CN106957572A - A kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof - Google Patents
A kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof Download PDFInfo
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- CN106957572A CN106957572A CN201710097605.0A CN201710097605A CN106957572A CN 106957572 A CN106957572 A CN 106957572A CN 201710097605 A CN201710097605 A CN 201710097605A CN 106957572 A CN106957572 A CN 106957572A
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- Prior art keywords
- dip
- clear paint
- coating
- gloss clear
- woodware
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/43—Thickening agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof, it is related to technical field of coatings.It is composed of the following components by weight percentage：Water-borne Self-Crosslinked Acrylic emulsion 35 45%, aqueous aliphatic polyurethane dispersion 35 45%, deionized water 10 15%, defoamer 0.1 0.5%, propandiol butyl ether 1 3%, anti-settling agent 2 4%, ground wetting agent 0.1 0.5%, thickener 0.1 0.5%；The MFFT of water-borne Self-Crosslinked Acrylic emulsion is 31 DEG C.Waterborne woodware high-gloss clear paint of the present invention has that VOC content is low, resist sagging performance is good, it is adaptable to the characteristics of dip application, and application prospect is wide.
Description
Technical field
The present invention relates to technical field of coatings.
Background technology
Cosmetic brush, the wooden handle of paintbrush are typically made from birch, its it is wooden it is hard, be unlikely to deform, surface is made using coating
It has abundant color, to play the effect of decoration and protection.Due to the various shapes of wooden handle, spraying is difficult to, typically
Constructed by the way of dip-coating.Current manufacturer typically uses the solvent based coating of quick-drying, wherein mainly nitrate paint.Nitro
Paint realizes its quick-drying by substantial amounts of fast-drying organic solvent is added, and organic solvent diluting is also used in use,
Organic solvent content may be up to 50% and more than.When ambient humidity is more than 60%, it is necessary to reduce ambient humidity to prevent that paint film from sending out
White disadvantage.Dip tank needs open placement in work progress, and workman can suck substantial amounts of organic solvent in operation,
Long-time operation produces great harm to body, and solvent based coating is inflammable and explosive, and the moment has potential safety hazard.
《HJ2537-2014 environmental labelling product technical requirements water paints》Middle water-borne wood coating is to VOC（Volatility
Organic compound）Be limited to 80g/L.Water paint is more suitable for dip-coating with its low VOC environmental protection characteristic, than solvent based coating to be applied
Work.
The high Tg self-crosslinking acrylics emulsion used in Chinese patent CN102051096A is, it is necessary to plus many solvent ability rooms
Warm film forming, solvent load is up to 235g/L, existing standard can not be met up to the 4-16% for being formulated total amount, obtained product VOC
It is required that, and product is only applicable to brushing, spraying application, is not suitable for dip application.
The content of the invention
It is high with aqueous wooden ware the technical problem to be solved in the present invention is to provide the good dip-coating of a kind of low VOC, resist sagging performance
Light varnish and preparation method thereof.
In order to solve the above technical problems, the technical solution used in the present invention is：A kind of dip-coating waterborne woodware high-gloss clear
Paint, it is composed of the following components by weight percentage：Water-borne Self-Crosslinked Acrylic emulsion 35-45%, aqueous aliphatic polyurethane disperses
Body 35-45%, deionized water 10-15%, defoamer 0.1-0.5%, propandiol butyl ether 1-3%, anti-settling agent 2-4%, ground wetting agent
0.1-0.5%, thickener 0.1-0.5%；The MFFT of water-borne Self-Crosslinked Acrylic emulsion is 31 DEG C.
It is preferred that, water-borne Self-Crosslinked Acrylic emulsion is the NeoCryl XK-12 of Dutch DSM DSM N. V..
It is preferred that, aqueous aliphatic polyurethane dispersion is the NeoRez R-2180 of Dutch DSM DSM N. V..
It is preferred that, thickener is nonionic polyurethane thickener.
It is further preferred that thickener is Borchi Gel 0625.
It is preferred that, anti-settling agent is polyamide sodium ammonium salt.
It is further preferred that anti-settling agent is the AQH-800 of Supreme Being Si Balong DISPARLON companies of Japan.
The above-mentioned dip-coating preparation method of waterborne woodware high-gloss clear paint, comprises the following steps：By water-borne Self-Crosslinked Acrylic
Emulsion is added in paint mixing tank, and aqueous aliphatic polyurethane dispersion, defoamer, deionized water, propane diols are added under stirring
Butyl ether, anti-settling agent, ground wetting agent and thickener, disperse, that is, dip-coating waterborne woodware high-gloss clear paint is made.
It is preferred that, the dip-coating preparation method of waterborne woodware high-gloss clear paint comprises the following steps：By waterborne self-crosslinkable propylene
Yogurt liquid is added in paint mixing tank, and aqueous aliphatic polyurethane dispersion, froth breaking are sequentially added under 400-500r/min stirrings
Agent, deionized water, propandiol butyl ether, anti-settling agent, ground wetting agent and thickener, disperse 20-30min, that is, dip-coating water is made
Property woodware high-gloss varnish.
It is using the beneficial effect produced by above-mentioned technical proposal：
（1）The present invention is used from water-borne Self-Crosslinked Acrylic emulsion with the collocation of aqueous aliphatic polyurethane dispersion, its reclaimed water
Property self-crosslinking acrylic emulsion there is the characteristic of self-crosslinking, its MFFT is 31 DEG C, need to only add a small amount of solvent can room temperature film-forming,
And the paint film formed has extraordinary chemical resistance and resistance to blocking.Aqueous aliphatic polyurethane dispersion NeoRez R-
2180 are free of solvent, and quick-drying, good weatherability, both blendings add solvent using the dip-coating made waterborne woodware high-gloss clear paint
Few, VOC content is low, and formation gloss of film is high, transparency is good, fast drying, and paint film patience is good；
（2）The present invention as anti-settling agent, can produce needle-like self-crosslinking structure from polyamide sodium ammonium salt in addition system, assign body
It is excellent thixotropic effects, while nonionic polyurethane thickener of arranging in pairs or groups, the effective flowing down problems for solving dip-coating；
（3）Product of the present invention is low compared with solvent-borne type nitrate paint and common aqueous woodware varnish lacquer VOC content, VOC≤30g/L, reduces
Environmental pollution and the health hazard to workman.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, this is opposed below in conjunction with embodiment
Invention is described in further detail.
Embodiment 1
A kind of dip-coating waterborne woodware high-gloss clear paint, it is composed of the following components by weight percentage：Water-borne Self-Crosslinked Acrylic breast
Liquid 35%, aqueous aliphatic polyurethane dispersion 45%, deionized water 15%, defoamer 0.3%, propandiol butyl ether 1%, anti-settling agent 3%,
Ground wetting agent 0.3%, thickener 0.4%.
Water-borne Self-Crosslinked Acrylic emulsion is NeoCryl XK-12, and MFFT is 31 DEG C.
Aqueous aliphatic polyurethane dispersion is NeoRez R-2180.
Anti-settling agent is polyamide sodium ammonium salt, specially DISPARLON AQH-800.
Thickener is Borchi Gel 0625.
The above-mentioned dip-coating preparation method of waterborne woodware high-gloss clear paint, comprises the following steps：By water-borne Self-Crosslinked Acrylic
Emulsion add paint mixing tank in, sequentially added under 400-500r/min stirrings aqueous aliphatic polyurethane dispersion, defoamer,
Deionized water, propandiol butyl ether, anti-settling agent, ground wetting agent and thickener, disperse 20min, that is, dip-coating aqueous wooden ware is made
Bloom varnish.
The above-mentioned dip-coating construction method of waterborne woodware high-gloss clear paint, comprises the following steps：Dip-coating is high with aqueous wooden ware
Light varnish is placed in dip tank, and the viscosity for adding appropriate water adjustment paint is 25-35s（Apply -4 glasss）, 15 ° of angles of wooden handle inclination are consolidated
It is projecting to be placed on automatic paint dipping machine due on plank, set the speed of rise and fall to be 2-3cm/s.By the top of wooden handle
Decline is put in dip tank, treats that wooden handle is all dipped in dip tank, then static 3s rises, after wooden handle all leaves dip tank,
Plank is removed, quickly turned, plank is placed on Auto-reversal Machine's after placing 30s, after upset 6min, first of dip-coating
Construction is completed.Wooden handle room temperature is placed after 4h, construction is repeated once as stated above, then room temperature places 4h, second dip-coating is applied
Work is completed.Wooden handle room temperature is placed after 4h, construction is repeated once as stated above, then room temperature places 4h, the 3rd road dip application
Complete.Dip-coating after the construction of three roads, can reach the road of solvent based coating three construction identical with waterborne woodware high-gloss clear paint
Surface effect.
Embodiment 2
A kind of dip-coating waterborne woodware high-gloss clear paint, the difference with embodiment 1 is, by weight percentage by following components group
Into：Water-borne Self-Crosslinked Acrylic emulsion 45%, aqueous aliphatic polyurethane dispersion 40%, deionized water 10%, defoamer 0.5%,
Propandiol butyl ether 2%, anti-settling agent 2%, ground wetting agent 0.4%, thickener 0.1%.
Embodiment 3
A kind of dip-coating waterborne woodware high-gloss clear paint, the difference with embodiment 1 is, by weight percentage by following components group
Into：Water-borne Self-Crosslinked Acrylic emulsion 40%, aqueous aliphatic polyurethane dispersion 42%, deionized water 10.3%, defoamer
0.1%, propandiol butyl ether 3%, anti-settling agent 4%, ground wetting agent 0.1%, thickener 0.5%.
Embodiment 4
A kind of dip-coating waterborne woodware high-gloss clear paint, the difference with embodiment 1 is, by weight percentage by following components group
Into：Water-borne Self-Crosslinked Acrylic emulsion 43.8%, aqueous aliphatic polyurethane dispersion 35%, deionized water 13%, defoamer
0.5%, propandiol butyl ether 3%, anti-settling agent 4%, ground wetting agent 0.5%, thickener 0.2%.
Dip-coating of the present invention waterborne woodware high-gloss clear paint and existing market solvent based coating and other water of existing market
The property competing product performance comparison such as following table of woodcare paint：
Dip-coating of the present invention is with waterborne woodware high-gloss clear paint compared with solvent based coating, and drying time is identical, does not influence efficiency of construction,
And VOC content is substantially reduced, the harm to workman and environment is reduced, and water paint is not non-ignitable quick-fried, and the security of construction is carried
It is high.
And the competing product of other aqueous woodware paints, because VOC content is high, paint film surface drying and to do solid work the time longer, it is impossible to meet
The requirement of curstomer's site dip application is without applying.
Claims (9)
1. a kind of dip-coating waterborne woodware high-gloss clear paint, it is characterised in that：It is composed of the following components by weight percentage：It is aqueous from
Crosslinking acrylic acid emulsion 35-45%, aqueous aliphatic polyurethane dispersion 35-45%, deionized water 10-15%, defoamer 0.1-
0.5%, propandiol butyl ether 1-3%, anti-settling agent 2-4%, ground wetting agent 0.1-0.5%, thickener 0.1-0.5%；
The MFFT of the water-borne Self-Crosslinked Acrylic emulsion is 31 DEG C.
2. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 1, it is characterised in that the waterborne self-crosslinkable
Acrylic emulsion is the NeoCryl XK-12 of Dutch DSM DSM N. V..
3. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 1, it is characterised in that the aqueous aliphatic
Dispersions of polyurethanes is the NeoRez R-2180 of Dutch DSM DSM N. V..
4. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 1, it is characterised in that the anti-settling agent is poly-
Acid amides sodium ammonium salt.
5. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 4, it is characterised in that the anti-settling agent is day
The AQH-800 of this Supreme Being Si Balong DISPARLON companies.
6. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 1, it is characterised in that the thickener is non-
Ionic polyurethanes thickener.
7. a kind of dip-coating waterborne woodware high-gloss clear paint according to claim 6, it is characterised in that the thickener is
Borchi Gel 0625。
8. a kind of dip-coating as described in claim any one of 1-7 preparation method of waterborne woodware high-gloss clear paint, its feature exists
In comprising the following steps：Water-borne Self-Crosslinked Acrylic emulsion is added in paint mixing tank, aqueous aliphatic poly is added under stirring
Urethane dispersion, defoamer, deionized water, propandiol butyl ether, anti-settling agent, ground wetting agent and thickener, disperse, that is, leaching is made
Painting waterborne woodware high-gloss clear paint.
9. a kind of dip-coating according to claim 8 preparation method of waterborne woodware high-gloss clear paint, it is characterised in that including
Following steps：Water-borne Self-Crosslinked Acrylic emulsion is added in paint mixing tank, water is sequentially added under 400-500r/min stirrings
Property aliphatic polyurethane dispersion, defoamer, deionized water, propandiol butyl ether, anti-settling agent, ground wetting agent and thickener, point
20-30min is dissipated, that is, dip-coating waterborne woodware high-gloss clear paint is made.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710097605.0A CN106957572A (en) | 2017-02-22 | 2017-02-22 | A kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710097605.0A CN106957572A (en) | 2017-02-22 | 2017-02-22 | A kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof |
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| CN201710097605.0A Pending CN106957572A (en) | 2017-02-22 | 2017-02-22 | A kind of dip-coating waterborne woodware high-gloss clear paint and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298910A (en) * | 2017-07-20 | 2017-10-27 | 合肥科天水性科技有限责任公司 | A kind of universal aqueous wooden ware colored varnish in bottom surface and preparation method thereof |
| CN107699083A (en) * | 2017-11-06 | 2018-02-16 | 江门市新合盛涂料实业有限公司 | A kind of bamboo stick waterborne dip paint and its preparation and dip-coating method |
| CN107841222A (en) * | 2017-11-21 | 2018-03-27 | 广东华兹卜新材料科技有限公司 | A kind of self-crosslinking aqueous wood lacquer emulsion and its synthetic method |
| CN109251649A (en) * | 2018-09-06 | 2019-01-22 | 中航百慕新材料技术工程股份有限公司 | A kind of UV-curable waterborne woodenware priming paint |
| CN109666352A (en) * | 2018-11-22 | 2019-04-23 | 河北晨阳工贸集团有限公司 | A kind of water paint and preparation method thereof for door and window |
| CN112358777A (en) * | 2020-09-28 | 2021-02-12 | 湖南松井新材料股份有限公司 | Water-based PU self-drying erasable protective coating and preparation method and application thereof |
| CN114292555A (en) * | 2021-12-31 | 2022-04-08 | 珠海展辰新材料股份有限公司 | Water-based woodenware coating, preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051096A (en) * | 2009-11-05 | 2011-05-11 | 紫荆花制漆(上海)有限公司 | Environmentally-friendly high-performance water-based woodware paint and using method thereof |
| CN105694691A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | A preparing method of mono-component waterborne polyurethane fully-matte highly-wear-resistant floor paint |
-
2017
- 2017-02-22 CN CN201710097605.0A patent/CN106957572A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051096A (en) * | 2009-11-05 | 2011-05-11 | 紫荆花制漆(上海)有限公司 | Environmentally-friendly high-performance water-based woodware paint and using method thereof |
| CN105694691A (en) * | 2014-11-27 | 2016-06-22 | 合众（佛山）化工有限公司 | A preparing method of mono-component waterborne polyurethane fully-matte highly-wear-resistant floor paint |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107298910A (en) * | 2017-07-20 | 2017-10-27 | 合肥科天水性科技有限责任公司 | A kind of universal aqueous wooden ware colored varnish in bottom surface and preparation method thereof |
| CN107699083A (en) * | 2017-11-06 | 2018-02-16 | 江门市新合盛涂料实业有限公司 | A kind of bamboo stick waterborne dip paint and its preparation and dip-coating method |
| CN107841222A (en) * | 2017-11-21 | 2018-03-27 | 广东华兹卜新材料科技有限公司 | A kind of self-crosslinking aqueous wood lacquer emulsion and its synthetic method |
| CN109251649A (en) * | 2018-09-06 | 2019-01-22 | 中航百慕新材料技术工程股份有限公司 | A kind of UV-curable waterborne woodenware priming paint |
| CN109251649B (en) * | 2018-09-06 | 2021-03-30 | 中航百慕新材料技术工程股份有限公司 | Water-based ultraviolet-curing wood primer |
| CN109666352A (en) * | 2018-11-22 | 2019-04-23 | 河北晨阳工贸集团有限公司 | A kind of water paint and preparation method thereof for door and window |
| CN112358777A (en) * | 2020-09-28 | 2021-02-12 | 湖南松井新材料股份有限公司 | Water-based PU self-drying erasable protective coating and preparation method and application thereof |
| CN114292555A (en) * | 2021-12-31 | 2022-04-08 | 珠海展辰新材料股份有限公司 | Water-based woodenware coating, preparation method and application |
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Application publication date: 20170718 |