CN101974273A - Exterior wall coating and preparation method thereof - Google Patents
Exterior wall coating and preparation method thereof Download PDFInfo
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- CN101974273A CN101974273A CN 201010503268 CN201010503268A CN101974273A CN 101974273 A CN101974273 A CN 101974273A CN 201010503268 CN201010503268 CN 201010503268 CN 201010503268 A CN201010503268 A CN 201010503268A CN 101974273 A CN101974273 A CN 101974273A
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Abstract
The invention discloses a multifunctional exterior wall coating with strong weather resistance, brushing resistance and high adhesion and a preparation method thereof. The exterior wall coating is prepared from the following raw materials in percentage by weight: 10-30% of silicone acrylic emulsion with a interpenetrating network structure, 10-40% of acrylic ester emulsion, 1-15% of hydrophobically modified inorganic nanoparticles, 10-40% of pigment and filler, 0.3-1% of a dispersing agent, 0.1-0.2% of a defoaming agent, 0.1-0.3% of a preservative, 0.3-0.6% of a flatting agent, 1-2% of a thickening agent, and the balance deionized water. The exterior wall coating of the invention has the advantages of strong weather resistance, brushing resistance, strong adhesion, long service life, simple and convenient preparation process and low equipment requirement, thus being easy for large-scale popularization and application. The exterior wall coating overcomes the defects of poor brushing resistance, poor ageing resistance and the like of the existing exterior wall coating.
Description
Technical field
The present invention relates to building material field, be specifically related to a kind of exterior coating and preparation method thereof.
Background technology
In recent years, Water-borne modification, environmental protectionization, multifunction and high performance have become the trend of building external paint development.Along with the raising of people's living standard, functions such as the waterproof of exterior coating, mildew-resistant, insect protected are also understood by the common people gradually and are accepted, thereby the decorative effect of coating is had higher requirement.
At present, the exterior coating of China's employing mainly is base-material with the ACRYLIC EMULSION.Water soluble acrylic acid coating has that cost is moderate, weathering resistance is good, adjustable is good, and advantages such as organic solvent-free release are development in recent years class coating products very rapidly.But at present the acrylic coating of throwing on the domestic market have that gloss is low, poor adhesive force, not water-fast shortcoming such as wash, and high temperature easily returns sticking, fragile under low temperature splitting, and causes coating to ftracture easily, peel off, rainwater etc. infiltrate metope, corrosion body of wall easily.This not only influences the beautiful decoration of buildings, and will reduce the work-ing life of buildings.
Summary of the invention
The shortcoming that primary and foremost purpose of the present invention is to overcome prior art provides a kind of high weather resisteant, anti-that scrub, high adhesive force, multi-functional exterior coating with not enough.
Another object of the present invention is to provide the preparation method of above-mentioned exterior coating.
Purpose of the present invention is achieved through the following technical solutions:
A kind of exterior coating obtains by the composition of following mass percent is prepared:
The organosilicon crylic acid latex of tool network interpenetrating structure: 10～30%
Acrylic emulsion: 10～40%
The inorganic nano-particle of hydrophobically modified: 1～15%
Color stuffing: 10～40%
Dispersion agent: 0.3～1%
Defoamer: 0.1～0.2%
Sanitas: 0.1～0.3%
Flow agent: 0.3～0.6%
Thickening material: 1～2%
Surplus is a deionized water.
Described acrylic emulsion is a kind of in pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, the organosilicon crylic acid latex.
Described color stuffing is one or more the mixture in Rutile type Titanium Dioxide, lime carbonate, barium sulfate, talcum powder and the kaolin.
Described dispersion agent is Sodium hexametaphosphate 99, sodium lauryl sulphate, Sodium dodecylbenzene sulfonate, trisodium phosphate, fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, BYK161, BYK163, BYK164, BYK167, BYK300, BYK170, EFKA64, EFKA66,5040, A1160 or Z6040.
Described defoamer is that fatty acid ester, long-chain alcohol, organophosphate, fatty acid amide, octadecylisocyanate, BYK065, BYK141, BYK019, BYK052, BYK057, BYK058, TP-39, moral are modest 2700, moral is modest 3100, moral is modest 3500, EFKA 2020 or EFKA2550.
Described sanitas is 2-methyl-4-isothiazoline-3-ketone, 5-chloro-2-methyl-4-isothiazoline-3-ketone, n-Salicylanlide, para toluene sulfonamide, pentachlorophenol, phenyl-8-mercury phenoxyl quinoline, phenylmercury acetate or zinc chloride.
Described flow agent is pure acrylic acid ester, modified polyacrylate, vinylformic acid alkali soluble resin, organic silicon modified by polyether, reactive organosilicon, polyester modification organosilicon, micronization wax emulsion, BYK333, BYK323, BYK306, BYK307, EFKA3031, EFKA 3033, EFKA3239, RM2020 or EFKA3777.
Described thickening material is carboxymethyl cellulose, methylcellulose gum, Natvosol, Vltra tears, polyacrylate, wilkinite or aerosil.
The organosilicon crylic acid latex of described tool network interpenetrating structure is prepared by following method:
(1) at first 20～25 parts by weight of ethylene base organosilane monomers, 5～6 parts by weight of acrylic acid (ester) monomer, 0.2～0.3 weight part self-cross linking monomer, 0.1～0.3 weight part emulsifying agent and 10～13 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) with 0.1～0.3 weight part buffer reagent, 0.2～0.45 weight part emulsifiers dissolve in 40～45 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.3～0.45 weight part initiator, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part organosilane monomers, 15～18 parts by weight of acrylic acid (ester) monomer, 0.5～0.6 weight part self-cross linking monomer, 0.15～0.2 weight part emulsifying agent and 10～14 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part initiator simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
Described vinyl organosilicon monomer is C
5～C
18A kind of in the alkenyl alkoxy silane; A kind of in preferred vinyl triethoxyl silane, the vinyl trichloro silane.
Described vinylformic acid (ester) monomer is one or more the mixture in methyl methacrylate, Jia Jibingxisuanyizhi, butyl methacrylate, Propenoic acid, 2-methyl, isobutyl ester, Isooctyl methacrylate, butyl acrylate, ethyl propenoate, Isooctyl acrylate monomer, the vinylformic acid.
Described self-cross linking monomer is a kind of in acrylamide, the N hydroxymethyl acrylamide.
Described emulsifying agent is one or more the mixture in sodium lauryl sulphate, dodecane agent benzene sulfonic acid sodium salt, polyoxyethylene-4-phenolic group ether ammonium sulfate salt fat, ethoxylated alkylphenol ammonium sulfate, polyoxyethylene nonylphenol ether, polyoxyethylene octylphenol ether, dodecyl Soxylat A 25-7, the nonyl phenol ethoxylate allyloxy Nonyl pheno.
Described buffer reagent is a kind of in sodium bicarbonate, yellow soda ash, potassiumphosphate, sal enixum, sodium-acetate, Sodium phosphate dibasic, the potassium primary phosphate.
Described initiator is a kind of in ammonium persulphate, Potassium Persulphate, the Sodium Persulfate.
Described organosilane monomer is a kind of in γ-r-chloropropyl trimethoxyl silane, γ-mercaptopropyl trimethoxysilane, the γ-An Bingjisanyiyangjiguiwan.
The inorganic nano-particle of described hydrophobically modified is prepared by following method:
(1) get 2～4 weight part inorganic nano-particles and join in 30～45 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 50～60 ℃ of heating in water bath;
(2) get 1～3.5 weight part silane coupling agent and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70～80 ℃, continue reaction 24 hours, discharging promptly gets the inorganic nano-particle of hydrophobically modified.
Described inorganic nano-particle is nanometer SiO
2, nano-TiO
2In a kind of.
Described silane coupling agent, its structural formula are Y (CH
2)
nSiX
3, wherein X is hydrolyzable chloro, methoxyl group, oxyethyl group, methoxy ethoxy, acetoxyl group; Y is vinyl, amino, epoxy group(ing), methacryloxy, sulfydryl or urea groups; N=0～3.
The preparation method of above-mentioned exterior coating may further comprise the steps:
(1), sheared 30～60 minutes with 550～700rpm the nanoparticle of water, 1～15% hydrophobically modified, 0.3～1% dispersant;
(2) add 10～40% color stuffings, 0.1～0.3% sanitas, 0.5～0.8% thickening material and 0.06% defoamer successively, shear with 500～600rpm, to the filler granularity less than 40 microns;
(3) add organosilicon crylic acid latex, 10～40% acrylic emulsions, 0.04～0.14% defoamer, 0.3～0.6% flow agent of 10～30% tool network interpenetrating structures more successively, with 250～300rpm dispersed with stirring 60 minutes;
(4) the pH value of reaction system is transferred to 8～9, adds 0.45～1.5% thickening material again and regulate viscosity, be uniformly dispersed, filter, packing gets product;
Described per-cent is the per-cent that accounts for the exterior coating total mass.
Base-material and color stuffing are to influence that coating is anti-ly scrubbed, the important factor of weather resisteant.Exterior coating of the present invention is a base-material with the network interpenetrating structure organosilicon crylic acid latex of light, good heat stability, introduce hydrophobic performance, the good inorganic nano-particle of weather resisteant again, and auxiliary agent etc. is optimized selection, prepare have high weather resisteant, anti-ly scrub, strong adhesion, the exterior coating of long service life.
The reticulated structure of interpenetrating net polymer is two or more polymer blend, and molecular chain runs through mutually, the network structure that polymer molecular chain forms with the mode interlinkage of chemical bond.On synthetic method, can add the synthetic seed polymer of the monomer that linking agent is arranged, and then seed emulsion be carried out the swelling initiation reaction, thereby generate interpenetrating net polymer with the monomer that is added with linking agent.
The present invention has following advantage and effect with respect to prior art:
(1) preparation technology of exterior coating of the present invention is easy, not high to equipment requirements, is easy to large-scale promotion application.
(2) exterior coating of the present invention has high weather resisteant, brushing resistance, strong adhesion, long service life.
Embodiment
The present invention is described in further detail below in conjunction with embodiment, but embodiments of the present invention are not limited thereto.
Embodiment one:
The exterior coating prescription is formed:
| Raw material | Consumption (kg) | Manufacturer/supplier |
| Water | 24.2 |
| Network interpenetrating structure organosilicon crylic acid latex | 20 | Self-control |
| Benzene emulsion | 20 | National starch |
| Modified manometer silicon dioxide | 5 | Self-control |
| Rutile type Titanium Dioxide | 10 | Shanghai face titanium |
| The calcium carbonate superfine powder powder | 10 | Peak, Shenzhen |
| Kaolin | 9 | Peak, Shenzhen |
| Dispersion agent 5040 | 0.3 | As sending out chemical industry |
| Defoamer TP-39 | 0.1 | Japan Nuo Puke |
| Sanitas KSG201 | 0.1 | Guangdong enlightening U.S. |
| Flow agent RM2020 | 0.3 | ROHM AND HAAS |
| Thickening material 3800 | 1 | River, sea chemical industry |
| Add up to | 100 |
The preparation process of the organosilicon crylic acid latex of tool network interpenetrating structure is as follows:
(1) at first 20 parts by weight of ethylene ethyl triethoxy silicane alkane, 6 parts by weight of methylmethacrylate, 0.2 weight part acrylamide, 0.1 weight part sodium lauryl sulphate and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) 0.1 weight part sodium bicarbonate, 0.2 weight part sodium lauryl sulphate are dissolved in 40 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.3 weight part ammonium persulphate, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part γ-r-chloropropyl trimethoxyl silanes, 15 weight part Isooctyl methacrylates, 0.5 weight part acrylamide, 0.2 weight part sodium lauryl sulphate and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part ammonium persulphate simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
The preparation process of the inorganic nano-particle of hydrophobically modified is as follows:
(1) gets 2 weight part nanometer SiO
2Join in the 30 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 50 ℃ of heating in water bath;
(2) get 1 parts by weight of ethylene ethyl triethoxy silicane alkane and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70 ℃, continue reaction 24 hours, discharging, the particle size range that promptly gets hydrophobically modified is the SiO of 120～160nm
2Nanoparticle.
The preparation process of exterior coating is as follows:
(1) in the Scattered Kettle that has the high speed shear dispersion machine, adds 24.2kg water, add 5kg modification SiO successively
2Nanoparticle, 0.3kg dispersion agent 5040,550rpm sheared 60 minutes, made it to be uniformly dispersed;
(2) speed that will shear dispersion machine is transferred 300rpm, add 10kg Rutile type Titanium Dioxide, 10kg calcium carbonate superfine powder powder, 9kg kaolin, 0.1kg KSG201,0.55kg3800 and 0.06kg TP-39 successively, high speed 600rpm shears again, to the filler granularity less than 40 microns;
(3) the velocity of shear 300rpm that slows down adds organosilicon crylic acid latex, 20kg pure-acrylic emulsion, 0.04kg TP-39, the 0.3kg RM2020 of 20kg tool network interpenetrating structure successively, shears with 250rpm and disperses 60 minutes to evenly;
(4) transfer between 8～9 with the scope of ammoniacal liquor with the pH value, add 0.45kg3800 again and regulate viscosity, be uniformly dispersed, filter, packing gets product.
The abrasion resistance test of filming of present embodiment exterior coating: 〉=12000 times; The artificial ageing resistance test: 1500 hours non-foaming, do not peel off, flawless, 0 grade of chalk rating, 1 grade of variable color grade.Brush this product, coatingsurface is bright and clean beautiful, exposes to the weather through the several months, and its paint film, color and luster are all as excellent as before.
The fundamental property of product of the present invention is measured according to the method for regulation among the GB GB/T9755-2001 " exterior wall coating material of synthetic resin emulsion "; The brushing resistance of filming is measured according to the method for stipulating among the GB GB/T9266-1988; Artificial ageing resistance carries out according to the method for stipulating among the GB GB/T1865-1997.Down together.
Embodiment two:
The exterior coating prescription is formed:
| Raw material | Consumption (kg) | Manufacturer/supplier |
| Water | 11.8 | |
| Network interpenetrating structure organosilicon crylic acid latex | 30 | Self-control |
| Organosilicon crylic acid latex | 20 | National starch |
| Modified nano-titanium dioxide | 5 | Self-control |
| Rutile type Titanium Dioxide | 10 | Shanghai face titanium |
| The calcium carbonate superfine powder powder | 10 | Peak, Shenzhen |
| Kaolin | 10 | Peak, Shenzhen |
| Dispersion agent 5040 | 1 | As sending out chemical industry |
| Defoamer TP-39 | 0.2 | Japan Nuo Puke |
| Sanitas KSG201 | 0.1 | Guangdong enlightening U.S. |
| Flow agent RM2020 | 0.4 | ROHM AND HAAS |
| Thickening material 3800 | 1.5 | River, sea chemical industry |
| Add up to | 100 |
The preparation process of the organosilicon crylic acid latex of tool network interpenetrating structure is as follows:
(1) at first 22 parts by weight of ethylene ethyl triethoxy silicane alkane, 3 parts by weight of acrylic acid butyl esters, 2 parts by weight of acrylic acid ethyl esters, 0.3 weight part acrylamide, 0.2 weight part sodium lauryl sulphate and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) 0.15 weight part potassiumphosphate, 0.2 weight part nonyl phenol ethoxylate allyloxy Nonyl pheno are dissolved in 45 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.4 weight part Potassium Persulphate, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part γ-mercaptopropyl trimethoxysilanes, 18 weight part Isooctyl methacrylates, 0.6 weight part acrylamide, 0.2 weight part nonyl phenol ethoxylate allyloxy Nonyl pheno and 14 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part Potassium Persulphate simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
The preparation process of the inorganic nano-particle of hydrophobically modified is as follows:
(1) gets 3 weight part TiO
2Join in the 30 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 50 ℃ of heating in water bath;
(2) get 1.5 weight part epoxy group(ing) trichlorine base silanes and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70 ℃, continue reaction 24 hours, discharging, the particle size range that promptly gets hydrophobically modified is the TiO of 140～180nm
2Nanoparticle.
The preparation process of exterior coating is as follows:
(1) in the Scattered Kettle that has the high speed shear dispersion machine, adds 11.8kg water, add 5kg modification TiO successively
2Nanoparticle, 1kg dispersion agent 5040,600rpm sheared 50 minutes, made it to be uniformly dispersed;
(2) speed that will shear dispersion machine is transferred 300rpm, add 10kg Rutile type Titanium Dioxide, 10kg calcium carbonate superfine powder powder, 10kg kaolin, 0.1kg KSG201,0.6kg3800 and 0.06kg TP-39 successively, high speed 550rpm shears again, to the filler granularity less than 40 microns;
(3) the velocity of shear 300rpm that slows down adds organosilicon crylic acid latex, 20kg pure-acrylic emulsion, 0.14kg TP-39, the 0.4kg RM2020 of 30kg tool network interpenetrating structure successively, shears with 300rpm and disperses 60 minutes to evenly;
(4) transfer between 8～9 with the scope of ammoniacal liquor with the pH value, add 0.9kg3800 again and regulate viscosity, be uniformly dispersed, filter, packing gets product.
The abrasion resistance test of filming of present embodiment exterior coating: 〉=10000 times; The artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless, 0 grade of chalk rating, 1 grade of variable color grade.Brushing coating of the present invention, coatingsurface is beautiful bright and clean, good leveling property.Through several months expose to the weather, coating was as excellent as before, was the good selection of Highrise buildings.
Embodiment three:
The exterior coating prescription is formed:
| Raw material | Consumption (kg) | Manufacturer/supplier |
| Water | 21.9 | |
| Network interpenetrating structure organosilicon crylic acid latex | 10 | Self-control |
| Pure-acrylic emulsion | 40 | National starch |
| Modified nano-titanium dioxide | 5 | Self-control |
| Rutile type Titanium Dioxide | 20 | Shanghai face titanium |
| Dispersion agent 5040 | 0.3 | As sending out chemical industry |
| Defoamer TP-39 | 0.1 | Japan Nuo Puke |
| Sanitas KSG201 | 0.1 | Guangdong enlightening U.S. |
| Flow agent RM2020 | 0.6 | ROHM AND HAAS |
| Thickening material 3800 | 2 | River, sea chemical industry |
| Add up to | 100 |
The preparation process of the organosilicon crylic acid latex of tool network interpenetrating structure is as follows:
(1) at first 23 parts by weight of ethylene ethyl triethoxy silicane alkane, 6 weight part Propenoic acid, 2-methyl, isobutyl esters, 0.25 weight part N hydroxymethyl acrylamide, 0.3 weight part ethoxylated alkylphenol ammonium sulfate and 13 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) 0.25 weight part sodium-acetate, 0.2 weight part ethoxylated alkylphenol ammonium sulfate are dissolved in 40 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.4 weight part Sodium Persulfate, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part γ-An Bingjisanyiyangjiguiwans, 15 weight part Isooctyl methacrylates, 0.5 weight part acrylamide, 0.2 weight part ethoxylated alkylphenol ammonium sulfate and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part Sodium Persulfate simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
The preparation process of the inorganic nano-particle of hydrophobically modified is as follows:
(1) gets 3.5 weight part nano-TiOs
2Join in the 40 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 55 ℃ of heating in water bath;
(2) get the amino Trimethoxy silane of 3 weight parts and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 80 ℃, continue reaction 24 hours, discharging, the particle size range that promptly gets hydrophobically modified is the TiO of 80～140nm
2Nanoparticle.
The preparation process of exterior coating is as follows:
(1) in the Scattered Kettle that has the high speed shear dispersion machine, adds 21.9kg water, add 5kg modification TiO successively
2Nanoparticle, 0.3kg dispersion agent 5040,650rpm sheared 40 minutes, made it to be uniformly dispersed;
(2) speed that will shear dispersion machine is transferred 300rpm, adds 20kg Rutile type Titanium Dioxide, 0.1kgKSG201,0.8kg 3800 and 0.06kg TP-39 successively, and high speed 500rpm shears again, to the filler granularity less than 40 microns;
(3) velocity of shear that slows down adds organosilicon crylic acid latex, 40kg pure-acrylic emulsion, 0.04kg TP-39, the 0.6kg RM2020 of 10kg tool network interpenetrating structure successively, shears with 250rpm and disperses 60 minutes to evenly;
(4) transfer between 8～9 with the scope of ammoniacal liquor with the pH value, add 1.2kg3800 again and regulate viscosity, be uniformly dispersed, filter, packing gets product.
The abrasion resistance test of filming of present embodiment exterior coating:＞6000 times; The artificial ageing resistance test: 1000 hours non-foaming, do not peel off, flawless, 0 grade of chalk rating, 1 grade of variable color grade.Coating is beautiful bright and clean, and antifouling property is good.
Embodiment four:
The exterior coating prescription is formed:
| Raw material | Consumption (kg) | Manufacturer/supplier |
| Water | 31.1 | |
| Network interpenetrating structure organosilicon crylic acid latex | 30 | Self-control |
| Acrylate and vinyl acetate emulsion | 10 | National starch |
| Modified manometer silicon dioxide | 15 | Self-control |
| Rutile type Titanium Dioxide | 10 | Shanghai face titanium |
| Dispersion agent 5040 | 1 | As sending out chemical industry |
| Defoamer TP-39 | 0.2 | Japan Nuo Puke |
| Sanitas KSG201 | 0.1 | Guangdong enlightening U.S. |
| Flow agent RM2020 | 0.6 | ROHM AND HAAS |
| Thickening material 3800 | 2 | River, sea chemical industry |
| Add up to | 100 |
The preparation process of the organosilicon crylic acid latex of tool network interpenetrating structure is as follows:
(1) at first 25 parts by weight of ethylene base trichlorosilanes, 6 weight part butyl methacrylate, 0.2 weight part acrylamide, 0.1 weight part sodium lauryl sulphate, 0.2 weight part polyoxyethylene octylphenol ether and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) 0.3 weight part sal enixum, 0.15 weight part sodium lauryl sulphate, 0.3 weight part polyoxyethylene octylphenol ether are dissolved in 45 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.45 weight part ammonium persulphate, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part γ-r-chloropropyl trimethoxyl silanes, 15 weight part Isooctyl methacrylates, 0.5 weight part acrylamide, 0.05 weight part sodium lauryl sulphate, 0.1 weight part polyoxyethylene octylphenol ether and 13 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part ammonium persulphate simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
The preparation process of the inorganic nano-particle of hydrophobically modified is as follows:
(1) gets 4 weight part SiO
2Join in the 45 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 60 ℃ of heating in water bath;
(2) get 3.5 weight part sulfydryl triacetoxysilanes and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70 ℃, continue reaction 24 hours, discharging, the particle size range that promptly gets hydrophobically modified is the SiO of 100～130nm
2Nanoparticle.
The preparation process of exterior coating is as follows:
(1) in the Scattered Kettle that has the high speed shear dispersion machine, adds 31.1kg water, add 15kg modification SiO successively
2Nanoparticle, 1kg dispersion agent 5040,700rpm sheared 30 minutes, made it to be uniformly dispersed;
(2) speed that will shear dispersion machine is transferred 300rpm, adds 10kg Rutile type Titanium Dioxide, 0.1kgKSG201,0.5kg3800 and 0.06kg TP-39 successively, and high speed 500rpm shears again, to the filler granularity less than 40 microns;
(3) velocity of shear that slows down adds organosilicon crylic acid latex, 10gk acrylate and vinyl acetate emulsion, 0.14kg TP-39, the 0.6kg RM2020 of 30kg tool network interpenetrating structure successively, shears with 300rpm and disperses 60 minutes to evenly;
(4) transfer between 8～9 with the scope of ammoniacal liquor with the pH value, add 1.5kg3800 again and regulate viscosity, be uniformly dispersed, filter, packing gets product.
The abrasion resistance test of filming of present embodiment exterior coating:＞15000 times; The artificial ageing resistance test: 1500 hours non-foaming, do not peel off, flawless, 0 grade of chalk rating, 1 grade of variable color grade.Brush this coating, the coating hardness height, good leveling property is lasted some months, and coating is sparkling clean.
Embodiment five:
The exterior coating prescription is formed:
| Raw material | Consumption (kg) | Manufacturer/supplier |
| Water | 16.6 | |
| Network interpenetrating structure organosilicon crylic acid latex | 30 | Self-control |
| Pure-acrylic emulsion | 10 | National starch |
| Modified manometer silicon dioxide | 1 | Self-control |
| Rutile type Titanium Dioxide | 20 | Shanghai face titanium |
| The calcium carbonate superfine powder powder | 20 | Peak, Shenzhen |
| Dispersion agent 5040 | 0.3 | As sending out chemical industry |
| Defoamer TP-39 | 0.2 | Japan Nuo Puke |
| Sanitas KSG201 | 0.3 | Guangdong enlightening U.S. |
| Flow agent RM2020 | 0.6 | ROHM AND HAAS |
| Thickening material 3800 | 1 | River, sea chemical industry |
| Add up to | 100 |
The preparation process of the organosilicon crylic acid latex of tool network interpenetrating structure is as follows:
(1) at first 25 parts by weight of ethylene ethyl triethoxy silicane alkane, 4 parts by weight of methylmethacrylate, 2 parts by weight of acrylic acid, 0.2 weight part acrylamide, 0.1 weight part sodium lauryl sulphate and 10 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) 0.3 weight part sodium bicarbonate, 0.2 weight part sodium lauryl sulphate are dissolved in 40 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.3 weight part ammonium persulphate, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part γ-r-chloropropyl trimethoxyl silanes, 15 weight part Isooctyl methacrylates, 0.5 weight part acrylamide, 0.2 weight part and 10 sodium lauryl sulphate parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part ammonium persulphate simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure.
The preparation process of the inorganic nano-particle of hydrophobically modified is as follows:
(1) gets 2 weight part SiO
2Join in the 30 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 50 ℃ of heating in water bath;
(2) get 1 weight part urea groups trimethoxy Ethoxysilane and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70 ℃, continue reaction 24 hours, discharging, the particle size range that promptly gets hydrophobically modified is the SiO of 150～200nm
2Nanoparticle.
The preparation process of exterior coating is as follows:
(1) in the Scattered Kettle that has the high speed shear dispersion machine, adds 16.6kg water, add 1kg modification SiO successively
2Nanoparticle, 0.3kg dispersion agent 5040,550rpm sheared 60 minutes, made it to be uniformly dispersed;
(2) speed that will shear dispersion machine is transferred 300rpm, adds 20kg Rutile type Titanium Dioxide, 20kg calcium carbonate superfine powder powder, 0.3kg KSG201,0.55kg3800 and 0.06kg TP-39 successively, and high speed 600rpm shears again, to the filler granularity less than 40 microns;
(3) velocity of shear that slows down adds organosilicon crylic acid latex, 10kg pure-acrylic emulsion, 0.14kg TP-39, the 0.6kg RM2020 of 30kg tool network interpenetrating structure successively, shears with 300rpm and disperses 60 minutes to evenly;
(4) transfer between 8～9 with the scope of ammoniacal liquor with the pH value, add 0.45kg3800 again and regulate viscosity, be uniformly dispersed, filter, packing gets product.
The abrasion resistance test of filming of present embodiment exterior coating:＞12000 times; The artificial ageing resistance test: 900 hours non-foaming, do not peel off, flawless, 0 grade of chalk rating, 1 grade of variable color grade.Use paint finishing exterior wall of the present invention, the coating antifouling property is good, the hardness height.
Following table is other performance test results of product of the present invention:
The foregoing description is a preferred implementation of the present invention; but embodiments of the present invention are not restricted to the described embodiments; other any do not deviate from change, the modification done under spirit of the present invention and the principle, substitutes, combination, simplify; all should be the substitute mode of equivalence, be included within protection scope of the present invention.
Claims (9)
1. exterior coating obtains by the composition of following mass percent is prepared:
The organosilicon crylic acid latex of tool network interpenetrating structure: 10～30%
Acrylic emulsion: 10～40%
The inorganic nano-particle of hydrophobically modified: 1～15%
Color stuffing: 10～40%
Dispersion agent: 0.3～1%
Defoamer: 0.1～0.2%
Sanitas: 0.1～0.3%
Flow agent: 0.3～0.6%
Thickening material: 1～2%
Surplus is a deionized water;
The organosilicon crylic acid latex of described tool network interpenetrating structure is prepared by following method:
(1) at first 20～25 parts by weight of ethylene base organosilane monomers, 5～6 parts by weight of acrylic acid (ester) monomer, 0.2～0.3 weight part self-cross linking monomer, 0.1～0.3 weight part emulsifying agent and 10～13 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(2) with 0.1～0.3 weight part buffer reagent, 0.2～0.45 weight part emulsifiers dissolve in 40～45 parts by weight of deionized water, be warming up to 65 ℃, add 15% of step (1) pre-emulsion quality, continue to be warming up to 80 ℃, and splash into remaining pre-emulsion of step (1) and 0.3～0.45 weight part initiator, control pre-emulsion and initiator dripped off in 1.5 hours, and insulation reaction 1.5 hours;
(3) 12 weight part organosilane monomers, 15～18 parts by weight of acrylic acid (ester) monomer, 0.5～0.6 weight part self-cross linking monomer, 0.15～0.2 weight part emulsifying agent and 10～14 parts by weight of deionized water are mixed, carry out pre-emulsion reaction, obtain pre-emulsion;
(4) pre-emulsion that step (3) is obtained splashes in the reaction system of step (2), splashes into 0.3 weight part initiator simultaneously, and the control dropping time is at 1.5 hours, insulation reaction 2.5 hours, and discharging promptly obtains the organosilicon crylic acid latex of tool network interpenetrating structure;
The inorganic nano-particle of described hydrophobically modified is prepared by following method:
(1) get 2～4 weight part inorganic nano-particles and join in 30～45 weight part dehydrated alcohols, ultra-sonic dispersion 20 minutes obtains nanoparticle dispersion liquid, with it at 50～60 ℃ of heating in water bath;
(2) get 1～3.5 weight part silane coupling agent and mix with 20 weight part dehydrated alcohols, obtain the silane coupling agent mixed solution, it is splashed in the nanoparticle dispersion liquid of step (1), the control dropping time is 2 hours; After dropwising, bath temperature is brought up to 70～80 ℃, continue reaction 24 hours, discharging promptly gets the inorganic nano-particle of hydrophobically modified.
2. a kind of exterior coating according to claim 1 is characterized in that:
Described acrylic emulsion is a kind of in pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, the organosilicon crylic acid latex;
Described color stuffing is one or more the mixture in Rutile type Titanium Dioxide, lime carbonate, barium sulfate, talcum powder and the kaolin.
3. a kind of exterior coating according to claim 1 is characterized in that: described vinyl organosilicon monomer is C
5～C
18A kind of in the alkenyl alkoxy silane.
4. a kind of exterior coating according to claim 1 is characterized in that: described vinyl organosilicon monomer is a kind of in vinyltriethoxysilane, the vinyl trichloro silane.
5. a kind of exterior coating according to claim 1 is characterized in that:
Described vinylformic acid (ester) monomer is one or more the mixture in methyl methacrylate, Jia Jibingxisuanyizhi, butyl methacrylate, Propenoic acid, 2-methyl, isobutyl ester, Isooctyl methacrylate, butyl acrylate, ethyl propenoate, Isooctyl acrylate monomer, the vinylformic acid;
Described self-cross linking monomer is a kind of in acrylamide, the N hydroxymethyl acrylamide.
6. a kind of exterior coating according to claim 1 is characterized in that:
Described emulsifying agent is one or more the mixture in sodium lauryl sulphate, dodecane agent benzene sulfonic acid sodium salt, polyoxyethylene-4-phenolic group ether ammonium sulfate salt fat, ethoxylated alkylphenol ammonium sulfate, polyoxyethylene nonylphenol ether, polyoxyethylene octylphenol ether, dodecyl Soxylat A 25-7, the nonyl phenol ethoxylate allyloxy Nonyl pheno;
Described buffer reagent is a kind of in sodium bicarbonate, yellow soda ash, potassiumphosphate, sal enixum, sodium-acetate, Sodium phosphate dibasic, the potassium primary phosphate.
7. a kind of exterior coating according to claim 1 is characterized in that:
Described initiator is a kind of in ammonium persulphate, Potassium Persulphate, the Sodium Persulfate;
Described organosilane monomer is a kind of in γ-r-chloropropyl trimethoxyl silane, γ-mercaptopropyl trimethoxysilane, the γ-An Bingjisanyiyangjiguiwan.
8. a kind of exterior coating according to claim 1 is characterized in that:
Described inorganic nano-particle is nanometer SiO
2, nano-TiO
2In a kind of;
Described silane coupling agent, its structural formula are Y (CH
2)
nSiX
3, wherein X is chloro, methoxyl group, oxyethyl group, methoxy ethoxy, acetoxyl group; Y is vinyl, amino, epoxy group(ing), methacryloxy, sulfydryl or urea groups; N=0～3.
9. the preparation method of the described exterior coating of claim 1 is characterized in that may further comprise the steps:
(1), sheared 30～60 minutes with 550～700rpm the nanoparticle of water, 1～15% hydrophobically modified, 0.3～1% dispersant;
(2) add 10～40% color stuffings, 0.1～0.3% sanitas, 0.5～0.8% thickening material and 0.06% defoamer successively, shear with 500～600rpm, to the filler granularity less than 40 microns;
(3) add organosilicon crylic acid latex, 10～40% acrylic emulsions, 0.04～0.14% defoamer, 0.3～0.6% flow agent of 10～30% tool network interpenetrating structures more successively, with 250～300rpm dispersed with stirring 60 minutes;
(4) the pH value of reaction system is transferred to 8～9, adds 0.45～1.5% thickening material again and regulate viscosity, be uniformly dispersed, filter, packing gets product;
Described per-cent is the per-cent that accounts for the exterior coating total mass.
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|---|---|---|---|
| CN201010503268A CN101974273B (en) | 2010-10-09 | 2010-10-09 | Exterior wall coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010503268A CN101974273B (en) | 2010-10-09 | 2010-10-09 | Exterior wall coating and preparation method thereof |
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| CN101974273B CN101974273B (en) | 2012-10-03 |
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Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385447A (en) * | 2002-04-29 | 2002-12-18 | 华南理工大学 | Organic silicon-acrylate nano emulsion |
| US20050025985A1 (en) * | 2003-07-29 | 2005-02-03 | Parker Richard Henry | Polymer coating blends |
| CN1629202A (en) * | 2004-10-22 | 2005-06-22 | 同济大学 | High-silicon content shell-core structured silicon/acrylic emulsion and method for preparing same |
| CN1912031A (en) * | 2006-08-18 | 2007-02-14 | 浙江中成建工集团有限公司 | Super whether resistant high antipollution composite elastic construction paint |
| US20080063797A1 (en) * | 2005-12-28 | 2008-03-13 | Industrial Technology Research Institute | Low stain and low mist adhesion coating |
| CN101250376A (en) * | 2008-03-19 | 2008-08-27 | 汕头经济特区龙湖科技有限公司 | Silicone exterior wall paint and preparation method thereof |
| CN101649153A (en) * | 2009-09-07 | 2010-02-17 | 大连工业大学 | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof |
| CN101824258A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Waterborne reflective heat-insulating building coating |
-
2010
- 2010-10-09 CN CN201010503268A patent/CN101974273B/en not_active Expired - Fee Related
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1385447A (en) * | 2002-04-29 | 2002-12-18 | 华南理工大学 | Organic silicon-acrylate nano emulsion |
| US20050025985A1 (en) * | 2003-07-29 | 2005-02-03 | Parker Richard Henry | Polymer coating blends |
| CN1629202A (en) * | 2004-10-22 | 2005-06-22 | 同济大学 | High-silicon content shell-core structured silicon/acrylic emulsion and method for preparing same |
| US20080063797A1 (en) * | 2005-12-28 | 2008-03-13 | Industrial Technology Research Institute | Low stain and low mist adhesion coating |
| CN1912031A (en) * | 2006-08-18 | 2007-02-14 | 浙江中成建工集团有限公司 | Super whether resistant high antipollution composite elastic construction paint |
| CN101250376A (en) * | 2008-03-19 | 2008-08-27 | 汕头经济特区龙湖科技有限公司 | Silicone exterior wall paint and preparation method thereof |
| CN101649153A (en) * | 2009-09-07 | 2010-02-17 | 大连工业大学 | Organic silicon modified acrylic ester aqueous wood lacquer latex and synthesizing method thereof |
| CN101824258A (en) * | 2010-04-23 | 2010-09-08 | 中国建筑材料科学研究总院苏州防水研究院 | Waterborne reflective heat-insulating building coating |
Non-Patent Citations (3)
| Title |
|---|
| 《化学建材》 20001231 孙中新等 有机硅改性丙烯酸建筑涂料的制备及性能研究 32-34 1-9 , 第5期 2 * |
| 《应用化学》 19970831 王镛先 聚有机硅氧烷-聚丙烯酸酯IPN涂料的合成 33-36 1-9 第14卷, 第4期 2 * |
| 《热固性树脂》 20100930 肖文清等 有机硅改性丙烯酸酯及其在高性能涂料中的应用 47-49,53 1-9 第25卷, 第5期 2 * |
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