CN101338156A - Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent - Google Patents
Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent Download PDFInfo
- Publication number
- CN101338156A CN101338156A CNA2007101184799A CN200710118479A CN101338156A CN 101338156 A CN101338156 A CN 101338156A CN A2007101184799 A CNA2007101184799 A CN A2007101184799A CN 200710118479 A CN200710118479 A CN 200710118479A CN 101338156 A CN101338156 A CN 101338156A
- Authority
- CN
- China
- Prior art keywords
- emulsion
- mildew
- agent
- preparation
- cleaning
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Paints Or Removers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a preparation method of an antifogging self-cleaning antibacterial mildewproof spraying agent. Under the stirring condition, nanometer titanium dioxide is added and dispersed uniformly. Then, hydrophilic medium is added for the surface modification of the nanometer titanium dioxide. Resin latex is added slowly. Then, accessory ingredient and silane coupling agent are added for the suspension mixing. The antifogging self-cleaning antibacterial mildewproof spraying agent is obtained. The hydrophilic medium is added for the surface modification of the nanometer titanium dioxide and the proper resin latex is selected to be matched with the mildewproof agent. Thus, the spraying agent prepared through the invention is provided with good antifogging self-cleaning performance and antibacterial mildewproof performance, can be widely applied to object surfaces of internal and external walls, glass, emtal material, ceramics, sanitations, furniture, and the like, and has the advantages of broad spectrum antibacterial performance, simple and easy preparation method and lower production cost than similar products.
Description
Technical field
The present invention relates to a kind of preparation method of antifogging self-cleaning antimicrobial mildew-proof spraying agent, particularly contain the preparation of nano titanium oxide antifogging self-cleaning antimicrobial mildew-proof spraying agent.The spraying agent of preparation can be used for body surface antibacterial and mouldproof and antifogging self-cleanings such as interior exterior wall, glass, metallic substance, pottery, sanitary equipment and furniture.
Background technology
Nano-TiO
2It is one of the most active inorganic nano material of research at present, have nontoxic, antibiotic and characteristic such as decomposing bacteria, antiultraviolet, super hydrophilic and super lipophilicity, germ resistance wide spectrum, long-acting has been applied in the various functional paints, as interior exterior wall antibiotic paint, glass antifogging anti, pigment lacquer etc.It is more common to utilize the photocatalytic preparation of nano titanium oxide to have antibacterial coating at present, as: Chinese patent 03114740.2 proposes a kind of nano-disinfection type coating, the basal component of its prescription is: polyacrylic ester is that resin is that basic water miscible latex 33%-38%, many micropores carry silver-colored sterilization material 4%-6%, ultra-fine filling material 21%-27%, rutile titanium white powder 9%-13%, carboxymethyl cellulose 0.08%-0.2%, sodium polymethacrylate 0.05%-0.1%, Sodium hexametaphosphate 99 0.1%-0.18%, sodium pentachlorophenate 0.2%-0.4%, and all the other are water.Chinese patent 200410015146.X proposes a kind of photocatalysis air-cleaning water-based environment-friendly interior wall coating, weight proportion is as follows: water 12.00～16.00, dispersion agent 1.20～1.80, Antisepticize and mildew preventive 0.10～0.40, defoamer 0.30～0.50, Mierocrystalline cellulose 0.10～0.30 helps knot agent 5.00～8.00, organic amine auxiliary agent 0.25～0.50, dichloride in anatase type TiO
26.00～12.00, rutile TiO
25.00～8.00, pigment, filler 0.00～16.00, waterborne organic silicon modified acrylic acid emulsion (solid content 50%) 18.00～28.00, silicon sol 25.00～35.00, special addition agent 0.20～0.50.Described special addition agent is polyether modified siloxane or nonionic polyurethane.In the above-mentioned existing technology, mainly be TiO
2Cooperate with acrylic emulsion and corresponding auxiliary material, utilize TiO
2Photocatalysis be equipped with the coating that sterilization or mildew-resistant auxiliary agent obtain the fungus and mildew resistance function, exterior wall or metal material surface were antibiotic in use range was generally limited to, and as the decorative paint of interior exterior wall, auxiliary material that need add and TiO
2Consumption is more, the tooling cost height.The applicant proposes a kind of preparation method who is used for the building surface antibacterial mildew inhibitor in the 200610114441.X patent application, add film coalescence aid, nano-TiO at building coating in the application emulsion
2, dispersion agent, emulsifying agent, multifunctional assistant and mildew-resistant auxiliary agent dispersing and mixing, wherein mainly be with phenylpropyl alcohol, acrylic emulsion and imidazoles or quaternary ammonium salt mould inhibitor compatibility, titanium dioxide obtains antibacterial and mouldproof effect preferably under photochemical catalysis, the antibacterial mildew inhibitor of this method preparation is mainly used in the antibacterial and mouldproof of building surface, do not consider the antifogging self-cleaning function, function ratio is more single.
In recent years, report TiO is arranged
2Nano thin-film is as the antifogging self-cleaning material, as: people such as Yu Jiaguo are at the 20th volume the 4th phase " TiO in " solar energy journal " October in 1999
2The preparation of coating self-cleaning glass and characteristic research thereof " the middle porous TiO that proposes to make at glass surface homogeneous transparent with sol-gel technology
2Nano thin-film utilizes TiO
2The effect of super hydrophilicity performance antifogging self-cleaning, but this film-forming process complexity.People such as Su Guodong proposed to form self-cleaning material at polyurethane material surface applied nanometer titanium dioxide titanium compound coating in the volume o. 11th " preparation of polyurethane material nano titanium oxide self-cleaning coat " in " mechanical engineering material " November the 28th in 2004, but had surface TiO
2The caducous problem of coating, and TiO
2Consumption big (7%), and only limit to self-cleaning property.The fungus and mildew resistance multifunctional coating that has at present antifogging self-cleaning is simultaneously rarely reported.
Summary of the invention
The present invention proposes a kind of preparation method of antifogging self-cleaning antimicrobial mildew-proof spraying agent, the spraying agent of preparation can make coating have stronger wetting ability, and body surface is had antifogging self-cleaning and the multiple function of antibacterial and mouldproof simultaneously.And the spraying agent preparation method is simple, the auxiliary material of use and TiO
2Few, cost is low, and is easy to use flexible, in extensive range.
Technical scheme of the present invention: add water outstanding mixing in the still, adding nano titanium oxide under agitation condition is uniformly dispersed, slowly add hydrophilic medium then, nano titanium oxide is carried out surface modification, 0.5 behind～the 4h, slowly add resin emulsion, the amount ratio of emulsion and water (mass ratio) is 0.2～5g/g, and the mass ratio of nano titanium oxide and emulsion is 1 * 10
-3～1.5 * 10
-2G/g, the mass ratio of hydrophilic medium and emulsion are 2.5 * 10
-3～1 * 10
-2G/g adds mildew-resistant auxiliary agent, silane coupling agent again, and silane coupling agent is 0.5 * 10 with the quality of the emulsion ratio
-2～3.0 * 10
-2G/g, stir 0.5～2h, make antifogging self-cleaning antimicrobial mildew-proof spraying agent, described hydrophilic medium is tensio-active agent PEP-101, Triton X-100, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, polyoxyethylene nonylphenol ether; Poly-aspartic-acid or polyoxyethylene glycol.
The resin emulsion that the present invention uses is one or more the mixture in urethane, polyacrylic ester, acrylate, acrylic acid modified polyurethane or other modified polyurethanes and the polyethers resin.
The mildew-resistant auxiliary agent that the present invention adds is imidazoles mould inhibitor, phenylformic acid, quaternary ammonium salt mould inhibitor or amino formate mould inhibitor commonly used, studies show that, the synergy that different emulsion systems and the mildew-resistant additive compatibility that suits produce, can produce different anti-mold effects, preferably with polyacrylate dispersion system and quaternary ammonium salt mould inhibitor compatibility, modified polyurethane emulsion system and amino formate mould inhibitor compatibility can produce outstanding anti-mold effect.The add-on of mildew-resistant auxiliary agent is grasped by general conventional method, and the present invention's add-on preferably is that the mass ratio of mildew-resistant auxiliary agent and emulsion is 0.5 * 10
-2～5.0 * 10
-2G/g.
The nano titanium oxide median size that the present invention uses is 5-100nm; Preferred modification or adulterated nano-TiO
2As: nitrating TiO
2, mix iron TiO
2Or modification TiO
2Product.
The present invention uses hydrophilic media to nano-titanium dioxide modified, makes the nano titanium oxide surface energy reduce, and has reduced intergranular reactive force, improved dispersiveness, strengthened the wetting ability of coatingsurface simultaneously, wherein preferred poly-aspartic-acid, Triton X-100.
It is commercially available product: KH-560, DB-792, DB-570, DB-560 or DB-172 etc. that the present invention adds silane coupling agent.Its role is known.
Mixing of materials of the present invention adopts suspendible still, 100～600 rev/mins of mixing speed, 5～60 ℃ of temperature with dispersion.
Effect of the present invention: 1, adopt hydrophilic medium to the nano titanium oxide surface modification again with emulsion compatibility film forming, make full use of nano titanium dioxide photocatalysis character and make the film surface have the self-cleaning and antibacterial and mouldproof effect of hydrophilic antifogging simultaneously.2, with different resin emulsion systems and the suitable outstanding anti-mold effect of mould inhibitor synergy generation.3, the spraying agent TiO of the present invention's preparation
2Consumption few (0.2%～1%), auxiliary material is few, and is nontoxic, flexible and convenient to use, can spray at any time at body surfaces such as interior exterior wall, glass, metallic substance, pottery, sanitary equipment and furniture.Spraying antifogging self-cleaning antimicrobial mildew-proof coating after 24 hours is more than 96% to the sterilizing rate of black-koji mould, and colibacillary sterilizing rate is almost reached 100%, through the self-cleaning and antifog test of coatingsurface, proves that it has self-cleaning preferably anti-mist characteristic.
Embodiment
Below by embodiment method provided by the invention is further specified, but be not limited to following examples.
The method of calculation of sterilizing rate of the present invention are as follows: bacterium liquid is evenly coated on the slide glass that scribbles antibacterial and mouldproof taste removal coating, after 0,2,4,8,12,24 hour, be placed in the physiological saline with cotton excellent bacterium liquid is wiped gently, vibration, get 0.3ml in culture dish, pour substratum into, in incubator, cultivated 48 hours, take out the number colony number, calculate sterilizing rate according to following formula.
Sterilizing rate=(A
0-A
e)/A
0* 100%
Wherein: A
0-initial colony number (individual); A
eColony number after the-sterilization (individual).
The method of self-cleaning of the present invention test is as follows: test the whiteness of the coating after the whiteness of untainted coating, contaminated thing are polluted, the whiteness that the back coating is decomposed in illumination respectively, self-cleaning rate is calculated as follows.
In addition, coating adopts the flushing with clean water method to the self-cleaning test of dust.
The antifog property testing method of the present invention is as follows: at first sample is applied on glassly, after waiting to do, places-20 ℃ to place 2h, take out, place in 70 ℃ of waters bath with thermostatic control, record forms the time and the moisture film area of moisture film.
Embodiment 1: outstanding mixing in the still adds water, 20 ℃, 200 commentaries on classics/min stir, and add 0.75g Germany P25 type nano titanium oxide, add the 1g Triton X-100 again, slowly add in the 100g polyacrylate dispersion, add 1.5g quaternary ammonium salt mould inhibitor behind the mixing, add 0.5g coupling agent DB-792 again and stir, treat to dissolve fully, behind the emulsion-stabilizing, obtain antifogging self-cleaning antimicrobial mildew-proof spraying agent, through filming and dry on glass.Bacterium liquid is coated on the antifogging self-cleaning antimicrobial mildew-proof coating, after 0,2,4,8,12,24 hour bacterium liquid is placed physiological saline, vibration is got 0.3ml in culture dish, pour substratum into, in incubator, cultivated 48 hours, and took out the number colony number, the sterilizing rate of colibacillus is respectively 70%, 75%, 84%, 88%, 95%; Sterilizing rate to aspergillus niger is 60%, 76%, 82%, 85%, 90%.Homemade organic pollutant is applied on the self-cleaning coat, and it is 80% that whiteness test obtains self-cleaning rate.The coating slide in-20 ℃ of placement 2h, is taken out, place in 70 ℃ of waters bath with thermostatic control, the moisture film area reaches 90% behind the 5min.
The working method of embodiment 2, embodiment 3, embodiment 4 is with embodiment 1, and operating parameters sees Table 1.
Table 1
Claims (6)
1, a kind of preparation method of antifogging self-cleaning antimicrobial mildew-proof spraying agent, in the film-forming resin emulsion, add nano titanium oxide, the mildew-resistant auxiliary agent is characterized in that: add water outstanding mixing in the still, add nano titanium oxide and be uniformly dispersed under agitation condition, add hydrophilic medium then, nano titanium oxide is carried out surface modification, behind 0.5～4h, add resin emulsion, the mass ratio of emulsion and water is 0.2～5g/g, and the mass ratio of nano titanium oxide and emulsion is 1 * 10
-3～1.5 * 10
-2G/g, the mass ratio of hydrophilic medium and emulsion are 2.5 * 10
-3～1 * 10
-2G/g adds mildew-resistant auxiliary agent and silane coupling agent again, and silane coupling agent is 0.5 * 10 with the quality of the emulsion ratio
-2～3.0 * 10
-2G/g, stir 0.5～2h, make antifogging self-cleaning antimicrobial mildew-proof spraying agent, described hydrophilic medium is tensio-active agent PEP-101, Triton X-100, sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, polyoxyethylene nonylphenol ether, poly-aspartic-acid or polyoxyethylene glycol.
2, according to the preparation method of claim 1, it is characterized in that described resin emulsion is one or more the mixture in urethane, polyacrylic ester, acrylate, acrylic acid modified polyurethane, polyethers, vinylformic acid, methacrylic acid, the butyl acrylate emulsion.
According to the preparation method of claim 1, it is characterized in that 3, the mildew-resistant auxiliary agent of adding is imidazoles mould inhibitor, phenylformic acid, quaternary ammonium salt mould inhibitor or amino formate mould inhibitor.
4, according to the preparation method of claim 2 or 3, it is characterized in that, described polyacrylate dispersion and described quaternary ammonium salt mould inhibitor compatibility; Described modified polyurethane emulsion system and described amino formate mould inhibitor compatibility.
According to the preparation method of claim 1, it is characterized in that 5, the mildew-resistant auxiliary agent of adding and the mass ratio of resin emulsion are 0.5 * 10
-2～5.0 * 10
-2G/g.
According to the preparation method of claim 1, it is characterized in that 6, described nano titanium oxide is modification or adulterated nano-TiO
2, median size is 5-100nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710118479A CN100587016C (en) | 2007-07-06 | 2007-07-06 | Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200710118479A CN100587016C (en) | 2007-07-06 | 2007-07-06 | Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101338156A true CN101338156A (en) | 2009-01-07 |
| CN100587016C CN100587016C (en) | 2010-02-03 |
Family
ID=40212328
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200710118479A Expired - Fee Related CN100587016C (en) | 2007-07-06 | 2007-07-06 | Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100587016C (en) |
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012055308A1 (en) * | 2010-10-25 | 2012-05-03 | 江苏考普乐新材料股份有限公司 | Photoelectrochemicalmethod on metal preservation |
| CN102876211A (en) * | 2012-09-30 | 2013-01-16 | 合肥长城制冷科技有限公司 | Steel pipe inner wall antirust compound and preparation method thereof |
| CN103102724A (en) * | 2012-12-18 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | Metal surface silane treating agent containing acrylic acid and preparation method of metal surface silane treating agent |
| CN103242687A (en) * | 2013-05-03 | 2013-08-14 | 东振嘉业（北京）科技有限公司 | Nanometer photocatalyst spray-coating agent and preparation method thereof |
| CN104497742A (en) * | 2014-11-27 | 2015-04-08 | 太仓顺如成建筑材料有限公司 | Radiation-resistant building interior wall coating |
| CN104745025A (en) * | 2014-08-22 | 2015-07-01 | 赵杰 | Environment-friendly type multifunctional nano modified coating and spraying method thereof |
| CN105153861A (en) * | 2015-09-12 | 2015-12-16 | 宁波申泰干粉建材有限公司 | Self-cleaning water-resistant paint and preparation method thereof |
| CN105271946A (en) * | 2015-09-27 | 2016-01-27 | 常州市奥普泰科光电有限公司 | Preparation method of self-cleaning ceramic coating |
| CN105669967A (en) * | 2016-04-20 | 2016-06-15 | 中国工程物理研究院化工材料研究所 | Polyether polymer brush hybrid inorganic nano-material and preparation method thereof |
| JP5948482B1 (en) * | 2015-12-25 | 2016-07-06 | 三菱樹脂アグリドリーム株式会社 | Antifogging composition and antifogging film |
| CN107022268A (en) * | 2017-06-02 | 2017-08-08 | 段辉 | A kind of cable water mildow-proof inhibition renovation agent and preparation method thereof |
| CN107313245A (en) * | 2017-07-25 | 2017-11-03 | 东莞市荣腾纳米科技有限公司 | A kind of flame retardant type fog-proof wet towel and its processing method |
| CN107353734A (en) * | 2017-06-19 | 2017-11-17 | 苏州乔纳森新材料科技有限公司 | A kind of preparation method of nano-material modified antifogging self-cleaning coating |
| CN108395788A (en) * | 2018-06-04 | 2018-08-14 | 马爱连 | A kind of UV resistance, antibiotic glass hydrophilic finishing agent and its preparation method and application |
| CN109054617A (en) * | 2018-07-05 | 2018-12-21 | 吕莉 | A kind of preparation method of nano paint |
| CN109971327A (en) * | 2017-12-28 | 2019-07-05 | 财团法人工业技术研究院 | The formed method of water paint |
| CN109971295A (en) * | 2019-02-22 | 2019-07-05 | 四川大学 | A kind of free-floride antibacterial transparent hydrophobic coating, preparation method and applications |
| CN111893774A (en) * | 2020-07-14 | 2020-11-06 | 广州荔子科技有限公司 | Antibacterial ultraviolet-proof fabric spraying agent and preparation method thereof, and fabric and preparation method thereof |
| CN112409988A (en) * | 2020-12-07 | 2021-02-26 | 北京理工大学 | Degerming anti-fog glasses wiping solution and degerming anti-fog glasses cloth |
| CN113755067A (en) * | 2021-09-29 | 2021-12-07 | 厦门市金宝源实业有限公司 | Antibacterial coating and preparation method thereof |
| CN114773888A (en) * | 2022-03-30 | 2022-07-22 | 陈茂祥 | Self-cleaning nano ceramic antibacterial and mildew-proof composite slurry as well as preparation method and application thereof |
| CN115119850A (en) * | 2022-07-11 | 2022-09-30 | 浙江新安化工集团股份有限公司 | Compound mildew-proof antibacterial agent, preparation method thereof, long-acting mildew-proof alcohol-type sealant and preparation method thereof |
| CN116814126A (en) * | 2023-08-03 | 2023-09-29 | 燕山大学 | Preparation method of self-healing photocatalytic super-hydrophilic anti-fog coating |
-
2007
- 2007-07-06 CN CN200710118479A patent/CN100587016C/en not_active Expired - Fee Related
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012055308A1 (en) * | 2010-10-25 | 2012-05-03 | 江苏考普乐新材料股份有限公司 | Photoelectrochemicalmethod on metal preservation |
| US9371589B2 (en) | 2010-10-25 | 2016-06-21 | Jiangsu Kfcc New Materials Co., Ltd. | Surface modified nano-scaled titanium dioxide, preparation process thereof, coating containing the same, and photoelectrochemical method for metal preservation using the coating |
| CN102876211A (en) * | 2012-09-30 | 2013-01-16 | 合肥长城制冷科技有限公司 | Steel pipe inner wall antirust compound and preparation method thereof |
| CN103102724A (en) * | 2012-12-18 | 2013-05-15 | 芜湖恒坤汽车部件有限公司 | Metal surface silane treating agent containing acrylic acid and preparation method of metal surface silane treating agent |
| CN103102724B (en) * | 2012-12-18 | 2016-01-06 | 芜湖恒坤汽车部件有限公司 | A kind of containing acrylic acid Metal surface silane treatment agent and preparation method thereof |
| CN103242687A (en) * | 2013-05-03 | 2013-08-14 | 东振嘉业（北京）科技有限公司 | Nanometer photocatalyst spray-coating agent and preparation method thereof |
| CN104745025A (en) * | 2014-08-22 | 2015-07-01 | 赵杰 | Environment-friendly type multifunctional nano modified coating and spraying method thereof |
| CN104497742A (en) * | 2014-11-27 | 2015-04-08 | 太仓顺如成建筑材料有限公司 | Radiation-resistant building interior wall coating |
| CN105153861A (en) * | 2015-09-12 | 2015-12-16 | 宁波申泰干粉建材有限公司 | Self-cleaning water-resistant paint and preparation method thereof |
| CN105271946B (en) * | 2015-09-27 | 2017-10-20 | 临沂市连顺建陶有限公司 | A kind of preparation method of self-cleaning ceramic coating |
| CN105271946A (en) * | 2015-09-27 | 2016-01-27 | 常州市奥普泰科光电有限公司 | Preparation method of self-cleaning ceramic coating |
| JP5948482B1 (en) * | 2015-12-25 | 2016-07-06 | 三菱樹脂アグリドリーム株式会社 | Antifogging composition and antifogging film |
| CN105669967B (en) * | 2016-04-20 | 2018-05-01 | 中国工程物理研究院化工材料研究所 | Nano inorganic material of polyether high molecular brush hydridization and preparation method thereof |
| CN105669967A (en) * | 2016-04-20 | 2016-06-15 | 中国工程物理研究院化工材料研究所 | Polyether polymer brush hybrid inorganic nano-material and preparation method thereof |
| CN107022268A (en) * | 2017-06-02 | 2017-08-08 | 段辉 | A kind of cable water mildow-proof inhibition renovation agent and preparation method thereof |
| CN107353734A (en) * | 2017-06-19 | 2017-11-17 | 苏州乔纳森新材料科技有限公司 | A kind of preparation method of nano-material modified antifogging self-cleaning coating |
| CN107313245A (en) * | 2017-07-25 | 2017-11-03 | 东莞市荣腾纳米科技有限公司 | A kind of flame retardant type fog-proof wet towel and its processing method |
| CN109971327B (en) * | 2017-12-28 | 2021-05-25 | 财团法人工业技术研究院 | Water-based paint and forming method thereof |
| CN109971327A (en) * | 2017-12-28 | 2019-07-05 | 财团法人工业技术研究院 | The formed method of water paint |
| CN108395788A (en) * | 2018-06-04 | 2018-08-14 | 马爱连 | A kind of UV resistance, antibiotic glass hydrophilic finishing agent and its preparation method and application |
| CN109054617A (en) * | 2018-07-05 | 2018-12-21 | 吕莉 | A kind of preparation method of nano paint |
| CN109971295A (en) * | 2019-02-22 | 2019-07-05 | 四川大学 | A kind of free-floride antibacterial transparent hydrophobic coating, preparation method and applications |
| CN111893774A (en) * | 2020-07-14 | 2020-11-06 | 广州荔子科技有限公司 | Antibacterial ultraviolet-proof fabric spraying agent and preparation method thereof, and fabric and preparation method thereof |
| CN111893774B (en) * | 2020-07-14 | 2021-10-29 | 上海威露佳新材料科技有限公司 | Antibacterial ultraviolet-proof fabric spraying agent and preparation method thereof, and fabric and preparation method thereof |
| CN112409988A (en) * | 2020-12-07 | 2021-02-26 | 北京理工大学 | Degerming anti-fog glasses wiping solution and degerming anti-fog glasses cloth |
| CN113755067A (en) * | 2021-09-29 | 2021-12-07 | 厦门市金宝源实业有限公司 | Antibacterial coating and preparation method thereof |
| CN113755067B (en) * | 2021-09-29 | 2022-06-21 | 厦门市金宝源实业有限公司 | Antibacterial coating and preparation method thereof |
| CN114773888A (en) * | 2022-03-30 | 2022-07-22 | 陈茂祥 | Self-cleaning nano ceramic antibacterial and mildew-proof composite slurry as well as preparation method and application thereof |
| CN114773888B (en) * | 2022-03-30 | 2022-12-09 | 北京淡谷科技有限公司 | Self-cleaning nano ceramic antibacterial mildew-proof composite slurry and preparation method and application thereof |
| CN115119850A (en) * | 2022-07-11 | 2022-09-30 | 浙江新安化工集团股份有限公司 | Compound mildew-proof antibacterial agent, preparation method thereof, long-acting mildew-proof alcohol-type sealant and preparation method thereof |
| CN116814126A (en) * | 2023-08-03 | 2023-09-29 | 燕山大学 | Preparation method of self-healing photocatalytic super-hydrophilic anti-fog coating |
| CN116814126B (en) * | 2023-08-03 | 2024-05-10 | 燕山大学 | Preparation method of self-healing photocatalytic super-hydrophilic anti-fog coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100587016C (en) | 2010-02-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100587016C (en) | Method for preparing antifogging self-cleaning antimicrobial mildew-proof spraying agent | |
| CN101177554B (en) | Preparation method of antibiotic anti-fungus agent for building surface | |
| CN105368164B (en) | Plant ecological interior wall coating and preparation method thereof | |
| CN104387816A (en) | Multifunctional inorganic diatom ooze coating and preparation method thereof | |
| CN104497765A (en) | Inner wall latex paint capable of removing formaldehyde and preparation method of inner wall latex paint | |
| CN109735158B (en) | Coating construction process for indoor wall surface | |
| CN112063249A (en) | Artistic paint and preparation method thereof | |
| CN108395867A (en) | A kind of high-performance water-based antibacterial adhesive of safety and environmental protection and preparation method thereof | |
| CN106243966A (en) | A kind of composite multifunction double-component aqueous woodenware white finish paint and preparation method thereof | |
| CN101153138A (en) | Method of producing ultra-bright light catalysis degradation antimicrobial environment protection paint | |
| CN105462411A (en) | Finish-coat paint for real stone paint and preparation method of finish-coat paint | |
| CN104327608B (en) | A kind of diatom coating with absorption decomposing formaldehyde function | |
| CN113321977A (en) | Water-based antibacterial and mildewproof coating and preparation method thereof | |
| CN102876142A (en) | Stain resisting and odor removing paint and preparation method thereof | |
| CN108178959A (en) | One kind is except formaldehyde interiro wall latex paint and preparation method thereof | |
| CN107541117A (en) | Nanometer fishing net waterborne anti-fouling coatings and its preparation method and application | |
| JP2005281299A (en) | Antibacterial/mildewproofing agent and coating material composition using the same | |
| CN105295459A (en) | Ecological shell powder wall paint | |
| CN112029332B (en) | Water-based antibacterial coating and preparation method thereof | |
| CN107474715A (en) | A kind of antifouling paint peculiar to vessel and preparation method thereof | |
| CN113321956A (en) | Inorganic interior wall coating with aldehyde-removing, antibacterial and antiviral functions and preparation method thereof | |
| CN101597447B (en) | Nano coating | |
| WO2008000571A1 (en) | Method of producing a detachable, anti-fouling coating | |
| KR100585189B1 (en) | Water-based Ceramic Photocatalyst Paint And Manufacturing Method Thereof | |
| CN103642348A (en) | Nano mildew-proof coating for outer wall |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20100203 Termination date: 20130706 |