CN102676009A - Anionic ecological multicolour paint and preparation method thereof - Google Patents
Anionic ecological multicolour paint and preparation method thereof Download PDFInfo
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- CN102676009A CN102676009A CN2012101973818A CN201210197381A CN102676009A CN 102676009 A CN102676009 A CN 102676009A CN 2012101973818 A CN2012101973818 A CN 2012101973818A CN 201210197381 A CN201210197381 A CN 201210197381A CN 102676009 A CN102676009 A CN 102676009A
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Abstract
The invention particularly relates to an anionic ecological multicolour paint and a preparation method thereof. The anionic ecological multicolour paint is a composition prepared from the following raw materials in parts by weight: 40-60 parts of nano-acrylic emulsion, 5-15 parts of pearl powder, 5-15 parts of 3% hydroxyethylcellulose, 0.1-0.5 parts of anionic additive, 0.1-1 part of dispersing agent, 0.1-0.5 parts of defoaming agent, 0.1-0.5 parts of surfactant, 0.1-0.5 parts of bactericide, 0.1-0.5 parts of functional additive, 0.1-0.5 parts of mildewcide, 1-5 parts of antifreezing agent, 1-5 parts of film-forming additive, 0.1-0.5 parts of thickening agent, and 20-30 parts of deionized water. The anionic ecological multicolour paint disclosed by the invention has the functions of reducing the contents of VOC (volatile organic compounds) and heavy metals, statically and continuously releasing 3200 anions per cubic metre, removing harmful gases such as formaldehyde, ammonia and benzene, resisting and inhibiting bacteria, and the like; and the anionic ecological multicolour paint is colourful, environmentally-friendly, and low in pollution index.
Description
Technical field
The present invention relates to coating and make the field, be specifically related to a kind of anion ecological illusion-colour lacquer and preparation method thereof.
Background technology
The overwhelming majority times are spent indoor in the human life, therefore, the saying of narrow sense, indoor environment to people's the live and work quality and the public's healthy influence considerably beyond outdoor environment.Current; Because energy shortage, the building energy conservation measure has generally been taked in countries in the world, reduces the Air conditioner air exchange number of times; Indoor shelter quality is significantly worsened, and obnoxious flavoures such as the formaldehyde that indoor decorating material and furniture discharge, benzene series thing, ammonia have all had a strong impact on people's health.Negative aeroion is the aerial electronegative minuteness particle that swims, and the content of human habitat negative ion is directly related with the HUMAN HEALTH level, ought judge the important indicator of environment and Air quality of negative aeroion.
In recent decades, trade sales coating has obtained widespread use in interior exterior wall, mainly contains the reason of following several respects, and the one, economic aspect adopts coating more than glass or metal curtain wall, TERRAZZO, material of construction such as wallpaper are cheap and convenient; The 2nd, coating wide in variety has advantages such as durable, anti-pollution, easy construction, can satisfy the needs of different building decorations; The 3rd, good decorating effect, bright-coloured lucid and lively with the interior wall rich color of coatings decoration, and can be according to people's hobby, conversion color after use for some time keeps indoor feeling of freshness; The 4th, coating light weight safety, and can the waterproof mildew-resistant compare with other finishing material, have more protectiveness, security.Traditional solvent based coating brings pollution owing to contain organic solvent to environment, and the infringement people's is healthy, and the environmental friendliness coating of development of new is following coating development trend.
Summary of the invention
For overcoming the defective of prior art; The object of the present invention is to provide a kind of anion ecological illusion-colour lacquer; Have reduce VOC and heavy metal content, static continuing discharges negative ion, dispels functions such as obnoxious flavoures such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic, not only rich color and environmental protection, pollution index are low.
Another object of the present invention is to provide a kind of preparation method of anion ecological illusion-colour lacquer, simple to operate, can widespread use.
The technical scheme that is adopted for the present invention of realization above-mentioned purpose is following:
A kind of anion ecological illusion-colour lacquer, it is the compsn of processing in order to the following component of weight part meter:
In the preferred scheme, anion ecological illusion-colour lacquer of the present invention is below the weight part meter
The compsn that component is processed:
Anionic additive described in the present invention is that granularity is the tourmaline powder of 50-200nm.
Said nanometer ACRYLIC EMULSION is that the model that French Arkema produces is the emulsion of SNAP720; Dispersion agent is that the model that Japanese Sheng Nuopuke company produces is the ammonium polyacrylate salt of SN-5027; Skimmer is that the model that Japanese Sheng Nuopuke company produces is a SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-certain herbaceous plants with big flowers alkynes-4,7-glycol; Sterilant is a first chloro plug azoles quinoline ketone; Functional agent is that the model of Dow Chemical production is the multi-functional ammonium auxiliary agent of AMP-95; Mould inhibitor is that the model that German Shu Mei ltd produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is that the model that French high Supreme Being Si company produces is the polyurethanes thickening material of COAPUR2025.
Frostproofer described in the present invention is a terepthaloyl moietie.
The SNAP720 emulsion that the present invention selected for use has nucleocapsid structure, and its solid content is 49.0% (mass percent), viscosity＜500cp; The pH value is 7.0, and minimum film-forming temperature is 0 ℃, and particle diameter is 0.08 μ m; Latex general volatile VOC is 5.0g/L, therefore adopts the anion ecological illusion-colour lacquer of this emulsion to have advantages such as fine and smooth, that viscosity is low, and free formaldehyde content is low; And after the film forming, have good gloss, snappiness, resistance to bond and water-repellancy.
The SN-5027 ammonium polyacrylate salt that the present invention adopted has low mill base viscosity, can improve the characteristics such as stability in storage, increase gloss and leveling characteristics of coating; The water resistant type dispersion agent dispersion effect that the dispersiveness of dispersion agent 5027 is more general is good, thereby consumption is low, can effectively improve the water tolerance of paint film, is specially adapted to the paint film of high gloss.
The SN154 skimmer that the present invention adopted is the silicon-dioxide defoamer, has good lasting froth breaking ability, can prevent for a long time that coating from bubbling, and has the good bubble ability that presses down, and is difficult for producing shrinkage cavity; The no disadvantage, attractive in appearance of filming, its toning property influence to coating is little.
The COASOL film coalescence aid that the present invention adopted is the mixture of diisobutyl SUMATRIPTAN SUCCINATE, diisobutyl glutarate and diisobutyl penta adipic acid ester, wherein by massfraction diisobutyl SUMATRIPTAN SUCCINATE 15-25%, diisobutyl glutarate 55-65%, diisobutyl penta adipic acid ester 10-25%; The COASOL film coalescence aid has zero VOC, extremely low smell and good stability to hydrolysis; Therefore, it has more complete hard ionomeric and hydrophobicity with respect to other film coalescence aid, and it can effectively reduce just surface tension in water-based system, and the more performance of the reduction MFFT of excellence is provided; Make that smell in the system is lower, toxicity is lower, and have low bubble property.
The COAPUR2025 thickening material that the present invention adopted is solvent-free and does not contain the polyurethane associative thickener of APE.
A kind of preparation method of anion ecological illusion-colour lacquer may further comprise the steps:
(1) deionized water is joined in the retort that has dispersion machine, start dispersion machine;
(2) when stirring, in order dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in the retort, stir into the dispersion liquid of homogeneous;
(3) improve stirring velocity then, the reacting by heating jar is to 40-60 ℃, adds skimmer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol more in order, and dispersed with stirring is even;
(4) add thickening material, anionic additive at last in order, stirred 10-20 minute.
In order to stir, in above-mentioned preparing method's the step (2), the speed of stirring is 400-500 commentaries on classics/min, and churning time is 5-10 minute.
In order further to reach the dispersive effect, prevent that pearl powder from living in the emulsion knot grain, above-mentioned preparing method's step is increased to 1000-1200 commentaries on classics/min with stirring velocity in (3), and churning time is 10-20 minute.
Beneficial effect of the present invention is: anion ecological illusion-colour of the present invention lacquer has the VOC of reduction and heavy metal content, staticly continues to discharge negative ion and reach 3200/m
3, dispel functions such as obnoxious flavoures such as formaldehyde, ammonia, benzene, antibacterial bacteriostatic, not only rich color and environmental protection, pollution index are low.The preparation method of anion ecological illusion-colour lacquer provided by the invention is simple to operation, can realize widespread use.
Embodiment below in conjunction with concrete is done further explain to the present invention.
Embodiment
It below is specific embodiment of the present invention.
The preparation method of anion ecological illusion-colour lacquer of the present invention may further comprise the steps:
(1) deionized water is joined in the retort that has dispersion machine, start dispersion machine;
(2) when stirring, in order dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in the retort, stir into the dispersion liquid of homogeneous;
(3) improve stirring velocity then, the reacting by heating jar is to 40-60 ℃, adds skimmer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol more in order, and dispersed with stirring is even;
(4) add thickening material, anionic additive at last in order, stirred 10-20 minute.
Among the following embodiment, mentioned nanometer ACRYLIC EMULSION is that the model that French Arkema produces is the emulsion of SNAP720; Dispersion agent is that the model that Japanese Sheng Nuopuke company produces is the ammonium polyacrylate salt of SN-5027; Skimmer is that the model that Japanese Sheng Nuopuke company produces is a SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-certain herbaceous plants with big flowers alkynes-4,7-glycol; Sterilant is a first chloro plug azoles quinoline ketone; Functional agent is that the model of Dow Chemical production is the multi-functional ammonium auxiliary agent of AMP-95; Mould inhibitor is that the model that German Shu Mei ltd produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is that the model that French high Supreme Being Si company produces is the polyurethanes thickening material of COAPUR2025.
Embodiment 1
A kind of anion ecological illusion-colour lacquer is made up of the following component in weight part: 40 parts of nanometer ACRYLIC EMULSIONs, 5 parts of pearl powders, 5 parts of 3% Mierocrystalline celluloses; 0.1 part of anionic additive, 0.1 part of dispersion agent, 0.1 part of skimmer, 0.1 part in tensio-active agent; 0.1 part in sterilant, 0.1 part of functional agent, 0.1 part of mould inhibitor; 1 part of frostproofer, 1 part of film coalescence aid, 0.1 part of thickening material, 20 parts of deionized waters; And process according to the above-mentioned preparation method of the present invention; Wherein in the step (2), the speed of stirring is 400 commentaries on classics/min, and churning time is 10 minutes, and step is increased to 1200 commentaries on classics/min with stirring velocity in (3), and churning time is 10 minutes.
Embodiment 2
A kind of anion ecological illusion-colour lacquer is made up of the following component in weight part: 50 parts of nanometer ACRYLIC EMULSIONs, 10 parts of pearl powders, 10 parts of 3% Mierocrystalline celluloses; 0.5 part of anionic additive, 0.6 part of dispersion agent, 0.2 part of skimmer, 0.1 part in tensio-active agent; 0.15 part in sterilant, 0.1 part of functional agent, 0.3 part of mould inhibitor; 2 parts of frostproofers, 2.4 parts of film coalescence aid, 0.3 part of thickening material, 23 parts of deionized waters; And process according to the above-mentioned preparation method of the present invention; Wherein in the step (2), the speed of stirring is 500 commentaries on classics/min, and churning time is 5 minutes, and step is increased to 1200 commentaries on classics/min with stirring velocity in (3), and churning time is 10 minutes.
Embodiment 3
A kind of anion ecological illusion-colour lacquer is made up of the following component in weight part: 60 parts of nanometer ACRYLIC EMULSIONs, 15 parts of pearl powders, 15 parts of 3% Mierocrystalline celluloses; 0.5 part of anionic additive, 1 part of dispersion agent, 0.5 part of skimmer, 0.5 part in tensio-active agent; 0.5 part in sterilant, 0.5 part of functional agent, 0.5 part of mould inhibitor; 5 parts of frostproofers, 5 parts of film coalescence aid, 0.5 part of thickening material, 30 parts of deionized waters; And process according to the above-mentioned preparation method of the present invention; Wherein in the step (2), the speed of stirring is 400 commentaries on classics/min, and churning time is 10 minutes, and step is increased to 1000 commentaries on classics/min with stirring velocity in (3), and churning time is 20 minutes.
Performance Detection:
The anion ecological illusion-colour lacquer of embodiment of the invention 1-3 preparation is 3200/m through the negative ion that detects its release
3More than, and according to the performance of GB/T 9756-2001 standard and GB18582-2001 standard detection anion ecological illusion-colour lacquer, PI is seen table 1 and table 2:
Table 1: according to the data of GB/T 9756-2001 detection
Table 2: according to the data of GB18582-2001 detection
Above-mentioned embodiment is merely preferred implementation of the present invention; Can not limit the scope of the present invention's protection with this, the variation of any unsubstantiality that those skilled in the art is done on basis of the present invention and replacement all belong to the present invention's scope required for protection.
Claims (8)
1. an anion ecological illusion-colour coats with lacquer, and it is characterized in that it is the compsn of processing in order to the following component of weight part meter:
Nanometer ACRYLIC EMULSION 40-60 part,
Pearl powder 5-15 part,
3% Natvosol 5-15 part,
Anionic additive 0.1-0.5 part,
Dispersion agent 0.1-1 part,
Skimmer 0.1-0.5 part,
Tensio-active agent 0.1-0.5 part,
Sterilant 0.1-0.5 part,
Functional agent 0.1-0.5 part,
Mould inhibitor 0.1-0.5 part,
Frostproofer 1-5 part,
Film coalescence aid 1-5 part,
Thickening material 0.1-0.5 part,
Deionized water 20-30 part.
2. anion ecological illusion-colour lacquer according to claim 1 is characterized in that it is to process compsn in order to the following component of weight part meter:
50 parts of nanometer ACRYLIC EMULSIONs,
10 parts of pearl powders,
10 parts of 3% Mierocrystalline celluloses,
0.1 part of anionic additive,
0.6 part of dispersion agent,
0.2 part of skimmer,
0.1 part in tensio-active agent,
0.15 part in sterilant,
0.1 part of functional agent,
0.3 part of mould inhibitor,
2 parts of frostproofers,
2.4 parts of film coalescence aid,
0.3 part of thickening material,
23 parts of deionized waters.
3. anion ecological illusion-colour lacquer according to claim 1 and 2, it is characterized in that: said anionic additive is that granularity is the tourmaline powder of 50-200nm.
4. anion ecological illusion-colour lacquer according to claim 3 is characterized in that: said nanometer ACRYLIC EMULSION is that the model that French Arkema produces is the emulsion of SNAP720; Dispersion agent is that the model that Japanese Sheng Nuopuke company produces is the ammonium polyacrylate salt of SN-5027; Skimmer is that the model that Japanese Sheng Nuopuke company produces is a SN154 silicon-dioxide defoamer; Tensio-active agent is 2,4,7,9-tetramethyl--5-certain herbaceous plants with big flowers alkynes-4,7-glycol; Sterilant is a first chloro plug azoles quinoline ketone; Functional agent is that the model of Dow Chemical production is the multi-functional ammonium auxiliary agent of AMP-95; Mould inhibitor is that the model that German Shu Mei ltd produces is the mould inhibitor of Parmetol DF 19 forte; Film coalescence aid is the COASOL film coalescence aid that Dow Chemical produces; Thickening material is that the model that French high Supreme Being Si company produces is the polyurethanes thickening material of COAPUR2025.
5. anion ecological illusion-colour lacquer according to claim 3, it is characterized in that: said frostproofer is a terepthaloyl moietie.
6. like the preparation method of claim 1,2,4 or 5 described anion ecological illusion-colour lacquers, it is characterized in that it may further comprise the steps:
(1) deionized water is joined in the retort that has dispersion machine, start dispersion machine;
(2) when stirring, in order dispersion agent, tensio-active agent, sterilant, functional agent, mould inhibitor, frostproofer, film coalescence aid are joined in the retort, stir into the dispersion liquid of homogeneous;
(3) improve stirring velocity then, the reacting by heating jar is to 40-60 ℃, adds skimmer, nanometer ACRYLIC EMULSION, pearl powder, 3% Natvosol more in order, and dispersed with stirring is even;
(4) add thickening material, anionic additive at last in order, stirred 10-20 minute.
7. the preparation method of anion ecological illusion-colour lacquer according to claim 6, it is characterized in that: in the step (2), the speed of stirring is 400-500 commentaries on classics/min, and churning time is 5-10 minute.
8. the preparation method of anion ecological illusion-colour lacquer according to claim 6, it is characterized in that: step is increased to 1000-1200 commentaries on classics/min with stirring velocity in (3), and churning time is 10-20 minute.
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| CN201210197381.8A CN102676009B (en) | 2012-06-14 | 2012-06-14 | Anionic ecological multicolour paint and preparation method thereof |
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| CN201210197381.8A CN102676009B (en) | 2012-06-14 | 2012-06-14 | Anionic ecological multicolour paint and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI547530B (en) * | 2015-10-28 | 2016-09-01 | Zhang Zhou San De Li Paints Co Ltd | Nano - Anion Functional Interior Interior Latex Paint and Its Preparation |
| CN106634252A (en) * | 2016-11-16 | 2017-05-10 | 常州市坤建筑材料有限公司 | Preparation method of coating with super stain resistance and colorful effect and using method thereof |
| CN106867336A (en) * | 2017-03-29 | 2017-06-20 | 崔玉香 | A kind of negative oxygen glory paint and preparation method thereof |
| CN107629555A (en) * | 2017-11-08 | 2018-01-26 | 重庆市龙凤工艺品有限公司 | A kind of non-toxic unreal colour paint for Wood craft surface treatment |
| CN111151228A (en) * | 2019-12-25 | 2020-05-15 | 天津米一科技有限公司 | Industrial workshop moisture-proof and pollutant adsorbing material and preparation method thereof |
| CN114989684A (en) * | 2022-05-26 | 2022-09-02 | 广西北海隆万科技有限公司 | Ecological pearl coating capable of releasing negative oxygen ions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5430083A (en) * | 1990-05-26 | 1995-07-04 | Basf Lacke & Farben Aktiengesellschaft | Paints and use of these paints as topcoats for the finishing of automobile bodies |
| CN1900187A (en) * | 2006-07-06 | 2007-01-24 | 北京中化科城技术研究所 | Environment friendly emulsion paint |
-
2012
- 2012-06-14 CN CN201210197381.8A patent/CN102676009B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5430083A (en) * | 1990-05-26 | 1995-07-04 | Basf Lacke & Farben Aktiengesellschaft | Paints and use of these paints as topcoats for the finishing of automobile bodies |
| CN1900187A (en) * | 2006-07-06 | 2007-01-24 | 北京中化科城技术研究所 | Environment friendly emulsion paint |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI547530B (en) * | 2015-10-28 | 2016-09-01 | Zhang Zhou San De Li Paints Co Ltd | Nano - Anion Functional Interior Interior Latex Paint and Its Preparation |
| CN106634252A (en) * | 2016-11-16 | 2017-05-10 | 常州市坤建筑材料有限公司 | Preparation method of coating with super stain resistance and colorful effect and using method thereof |
| CN106867336A (en) * | 2017-03-29 | 2017-06-20 | 崔玉香 | A kind of negative oxygen glory paint and preparation method thereof |
| CN107629555A (en) * | 2017-11-08 | 2018-01-26 | 重庆市龙凤工艺品有限公司 | A kind of non-toxic unreal colour paint for Wood craft surface treatment |
| CN111151228A (en) * | 2019-12-25 | 2020-05-15 | 天津米一科技有限公司 | Industrial workshop moisture-proof and pollutant adsorbing material and preparation method thereof |
| CN114989684A (en) * | 2022-05-26 | 2022-09-02 | 广西北海隆万科技有限公司 | Ecological pearl coating capable of releasing negative oxygen ions |
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| Publication number | Publication date |
|---|---|
| CN102676009B (en) | 2014-07-09 |
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Denomination of invention: Anionic ecological multicolour paint and preparation method thereof Effective date of registration: 20150316 Granted publication date: 20140709 Pledgee: Bank of China, Limited by Share Ltd, Guangzhou, Zengcheng branch Pledgor: Guangzhou Futian Chemical Industry Paint Co., Ltd. Registration number: 2015990000195 |
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