CN101348629A - Indoor coating having humidity conditioning function and construction method thereof - Google Patents
Indoor coating having humidity conditioning function and construction method thereof Download PDFInfo
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- CN101348629A CN101348629A CNA2008102223776A CN200810222377A CN101348629A CN 101348629 A CN101348629 A CN 101348629A CN A2008102223776 A CNA2008102223776 A CN A2008102223776A CN 200810222377 A CN200810222377 A CN 200810222377A CN 101348629 A CN101348629 A CN 101348629A
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Abstract
The invention provides internal wall decorative paint with the function of adjusting air humidity and a construction method thereof, belonging to the building material field. The paint in every 100 weight portion at least comprises 15 to 45 weight portions of a material with the function of adjusting the humidity. The internal wall decorative paint takes a porous inorganic mineral material such as sepiolite, diatomite and attapulgite as the material with the function of adjusting the humidity, is applied to the building internal wall paint, and is matched with the corresponding paint construction process. The paint construction process comprises the following steps: a substrate is polished and leveled and keeps clean and dry firstly; secondly, the paint is sprayed on the internal wall surface by a spray gun with a large-caliber nozzle of 2.5 millimeters, and the thickness of a coat is between one and two millimeters so that the paint can effectively adjust the indoor air humidity as well as has the function of decorating and the indoor air humidity is controlled within the range beneficial to the human body health; meanwhile, the paint does not pollute the environment, and has zero VOC emission. The construction process ensures that the paint effectively fulfills the humidity adjusting function aiming at the characteristic of the humidity adjusting function of the paint.
Description
Technical field
The present invention relates to building and ornament materials, be specifically related to a kind of functional interior wall coating and construction technology thereof.
Background technology
Relative air humidity is an important parameter weighing indoor environment, and is all significant to depositing of HUMAN HEALTH, IAQ (indoor air quality) and article.Open country, rattan palace, Japan scholar west has at first proposed " humidity adjusting material " this notion, and humidity adjusting material develops gradually in recent years, and the damping product covers fields such as building materials, weaving.
Japan takes its place in the front ranks of the world on the Application and Development of humidity adjusting material always.Japan had obtained multinomial patent aspect humidity adjusting material in recent years, mainly was that admixture is gone in other material, plays the function of moisture control with humidity adjusting materials such as special silica-gel commonly used, polynite class, inorganic salts, organic polymer materials." healthy building materials " as the development of Japanese INAX company have the effect of regulating indoor humidity; Hanada Kozo adds the binding agent heating and pressurizing with the carbide particle and has made carbide humidity adjusting material etc.But more or less all there is shortcoming in these products: silica gel moisture presents than the serious lag phenomenon when resolving; The polynite wet volume capacity is little; The inorganic salts humidity adjusting material easily produces and saltouts, and the article space of preserving is produced pollute; Organic humidity adjusting material moisture releasing amount is little, and moisture releasing speed is slow; The humidity adjusting material manufacturing process complexity that some is novel, production cost is too high.Chinese patent application 200610099093.3 discloses a kind of humidity adjusting material that is used for textiles and body of wall, mesoporous material (sepiolite, diatomite, attapulgite etc.) and super absorbent resin by biocatalyzer, 2-5nm are formed, and the damping scope is relative humidity 35-75%.Super absorbent resin performance humidity conditioning function in this humidity adjusting material, mesoporous material is the carrier of other components, and this humidity adjusting material moisture uptake is big, good water-retaining property, the moisture releasing amount is little, the slow-footed defective of moisture releasing but also exist simultaneously, if damping speed is slow among being directly used in coating.
Indoor environments such as coating and people's routine work, life are closely bound up, and the use of humidity conditioning function coating can be brought into play its effect to greatest extent.Humidity controlling coating is a kind of new function building and ornament materials of rising in recent years, and domestic researcher has begun to be devoted to its developmental research work.The Li Shuanlin of Beijing University of Technology is that humidity-controlling functional material is prepared a kind of ceramic humidity controlling coating (Li Shuanlin with the organic resin, Wu Yuting, Ma Chongfang, Meng Sheng. the tentative experiment research of novel humidity controlling coating damping performance. Engineering Thermophysics journal .2004, (3): 502-504), its defective is to adopt organic resin as humidity-controlling functional material, and hygroscopic property is better, but wet putting is relatively poor.The Li Xiaoli of Huaqiao University etc. are the humidity controlling coating (Li Xiaoli that humextant is prepared with the polyacrylic resin, the woods pine and cypress. the performance study of polyacrylic ester interior wall humidity controlling coating. coatings industry .2007,37 (9:21-24)) better at RH＞75% o'clock moisture sorption effect, but do not carry out the test of coating moisture releasing performance.
In construction work, the engineering of selecting for use fine coating to make, reason are that people generally pay close attention to the performance and the quality of coating, have but ignored the control of coating application technology and coating project quality.It is several that coating application technology commonly used at present mainly contains roller coat, spraying, brushing and blade coating.Suitable construction technology is selected in performance and the decoration requirement different according to coating.
In a word, humidity controlling coating will become the another developing direction of functional coating because of its specific purposes.But there is not the low coating products of damping excellent performance and price to occur at present as yet.Selecting suitable construction technology simultaneously is the prerequisite of maximum its damping performance of performance.
Summary of the invention
The purpose of this invention is to provide and have the excellent indoor coating having humidity conditioning function of regulating interior space psychometric performance.
The present invention has the inner wall decorative coating of atmospheric moisture regulatory function, in the described coating of per 100 weight parts, contains humidity-controlling functional material 15-45 weight part at least.
Concrete, described interior wall coating with atmospheric moisture regulatory function, contain following component:
Filmogen 10-40 weight part;
Humidity-controlling functional material 15-45 weight part;
Mineral filler 10-45 weight part;
Auxiliary agent 1-5 weight part; And
Water 15-35 weight part.
Wherein, described humidity-controlling functional material is one or more compound in the mineral materials such as diatomite, sepiolite, attapulgite, vermiculite, zeolite powder, kaolin.
Wherein, described humidity-controlling functional material is for to obtain after cleanup acid treatment.The acidification process is for soaking the porous mineral material after-filtration, the use of oven dry back in sulfuric acid or hydrochloric acid.
Wherein, described filmogen is a kind of in the various emulsions such as pure acrylic acid emulsion, acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion.
Wherein, described mineral filler is one or more in dicalcium powder, light calcium carbonate powder, titanium dioxide, white cement, talcum powder, zinc sulfide white, wollastonite powder and the grey calcium powder.
Wherein, described auxiliary agent be in dispersion agent, film coalescence aid, thickening material, defoamer, flow agent, sanitas, pH value conditioning agent and the sanitas one or more.
Another object of the present invention is to provide the constructional method of this indoor coating having humidity conditioning function.This method polishes flat substrate earlier, and keeps clean and tidy, dry, use then have 2.5mm heavy caliber nozzle spray gun with described paint spay-coating at inner wall surface, coat-thickness is 1～2mm.
The present invention is applied to porous, inorganic mineral materials such as environmental protection, free of contamination sepiolite, diatomite, attapulgite in the dope for inner wall of architecture as humidity-controlling functional material, porous mineral material and other component mix, be sprayed at metope, when playing decoration function, can effectively regulate indoor air humidity, make it to be controlled in the scope that is of value to HUMAN HEALTH, simultaneously pollution-free, zero VOC discharges.Humidity-controlling functional material does not use any organic constituent in the coating of the present invention, meets the National Environmental specification of quality, and has the function of ambient moisture in the good surge chamber.Simultaneously, owing to specific functionally make it adopt unique technology to construct, can reach good result of use.
Description of drawings
Fig. 1 is 25 ℃ of temperature, each sample sucting wet curve under the condition of relative humidity 85%.
Fig. 2 is for being each sample moisture releasing curve under 35% the condition in 25 ℃ of temperature, relative humidity.
Embodiment
The present invention is intended to overcome mechanical damping such as air-conditioning technical and produces problems such as power consumption and pollution, utilizes special construction technology, and indoor decoration coating is reached the self-regulating effect of indoor environment humidity.In the present invention, damping refers to moisture absorption and two aspects of moisture releasing.
1. humidity controlling coating prescription:
Base-material-filmogen: a kind of in the various emulsions such as pure acrylic acid emulsion, acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion accounts for 10～40% of coating total amount.
Humidity-controlling functional material: humidity-controlling functional material is porous mineral materials such as main diatomite, sepiolite, attapulgite, zeolite.Can be in diatomite, sepiolite, attapulgite, vermiculite, zeolite powder, the kaolin at least a, or multiple being used in combination, the portfolio ratio when being used in combination is unqualified.Humidity-controlling functional material accounts for 15～45% of coating total amount.
Mineral material pre-treatment: the inorganic mineral material for having porous road structure such as diatomite, sepiolite, attapulgite, vermiculite, zeolite powder, kaolin, the present invention utilizes its its specific structure that water vapour is had good absorption, releasability, and, do not use any organic materials as the humidity conditioning function component to the characteristics of HUMAN HEALTH without any influence.When optimizing humidity-controlling functional material, can obtain by acidification to mineral material; The acidification process is: the porous mineral material is soaked (more than 6 hours) after-filtration, the use of oven dry back in sulfuric acid (for example concentration is 6%) or hydrochloric acid (for example concentration is 10%), when removing impurity, improve the pore structure of mineral in the acidifying preprocessing process, make it have rational pore size distribution (most of pore size distribution is between 2-10nm), keep higher degree and improve the moisture control ability.
Color stuffing: white cement, zinc sulfide white, talcum powder, fine particle calcium carbonate, coarse whiting, titanium dioxide, wollastonite powder, grey calcium powder etc. are wherein at least a, and the portfolio ratio during multiple being used in combination is unqualified.Weight accounts for 10～45% of coating total amount.
Auxiliary agent: include but not limited to use dispersion agent (as DISPERBYK-108), film coalescence aid (as alcohol ester-12), thickening material (as ACRYLIC EMULSION T-117A), defoamer (as BYK-052), flow agent (as L150), sanitas (as KATHON
LXE), pH value conditioning agent (as ammoniacal liquor, hydrochloric acid) etc., more than all can adopt the water-borne coatings accessory ingredient of in common use, add up to account for 1～5% of coating total amount.
Water: account for 15～35% of coating total amount.
More than all raw materials all commercially available.
Coating preparation: take by weighing water by the prescription requirement, adding auxiliary agents such as dispersion agent, defoamer, PH conditioning agent disperses, add mineral filler and adjusting humidity functional materials to above-mentioned dispersive solution for continuous dispersion in proportion then, adding gathers materials is uniformly dispersed, supply some auxiliary dosages according to prescription at last, as thickening material, film coalescence aid, defoamer, sanitas etc.Stir during use and can use.
2. humidity controlling coating construction technology
At first substrate is cleared up, require firm, smooth, dry, cleaning, need not the brushing bottom closing paint.Before the construction coating is stirred, select for use the gravity type boat davit spray gun of 2.5mm heavy caliber nozzle to spray, the about 1～2mm of coat-thickness.Wherein:
The operation of base treatment is:
(1) determines basic unit's contained humidity drying;
(2) remove surperficial mortar, accumulation of salt in the surface soil thing, bleeding cement and other bulk materials with the instrument of doing;
(3) foul that surface and oil contaminant etc. is difficult for brushing can be scrubbed with warm water, uses the clear water rinsing then, dries;
When (4) surface was too smooth, methods such as available acid etching, sandblast, polishing or natural weathering made its roughen;
The purpose of base treatment is not influence coating cohering basic unit.Substrate such as concrete, cement based can with water molecules generation hydration reaction, be beneficial to the strength development of self, and do not influence the humidity controlling coating performance, so need not the brushing seal coat.Product utilization vesicular structure of the present invention absorbs and discharges the water molecules of surrounding environment, thereby reaches the purpose of regulating ambient moisture, selects for use the heavy caliber spray gun can guarantee that coating film forming rear surface keeps microvoid structure, brings into play its good moisture control effect.
Followingly assembly of the present invention and function are described according to specific embodiment:
Example one:
ACRYLIC EMULSION 100 grams
Attapulgite (after the pre-treatment) 200 grams
Diatomite (after the pre-treatment) 100 grams
Fine particle calcium carbonate 100 grams
Talcum powder 100 grams
DISPERBYK-108 15 grams
Alcohol ester-12 10 gram
BYK-052 15 grams
Water 350 grams
Obtain this routine humidity controlling coating by the preparation of coating compound method.
Testing method and result: coating is sprayed on according to construction technology of the present invention on the sheet glass of two 150mm * 150mm, dries naturally and be placed in the baking oven, oven dry is 5 hours under 80 ℃ of conditions.Two models are placed in the 10L encloses container of 25 ℃ of temperature, relative humidity 85% the maximum reduction of the relative humidity in the measuring vessel.After relative humidity reached balance in the encloses container, changing the interior envrionment conditions of container was 25 ℃, relative humidity 35%, the maximum increasing amount of the relative humidity in the measuring vessel.By relative humidity variations situation in the Temperature Humidity Sensor record container.
Test result: at 25 ℃, under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 10%RH, illustrates that this test coating has moisture absorbing; After moisture absorption is saturated, be under 35% the condition in 25 ℃ of temperature, relative humidity, test coating can moisture releasing, and the maximum increasing amount of relative humidity reaches 7%RH.
The test of contrast coating:
According to above-mentioned experimental technique, the rh value of record different time encloses container, curve plotting.Fig. 1 is presented at 25 ℃ of temperature, and it is moisture releasing curve under 35% the condition that sucting wet curve under the condition of relative humidity 85%, Fig. 2 are presented at 25 ℃ of temperature, relative humidity.Wherein: the humidity controlling coating of 1# representative instance one, the sample that adopts constructional method of the present invention to spray; The humidity controlling coating of 2# representative instance one prescription, the sample that adopts the blade coating mode to construct; 3# represents same recipe, and the humidity adjusting material with 200610099093.3 is the coating that humidity-controlling functional material is made, the sample that adopts the blade coating mode to construct; 4# represents same recipe, and humidity-controlling functional material is unprocessed, and the higher and coating made of foreign matter content adopts the sample of constructional method spraying of the present invention.
Test result: referring to shown in Figure 1,25 ℃ of temperature, under the condition of relative humidity 85%, the maximum reduction of relative humidity is respectively 1#～10.38%RH, 2#～6.44%RH, 3#～5.68%RH, 4#～5.28%RH; After moisture absorption is saturated, be test coating moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, referring to shown in Figure 2, the maximum increasing amount of relative humidity is respectively 1#～7.35%RH, 2#～5.29%RH, 3#～5.12%RH, 4#～4.72%RH as a result.By contrast as can be seen: compare with other several coating and knife-coat application method, humidity controlling coating of the present invention has good damping effect after adopting spraying application.
Example two:
Benzene emulsion 400 grams
Sepiolite (after the pre-treatment) 210 grams
Zinc sulfide white 80 grams
Wollastonite powder 60 grams
ACRYLIC EMULSION T-117A 5 grams
Water 150 grams
Carry out Function detection with the method identical with embodiment one, the result is 25 ℃ of temperature, and under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 8%RH; After moisture absorption is saturated, be moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, the maximum increasing amount of relative humidity reaches 6%RH as a result.
Example three:
Acrylate and vinyl acetate emulsion 200 grams
Zeolite powder (after the pre-treatment) 150 grams
Kaolin (after the pre-treatment) 150 grams
Attapulgite 150 grams
Talcum powder 100 grams
DISPERBYK-108 5 grams
BYK-052 5 grams
Water 240 grams
Carry out Function detection with the method identical with embodiment one, the result is 25 ℃ of temperature, and under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 10%RH; After moisture absorption is saturated, be moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, the maximum increasing amount of relative humidity reaches 6%RH as a result.
Example four:
Pure acrylic acid emulsion 250 grams
Vermiculite power (after the pre-treatment) 100 grams
Diatomite (after the pre-treatment) 150 grams
Ash calcium powder 120 grams
Zinc sulfide white 100 grams
Titanium dioxide 40 grams
DISPERBYK-108 10 grams
Water 220 grams
Carry out Function detection with the method identical with embodiment one, the result is 25 ℃ of temperature, and under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 9%RH; After moisture absorption is saturated, be moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, the maximum increasing amount of relative humidity reaches 7%RH as a result.
Example five:
Vinylformic acid Synolac 200 grams
Attapulgite (after the pre-treatment) 150 grams
Ash calcium powder 100 grams
Wollastonite 150 grams
White cement 100 grams
Talcum powder 100 grams
DISPERBYK-108 15 grams
Water 180 grams
Carry out Function detection with the method identical with embodiment one, the result is 25 ℃ of temperature, and under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 7%RH; After moisture absorption is saturated, be moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, the maximum increasing amount of relative humidity reaches 5%RH as a result.
Example six:
Organosilicon crylic acid latex 350 grams
Sepiolite powder (after the pre-treatment) 100 grams
Diatomite (after the pre-treatment) 100 grams
Light calcium carbonate powder 80 grams
Zinc sulfide white 100 grams
DISPERBYK-108 10 grams
ACRYLIC EMULSION T-117A 10 grams
Water 250 grams.
Carry out Function detection with the method identical with embodiment one, the result is 25 ℃ of temperature, and under the condition of relative humidity 85%, the maximum reduction of relative humidity reaches 11%RH; After moisture absorption is saturated, be moisture releasing under 35% the condition in 25 ℃ of temperature, relative humidity, the maximum increasing amount of relative humidity reaches 8%RH as a result.
Claims (9)
1, a kind of inner wall decorative coating with atmospheric moisture regulatory function is characterized in that, in the described coating of per 100 weight parts, contains humidity-controlling functional material 15-45 weight part at least.
2, the interior wall coating with atmospheric moisture regulatory function according to claim 1, contain following component:
Filmogen 10-40 weight part;
Humidity-controlling functional material 15-45 weight part;
Mineral filler 10-45 weight part;
Auxiliary agent 1-5 weight part; And
Water 15-35 weight part.
3, the interior wall coating with atmospheric moisture regulatory function according to claim 1 and 2, it is characterized in that described humidity-controlling functional material is one or more compound in the mineral materials such as diatomite, sepiolite, attapulgite, vermiculite, zeolite powder, kaolin.
4, the interior wall coating with atmospheric moisture regulatory function according to claim 3 is characterized in that, described humidity-controlling functional material is for to obtain after the acidifying pre-treatment.
5, the interior wall coating with atmospheric moisture regulatory function according to claim 4 is characterized in that, described acidification process is for soaking the porous mineral material after-filtration, the use of oven dry back in sulfuric acid or hydrochloric acid.
6, the interior wall coating with atmospheric moisture regulatory function according to claim 3, it is characterized in that described filmogen is a kind of in the various emulsions such as pure acrylic acid emulsion, acrylic resin, vinylformic acid Synolac, organosilicon crylic acid latex, acrylate and vinyl acetate emulsion, benzene-acrylic emulsion.
7, the interior wall coating with atmospheric moisture regulatory function according to claim 3, it is characterized in that described mineral filler is one or more in dicalcium powder, light calcium carbonate powder, titanium dioxide, white cement, talcum powder, zinc sulfide white, wollastonite powder and the grey calcium powder.
8, the interior wall coating with atmospheric moisture regulatory function according to claim 3 is characterized in that, described auxiliary agent be in dispersion agent, film coalescence aid, thickening material, defoamer, flow agent, sanitas, pH value conditioning agent and the sanitas one or more.
9, a kind of interior wall construction method of humidity controlling coating, it is characterized in that, use the arbitrary described humidity controlling coating of claim 1 to 8, earlier substrate is polished flat, and keep clean and tidy, dry, use then have 2.5mm heavy caliber nozzle spray gun with paint spay-coating at inner wall surface, coat-thickness is 1～2mm.
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