CN106867336A - A kind of negative oxygen glory paint and preparation method thereof - Google Patents
A kind of negative oxygen glory paint and preparation method thereof Download PDFInfo
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- CN106867336A CN106867336A CN201710196596.0A CN201710196596A CN106867336A CN 106867336 A CN106867336 A CN 106867336A CN 201710196596 A CN201710196596 A CN 201710196596A CN 106867336 A CN106867336 A CN 106867336A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
A kind of negative oxygen glory paint and preparation method thereof, is related to art paint technical field.The raw material of negative oxygen glory paint includes：Acrylate and vinyl acetate emulsion, pure-acrylic emulsion, alumina powder, clay, surfactant, diatomite, sepiolite powder, montmorillonite powder, linseed oil, deionized water, APM 95, gloss additive and negative oxygen ion powder.Preparation method includes pre-treatment step and batch mixing step.Pre-treatment step includes for sepiolite powder mixing to obtain mixed powder with montmorillonite powder, to mixed powder plus portions of de-ionized water, part APM 95, part surface activating agent, whole alumina powders and whole clays, stirs 5~15min, obtains the first intermediate.Batch mixing step includes being added to the first intermediate the remainder of raw material, stirs 5~20min.The method is easy to operate, and prepared above-mentioned negative oxygen glory paint good stability, color and luster is difficult to go down, paint film quality better, sustainable releasing negative oxygen ion.
Description
Technical field
The present invention relates to art paint technical field, in particular to a kind of negative oxygen glory paint and preparation method thereof.
Background technology
Art paint can be coated in wall surface with different construction technologies, formed adhesion firmly, with some strength, even
Continuous solid film, as paint film.Art paint not only has to be protected, decorates, covering up the effect such as defect, and with unique texture matter
Sense and plastic relief sense, go back and can build simple, fashion, elegance, wealth and rank, magnificent high-grade visual effect.Art paint
These functions all substantially determine that the quality and stability of the paint film of formation directly determine artistic paint by its paint film for being formed
Quality.
The paint film strength of existing art paint can weaken rapidly with the extension of time, and film defect occurs.It is existing
Theoretical life-span of art paint be generally 10 years, but will start color depth occur at 3 years or so goes down, what gloss weakened
Problem, can also start film defect occur at 5 years or so, such as localized crackses, local shedding or hole etc. occur, and these are all needed
Continually paint film repaired halfway, improve the use cost of paint film, reduce experience.If do not repaired
Words, the actual life of paint film can be had a greatly reduced quality, and its visual effect can also be substantially reduced.Additionally, existing art paint
Typically only have and protect, decorate, covering up the effect such as defect, function limitation.
The content of the invention
It is an object of the invention to provide a kind of negative oxygen glory paint, the paint film stability that it is formed is good, and color stability is difficult
Go down, the problems such as being less prone to localized crackses, local shedding or hole occur, paint film quality better；The sustainable negative oxygen of release
Ion, improves indoor environment, improves human comfort.
Another object of the present invention is to provide a kind of preparation method of negative oxygen glory paint, its is easy to operate, prepared
The paint film stability that negative oxygen glory paint is formed is good, and color stability is not susceptible to go down, be less prone to localized crackses, local shedding or
The problems such as there is hole, paint film quality better；Sustainable releasing negative oxygen ion, improves indoor environment, improves human comfort.
What embodiments of the invention were realized in：
A kind of negative oxygen glory paint, its raw material includes by weight：60~80 parts of acrylate and vinyl acetate emulsion, pure the third of 7~13 parts
Emulsion, 4~8 parts of alumina powder, 2~5 parts of clay, 1~5 part of surfactant, 11~19 parts of diatomite, 4~8
The sepiolite powder, 2~6 parts of montmorillonite powder, 2~7 parts of linseed oil, 75~100 parts of deionized water, 0.5~2 of part
Part 2-amino-2-methyl-1-propanol, 5~30 parts of gloss additive and 5~30 parts of negative oxygen ion powder.Its paint for being formed
Membrane stability is good, and color stability is not susceptible to go down, the problems such as be less prone to localized crackses, local shedding or hole, paint film product
Matter is good.Sustainable releasing negative oxygen ion, improves indoor environment, improves human comfort.
A kind of preparation method of above-mentioned negative oxygen glory paint, it includes pre-treatment step and batch mixing step.
In pre-treatment step, sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixing
Powder add 20~35 parts of deionized waters, 0.1~0.2 part of 2-amino-2-methyl-1-propanol, 0.8~1.2 part of surfactant,
Whole alumina powders and whole clays, and 5~15min is stirred, obtain the first intermediate.
In batch mixing step, the remainder of raw material is added to the first intermediate, stir 5~20min.
Its is easy to operate, and the paint film stability that prepared negative oxygen glory paint is formed is good, and color stability is not susceptible to go down,
The problems such as being less prone to localized crackses, local shedding or hole occur, paint film quality better；Sustainable releasing negative oxygen ion, improves
Indoor environment, improves human comfort.
The beneficial effect of the embodiment of the present invention is：The paint film that negative oxygen glory paint provided in an embodiment of the present invention is formed it is uniform and
Good stability.Can guarantee that the uniform of moisture scatters and disappears in dry process, paint film each several part uniformity is good, and formed gloss of film is equal
Even, smooth, color stability is not susceptible to go down.Paint film stability is good, can largely reduce pin hole, foaming,
Lifting, from oil, loss of gloss and it is coarse situations such as generation, film integrity is good, and quality of forming film is high.Paint film has good intensity,
It is sun protection good and can high temperature resistance, disintegration is also less likely to occur in wet environment, the ageing resistace of paint film is notable.Additionally,
Paint film can improve indoor negative oxygen ion concentration with sustained release negative oxygen ion, improve indoor environment, improve human comfort.
Negative oxygen ion can be effectively improved the air quality of interior, can promote the decomposition of the pernicious gases such as formaldehyde, reduce respiratory tract disease
Disease, also has adjuvant treatment effect to cardiovascular and cerebrovascular and respiratory tract, is favorably improved fitness.
The preparation method of above-mentioned negative oxygen glory paint is simple and easy to apply, easily implements, and is not limited by place, and allotment is convenient.Institute
The paint film stability that the negative oxygen glory paint for preparing is formed is good, and color stability is not susceptible to go down, and is less prone to localized crackses, part
The problems such as coming off or hole occur, paint film quality better.Sustainable releasing negative oxygen ion, improves indoor environment, improves human comfort
Degree.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below will be in the embodiment of the present invention
Technical scheme be clearly and completely described.Unreceipted actual conditions person, builds according to normal condition or manufacturer in embodiment
The condition of view is carried out.Agents useful for same or the unreceipted production firm person of instrument, are the conventional product that can be obtained by commercially available purchase
Product.
Negative oxygen glory paint of the embodiment of the present invention and preparation method thereof is specifically described below.
A kind of negative oxygen glory paint provided in an embodiment of the present invention, its raw material includes by weight：60~80 parts of vinegar third
Emulsion, 7~13 parts of pure-acrylic emulsion, 4~8 parts of alumina powder, 2~5 parts of clay, 1~5 part of surfactant, 11
~19 parts of diatomite, 4~8 parts of sepiolite powder, 2~6 parts of montmorillonite powder, 2~7 parts of linseed oil, 75~100
The deionized water, 0.5~2 part of 2-amino-2-methyl-1-propanol of part are (hereinafter referred to as：APM-95), 5~30 parts of gloss adds
Plus agent and 5~30 parts of negative oxygen ion powder.
The paint film that negative oxygen glory paint provided in an embodiment of the present invention is formed is uniform and good stability.Formed gloss of film is equal
Even, smooth, color stability is not susceptible to go down.Paint film stability is good, and quality of forming film is high.Additionally, paint film can also continue
Releasing negative oxygen ion, improves indoor negative oxygen ion concentration, improves indoor environment, improves human comfort.Negative oxygen ion can have
Effect improves indoor air quality, can promote the decomposition of the pernicious gases such as formaldehyde, reduces breathing problem, to cardiovascular and cerebrovascular and
Respiratory tract also has adjuvant treatment effect, is favorably improved fitness.
Wherein, acrylate and vinyl acetate emulsion is used as film forming matter.Acrylate and vinyl acetate emulsion particle diameter is thin, gloss is high；Water-tolerant, hardness are big, anti-scratch
Wash；Film-forming temperature is low, and film forming speed is fast, and paint film is fine and smooth, flat smooth, good decorating effect.
Pure-acrylic emulsion can effectively improve gloss, weatherability and the anti-after tack of negative oxygen glory paint.
Gloss additive is bronze or pearl powder.Gloss additive can provide high glaze for negative oxygen glory paint.
Alumina powder, both clays are used cooperatively with surfactant, both APM-95, surfactant and APM-95
Alumina powder and clay can be made fully dispersed and contribute to alumina powder and the particle of clay to be sufficiently mixed.Negative
In oxygen glory paint system, alumina powder and clay play a part of important stirring, dispersion and grind, in negative oxygen glory paint
In mixed process, the activity of alumina powder and clay particle, aluminum oxide can be improved due to surfactant and APM-95
Powder has significant abrasive action to negative oxygen glory paint system, can effectively prevent local caking or a certain component at certain
Occur localized clusters at one, be conducive to the fully dispersed of each component and mix, be conducive to improving each inside negative oxygen glory paint
The uniformity of individual component distribution and the uniformity of formed paint film.
Additionally, clay hardness is low, in the mixing process of negative oxygen glory paint, clay is easier by alumina powder
Abrasive action and turn into the smaller clay particle of particle, in the presence of surfactant and APM-95, clay particle mobility
Improve, when being ground in alumina powder foot couple each component, mixing or be ground broken to the part of caking, clay particle
Micropore or the gap ground or stirred by alumina powder and produced can be quickly entered, due to clay particle good fluidity, friction
Power is small and can improve surfactant and APM-95 to above-mentioned micropore or the wetting effect in gap, can effectively prevent above-mentioned
Micropore or gap close, may advantageously facilitate the part lumpd and each component be disintegrated and fully dispersed.Fill
It is full of by alumina powder, clay, surfactant and APM-95, therefore between each component not between point scattered each component
Easily there is agglomerate or caking again again.
Alumina powder, clay, surfactant and APM-95 substantially increase negative oxygen glory paint system mobility,
Even property and dispersiveness, while ensure that the stability of whole dispersion.Surfactant and APM-95 are used cooperatively simultaneously
Negative oxygen glory paint system can be made has preferable mobility and dispersiveness, while avoid the generation of air bubble, can be with
Prevent from causing painting quality to decline due to having air bubble in negative oxygen glory paint.Can so greatly improve the uniformity of paint film with
And the uniformity that each component is distributed in paint film so that release of the paint film to negative oxygen ion becomes uniform, make indoor negative oxygen from
The supplement speed of son tends to uniform gentle, is conducive to keeping the balance of indoor negative oxygen ion concentration.Because painting quality is good, it is difficult
There is damaged and defect, also cause that the release of negative oxygen ion is not easy rapid decay.
If paint film a large amount of crackles occurs or breakage occurs, paint film will be made to increase with the contact area of air, negative oxygen ion is released
Putting area can also increase, while the inside of paint film can also be exposed, the rate of release of negative oxygen ion will so cannot get
Control, in a short time, the rate of release of negative oxygen ion occur be widely varied and rate of release can rapid decay, it is unfavorable
In continual and steady releasing negative oxygen ion, do not have continual and steady effect to the improvement of room air yet.The embodiment of the present invention
The negative oxygen glory paint for providing can keep the integrality and stability of its paint film, and then ensure the steady of its negative oxygen ion release area
It is fixed, the rate of release of negative oxygen ion is maintained at a metastable scope, being capable of sustainedly and stably releasing negative oxygen ion.
Diatomite, sepiolite powder and montmorillonite powder three use cooperatively.Diatomite hardness is also smaller, oxidized aluminium powder
The peptizaiton of end, clay, surfactant and APM-95 etc. equally easily forms the smaller diatomite particle of particle, diatomite
Particle and clay particle can be mixed to form " double soil " system with ground, stirring." double soil " system can further strengthen clay
To above-mentioned micropore or the filling effect in gap, help further to improve the mobility of negative oxygen glory paint system, uniformity, divide
The stability of property and whole dispersion is dissipated, contributes to the further dispersion of negative oxygen ion powder, improve the equal of negative oxygen ion release
Even property, meanwhile, additionally aid the dispersion of gloss additive, it is ensured that the gloss of negative oxygen glory paint is uniformly natural.
The hardness of both sepiolite powder and montmorillonite powder is big compared with diatomaceous hardness, oxidized aluminium powder, clay, table
There is the particle bigger than diatomite particle and clay particle after the peptizaiton of face activating agent and APM-95 etc..Due to sepiolite
With water absorption character, can be absorbed water when running into water and become soft, and drying is then hardened, montmorillonite equally has water absorption character.
Water is absorbed when sepiolite and montmorillonite can around have water and is stored, water content is less than its internal water content around
When, just its internal water can be discharged again.
During the use of negative oxygen glory paint, before negative oxygen glory paint brushing, sepiolite powder and montmorillonite powder
It is well-dispersed in negative oxygen glory paint system.Now, due to being full of water, sepiolite powder and montmorillonite powder in negative oxygen glory paint system
End fully absorbs water and water is stored in inside it.After negative oxygen glory paint is painted, before paint film dries, each component is equal
It is even to be scattered in paint film.As paint film slowly dries, the water in paint film is fewer and feweri, when the water density in paint film is less than sepiolite
In powder and montmorillonite powder two during internal water density, sepiolite powder and montmorillonite powder start internal water to paint film
Release.
The inventors found that：In paint film water volatilization speed and whole paint film water volatilization uniformity with
Paint film whether occur pin hole, foaming, from oil, loss of gloss and it is coarse the problems such as have directly contact.When the water rate of volatilization in paint film
When too fast, the interface of paint film is very unstable, be susceptible to distortion even rupture, this will result directly in coating surface it is rough and
There is loss of gloss, can cause pin hole occur when serious, smearing can also leave slight crack after drying in coating surface, be susceptible to smearing
It is disintegrated and comes off.When the water rate of volatilization of whole paint film is uneven, i.e., there is larger water rate of volatilization on coating surface
Difference, particularly when diffusion rate of the water rate of volatilization difference more than paint film internal water, along the surface of paint film, it may appear that paint film is aqueous
The obvious difference of amount.Water rate of volatilization difference is more more than the diffusion rate of paint film internal water, and the difference of paint film water content is bigger,
Paint film is easier to the problems such as coarse and loss of gloss occur, and aqueous many parts are influenceed to be susceptible to certainly by surface tension in paint film
I assembles, and occurs, from oily phenomenon, foaming will being directly resulted in when serious.The speed and the water of whole paint film of the water volatilization in paint film
The uniformity of volatilization can all directly affect the quality of paint film.
In an embodiment of the present invention, both sepiolite powder and montmorillonite powder with diatomite particle and clay particle shape
Into " double soil " system constitute " water balance system ".When negative oxygen glory paint brushing is completed, in the dry process of paint film, Hai Pao
The inside of both stone powder and montmorillonite powder is each filled with water, and alumina powder is received both sepiolite powder and montmorillonite powder
And " double soil " system stirring, peptizaiton and be sufficiently mixed and be uniformly distributed in paint film.With the water in paint film slowly
Volatilization is scattered and disappeared, and the water density in paint film is gradually reduced, when the water density in paint film is less than sepiolite powder and montmorillonite powder two
During water density inside person, both sepiolite powder and montmorillonite powder start the water of respective inside towards discharging in paint film.
During water release, the water that " double soil " system is discharged to both sepiolite powder and montmorillonite powder has dispersion and homogenizes
Effect, i.e., both sepiolite powder and montmorillonite powder can the moisture of phase paint film release two pairs, water smearing suitably mended
Fill, the water that both sepiolite powder and montmorillonite powder are discharged can be disperseed rapidly and be made water in paint by " double soil " system
It is uniformly distributed in film.
" double soil " system can improve the uniformity of diffusion rate of the water in paint film and diffusion, and ensure by sepiolite powder
The water of end and the release of both montmorillonite powder can be uniform with rapid dispersion.On the one hand can utilize by sepiolite powder and montmorillonite
The water of both powder release is suitably supplemented the moisture smeared, and prevents paint film from fold occur because water volatilization is too fast, turning round
It is bent even to rupture, that is, prevent paint film pin hole or disintegration occur.On the other hand diffusion rate of the water in paint film is improved, makes paint film
In water can be evenly distributed rapidly, can effectively prevent smear cause paint film locally aqueous because water rate of volatilization is uneven
Amount has differences, that is, prevent paint film occur from oil, loss of gloss, it is coarse and foaming the problems such as." double soil " system can also be carried simultaneously
The anti-solarization ability and high-temperature resistance of paint film high.So substantially increase the quality of paint film.
Due to the effect of " water balance system ", paint film will not too fast also be not in too big in scattering and disappearing for dry process reclaimed water
Water content difference, can so ensure to be applied in dry process still has certain diffusivity, while with " water balance body
System " is medium, and the distribution of each component is more uniform more conducively in paint film, it is to avoid because scattering and disappearing for paint film reclaimed water will not be too fast or contains
There is larger difference and cause paint film various pieces component uneven in water, improve the uniformity and stabilization of paint film
Property.
Gloss additive can be stablized during paint film is formed during the above-mentioned characteristic of " water balance system " causes paint film
Uniformly it is present in paint film, will not occurs localized clusters because water can be sent out uneven in dry process because of paint film, effectively
The inequality of gloss is prevented to homogenize or part loss of gloss so that the gloss of paint film keeps high homogeneity.
Further, since its volume has certain increase, and Hai Pao after the water suction of both sepiolite powder and montmorillonite powder
Can be limbered up after stone powder water suction, and volume has certain diminution after both sepiolite powder and montmorillonite powder are dried, together
When sepiolite powder dry after can be hardened again.Using this characteristic, the thickness after paint film dries is less than the thickness before drying, this
Sample is conducive to brushing thinner paint film, improves the range of choice of the brushing thickness of paint film.On the other hand, after paint film makes moist, moisture
A part can be absorbed by sepiolite powder and montmorillonite powder, slow down paint film damp degree, after the water suction of sepiolite powder
Can soften, paint film has certain elastic allowance, the paint film for making moist is less likely to occur to be disintegrated or comes off.When paint film is by the state of making moist
When starting to dry, the water that sepiolite powder and montmorillonite powder will can absorb before is discharged, it is to avoid paint film is due to the shape that makes moist
Rapid translating between state and drying regime and be broken, the effect of protection paint film is served, while sepiolite powder is dried
After be hardened, paint film strength can recover.So substantially increase the moisture resistance of paint film.
For paint film, the larger factor of alignment color and luster influence includes：Humidity, illumination etc., particularly humidity.Due to
The balanced action of " water balance system ", in season alternation, particularly in dry and wet season alternation, when from dry season to rainy season transition
When or in rainy season, paint film is not easy to make moist, when from rainy season to dry season transition when, paint film is not easy weathering phenomenon occur.This
All be conducive to paint film to keep its brightness and gloss a bit, be not susceptible to color and luster and go down.On the other hand, when ambient humidity changes width
When spending larger, due to the balanced action of " water balance system ", paint film is not in rapid wet and rapid dry situation, and paint film is not easy hair
Raw cracking.It is equally beneficial for paint film and keeps its color and luster, and negative oxygen ion can be made more stably to discharge.
When paint film environment temperature is raised rapidly, the water in paint film further scatters and disappears, because the supplement of water balance system is put down
Weighing apparatus is acted on, and can prevent paint film from being ruptured due to rapid dry, can further improve the sun-proof and high-temperature resistance of paint film.Can
Effectively to mitigate influence of the illumination to paint film color and luster, paint film color and luster is conducive to keep permanent light.
Linseed oil can further improve the mobility and dispersiveness of " double soil " system, while being grinding for alumina powder
Mill effect is stronger, and before paint film dries, is conducive to keeping the stability at paint film interface, improves the intensity for smearing interface,
Be conducive to further preventing pin hole, foaming, from oil, loss of gloss, coarse and lifting the problems such as appearance.
Entirely each component of negative oxygen glory paint system dispersiveness, uniformity are good, and paint film stability is excellent, can be in very great Cheng
Reduced on degree and prevented pin hole, foaming, lifting, from oil, loss of gloss and it is coarse situations such as generation, film integrity is good, into film quality
Amount is high.Paint film has good intensity, it is sun protection good and can high temperature resistance, disintegration, paint are also less likely to occur in wet environment
The ageing resistace of film is notable.
It should be noted that in an embodiment of the present invention, surfactant is nonionic surfactant.For example：Fat
Fatty acid glyceride, fatty acid sorbitan, polysorbate etc., but not limited to this.
Preferably, in preferred embodiments of the present invention, the raw material of negative oxygen glory paint includes by weight：65~75
The acrylate and vinyl acetate emulsion, 9~12 parts of pure-acrylic emulsion, 5~7 parts of alumina powder, 3~4.5 parts of clay, 2~4 parts of surface of part
Activating agent, 14~19 parts of diatomite, 5~8 parts of sepiolite powder, 4~6 parts of montmorillonite powder, 3~5 parts of flaxseed
Oil, 80~90 parts of deionized water, 0.5~1 part of APM-95,10~25 parts of gloss additive and 10~25 parts of negative oxygen from
Sub- powder.It is further preferred that the raw material of negative oxygen glory paint includes by weight：68~72 parts of acrylate and vinyl acetate emulsion, 10~12 parts
Pure-acrylic emulsion, 5~7 parts of alumina powder, 3~4.5 parts of clay, 3~3.5 parts of surfactant, 15~17 parts
Diatomite, 6~7.5 parts of sepiolite powder, 5~5.5 parts of montmorillonite powder, 4~5 parts of linseed oil, 84~88 parts
Deionized water, 0.5~0.8 part of APM-95,15~25 parts of gloss additive and 15~25 parts of negative oxygen ion powder.
The performance that formed negative oxygen glory paint is matched more than is more excellent.
Preferably, in preferred embodiments of the present invention, alumina powder is -200 mesh of mesh~+325, and clay is -200
The mesh of mesh~+325.It is further preferred that alumina powder is -230 mesh of mesh~+325.It should be noted that with -200 mesh~+
As a example by the alumina powder of 325 mesh, the alumina powder in the particle size range can be obtained in the following manner：Make aluminum oxide
The mesh that powder first passes through 200 mesh is screened, and collection has passed through the alumina powder of mesh and made it again by 325 purposes
Mesh is screened, and is collected as being by the powder of mesh the alumina powder of -200 above-mentioned mesh of mesh~+325.Other particles
Or the preparation method of powder is similarly, but it is not limited only to this.
Preferably, in preferred embodiments of the present invention, diatomite be -200 mesh of mesh~+400, sepiolite powder for -
200 mesh of mesh~+400, montmorillonite powder is -200 mesh of mesh~+400.It is further preferred that diatomite is -270 mesh of mesh~+400,
Sepiolite powder is -270 mesh of mesh~+400, and montmorillonite powder is -270 mesh of mesh~+400.
Preferably, in preferred embodiments of the present invention, the parts by weight of sepiolite powder and both montmorillonite powder
Than being 1~1.5：1.
Embodiments of the invention also provide a kind of preparation method of above-mentioned negative oxygen glory paint, it include pre-treatment step and
Batch mixing step.
In pre-treatment step, sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixing
Powder adds 20~35 parts of deionized waters, 0.1~0.2 part of APM-95,0.8~1.2 part of surfactant, whole alumina powders
With whole clays, and 5~15min of stirring, the first intermediate is obtained.
Pre-treatment step can make sepiolite powder be absorbed water in advance with montmorillonite powder, prevent in negative oxygen glory paint batch mixing
Negative oxygen glory raw materials for varnish component is caused to wrap in sepiolite powder because sepiolite powder and montmorillonite powder absorb water in step
Or montmorillonite powder, it is ensured that sepiolite powder can normally play water balance function with both montmorillonite powder.Additionally, sepiolite
Powder has to the color of clay covers function, and sepiolite powder is mixed in advance with clay, can effectively prevent clay to light
The color and luster of damp additive produces influence, it is ensured that paint film has enough gloss and colourity.
In batch mixing step, the remainder of raw material is added to the first intermediate, stir 5~20min, obtain above-mentioned negative oxygen
Glory paint.
The preparation method of the negative oxygen glory paint is simple and easy to apply, easily implements, and is not limited by place, and allotment is convenient.It is prepared
Negative oxygen glory paint formed paint film stability it is good, color stability is not susceptible to go down, and is less prone to localized crackses, local shedding
Or the problems such as there is hole, paint film quality better；Sustainable releasing negative oxygen ion, improves indoor environment, improves human comfort.
Preferably, in preferred embodiments of the present invention, in pre-treatment step, to the deionization that mixed powder is added
Water is 25~30 parts, APM-95 is 0.1~0.15 part, surfactant is 0.8~1 part, and stirs 10~15min.In batch mixing
In step, 10~15min is stirred.
Feature of the invention and performance are described in further detail with reference to embodiments.
Embodiment 1
The present embodiment provides a kind of raw material of negative oxygen glory paint, and the raw material includes by weight：70 parts of acrylate and vinyl acetate emulsion,
10 parts of pure-acrylic emulsion, 6 parts of alumina powder, 3.5 parts of clay, 3 parts of surfactant, 15 parts of diatomite, 6 parts
Sepiolite powder, 5 parts of montmorillonite powder, 5 parts of linseed oil, 86 parts of deionized water, 0.8 part of APM-95,30 parts
Pearl powder and 25 parts of negative oxygen ion powder.
Embodiment 2
The present embodiment provides a kind of raw material of negative oxygen glory paint, and the raw material includes by weight：68 parts of acrylate and vinyl acetate emulsion,
11 parts of pure-acrylic emulsion, 5 parts of alumina powder, 3 parts of clay, 3.5 parts of surfactant, 17 parts of diatomite, 7 parts
Sepiolite powder, 5.5 parts of montmorillonite powder, 4.5 parts of linseed oil, 88 parts of deionized water, 0.6 part of APM-95,25
The pearl powder and 15 parts of negative oxygen ion powder of part.
Embodiment 3
The present embodiment provides a kind of raw material of negative oxygen glory paint, and the raw material includes by weight：72 parts of acrylate and vinyl acetate emulsion,
12 parts of pure-acrylic emulsion, 7 parts of alumina powder, 4.5 parts of clay, 3.5 parts of surfactant, 16 parts of diatomite, 7.5
Part sepiolite powder, 5.5 parts of montmorillonite powder, 4 parts of linseed oil, 84 parts of deionized water, 0.5 part of APM-95,
10 parts of pearl powder and 30 parts of negative oxygen ion powder.
Each component for the negative oxygen glory raw materials for varnish that embodiment 4~10 is provided is as shown in table 1 by weight：
Negative oxygen glory raw materials for varnish component and content (unit that 1 embodiment of table 4~10 is provided：Part)
It should be noted that in embodiment 1~4, alumina powder is -230 mesh of mesh~+325, clay be -200 mesh~
+ 325 mesh, diatomite, sepiolite and montmorillonite three are -270 mesh of mesh~+400.In embodiment 5~7, alumina powder
Be -200 mesh of mesh~+230, clay is -200 mesh of mesh~+325, diatomite, sepiolite and montmorillonite three be -200 mesh~+
270 mesh.In embodiment 8~10, alumina powder be -200 mesh of mesh~+325, clay be -200 mesh of mesh~+325, diatomite,
Sepiolite and montmorillonite three are -200 mesh of mesh~+400.
Embodiment 11
The present embodiment provides a kind of preparation method of negative oxygen glory paint, and the preparation method includes that pre-treatment step and batch mixing are walked
Suddenly.
Pre-treatment step：Sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixed powder
30 parts of deionized waters, 0.15 part of APM-95,1.2 parts of surfactants, whole alumina powders and whole clays are added, and is stirred
10min, obtains the first intermediate.
Batch mixing step：The remainder of raw material is added to the first intermediate, 15min is stirred, negative oxygen glory paint is obtained.
Embodiment 12
The present embodiment provides a kind of preparation method of negative oxygen glory paint, and the preparation method includes that pre-treatment step and batch mixing are walked
Suddenly.
Pre-treatment step：Sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixed powder
35 parts of deionized waters, 0.2 part of APM-95,1 part of surfactant, whole alumina powders and whole clays are added, and is stirred
15min, obtains the first intermediate.
Batch mixing step：The remainder of raw material is added to the first intermediate, 10min is stirred, negative oxygen glory paint is obtained.
Embodiment 13
The present embodiment provides a kind of preparation method of negative oxygen glory paint, and the preparation method includes that pre-treatment step and batch mixing are walked
Suddenly.
Pre-treatment step：Sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixed powder
25 parts of deionized waters, 0.1 part of APM-95,0.8 part of surfactant, whole alumina powders and whole clays are added, and is stirred
5min, obtains the first intermediate.
Batch mixing step：The remainder of raw material is added to the first intermediate, 20min is stirred, negative oxygen glory paint is obtained.
Embodiment 14
The present embodiment provides a kind of preparation method of negative oxygen glory paint, and the preparation method includes that pre-treatment step and batch mixing are walked
Suddenly.
Pre-treatment step：Sepiolite powder and montmorillonite powder mixing and stirring are obtained into mixed powder, to mixed powder
20 parts of deionized waters, 0.18 part of APM-95,1 part of surfactant, whole alumina powders and whole clays are added, and is stirred
12min, obtains the first intermediate.
Batch mixing step：The remainder of raw material is added to the first intermediate, 5min is stirred, negative oxygen glory paint is obtained.
Embodiment 15
The present embodiment provides a series of negative oxygen glory paints, the negative oxygen that this series of negative oxygen glory paint is provided by embodiment 11
The preparation method of glory paint is utilized respectively the negative oxygen glory raw materials for varnish that embodiment 1~4 provided and is obtained, this series of negative oxygen glory
Paint is respectively designated as：Bear oxygen glory paint 1 (raw material that correspondence embodiment 1 is provided), (correspondence embodiment 2 is carried negative oxygen glory paint 2
The raw material of confession), negative oxygen glory paint 3 (raw material that correspondence embodiment 3 is provided) and negative oxygen glory paint 4 (correspond to embodiment 4 to be provided
Raw material).
Embodiment 16
The present embodiment provides a series of negative oxygen glory paints, the negative oxygen that this series of negative oxygen glory paint is provided by embodiment 12
The preparation method of glory paint is utilized respectively the negative oxygen glory raw materials for varnish that embodiment 5~7 provided and is obtained, this series of negative oxygen glory
Paint is respectively designated as：Bear oxygen glory paint 5 (raw material that correspondence embodiment 5 is provided), (correspondence embodiment 6 is carried negative oxygen glory paint 6
The raw material of confession) and negative oxygen glory paint 7 (raw material that correspondence embodiment 7 is provided).
Embodiment 17
The present embodiment provides a series of negative oxygen glory paints, the negative oxygen that this series of negative oxygen glory paint is provided by embodiment 13
The preparation method of glory paint is utilized respectively the negative oxygen glory raw materials for varnish that embodiment 8~10 provided and is obtained, and this series of negative oxygen is color
Lac varnish is respectively designated as：Negative oxygen glory paint 8 (raw material that correspondence embodiment 8 is provided), negative (correspondence embodiment 9 institute of oxygen glory paint 9
The raw material of offer) and negative oxygen glory paint 10 (raw material that correspondence embodiment 10 is provided).
Embodiment 18
The present embodiment provides a series of negative oxygen glory paints, the negative oxygen that this series of negative oxygen glory paint is provided by embodiment 14
The preparation method of glory paint is utilized respectively the negative oxygen glory raw materials for varnish that embodiment 1~4 provided and is obtained, this series of negative oxygen glory
Paint is respectively designated as：Negative oxygen glory paint 11 (raw material that correspondence embodiment 1 is provided), negative (correspondence embodiment 2 institute of oxygen glory paint 12
The raw material of offer), negative oxygen glory paint 13 (raw material that correspondence embodiment 3 is provided) and negative oxygen glory paint 14 (correspond to the institute of embodiment 4
The raw material of offer).
Experimental example 1
It is the negative oxygen glory paint of bottom with how happy scholar's emulsion paint (A914-65663), respectively with negative oxygen glory paint 1~14 and good
U.S. this environment-friendly interior wall coating KM3000 is brushed, and brushing is shaped as square, and brushing surface is 1m2, brushed during brushing thick
Degree is consistent.It is average pinhole number ratio respectively to each paint film, average bubbling area ratio, average after paint film is molded completely
Roughness ratio, average loss of gloss area ratio and it is average from pasta product ratio take statistics.Wherein,
Average pinhole number is than the paint for average pinhole number in paint film unit area and Jia Meisi environment-friendly interior wall coatings KM3000
Ratio in film unit area between average pinhole number.
Average bubbling area ratio is average bubbling area and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in ratio between average bubbling area.
Average loss of gloss area ratio is average loss of gloss area and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in ratio between average loss of gloss area.
Average is average from pasta product and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area from pasta product ratio
Paint film unit area in it is average from pasta product between ratio.
Mean roughness is than the paint film average roughness for paint film mean roughness and Jia Meisi environment-friendly interior wall coatings KM3000
Ratio between degree.It should be noted that above-mentioned roughness is surface roughness, the deviation Ra that averagely counted using profile is used as commenting
Valency parameter.Otherwise Ra is bigger, and expression surface is more coarse more smooth.Above-mentioned each statistics is as shown in table 2：
The paint film property statistics of the negative oxygen glory paint 1~14 of table 2 and Jia Meisi environment-friendly interior wall coatings KM3000
As shown in Table 2：Negative oxygen glory paint 1~14 provided in an embodiment of the present invention can significantly reduce pin hole, bubble, stings
Bottom, from oil, loss of gloss and it is coarse the problems such as appearance, improve negative oxygen glory paint into paint film quality.Paint film stability is good, color and luster
Stabilization is not susceptible to go down, the problems such as being less prone to localized crackses, local shedding or hole occur, paint film quality better.
Experimental example 2
It is the negative oxygen glory paint of bottom with how happy scholar's emulsion paint (A914-65663), respectively with negative oxygen glory paint 1~14 and good
U.S. this environment-friendly interior wall coating KM3000 is brushed, and brushing is shaped as square, and brushing surface is 1m2, brushed during brushing thick
Degree is consistent.After paint film is molded completely, the metal halide lamp senile experiments of DIN 75220 are carried out to each paint film respectively.
Specific experiment standard is each paint film to be placed in the metal halide lamp chambers of DIN 75220, and control its parameter such as
Shown in table 3, experimental period is 720h.After experiment terminates, average discoloration area ratio respectively to each paint film, averagely go mouldy area
Than, average crack areas ratio, average efflorescence area ratio and the average area ratio that peels off take statistics.
The metal halide lamp chamber parameter lists of table 3DIN 75220
Wherein：
Average colour fading area ratio is average colour fading area and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in ratio between average colour fading area.
The average area ratio that goes mouldy is average area and the Jia Meisi environment-friendly interior wall coatings KM3000 of going mouldy in paint film unit area
Paint film unit area in ratio between the average area that goes mouldy.
Average crack areas ratio is average crack areas and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in ratio between average crack areas.
Average loss of gloss area ratio is average loss of gloss area and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in ratio between average loss of gloss area.
The average area ratio that peels off is average peeling area and Jia Meisi environment-friendly interior wall coatings KM3000 in paint film unit area
Paint film unit area in the average ratio peeled off between area.Above-mentioned each statistics is as shown in table 4：
The negative oxygen glory paint 1~14 of table 4 and Jia Meisi environment-friendly interior wall coatings KM3000 through the metal halide lamps of DIN 75220 at
Paint film property statistics after reason
As shown in Table 4, paint film ageing resistance formed by negative oxygen glory paint 1~14 provided in an embodiment of the present invention is excellent.
In general, paint film formed by negative oxygen glory paint 1~14 has good intensity, and radiation resistance is good and moisture resistant ability is strong,
Also it is less likely to occur to go bad in wet environment, the ageing resistace of paint film is notable.Paint film pair formed by negative oxygen glory paint 1~14
Humidity changes and the resistivity of illumination is preferable, and colourity and the gloss of its color keep fine, it is not easy to which color color occurs
That spends goes down, while the high glaze of stabilization can be kept.
Experimental example 3
In a 20m2Room in metope is brushed with negative oxygen liquid wall clothing 1, brushing is shaped as square, brushing surface
Product is 6m2.Window is closed, and half-open door is detected after wall clothing dries to indoor negative oxygen ion concentration.Statistics negative oxygen ion
Change in concentration data.
Wherein, daily 12 noon detection once, counts the data of 30 days.Result is as shown in table 5.It should be noted that
Statistics is the ratio of each testing result and testing result when detecting for the first time.
The negative oxygen ion concentration detection data of table 5
As shown in Table 5, negative oxygen liquid wall clothing 1 provided in an embodiment of the present invention continually and steadily releasing negative oxygen ion and can be protected
The indoor negative oxygen ion concentration of card is maintained in certain stability range, and negative oxygen ion concentration is basicly stable, is not in big amplitude wave
Dynamic or decay.
In sum, the paint film that negative oxygen glory paint provided in an embodiment of the present invention is formed is uniform and good stability.Drying
During can guarantee that the uniform of moisture scatters and disappears, paint film each several part uniformity is good, and formed gloss of film is uniform, smooth, color
Pool stabilization, is not susceptible to go down.Paint film stability is good, can largely reduce pin hole, foaming, lifting, from oil, loss of gloss
And it is coarse situations such as generation, film integrity is good, and quality of forming film is high.Paint film has good intensity, sun protection good and can
High temperature resistance, is also less likely to occur disintegration in wet environment, and the ageing resistace of paint film is notable.Additionally, paint film can also continue
Releasing negative oxygen ion, improves indoor negative oxygen ion concentration, improves indoor environment, improves human comfort.Negative oxygen ion can have
Effect improves indoor air quality, can promote the decomposition of the pernicious gases such as formaldehyde, reduces breathing problem, to cardiovascular and cerebrovascular and
Respiratory tract also has adjuvant treatment effect, is favorably improved fitness.
The preparation method that the embodiment of the present invention provides negative oxygen glory paint is simple and easy to apply, easily implements, and is not limited by place, adjusts
With convenient.The paint film stability that prepared negative oxygen glory paint is formed is good, and color stability is not susceptible to go down, and is less prone to part
Crackle, local shedding or the problems such as there is hole, paint film quality better；Sustainable releasing negative oxygen ion, improves indoor environment, improves
Human comfort.
The preferred embodiments of the present invention are the foregoing is only, is not intended to limit the invention, for the skill of this area
For art personnel, the present invention can have various modifications and variations.It is all within the spirit and principles in the present invention, made any repair
Change, equivalent, improvement etc., should be included within the scope of the present invention.
Claims (10)
1. a kind of negative oxygen glory paint, it is characterised in that its raw material includes by weight：
2. negative oxygen glory paint according to claim 1, it is characterised in that the raw material includes by weight：
3. negative oxygen glory paint according to claim 2, it is characterised in that the raw material includes by weight：
The gloss additive is bronze or pearl powder.
4. negative oxygen glory paint according to claim 1, it is characterised in that the alumina powder is -200 mesh~+325
Mesh, the clay is -200 mesh of mesh~+325.
5. negative oxygen glory paint according to claim 4, it is characterised in that the alumina powder is -230 mesh~+325
Mesh.
6. negative oxygen glory paint according to claim 1, it is characterised in that the diatomite is -200 mesh of mesh~+400, institute
Sepiolite powder is stated for -200 mesh of mesh~+400, the montmorillonite powder is -200 mesh of mesh~+400.
7. negative oxygen glory paint according to claim 6, it is characterised in that the diatomite is -270 mesh of mesh~+400, institute
Sepiolite powder is stated for -270 mesh of mesh~+400, the montmorillonite powder is -270 mesh of mesh~+400.
8. negative oxygen glory paint according to claim 1, it is characterised in that the sepiolite powder and the montmorillonite powder
The ratio of weight and number of the two is 1~1.5：1.
9. the preparation method of the negative oxygen glory paint according to claim 1-8 any one, it is characterised in that including：
Pre-treatment step：The sepiolite powder is mixed into obtain mixed powder with the montmorillonite powder, to the mixed powder
Add 20~35 parts of deionized waters, 0.1~0.2 part of 2-amino-2-methyl-1-propanol, 0.8~1.2 part of table
Face activating agent, all alumina powder and all clay, and 5~15min is stirred, obtain the first intermediate；And
Batch mixing step：The remainder of the raw material is added to first intermediate, 5~20min is stirred.
10. preparation method according to claim 9, it is characterised in that in the pre-treatment step, to the mixed powder
Expect that the deionized water of addition is 0.1~0.15 part, the surface for 25~30 parts, the 2-amino-2-methyl-1-propanol
Activating agent is 0.8~1 part, and stirs 10~15min；In the batch mixing step, 10~15min is stirred.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110079143A (en) * | 2019-04-03 | 2019-08-02 | 唐山立雄峰汇材料科技有限公司 | Functional paint companion |
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