CN104031465B - A kind of negative ion water color ink and preparation method thereof - Google Patents

A kind of negative ion water color ink and preparation method thereof Download PDF

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CN104031465B
CN104031465B CN201410185152.3A CN201410185152A CN104031465B CN 104031465 B CN104031465 B CN 104031465B CN 201410185152 A CN201410185152 A CN 201410185152A CN 104031465 B CN104031465 B CN 104031465B
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negative ion
color ink
water color
ion water
ink
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CN104031465A (en
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许华君
许少宏
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Hangzhou danshili Decoration Co., Ltd
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Hangzhou Hai Weite Chemical Industry Science Co Ltd
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Abstract

The invention discloses a kind of negative ion water color ink and preparation method thereof, described negative ion water color ink is made up of the raw material of following weight proportion: polymer emulsion 28 ~ 40 parts, pigment 15 parts, filler 4 ~ 8 parts, anionic additive 1 ~ 5 part, alcohol 3.5 ~ 8 parts, dispersion agent 0.6 ~ 3.6 part, thickening material 0.1 ~ 0.8 part, flow agent 0.05 ~ 0.3 part, defoamer 0.1 ~ 0.8 part, sanitas 0.05 ~ 0.06 part, 26.92 ~ 41 parts, water; Negative ion water color ink of the present invention is without the need to external energy just release air negative ion sustainably, be conducive to maintaining HUMAN HEALTH, and and then the object reaching sterilization, purify air, and there is Environmental Safety, excellent storage stability, coating is plentiful, decorative effect is good feature.

Description

A kind of negative ion water color ink and preparation method thereof
(1) technical field
The present invention relates to water color ink and preparation method thereof, be specifically related to water color ink of a kind of energy anion releasing and preparation method thereof, water color ink of the present invention can be applicable to wallpaper printing.
(2) background technology
Wallpaper, as a kind of house decorative material, because of features such as its color are various, pattern abundant, construction safety is convenient, more and more instead of interior wall coating by masses accept also part.Wallpaper, from being applied in the public places such as hotel, hotel and office at first, being applied to the interior decoration of family by now more and more widely, thus more and more being paid close attention to.But, wallpaper printing ink mostly in the market is solvent type ink, it contains a large amount of organic volatiles (content is usually more than 40%), these organic volatile materials discharged to air, all cause larger murder by poisoning to the health of inhabitation personnel in printing, construction worker and wallpaper decoration building in printing and construction process.Therefore the development trend of industry has been become with the environment-friendly type aqueous printing-ink of water to replace organic solvent.On the other hand, at present the research of wallpaper is rested on more to the decorate properties research on its surface, and few to the research of its health application function.Because the most of the time of people is all spent in indoor, the quality of indoor environmental quality directly affects the healthy of people, and it is larger for the area that the wallpaper of upholstery is indoor shared by it, if it therefore can be made to possess some functional health performance, then will more by the welcome of consumers in general.In sum; along with the enhancing of popular environmental protection, health perception; people are no longer only confined to beautiful decoration effect to the requirement of wallpaper; and more wish that it has many-sided performance such as environmental protect, protection human health; therefore, developing a kind of environment protection type wallpaper printing water color ink with nourishing function is the key widening the application of its market.
At present, the negative ion concentration in air has been listed in the important indicator that is weighed environment, Air quality.Its content and HUMAN HEALTH have substantial connection, as shown in the table:
Negative ion concentration and HUMAN HEALTH relation (draw and report from " International Medical magazine ") in table 1. environment
From table 1, the negative ion concentration in the enclosed space such as house, office in air does not reach the basic demand maintaining HUMAN HEALTH far away.A kind of settling mode now taked is at indoor location anion generator, but this both took up space, and increases again the expense such as equipment, power consumption, and the switching on and shutting down of every day operation makes troubles also to the use of people.It is add anionic additive in indoor interior wall coating or wallpaper ink that another kind compares efficient manner, enables interior wall coating or wallpaper ink produce negative aeroion constantly.Common anionic additive is the natural crystal mixtures such as tourmalinite.The anionic additives such as tourmalinite are containing multiple elements such as Si, Mg, Fe, Al, K, Na, and have permanent spontaneous electrode, this electrode can make the water molecules in ambient air that faint electrolytic action occurs, and generate OH-and H +.H +electronics is obtained, OH in weak current between tourmalinite electrode -negative aeroion (H is formed with the water molecules in air 3o 2) -.Numerous result of study shows, interior wall coating or the wallpaper ink of introducing anionic additive can improve room air negative ion concentration significantly, are conducive to HUMAN HEALTH.But function interior wall coating, wallpaper ink etc. that major part in the market contains anionic additive are solvent-based system, unfavorable to environment; And the film that solvent-based system is formed is comparatively fine and close, is unfavorable for the contact of tourmalinite and water in air molecule, therefore can not produces more negative ion.In addition, part interior wall coating, wallpaper ink adopt photoactivation mode to produce negative aeroion, must could produce negative ion, this greatly limits it and apply under illumination condition.
The object of the invention is to overcome the deficiencies in the prior art, a kind of wallpaper printing water color ink of energy anion releasing is provided.This ink adopts emulsion system, Environmental Safety, and it not only has the effect of attractive, decorative, can also for good and all release air negative ion, and without the need to external energy, is a kind of novel environment friendly wallpaper printing water color ink with nourishing function.
(3) summary of the invention
The object of the present invention is to provide a kind of negative ion water color ink and preparation method thereof that can be used for wallpaper printing, and, negative ion water color ink of the present invention just can release air negative ion constantly without the need to external energy, makes room air negative ion concentration reach the level maintained needed for HUMAN HEALTH.
The object of the invention is to be achieved through the following technical solutions:
A kind of negative ion water color ink, described negative ion water color ink is made up of the raw material of following weight proportion: polymer emulsion 28 ~ 40 parts, pigment 15 parts, filler 4 ~ 8 parts, anionic additive 1 ~ 5 part, alcohol 3.5 ~ 8 parts, dispersion agent 0.6 ~ 3.6 part, thickening material 0.1 ~ 0.8 part, flow agent 0.05 ~ 0.3 part, defoamer 0.1 ~ 0.8 part, sanitas 0.05 ~ 0.06 part, 26.92 ~ 41 parts, water; Described polymer emulsion is the mixture of one or more arbitrary proportions in benzene emulsion, vac-veova emulsion, acrylate and vinyl acetate emulsion, polyacrylic ester pure-acrylic emulsion, polyaminoester emulsion, organosilicon crylic acid latex, fluoro-resin emulsion, further, the solid content of described polymer emulsion is 45wt% ~ 50wt%; Described filler can be the mixture of one or more arbitrary proportions in talcum powder, coarse whiting, fine particle calcium carbonate, kaolin, wollastonite powder physique filler.
The polyacrylic ester pure-acrylic emulsion of the preferably described polymer emulsion of the present invention to be solid content be 45wt% ~ 50wt%.
Pigment of the present invention can be the one in titanium dioxide, zinc oxide, zinc sulfide white, carbon black, iron oxide black, nigrosine, lead-chrome yellow, iron oxide yellow, iron oxide red, red, phthalocyanine blue b, ultramarine, and the pigment described in the present invention is preferably titanium dioxide R-902+ (E.I.Du Pont Company) or water-based carbon black HD-300M (Hangzhou Hei Yuan Chemical Co., Ltd.).
Anionic additive of the present invention is preferably tourmaline powder, as TZY-01 (Beijing Health-care Science & Technology Co., Ltd.).
Dispersion agent of the present invention can be that polycarboxylate is (as DisponerW-922, De Qian company; KP010, Shanghai De Yu get trade Co., Ltd; BYK-P-104, BYK company), polyacrylic acid derivative is (as DisponerW-511, De Qian company; DisponerW-519, De Qian company), along divinyl anhydride multipolymer (as diisobutylene-cis-butenedioic anhydride multipolymer or styrene-maleic anhydride copolymer; As SMA1000P, Sartomer), condensation naphthalenesulfonate is (as PD, Qingdao Chemical Inst.), poly carboxylic acid (as Anti-Terra-203, BYK company), polyvinyl alcohol (as BP-20, the good Chemical Industry Science Co., Ltd of Shanghai fond dream; BP-17, the good Chemical Industry Science Co., Ltd of Shanghai fond dream) in the mixture of one or more arbitrary proportions; Preferred polycarboxylic acid salt's dispersion agent.
Thickening material of the present invention can be that cellulose thickener is (as CELLOSIZE tMqP4400H, Dow Chemical; CELLOSIZE tMqP15000H, Dow Chemical; CELLOSIZE tMqP30000H, Dow Chemical; CELLOSIZE tMqP52000H, Dow Chemical; CELLOSIZE tMqP100MH, Dow Chemical; CELLOSIZE tMeR30M, Dow Chemical; CELLOSIZE tMeR52M, Dow Chemical), polyurethanes thickening material is (as 8020, Long Shida Chemical Industry Science Co., Ltd; 216, De Qian company; DeuRheoWT-105A, De Qian company; DeuRheoWT-201, De Qian company; DeuRheoWT-202, De Qian company; DeuRheoWT-204, De Qian company), agent for polyacrylic acid thickening is (as DeuRheoWT-113, De Qian company; DeuRheoWT-115, De Qian company; DeuRheoWT-120, De Qian company), polyacrylate-type thickeners (as thickening material D-11, Gaoming District, Foshan City Hang Run auxiliary agent company limited; LatekollD, BASF AG) in the mixture of any one or two or more arbitrary proportion; Optimization polypropylene acids or polyacrylate-type thickeners.
Flow agent of the present invention can be polyacrylate(s) flow agent (as A900, Mei Liken Chemical Group company limited of the U.S.; ResiflowW50, BYK company), silicone resin class flow agent is (as Silcn353, Shanghai De Yu get trade Co., Ltd), the mixture of one or more arbitrary proportions in fluoroolefins flow agent (as 5100, Long Shida Chemical Industry Science Co., Ltd); Optimization polypropylene esters of gallic acid flow agent.
Defoamer of the present invention can be lower alcohols defoamer (as dF1492, De Qian company; dF1760, De Qian company; dF3163, De Qian company), mineral oil defoaming agent is (as DrewplusT-4507, ASHLAND-AQUALON company; ADVANTAGEAM-1512, ASHLAND-AQUALON company), silicone based defoamer (as Pulcra1918, Kekai Fine Chemical (Shanghai) Co., Ltd.; Pulcra1920, Kekai Fine Chemical (Shanghai) Co., Ltd.; DrewplusT-4201, ASHLAND-AQUALON company; DrewplusTS-4400, ASHLAND-AQUALON company; DrewplusTS-4481, ASHLAND-AQUALON company) in the mixture of one or more arbitrary proportions; Preferred mineral oil defoaming agent.
Sanitas of the present invention is the mixture of one or more arbitrary proportions in substituted arene class sanitas, heterocycles sanitas, aminated compounds class sanitas, as DeuAddMB-11 (De Qian company), DeuAddMB-16 (De Qian company), KathonLXE (Rhom and Hass) etc., prerequisite is the stability not hindering ink system, little on system impact, preferred KathonLXE (Rhom and Hass).
Present invention also offers a kind of preparation method of negative ion water color ink of the present invention, described preparation method carries out as follows:
(1) water of formula ratio, dispersion agent, pigment, filler, anionic additive and granulated glass sphere are added in rapid dispersion machine, disperse 2 ~ 3 hours, obtain mill base;
(2) mill base that the polymer emulsion of formula ratio, defoamer and step (1) prepare is added in dispersion sand mill, stir 10 ~ 60 minutes with the speed of 800 ~ 1500 turns/min, then add thickening material and the flow agent of formula ratio;
(3) keep stirring, after adding the alcohol of formula ratio, sanitas, namely obtain described negative ion water color ink.
Compared with prior art, the present invention has following advantage:
1, adopt tourmaline powder to be anionic additive, evenly, be stably dispersed in ink, without the need to external energy just release air negative ion sustainably, make negative ion concentration in air up to 1200 ~ 2300/cm 3, reach the Air quality of town park rank, be conducive to maintain HUMAN HEALTH, and and then the object reaching sterilization, purify air;
2, (homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention to select homemade polyacrylic ester pure-acrylic emulsion, application number is 2013105793039, publication number is CN103601837A) be the low-melting ink vehicle of ink, traditional solvent-borne ink is become water color ink, not only Environmental Safety, and add the ventilation property of coating, more tourmalinite can be made to contact with the water molecules in air, discharge more negative ion;
3, by the choose reasonable of each analog assistant, ensure that ink is fine and smooth, do not precipitate, not stratified that there is excellent storage stability, coating is plentiful, decorative effect is good feature.
(4) embodiment
Below in conjunction with specific embodiment, the present invention is described further, but protection scope of the present invention is not limited in this:
The package stability of ink refers to that ink leaves standstill 6 days under 60 DEG C of conditions, not precipitate, not stratifiedly represents ink storage stability >6 month;
The generating capacity of negative aeroion is checked in the detection of the negative ion concentration that wallpaper ink discharges according to Q/JCJJT030 ~ 2002, by Chinese architecture material tests Spot detection.
Embodiment 1
The composition of raw materials (1wt% negative ion powder addition) of table 2 ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention, application number is 2013105793039, and publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 2, the granulated glass sphere being 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 2 hours, obtain stock white;
(2) stock white that polyacrylic ester pure-acrylic emulsion, ADVANTAGEAM-1512 defoamer and step (1) prepare is added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir 60 minutes with the speed of 1000 turns/min, and add LatekollD thickening material and ResiflowW50 flow agent successively;
(3) keep stirring, after adding alcohol and KathonLXE sanitas, can ink product be packaged to be.
Target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce was 1213/cm 3, compared with following comparative example 1, add 992/cm 3negative ion concentration, reach the Air quality of town park rank.
Comparative example 1
By the formula ratio in table 2, the addition of TZY-01 negative ion powder is 0, all the other component formula amounts remain unchanged, ink is made into by the operation steps of embodiment 1, obtain target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce is 221/cm 3, far below the primary demand maintaining HUMAN HEALTH.
Embodiment 2
The composition of raw materials (2wt% negative ion powder addition) of table 3. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention, application number is 2013105793039, and publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 3, the granulated glass sphere being 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain stock white;
(2) stock white that polyacrylic ester pure-acrylic emulsion, ADVANTAGEAM-1512 defoamer and step (1) prepare is added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir 40 minutes with the speed of 1200 turns/min, and add LatekollD thickening material and ResiflowW50 flow agent successively;
(3) keep stirring, after adding alcohol and KathonLXE sanitas, can ink product be packaged to be.
Target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce was 1340/cm 3, compared with following comparative example 2, add 1109/cm 3negative ion concentration, reach the Air quality of town park rank.
Comparative example 2
By the formula ratio in table 3, the addition of TZY-01 negative ion powder is 0, all the other component formula amounts remain unchanged, ink is made into by the operation steps of embodiment 2, obtain target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce is 231/cm 3, far below the primary demand maintaining HUMAN HEALTH.
Embodiment 3
The composition of raw materials (3wt% negative ion powder addition) of table 4. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention, application number is 2013105793039, and publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 4, the granulated glass sphere being 2mm by water, BYK-P-104 dispersion agent, water-based carbon black HD-300M, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain black slurry;
(2) black slurry that polyacrylic ester pure-acrylic emulsion, ADVANTAGEAM-1512 defoamer and step (1) prepare is added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir 60 minutes with the speed of 800 turns/min, and add LatekollD thickening material and ResiflowW50 flow agent successively;
(3) keep stirring, after adding alcohol and KathonLXE sanitas, can ink product be packaged to be.
Target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce was 1575/cm 3, compared with following comparative example 3, add 1360/cm 3negative ion concentration, reach the Air quality of town park rank.
Comparative example 3
By the formula ratio in table 4, the addition of TZY-01 negative ion powder is 0, all the other component formula amounts remain unchanged, ink is made into by the operation steps of embodiment 3, obtain target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce is 215/cm 3, far below the primary demand maintaining HUMAN HEALTH.
Embodiment 4
The composition of raw materials (4wt% negative ion powder addition) of table 5. ink composite
Note: homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention, application number is 2013105793039, and publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 5, the granulated glass sphere being 2mm by water, BYK-P-104 dispersion agent, water-based carbon black HD-300M, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain black slurry;
(2) black slurry that polyacrylic ester pure-acrylic emulsion, ADVANTAGEAM-1512 defoamer and step (1) prepare is added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir 20 minutes with the speed of 1300 turns/min, and add LatekollD thickening material and ResiflowW50 flow agent successively;
(3) keep stirring, after adding alcohol and KathonLXE sanitas, can ink product be packaged to be.
Target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce was 2054/cm 3, compared with following comparative example 4, add 1825/cm 3negative ion concentration, reach the Air quality of town park rank.
Comparative example 4
By the formula ratio in table 5, the addition of TZY-01 negative ion powder is 0, all the other component formula amounts remain unchanged, ink is made into by the operation steps of embodiment 4, obtain target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce is 229/cm 3, far below the primary demand maintaining HUMAN HEALTH.
Embodiment 5
Table 6. ink combination composition formula (5wt% negative ion powder addition)
Note: homemade polyacrylic ester pure-acrylic emulsion applies for patent of invention, application number is 2013105793039, and publication number is CN103601837A.
The preparation method of ink product carries out as follows:
(1) according to the formula in table 6, the granulated glass sphere being 2mm by water, BYK-P-104 dispersion agent, titanium dioxide R-902+, coarse whiting and TZY-01 negative ion powder and diameter adds rapid dispersion machine (KS-370 coating rapid dispersion machine, Shanghai Modern Environmental Engineering Technology Co., Ltd.) in, disperse 3 hours, obtain stock white;
(2) stock white that polyacrylic ester pure-acrylic emulsion, ADVANTAGEAM-1512 defoamer and step (1) prepare is added dispersion sand mill (SDF400 experiment dispersion sand mill, Shuan Feng chemical machinery company limited of Jiangyin City) in, stir 10 minutes with the speed of 1500 turns/min, and add LatekollD thickening material and ResiflowW50 flow agent successively;
(3) keep stirring, after adding alcohol and KathonLXE sanitas, can ink product be packaged to be.
Target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce was 2296/cm 3, compared with following comparative example 5, add 2064/cm 3negative ion concentration, reach the Air quality of town park rank.
Comparative example 5
By the formula ratio in table 6, the addition of TZY-01 negative ion powder is 0, all the other component formula amounts remain unchanged, ink is made into by the operation steps of embodiment 5, obtain target ink product package stability >6 month, after Ink Application is in PVC wallpaper, by Chinese architecture material tests Spot detection, the negative ion concentration that detected result shows to use the PVC wallpaper scribbling target ink to produce is 232/cm 3, far below the primary demand maintaining HUMAN HEALTH.
Above-described embodiment is used for explaining and the present invention is described, instead of limits the invention, and in the protection domain of spirit of the present invention and claim, any amendment make the present invention and change, all fall into protection scope of the present invention.

Claims (10)

1. a negative ion water color ink, it is characterized in that described negative ion water color ink is made up of the raw material of following weight proportion: polymer emulsion 28 ~ 40 parts, pigment 15 parts, filler 4 ~ 8 parts, anionic additive 1 ~ 5 part, alcohol 3.5 ~ 8 parts, dispersion agent 0.6 ~ 3.6 part, thickening material 0.1 ~ 0.8 part, flow agent 0.05 ~ 0.3 part, defoamer 0.1 ~ 0.8 part, sanitas 0.05 ~ 0.06 part, 26.92 ~ 41 parts, water; Described polymer emulsion is the mixture of one or more arbitrary proportions in benzene emulsion, vac-veova emulsion, acrylate and vinyl acetate emulsion, polyacrylic ester pure-acrylic emulsion, polyaminoester emulsion, organosilicon crylic acid latex, fluoro-resin emulsion, further, the solid content of described polymer emulsion is 45wt% ~ 50wt%; Described filler is the mixture of one or more arbitrary proportions in talcum powder, coarse whiting, fine particle calcium carbonate, kaolin, wollastonite powder physique filler.
2. negative ion water color ink as claimed in claim 1, is characterized in that described pigment is the one in titanium dioxide, zinc oxide, zinc sulfide white, carbon black, iron oxide black, nigrosine, lead-chrome yellow, iron oxide yellow, iron oxide red, red, phthalocyanine blue b, ultramarine.
3. negative ion water color ink as claimed in claim 1, is characterized in that described anionic additive is tourmaline powder.
4. negative ion water color ink as claimed in claim 1, is characterized in that described dispersion agent is the mixture of one or more arbitrary proportions in polycarboxylate, polyacrylic acid derivative, suitable divinyl anhydride multipolymer, condensation naphthalenesulfonate, poly carboxylic acid or polyvinyl alcohol.
5. negative ion water color ink as claimed in claim 4, is characterized in that wherein said suitable divinyl anhydride multipolymer is diisobutylene-cis-butenedioic anhydride multipolymer or styrene-maleic anhydride copolymer.
6. negative ion water color ink as claimed in claim 1, is characterized in that described thickening material is the mixture of any one or two or more arbitrary proportion in cellulose thickener, polyurethanes thickening material, agent for polyacrylic acid thickening, polyacrylate-type thickeners.
7. negative ion water color ink as claimed in claim 1, is characterized in that described flow agent is the mixture of one or more arbitrary proportions in polyacrylate(s) flow agent, silicone resin class flow agent, fluoroolefins flow agent.
8. negative ion water color ink as claimed in claim 1, is characterized in that described defoamer is the mixture of one or more arbitrary proportions in lower alcohols defoamer, mineral oil defoaming agent, silicone based defoamer.
9. negative ion water color ink as claimed in claim 1, is characterized in that described sanitas is the mixture of one or more arbitrary proportions in substituted arene class sanitas, heterocycles sanitas, aminated compounds class sanitas.
10. the preparation method of negative ion water color ink as claimed in claim 1, is characterized in that described preparation method carries out as follows:
(1) water of formula ratio, dispersion agent, pigment, filler, anionic additive and granulated glass sphere are added in rapid dispersion machine, disperse 2 ~ 3 hours, obtain mill base;
(2) mill base that the polymer emulsion of formula ratio, defoamer and step (1) prepare is added in dispersion sand mill, stir 10 ~ 60 minutes with the speed of 800 ~ 1500 turns/min, then add thickening material and the flow agent of formula ratio;
(3) keep stirring, after adding the alcohol of formula ratio, sanitas, namely obtain described negative ion water color ink.
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