CN104387816A - Multifunctional inorganic diatom ooze coating and preparation method thereof - Google Patents
Multifunctional inorganic diatom ooze coating and preparation method thereof Download PDFInfo
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- CN104387816A CN104387816A CN201410710594.5A CN201410710594A CN104387816A CN 104387816 A CN104387816 A CN 104387816A CN 201410710594 A CN201410710594 A CN 201410710594A CN 104387816 A CN104387816 A CN 104387816A
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Abstract
The invention relates to a multifunctional inorganic diatom ooze coating, which is prepared from the following components in percentage by mass: 10%-25% of water, 0.4%-0.8% of cellulose, 10-30% of a mixture of potassium metasilicate and silica sol, 0.2%-0.4% of a stabilizer, 0.1%-0.3% of a dispersing agent, 0.1%-0.3% of a silicon additive, 0.3%-0.5% of a defoaming agent, 0.1%-0.3% of an antibacterial agent, 0-20% of titanium dioxide, 5%-15% of nanometer kieselguhr, 10%-30% of coarse whiting, 2%-4% of talcum powder, 1%-3% of medical stone, 0-1.5% of anion, 0-2% of a nano-photocatalyst, 1%-2% of inorganic gel powder, 0-9% of an order-removing emulsion and 0-1.5% of pigment, wherein the sum of the components is 100%. The invention also provides a preparation method of the coating. The coating disclosed by the invention has the functions of sterilizing, preventing mold, purifying air and the like; and the preparation method disclosed by the invention is simple and easy to operate.
Description
Technical field
The present invention relates to paint field, be specifically related to a kind of multifunctional inorganic diatom ooze coating and preparation method thereof.
Background technology
Coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms adhere well, has some strength, continuous print solid film.The film common name film of such formation, also known as paint film or coating, it is made up of filmogen, film forming subsidiary material matter and auxiliary film forming matter three kinds of base substances.Existing coating, adopt potassium silicate solution as filmogen, potassium silicate provides excellent bond properties, but due to the existence of alkalimetal ion, makes coating adhesion inadequate, simultaneously due to the existence of alkalimetal ion, make the water tolerance of coating on the low side; In addition also to there is permeability bad for existing filmogen, and the performance such as anticorrosion, antibacterial, absorption agent making to add in coating is not out.
Summary of the invention
The object of the present invention is to provide that a kind of bond properties is good, permeability is good, can give full play to the multifunctional inorganic diatom ooze coating of additive performance, the present invention also provides the preparation method of simple, the easy-operating multifunctional inorganic diatom ooze coating of a kind of technique in addition.
For solving the problem, the technical solution adopted in the present invention is as follows:
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: water 10-25%, Mierocrystalline cellulose 0.4-0.8%, the mixture 10-30% of potassium silicate and silicon sol, stablizer 0.2-0.4% part, dispersion agent 0.1-0.3%, silicon additive 0.1-0.3%, defoamer 0.3-0.5%, antiseptic-germicide 0.1-0.3%, titanium dioxide 0-20%, nano diatomite 5-15%, coarse whiting 10-30%, talcum powder 2-4%, medical stone 1-3%, nanometer anion powder 0-1.5%, nano photo-catalytic 0-2%, inorganic gel powder 1-2%, clean taste emulsion 0-9%, pigment 0-1.5%, the summation of described each component is 100%, and the quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:6-8.(numerical range of the present invention, comprises endpoint value).
Mierocrystalline cellulose; effect in coating is have good thickening, suspension, dispersion, emulsification, bonding, film forming, protection moisture and provide the features such as protective colloid, includes but not limited to lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, Polyanionic Cellulose, sodium polyacrylate ethyl cellulose, methylcellulose gum, calcium mercaptoacetate polyoxyethylene glycol Vltra tears.
Stablizer, can increase solution, colloid, solid, mixture stability chemicals be all stablizer.It can slow down reaction, keeps chemical equilibrium, reduces surface tension, prevents the effects such as light, thermolysis or oxygenolysis.Include but not limited to calcium stearate, phosphorous acid ester etc.
Dispersion agent is a kind of interfacial agent simultaneously in molecule with lipophilicity and wetting ability two kinds of opposite nature.Can homogeneous dispersion those be difficult to be dissolved in the inorganic of liquid, the solid particulate of pigment dyestuff, also can prevent sedimentation and the cohesion of solid particulate simultaneously, forms stable material needed for suspension, and dispersion agent is generally divided into inorganic dispersant and the large class of organic dispersing agent two.Conventional inorganic dispersant has silicates (such as water glass) and alkali metal phosphate class (such as tripoly phosphate sodium STPP, Sodium hexametaphosphate 99 and trisodium phosphate etc.).Organic dispersing agent comprises triethyl hexyl phosphoric acid, sodium lauryl sulphate, methyl amyl alcohol, derivatived cellulose, polyacrylamide, guar gum, fatty acid polyglycol ester etc.
Silicon additive, comprises silane coupling agent, silicone oil, silicone resin, as dimethyl-silicon wet goods.
Inorganic gel, white powder; Tasteless, nontoxic, nonirritant; Water insoluble, oil and ethanol.Soak swelling, compared with high-clarity, full-bodied colloid can be formed under low-solid content, as magnesium aluminium silicate gel, lithium magnesium silicate gel.
Described defoamer includes but not limited to methyl alcohol, ethanol, Virahol, sec-butyl alcohol, tributyl phosphate, tallol.
Antiseptic-germicide refers to and can within a certain period of time, make the growth of certain micro-organisms (bacterium, fungi, yeast, algae and virus etc.) or breeding remain on chemical substance necessary below horizontal.Comprise silver ions class antiseptic-germicide, as silver suboxide.
Most inorganic paints in the market adopt potassium silicate solutions as tackiness agent, and potassium silicate provides excellent bond properties, but due to the existence of alkalimetal ion, the water tolerance of coating reduces.Contriver finds, can head it off by silicon sol, but when silicon sol and the mixture of potassium silicate and the mass ratio of potassium silicate are greater than 10:8, the stability of coating system can reduce, show that coating viscosity within the shelf lives rises, even gel solidification, makes coating cannot meet storage needs, and impact construction fluency; When the mixture of silicon sol and potassium silicate and the mass ratio of potassium silicate are lower than 4:6, the water tolerance performance of coating does not still improve; When the mixture of silicon sol and potassium silicate and the mass ratio of potassium silicate are 10:7, water resistance and stability best.
In the present invention, potassium silicate and silicon sol are mixed, make potassium silicate in the solution containing Nano particles of silicon dioxide, the hydroxyl of its particle surface is through inertia modification, not easily there is particle agglomeration, excellent stability in salts solution, adds coating system to as filmogen and shows excellent stability in storage; Using the mixture of potassium silicate and silicon sol as filmogen, permeability spy is good, can not impact the absorption effect of algae clay, plays nano photo-catalytic, the decomposing formaldehyde of nanometer anion powder and taste removal, sterilizing function very well; Clean taste emulsion can optimize the mixture film forming of potassium silicate and silicon sol after fragility, adhesive property and improve workability.
In the present invention, the medical stone of interpolation, has health-care effect to human body; The nano photo-catalytic added can be degraded toxic and harmful in air effectively; Effectively can kill various bacteria, and the toxin that bacterium or fungi can be discharged decomposes and harmless treatment; The function such as simultaneously also possess deodorizing, anti-soil, purify air; Not containing formaldehyde and other organic volatile solvent in raw material, VOC content is close to zero; The mixture of potassium silicate and silicon sol is reacted and body of wall mortise by petrochemical industry, paint colors is oozed in buildings completely, allows coating become a part for buildings, make coating reach 50 years work-ing life; Coating of the present invention has water-repellancy and breathing power, and building interior moisture is evaporated freely, prevent body of wall tide elongated mould, and can alkaloid substance have been filtered, prevent coating bubbling, produce thermal spalling and play scale and peel off and after constructing by alkali pollution; The fine and closely woven material structure of coatingsurface that coating is formed, is not needed special processing by painting body of wall ground, have hardness high, do not produce electrostatic (dust is difficult to adhere to), stain resistance is high, safeguard the high-performances such as maintenance is convenient; Rich in mineral substances in coating, its mineralogical composition is not also burnt (fire prevention coefficient reaches A level) at 1000 DEG C of high temperature, and secret worry suffered from by the fire alleviating constructor and user.
In the present invention, preferred scheme is it is characterized in that being made up of the following component according to percent by weight: the mixture 10-30% of water 21.4%, Mierocrystalline cellulose 0.6%, potassium silicate and silicon sol, stablizer 0.3%, dispersion agent 0.2%, silicon additive 0.2%, defoamer 0.4%, antiseptic-germicide 0.2%, titanium dioxide 5%, nano diatomite 5-15%, coarse whiting 10%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano photo-catalytic 1%, inorganic gel powder 1-2%, clean taste emulsion 5-9%, pigment 0-1%; The summation of described each component is 100%, and the quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the particle diameter of described coarse whiting is 800 orders.
In the present invention, preferred scheme is the anion-generating capacity of described nanometer anion powder is 20000ionS/CC.
In the present invention, one or more the mixing that to be described Mierocrystalline cellulose be in lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, Polyanionic Cellulose, sodium polyacrylate ethyl cellulose, methylcellulose gum and calcium mercaptoacetate polyoxyethylene glycol Vltra tears of preferred scheme.
In the present invention, the one or more kinds of mixing that to be described nano photo-catalytic be in nano titanium oxide, stannic oxide, zirconium dioxide and zinc oxide of preferred scheme.
In the present invention, one or more the combination that to be described silicon additive be in dimethyl silicone oil, silane coupling agent and silicone resin of preferred scheme.
In the present invention, preferred scheme is described talcous model is 800#.
In the present invention, preferred scheme is described inorganic gel powder is magnesium aluminium silicate gel powder and/or lithium magnesium silicate gel powder.
In the present invention, preferred scheme is that described multifunctional inorganic diatom ooze coating is made up of the following component according to percent by weight: water 21.4%, hydroxypropylcellulose 0.6%, the mixture 20% of potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.4%, silver suboxide 0.2%, titanium dioxide 10%, nano diatomite 13%, coarse whiting 18%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 1%, magnesium aluminium silicate gel powder 1.7%, clean taste emulsion 6%, pigment 1%, the quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.
The present invention also provides the preparation method of this multifunctional inorganic diatom ooze coating, and it in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 8-12min with the stirring velocity of 380-420r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 4-6min with the stirring velocity of 380-420r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 15-25min with the stirring velocity of 1400-1600r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 8-12min with the stirring velocity of 750-850r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 8-12min with the stirring velocity of 750-850r/min;
F. in stirred vessel, add pigment, stir, obtain product.
In the present invention, the preparation method of preferred multifunctional inorganic diatom ooze coating, it in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 10min with the stirring velocity of 400r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 5min with the stirring velocity of 400r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 20min with the stirring velocity of 1500r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Compared with prior art, the invention has the advantages that: in the present invention, potassium silicate and silicon sol are mixed, make potassium silicate in the solution containing Nano particles of silicon dioxide, the hydroxyl of its particle surface is through inertia modification, not easily there is particle agglomeration, excellent stability in salts solution, adds coating system to as filmogen and shows excellent stability in storage; Using the mixture of potassium silicate and silicon sol as filmogen, permeability spy is good, can not impact the absorption effect of algae clay, plays nano photo-catalytic, the decomposing formaldehyde of nanometer anion powder and taste removal, sterilizing function very well; Clean taste emulsion can optimize the mixture film forming of potassium silicate and silicon sol after fragility, adhesive property and improve workability; Outside secondary, coating of the present invention also has sterilization, mildew-resistant, deodorizing, purifies air and fire-proof function; Preparation method of the present invention is simple, easy to operate, is convenient to realize scale operation.
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment
Embodiment 1
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight:
The mixture 20% of water 21.4%, hydroxypropylcellulose 0.6%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.4%, silver suboxide 0.2%, titanium dioxide 10%, nano diatomite 13%, coarse whiting 18%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 1%, magnesium aluminium silicate gel powder 1.7%, clean taste emulsion 6%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.
Its preparation method in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 10min with the stirring velocity of 400r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 5min with the stirring velocity of 400r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 20min with the stirring velocity of 1500r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Embodiment 2
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 30% of water 11.3%, hydroxypropylcellulose 0.5%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.3%, silver suboxide 0.2%, titanium dioxide 15%, nano diatomite 10%, coarse whiting 22%, talcum powder 4%, medical stone 2%, nanometer anion powder 0.5%, nano titanium oxide 0.5%, magnesium aluminium silicate gel powder 2%, clean taste emulsion 0%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.Its preparation method is with embodiment 1.
Embodiment 3
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 25% of water 16%, hydroxypropylcellulose 0.6%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.4%, silver suboxide 0.2%, titanium dioxide 5%, nano diatomite 12%, coarse whiting 26%, talcum powder 4%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 0.6%, magnesium aluminium silicate gel powder 1.5%, clean taste emulsion 4%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.Its preparation method is with embodiment 1.
Embodiment 4
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 20% of water 18.5%, hydroxypropylcellulose 0.4%, potassium silicate and silicon sol, calcium stearate 0.4% part, methyl amyl alcohol 0.3%, dimethyl silicone oil 0.3%, tributyl phosphate 0.5%, silver suboxide 0.3%, titanium dioxide 11%, nano diatomite 10%, coarse whiting 20%, talcum powder 4%, medical stone 3%, nanometer anion powder 0.5%, nano titanium oxide 0.3%, magnesium aluminium silicate gel powder 2%, clean taste emulsion 7%, pigment 1.5%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:6.
Its preparation method in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 12min with the stirring velocity of 380r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 6min with the stirring velocity of 380r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 25min with the stirring velocity of 1400r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 12min with the stirring velocity of 750r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 12min with the stirring velocity of 750r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Embodiment 5
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 18% of water 17.3%, hydroxypropylcellulose 0.6%, potassium silicate and silicon sol, calcium stearate 0.2% part, methyl amyl alcohol 0.1%, dimethyl silicone oil 0.1%, tributyl phosphate 0.3%, silver suboxide 0.1%, titanium dioxide 10%, nano diatomite 10%, coarse whiting 25%, talcum powder 4%, medical stone 2%, nanometer anion powder 0.5%, nano titanium oxide 0.3%, magnesium aluminium silicate gel powder 2%, clean taste emulsion 8%, pigment 1.5%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:8.
Its preparation method in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 8min with the stirring velocity of 420r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 4min with the stirring velocity of 420r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 15min with the stirring velocity of 1600r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 8min with the stirring velocity of 850r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 8min with the stirring velocity of 850r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Embodiment 6
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 15% of water 21.8%, methylcellulose gum 0.4%, potassium silicate and silicon sol, calcium stearate 0.4% part, methyl amyl alcohol 0.3%, dimethyl silicone oil 0.3%, tributyl phosphate 0.5%, silver suboxide 0.3%, titanium dioxide 8% part, nano diatomite 11%, coarse whiting 24%, talcum powder 4%, medical stone 3%, nanometer anion powder 0.5%, nano titanium oxide 0.5%, magnesium aluminium silicate gel powder 2%, clean taste emulsion 8%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:6.Its preparation method is with embodiment 4.
Embodiment 7
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 15% of water 24.6%, methylcellulose gum 0.7%, potassium silicate and silicon sol, calcium stearate 0.3%, sodium lauryl sulphate 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.4%, silver suboxide 0.2%, titanium dioxide 5%, nano diatomite 10%, coarse whiting 26%, talcum powder 3%, medical stone 2%, nanometer anion powder 0.2%, nano titanium oxide 0.2%, lithium magnesium silicate gel powder 2%, clean taste emulsion 9%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.
Embodiment 8
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 15% of water 20.5.%, carboxymethyl cellulose 0.6%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, silane coupling agent 0.2%, sec-butyl alcohol 0.4%, silver suboxide 0.2%, titanium dioxide 5%, nano diatomite 8%, coarse whiting 30%, talcum powder 4%, medical stone 3%, nanometer anion powder 0%, nano titanium oxide 0.1%, lithium magnesium silicate gel powder 1.5%, clean taste emulsion 9%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.
Comparative example 1
A kind of inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 19.4% of water 25%, hydroxypropylcellulose 0.3%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.5%, tributyl phosphate 0.1%, silver suboxide 0.2%, titanium dioxide 5%, nano diatomite 13%, coarse whiting 10%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 1%, magnesium aluminium silicate gel powder 6%, clean taste emulsion 13%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.Its preparation method is with embodiment 1.
Comparative example 2
A kind of multifunctional inorganic diatom ooze coating, it is made up of the following component according to percent by weight: the mixture 16% of water 18%, hydroxypropylcellulose 0.2%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.1%, dimethyl silicone oil 0.5%, tributyl phosphate 0.4%, silver suboxide 0.1%, titanium dioxide 5%, nano diatomite 19%, coarse whiting 10%, talcum powder 4.4%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 3%, magnesium aluminium silicate gel powder 10%, clean taste emulsion 9%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.Its preparation method is with embodiment 1.
Comparative example 3
A kind of multifunctional inorganic diatom ooze coating, its formula is identical with embodiment 1.Its preparation method in turn includes the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 8min with the stirring velocity of 350r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 4min with the stirring velocity of 430r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 10min with the stirring velocity of 1600r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 6min with the stirring velocity of 920r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 15min with the stirring velocity of 850r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Comparative example 4
A kind of multifunctional inorganic diatom ooze coating, its formula is identical with embodiment 2.Its preparation method in turn includes the following steps: a. has weighed each component by formula ratio, adds in stirred vessel by water, Mierocrystalline cellulose, stirs 8min with the stirring velocity of 440r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 6min with the stirring velocity of 370r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 14min with the stirring velocity of 1300r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 14min with the stirring velocity of 850r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 8min with the stirring velocity of 910r/min;
F. in stirred vessel, add pigment, stir, obtain product.
Experimental example
The inorganic diatom ooze coating of Example 1-8, comparative example 1-4 respectively, be coated on different aluminium sheets respectively, 20 are solidified at the temperature of 200 DEG C, min, form the coating of one deck 180-200 micron, the outward appearance (for appraisement system stability, then system is unstable if any particle, harsh feeling) of gained coating, pencil hardness, outward appearance, impact resistance and dry sticking power is tested according to " HG/T2006 thermosetting coating standard "; The aluminium sheet scribbling these coating is respectively placed in 1m
3space in, and inject formaldehyde and toluene makes the concentration of the two be respectively 1.5mg/m
3and 2.5mg/m
3, then utilize the purification efficiency of " JC/T1074-2008 function of purifying indoor air coating material purifying property " this coating PARA FORMALDEHYDE PRILLS(91,95) of standard testing and toluene.Concrete test result refers to following table 1:
The inorganic diatom ooze coating performance test table of table 1: embodiment 1-8, comparative example 1-4
Water resistance is tested: get the aluminium sheet of coating scribbling embodiment 1-8, comparative example 1-4 respectively, aluminium sheet bound edge being placed on temperature is in the constant temperature water bath of 40 DEG C, observe and the coating recorded on each aluminium sheet time of starting loss of gloss, coming off, concrete outcome refers to following table 2:
Table 2: water resistance test chart
Above-mentioned embodiment is only the preferred embodiment of the present invention; can not limit the scope of protection of the invention with this, change and the replacement of any unsubstantiality that those skilled in the art does on basis of the present invention all belong to the present invention's scope required for protection.
Claims (10)
1. a multifunctional inorganic diatom ooze coating, is characterized in that being made up of the following component according to percent by weight:
Water 10-25%, Mierocrystalline cellulose 0.4-0.8%, the mixture 10-30% of potassium silicate and silicon sol, stablizer 0.2-0.4% part, dispersion agent 0.1-0.3%, silicon additive 0.1-0.3%, defoamer 0.3-0.5%, antiseptic-germicide 0.1-0.3%, titanium dioxide 0-20%, nano diatomite 5-15%, coarse whiting 10-30%, talcum powder 2-4%, medical stone 1-3%, nanometer anion powder 0-1.5%, nano photo-catalytic 0-32%, inorganic gel powder 1-2%, clean taste emulsion 0-9%, pigment 0-1.5%, the summation of described each component is 100%, and the quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:6-8.
2. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that being made up of the following component according to percent by weight:
The mixture 10-30% of water 21.4%, Mierocrystalline cellulose 0.6%, potassium silicate and silicon sol, stablizer 0.3%, dispersion agent 0.2%, silicon additive 0.2%, defoamer 0.4%, antiseptic-germicide 0.2%, titanium dioxide 5%, nano diatomite 5-15%, coarse whiting 10%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano photo-catalytic 1%, inorganic gel powder 1-2%, clean taste emulsion 5-9%, pigment 0-1%; The summation of described each component is 100%, and the quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the particle diameter of described coarse whiting is 800 orders.
3. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that: the anion-generating capacity of described nanometer anion powder is 20000ionS/CC.
4. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that: described Mierocrystalline cellulose is one or more the mixing in lignocellulose, hydroxypropylcellulose, carboxymethyl cellulose, Polyanionic Cellulose, sodium polyacrylate ethyl cellulose, methylcellulose gum and calcium mercaptoacetate polyoxyethylene glycol Vltra tears.
5. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that: described nano photo-catalytic is the one or more kinds of mixing in nano titanium oxide, stannic oxide, zirconium dioxide and zinc oxide.
6. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that: described silicon additive is one or more the combination in dimethyl silicone oil, silane coupling agent and silicone resin.
7. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that: described inorganic gel powder is magnesium aluminium silicate gel powder and/or lithium magnesium silicate gel powder.
8. multifunctional inorganic diatom ooze coating according to claim 1, is characterized in that being made up of the following component according to percent by weight:
The mixture 20% of water 21.4%, hydroxypropylcellulose 0.6%, potassium silicate and silicon sol, calcium stearate 0.3%, methyl amyl alcohol 0.2%, dimethyl silicone oil 0.2%, tributyl phosphate 0.4%, silver suboxide 0.2%, titanium dioxide 10%, nano diatomite 13%, coarse whiting 18%, talcum powder 3%, medical stone 2%, nanometer anion powder 1%, nano titanium oxide 1%, magnesium aluminium silicate gel powder 1.7%, clean taste emulsion 6%, pigment 1%; The quality of the mixture of described potassium silicate and silicon sol and the mass ratio of potassium silicate are 10:7, and the anion-generating capacity of described nanometer anion powder is 20000ionS/CC, and the particle diameter of described coarse whiting is 800 orders.
9. the preparation method of the multifunctional inorganic diatom ooze coating according to any one of claim 1-8, is characterized in that in turn including the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 8-12min with the stirring velocity of 380-420r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 4-6min with the stirring velocity of 380-420r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 15-25min with the stirring velocity of 1400-1600r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 8-12min with the stirring velocity of 750-850r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 8-12min with the stirring velocity of 750-850r/min;
F. in stirred vessel, add pigment, stir, obtain product.
10. the preparation method of multifunctional inorganic diatom ooze coating according to claim 9, is characterized in that in turn including the following steps:
A. weigh each component by formula ratio, water, Mierocrystalline cellulose have been added in stirred vessel, stir 10min with the stirring velocity of 400r/min;
B. the defoamer of the mixture of potassium silicate and silicon sol, stablizer, dispersion agent, silicon additive, antiseptic-germicide and half formula ratio is added in stirred vessel, stir 5min with the stirring velocity of 400r/min;
C. titanium dioxide, nano diatomite, coarse whiting, talcum powder, medical stone, nanometer anion powder and nano photo-catalytic are added in stirred vessel, stir 20min with the stirring velocity of 1500r/min;
D. inorganic gel powder and clean taste emulsion are added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
E. the defoamer of second half formula ratio is added in stirred vessel, stir 10min with the stirring velocity of 800r/min;
F. in stirred vessel, add pigment, stir, obtain product.
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Application publication date: 20150304 |