000r/min rotating speed stirs, add rear Keep agitation 10-15min, namely obtain true mineral varnish finishing paint.
9. the preparation method of true mineral varnish finishing paint according to claim 8, is characterized in that: also need sequentially to add nano-TiO in its step (2) after adding wetting agent with before adding lotus leaf hydrophobizing agent
2colloidal sol and nano-ZnO slurry.
10. the preparation method of true mineral varnish finishing paint according to claim 9, is characterized in that: also need to add the mute powder of amorphous silica class in its step (2) after adding nano-ZnO slurry with before adding lotus leaf hydrophobizing agent.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510961095.8A CN105462411A (en) | 2015-12-18 | 2015-12-18 | Finish-coat paint for real stone paint and preparation method of finish-coat paint |
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| CN201510961095.8A CN105462411A (en) | 2015-12-18 | 2015-12-18 | Finish-coat paint for real stone paint and preparation method of finish-coat paint |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459884A (en) * | 2017-08-31 | 2017-12-12 | 北京康烨科技有限公司 | A kind of dust-proof static conductive environmental protection coating material of air cleaning facility |
| CN107603387A (en) * | 2017-09-22 | 2018-01-19 | 苏州振振好新型建材科技有限公司 | Third finish of a kind of environment-friendly waterproof resistant silicon and preparation method thereof |
| CN107699088A (en) * | 2017-11-02 | 2018-02-16 | 苏雪杏 | Interior wall coating and preparation method thereof |
| CN110093075A (en) * | 2018-01-29 | 2019-08-06 | 立邦涂料（中国）有限公司 | A kind of coating, coating and product |
| CN113801579A (en) * | 2021-10-21 | 2021-12-17 | 重庆裕时科技有限公司 | Finishing agent |
| CN115521679A (en) * | 2022-08-29 | 2022-12-27 | 广东美涂士建材股份有限公司 | Non-top-coat silicone-acrylic self-cleaning stone-like paint and preparation process thereof |
| CN115948086A (en) * | 2022-03-28 | 2023-04-11 | 上海涂固安高科技有限公司 | Multifunctional antifouling stone-like paint and application thereof |
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| CN102627895A (en) * | 2012-03-29 | 2012-08-08 | 黑龙江省玉琦装饰涂料有限公司 | Multifunctional dustproof self-cleaning wall paint |
| CN103725138A (en) * | 2013-12-14 | 2014-04-16 | 青岛益群漆业集团有限公司 | Silica sol high-permeability multifunctional transparent finish-coat paint |
| CN104356936A (en) * | 2014-11-21 | 2015-02-18 | 苏州大乘环保建材有限公司 | High-performance hydrophobic finishing paint for outer walls |
| CN104559567A (en) * | 2014-12-30 | 2015-04-29 | 三棵树涂料股份有限公司 | Finishing-free stone-like paint and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102627895A (en) * | 2012-03-29 | 2012-08-08 | 黑龙江省玉琦装饰涂料有限公司 | Multifunctional dustproof self-cleaning wall paint |
| CN103725138A (en) * | 2013-12-14 | 2014-04-16 | 青岛益群漆业集团有限公司 | Silica sol high-permeability multifunctional transparent finish-coat paint |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107459884A (en) * | 2017-08-31 | 2017-12-12 | 北京康烨科技有限公司 | A kind of dust-proof static conductive environmental protection coating material of air cleaning facility |
| CN107603387A (en) * | 2017-09-22 | 2018-01-19 | 苏州振振好新型建材科技有限公司 | Third finish of a kind of environment-friendly waterproof resistant silicon and preparation method thereof |
| CN107699088A (en) * | 2017-11-02 | 2018-02-16 | 苏雪杏 | Interior wall coating and preparation method thereof |
| CN110093075A (en) * | 2018-01-29 | 2019-08-06 | 立邦涂料（中国）有限公司 | A kind of coating, coating and product |
| CN113801579A (en) * | 2021-10-21 | 2021-12-17 | 重庆裕时科技有限公司 | Finishing agent |
| CN115948086A (en) * | 2022-03-28 | 2023-04-11 | 上海涂固安高科技有限公司 | Multifunctional antifouling stone-like paint and application thereof |
| CN115521679A (en) * | 2022-08-29 | 2022-12-27 | 广东美涂士建材股份有限公司 | Non-top-coat silicone-acrylic self-cleaning stone-like paint and preparation process thereof |
| CN115521679B (en) * | 2022-08-29 | 2024-04-12 | 广东美涂士建材股份有限公司 | Finishing-free silicone-acrylic self-cleaning real stone paint and preparation process thereof |
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Application publication date: 20160406 |