CN104073164B - Elastic heat-insulated weather-resistant protection paint - Google Patents

Elastic heat-insulated weather-resistant protection paint Download PDF

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Publication number
CN104073164B
CN104073164B CN201310110133.XA CN201310110133A CN104073164B CN 104073164 B CN104073164 B CN 104073164B CN 201310110133 A CN201310110133 A CN 201310110133A CN 104073164 B CN104073164 B CN 104073164B
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China
Prior art keywords
agent
elastic
weather
emulsion
titanium dioxide
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Expired - Fee Related
Application number
CN201310110133.XA
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Chinese (zh)
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CN104073164A (en
Inventor
罗智明
陈寿生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Beijing Zhan Chen Novel Material Co Ltd
Chengdu Zhan Chen Coating Co Ltd
Qingdao Zhan Chen Novel Material Co Ltd
SHANGHAI ZHANCHEN PAINT Co Ltd
China Zhanchen Paints Group Ltd
Original Assignee
Beijing Zhan Chen Novel Material Co Ltd
Chengdu Zhan Chen Coating Co Ltd
Qingdao Zhan Chen Novel Material Co Ltd
SHANGHAI ZHANCHEN PAINT Co Ltd
China Zhanchen Paints Group Ltd
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Publication date
Application filed by Beijing Zhan Chen Novel Material Co Ltd, Chengdu Zhan Chen Coating Co Ltd, Qingdao Zhan Chen Novel Material Co Ltd, SHANGHAI ZHANCHEN PAINT Co Ltd, China Zhanchen Paints Group Ltd filed Critical Beijing Zhan Chen Novel Material Co Ltd
Priority to CN201310110133.XA priority Critical patent/CN104073164B/en
Publication of CN104073164A publication Critical patent/CN104073164A/en
Application granted granted Critical
Publication of CN104073164B publication Critical patent/CN104073164B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention discloses elastic heat-insulated weather-resistant protection paint which comprises the following components by weight percent: 8%-18% of water, 1%-2% of propylene glycol, 0.3%-1% of a dispersant, 0.1%-0.5% of a wetting agent, 1%-2% of a film-forming aid, 0.1%-0.5% of a de-foaming agent, 0.1%-0.3% of a preservative, 10%-30% of titanium dioxide, 6%-10% of calcium carbonate, 30%-50% of an elastic emulsion, 5%-9% of a nano silicone-acrylic emulsion, 3%-7% of sodium borosilicate hollow microspheres, 1%-5% of far-infrared ceramic powder, 0.1%-0.5% of a water-based nano stain-resistant agent, 0.4%-1.2% of a thickener and 0.1%-0.3% of a pH regulator. The elastic heat-insulated weather-resistant protection paint is relatively good in elasticity and reflective insulation performance and excellent in stain resistance and weather resistance, and cracks of heavy coating are avoided.

Description

The weather-proof protective paint of Elastic heat insulation
Technical field
The present invention relates to a kind of building coating is and in particular to one kind has the weather-proof protective paint of Elastic heat insulation.
Background technology
The building of prior art number greatly absolutely is high energy consumption non-economized building.This building during use, heating, The aspects such as air-conditioning, ventilation, hot water supply consume the substantial amounts of energy, account for the 30%~40% of mankind's energy resource consumption.Insulating moulding coating It is a kind of new function type coating developing in recent years, the surface using it for building can reach reduction interior of building temperature Degree, reduces the purpose that air-conditioning equal energy source consumes.Research to this kind of coating is in the ascendant both at home and abroad at present, and insulating moulding coating is heat-insulated One of main development direction of insulation material.In numerous heat-barrier materials, thin matter outer wall heat-insulating coating, with its economy, uses Conveniently with advantages such as cooling-down effects, and it is widely accepted and gets a lot of applications.
But in the market insulating moulding coating exist easy to crack, there is no that elasticity, stain resistant are poor, weatherability is not good enough, involve great expense The problems such as.
Content of the invention
In place of solving above-mentioned the deficiencies in the prior art, the present invention provides a kind of weather-proof protective paint of Elastic heat insulation.This bullet Property heat-insulated weather-proof protective paint have preferably elasticity and reflective insulation performance, thick painting is not ftractureed, and has excellent resistance to soiling and weather-proof Property.
Further object is that providing the preparation method of the weather-proof protective paint of above-mentioned Elastic heat insulation.
The purpose of the present invention is achieved through the following technical solutions:
A kind of weather-proof protective paint of Elastic heat insulation, this protective paint is grouped into by following weight percentage group:
Described dispersant is sodium acrylate dipersant A4100;Described wetting agent is alkyl polyoxyethylene ether LCN407;Described coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrate;Described defoamer is organosilicon Defoamer SN-154;Described preservative is BIT NIPACIDE BIT 20;Described Calcium Carbonate Titanium dioxide described in Calcium Carbonate CC-1500 is Rutile type titanium dioxide, preferably Rutile type titanium dioxide R900;Described elasticity Emulsion is elastic emulsion 2468M;Described nanometer silicone acrylic emulsion is nanometer silicone acrylic emulsion SD-5281;Described borsal is empty Heart microsphere is borsal tiny balloon 5020;Described far infrared ceramic powder is nano-scale far infrared ceramic powder;Described water Property nanometer stain resistant agent be NZW-I water nano stain resistant agent;Described thickening agent is nonionic modified polyurethane RM-8W; Described pH adjusting agent is 2-amino-2-methyl-1-propanol.
The weather-proof protective paint of above-mentioned Elastic heat insulation is it is further preferred that consist of the following components in percentage by weight:
A kind of preparation method of the weather-proof protective paint of Elastic heat insulation, comprises the following steps:In percentage by weight, by water 8 ~18%, propylene glycol 1~2%, dispersant 0.3~1%, wetting agent 0.1~0.5%, coalescents 1~2%, defoamer 0.1~ 0.5%th, preservative 0.1~0.3% mixes under 300~400 revs/min, under 700~800 revs/min, add titanium dioxide 10~ 30%th, after Calcium Carbonate 6~10%, 1000~1200 revs/min of dispersions are less than 50 microns to Hegman fineness grind in 30 minutes, and 700~800 Elastic emulsion 30~50%, nanometer silicone acrylic emulsion 5~9%, borsal tiny balloon 3~7%, far infrared pottery is added under rev/min Porcelain powder 1~5% and water nano stain resistant agent 0.1~0.5%, after stirring, add thickening agent 0.4~1.2%, adjust viscosity To 100~105KU, it is eventually adding pH adjusting agent 0.1~0.3%, adjust pH value to 8.5~9.5, that is, obtain Elastic heat insulation weather-proof Protective paint.
The present invention compared with prior art, has an advantage in that:The present invention passes through to adjust emulsion, tiny balloon and far infrared pottery The collocation of porcelain powder and the application of water nano stain resistant agent, make coating have preferably elasticity and reflective insulation performance, thick painting is not Cracking, and has excellent resistance to soiling and weatherability, and decorative effect is good, easy construction the advantages of, utilization of energy can be improved Rate, energy saving, solvent-free and disposal of pollutants, environmental protection.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but the embodiment not limited to this of invention.
Embodiment 1
First weigh each composition according to above-mentioned percentage by weight, above-mentioned water, propylene glycol, dispersant, wetting agent, film forming are helped Agent, defoamer, preservative, in 300 revs/min of lower mix homogeneously, then under the conditions of 700 revs/min, add titanium dioxide, carbonic acid Calcium, after 1000 revs/min of dispersions are less than 50 microns to Hegman fineness grind in 30 minutes, adds elastic emulsion, nano-silicon under the conditions of middling speed Acrylic emulsion, borsal tiny balloon, far infrared ceramic powder and water nano stain resistant agent, after stirring, add thickening agent, Adjust viscosity to 100KU, be eventually adding pH adjusting agent, adjust pH value to 8.5, that is, obtain the weather-proof protective paint of Elastic heat insulation.
Wherein, described propylene glycol is bought in Hualun Chemical Co., Ltd., Jiangsu;Dispersant disperses for polyacrylic acid sodium salt Agent A4100, buys in Clariant Chemical Co., Ltd.;Wetting agent is alkyl polyoxyethylene ether LCN407, buys in Clariant Work company limited;Coalescents are 2,2,4- trimethyl -1, and 3- pentanediol mono isobutyrate is bought in the limited public affairs of Eastman Chemical Department;Defoamer is organic silicon defoamer SN-154, buys in NOPOC company;Preservative is BIT NIPACIDE BIT 20, buys in Clariant Chemical Co., Ltd.;Titanium dioxide is Rutile type titanium dioxide R900, is that Du Pont is public Department;Calcium Carbonate is CC-1500, buys in Jiangxi Guang Yuan chemical industry Co., Ltd;Elastic emulsion is 2468M, buys in DOW Family name company;Nanometer silicone acrylic emulsion is SD-5281, buys in Nantong Sheng Da chemical company;Borsal tiny balloon is 5020, buy in baud company of the U.S.;Far infrared ceramic powder is nano level, buys in Tianjin Silicate Inst;Aqueouss Nanometer stain resistant agent is NZW-I, buys in Beijing Shouchuang Nano Techn Co., Ltd.;Thickening agent is nonionic modified polyurethane RM-8W, buys in DOWShi company;PH regulator is 2-amino-2-methyl-1-propanol, buys in DOWShi company.
The weather-proof protective paint of Elastic heat insulation to embodiment 1 preparation, using GB24408-2009《Have in exterior coating for building Evil material limitation》Standard detection, result is as follows:
Using JG/T172-2005《Elastic building paint》And JG/T235-2008《Architectural reflective heat-insulation paint》Standard is examined Survey, result is as follows:
Embodiment 2
First weigh each composition according to above-mentioned percentage by weight, above-mentioned water, propylene glycol, dispersant, wetting agent, film forming are helped Agent, defoamer, preservative, in 400 revs/min of lower mix homogeneously, then under the conditions of 800 revs/min, add titanium dioxide, carbonic acid Calcium, 1200 revs/min of dispersions add elastic emulsion, nano-silicon third breast under 400 revs/min after being less than 50 microns to fineness within 30 minutes Liquid, borsal tiny balloon, far infrared ceramic powder and water nano stain resistant agent, after stirring, add thickening agent, adjust Viscosity, to 105KU, is eventually adding pH adjusting agent, adjusts pH value to 9.5, that is, obtains the weather-proof protective paint of Elastic heat insulation.
Wherein, described propylene glycol is bought in Hualun Chemical Co., Ltd., Jiangsu;Dispersant disperses for polyacrylic acid sodium salt Agent A4100, buys in Clariant Chemical Co., Ltd.;Wetting agent is alkyl polyoxyethylene ether LCN407, buys in Clariant Work company limited;Coalescents are 2,2,4- trimethyl -1, and 3- pentanediol mono isobutyrate is bought in the limited public affairs of Eastman Chemical Department;Defoamer is organic silicon defoamer SN-154, buys in NOPOC company;Preservative is BIT NIPACIDE BIT 20, buys in Clariant Chemical Co., Ltd.;Titanium dioxide is Rutile type titanium dioxide R900, is that Du Pont is public Department;Calcium Carbonate is CC-1500, buys in Jiangxi Guang Yuan chemical industry Co., Ltd;Elastic emulsion is 2468M, buys in DOW Family name company;Nanometer silicone acrylic emulsion is SD-5281, buys in Nantong Sheng Da chemical company;Borsal tiny balloon is 5020, buy in baud company of the U.S.;Far infrared ceramic powder is nano level, buys in Tianjin Silicate Inst;Aqueouss Nanometer stain resistant agent is NZW-I, buys in Beijing Shouchuang Nano Techn Co., Ltd.;Thickening agent is nonionic modified polyurethane RM-8W, buys in DOWShi company;PH regulator is 2-amino-2-methyl-1-propanol, buys in DOWShi company.
The weather-proof protective paint of Elastic heat insulation to embodiment 2, using GB24408-2009《Nuisance in exterior coating for building Matter is limited the quantity》Standard detection, result is as follows:
Using JG/T172-2005《Elastic building paint》And JG/T235-2008《Architectural reflective heat-insulation paint》Standard is examined Survey, result is as follows:
Above-described embodiment is the present invention preferably embodiment, but embodiments of the present invention are not subject to above-described embodiment Limit, other any spirit without departing from the present invention and the change made under principle, modification, replacement, combine, simplify, All should be equivalent substitute mode, be included within protection scope of the present invention.

Claims (1)

1. a kind of weather-proof protective paint of Elastic heat insulation it is characterised in that:This protective paint is grouped into by following weight percentage group:
Water 14.8~15.5%
Propylene glycol 1.5%
Dispersant 0.6~0.7%
Wetting agent 0.3~0.4%
Coalescents 1.3~1.5%
Defoamer 0.2~0.3%
Preservative 0.15~0.2%
Titanium dioxide 16~20%
Calcium Carbonate 8~9%
Elastic emulsion 35~40%
Nanometer silicone acrylic emulsion 7~9%
Borsal tiny balloon 4.5~5%
Far infrared ceramic powder 2~3%
Water nano stain resistant agent 0.2~0.3%
Thickening agent 0.8~1%
PH adjusting agent 0.1~0.15%;
Described dispersant is sodium acrylate dipersant A4100;Described wetting agent is alkyl polyoxyethylene ether LCN407;Institute The coalescents stated are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrate;Described defoamer is organic silicon defoamer SN- 154;Described preservative is BIT NIPACIDE BIT 20;Described Calcium Carbonate is Calcium Carbonate CC-1500;Described titanium dioxide is Rutile type titanium dioxide R900;Described elastic emulsion is elastic emulsion 2468M;Described Nanometer silicone acrylic emulsion is nanometer silicone acrylic emulsion SD-5281;Described borsal tiny balloon is borsal tiny balloon 5020;Described far infrared ceramic powder is nano-scale far infrared ceramic powder;Described water nano stain resistant agent is NZW-I aqueouss Nanometer stain resistant agent;Described thickening agent is nonionic modified polyurethane RM-8W;Described pH adjusting agent is 2- amino -2- Methyl isophthalic acid-propanol.
CN201310110133.XA 2013-03-29 2013-03-29 Elastic heat-insulated weather-resistant protection paint Expired - Fee Related CN104073164B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105462501A (en) * 2015-12-15 2016-04-06 三棵树涂料股份有限公司 Organic and inorganic combined type stain resistance elastic flat emulsion paint and preparation method thereof
CN106800887A (en) * 2016-12-13 2017-06-06 张世平 A kind of Domestic antitheft door surface protection paint and preparation method thereof
CN106752636A (en) * 2016-12-13 2017-05-31 张世平 A kind of door and window high temperature resistant protective paint and preparation method thereof
CN107474291A (en) * 2017-09-30 2017-12-15 浙江跃进机械有限公司 A kind of automobile using damping trouble-proof tire

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974273A (en) * 2010-10-09 2011-02-16 广州市枫源化工有限公司 Exterior wall coating and preparation method thereof
CN102898917A (en) * 2012-10-29 2013-01-30 苏州市建筑科学研究院有限公司 Reflection and heat insulation paint for buildings
CN102964971A (en) * 2012-12-24 2013-03-13 青岛宣威涂层材料有限公司 Improved reflective heat-insulation coating

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001262072A (en) * 2000-03-21 2001-09-26 Soko Seiren Kk Light and heat-proofing coating material
KR20100031440A (en) * 2008-09-12 2010-03-22 김영 Heating vessel with fixed thermal conductivity and coating method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974273A (en) * 2010-10-09 2011-02-16 广州市枫源化工有限公司 Exterior wall coating and preparation method thereof
CN102898917A (en) * 2012-10-29 2013-01-30 苏州市建筑科学研究院有限公司 Reflection and heat insulation paint for buildings
CN102964971A (en) * 2012-12-24 2013-03-13 青岛宣威涂层材料有限公司 Improved reflective heat-insulation coating

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Address after: 518107 on the south side of Shenzhen Industrial Park, Guangming New District, Guangdong

Applicant after: CHINA ZHANCHEN PAINTS GROUP LTD.

Applicant after: Shanghai Zhanchen Paint Co., Ltd.

Applicant after: Beijing Zhan Chen novel material company limited

Applicant after: Qingdao Zhan Chen novel material company limited

Applicant after: Chengdu Zhan Chen coating company limited

Address before: 518107, Shenzhen, Guangdong province Baoan District Guangming Street white industrial park on the south side of the sightseeing highway

Applicant before: Zhanchen Coatings Group Co., Ltd.

Applicant before: Shanghai Fuchen Chemical Co., Ltd.

Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd.

Applicant before: Qingdao Fuchen Chemical Co., Ltd.

Applicant before: Chengdu Zhanchen Chemical Co., Ltd.

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