CN102399483A - Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof - Google Patents
Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof Download PDFInfo
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Abstract
The invention discloses an organic/inorganic composite heat-insulating heat-preserving water-based building coating and a preparation method thereof. The coating comprises the following components: organic polymer emulsion, silica sol, infrared ceramic powder, titanium white, hollow glass beads, ceramic microspheres, wood fiber, talcpowder, kaolin, a wetting agent, a dispersing agent, a film-forming aid, an anti-freezing agent, a silane coupling agent, a fluorine-containing aid, a thickening agent, a sterilizing mildewproof agent, a defoaming agent, a pH regulator and deionized water. Due to reflecting action of the ceramic microspheres and the hollow glass beads and low heat conductivity coefficient and low absorbance of the silica sol, the coating has high sunlight reflectivity, hemispherical emissivity, heat-insulating property, weather resistance, water resistance and stain resistance, and can be widely applied to the heat-insulating heat-preserving coatings of buildings, vehicles and oil storage tanks.
Description
Technical field
The invention belongs to the trade sales coating field, be specifically related to compound heat-insulation and heat-preservation aqueous architectural coating of a kind of organic/inorganic and preparation method thereof.
Background technology
After the seventies in 20th century, world climate warms, and earth energy is exhausted day by day.In AND ENERGY RESOURCES CONSUMPTION IN CHINA, 30～40% of the human energy consumption of building energy consumption account, improving the building heat preserving heat-proof quality is the important channel of save energy, raising buildings functions of use.Thermal insulating coating is applied over building surface can effectively reduce building surface and temperature inside.In recent years, along with the popularization of building energy conservation, thermal insulating coating more and more receives people's attention because of advantages such as economic, convenient and good heat-insulation effect.Therefore, novel, the compound insulating mold coating of research and development is of great immediate significance to the mankind's daily life.
Existing insulating mold coating mainly adopts heat insulation color stuffings such as organic polymer emulsion, cenosphere, porous filler and heat-reflecting material to reach heat insulating, the antifouling purpose of waterproof, like the disclosed a kind of counter radiation thermal insulating coating of Chinese patent ZL99114454.6, the disclosed a kind of aquosity elastic heat preserving insulating paint of ZL200710075800.X and preparation method thereof, the disclosed insulating mold coating of ZL200910061883.6, the disclosed a kind of thermal insulating coating of ZL200510000149.0 and uses thereof, the disclosed a kind of thermal insulating coating that reflects the solar heat ray of ZL200710035834.6 etc.Wherein the disclosed a kind of thermal insulating coating that reflects the solar heat ray of patent ZL200710035834.6 is made up of bottom-coating and painting coating, and primary coat adopts hollow beads lagging material, heat-reflecting material and macromolecule resin to process; Face is coated with and adopts surface coating reverberation ray matrix material, heat-reflecting material and macromolecule resin to process; Since contain in the organic polymer a large amount of-C=O ,-C-O-C ,-extinction groups such as OH; Degree of absorption to sunshine will be higher than inorganic color stuffing, so when the addition of organic polymer emulsion was big more, it was also big more to the absorbed dose of sunshine to film; The thermal conductivity of filming also can correspondingly improve, and can reduce the effect of heat insulation of coating.For basic physics and the chemical property requirement that reaches common exterior coating, the existing traditional thermal insulating coating of this type must guarantee the higher addition of organic polymer emulsion in coating, causes its effect of heat insulation undesirable.
Summary of the invention
The objective of the invention is to deficiency, a kind of high-reflectivity, high hemispherical emissivity, the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic weather-proof and anti-contamination and preparation method thereof are provided to prior art.
The present invention adopts polymer emulsion and the composite mode of silicon sol, has improved the fundamental property of coating, comprises weathering resistance, abrasion resistance, water tolerance and contamination resistance etc.Because what form after the silicon sol film forming is Si-O-Si inorganic polymer reticulated structure, lower than organic polymer to the degree of absorption of sunshine; Simultaneously,, help the reduction of the heat insulation temperature difference decay of thermal insulating coating, help improving the heat preservation and insulation of coating owing to can improve the contamination resistance of compound coating after the silicon sol film forming; In addition, owing to do not need film coalescence aid in the silicon sol film process, so (abbreviation: VOC) content is lower than the coating that pure organic polymer is made into the volatile organic compounds of the composite coating of silicon sol and organic polymer.Therefore, the resulting compound thermal insulating coating of the present invention not only has excellent heat-proof quality, also has excellent physics and chemical property, and its VOC content is low.
In order to achieve the above object, the present invention has adopted following technical scheme:
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic, by weight percentage, it is filled a prescription as follows:
Organic polymer emulsion 9.5～15%;
Silicon sol 15～22%;
Far infrared ceramic powder 5～15%;
White titanium pigment 15～25%;
Hollow glass micropearl 0～5%;
Ceramic microsphere 0～10%;
Wood fibre 0～1%;
Talcum powder 4～15%;
Kaolin 0～10%;
Wetting agent 0.1～0.5%;
Dispersion agent 0.2～1.0%;
Film coalescence aid 0～1.5%;
Frostproofer 0.5～1.5%;
Silane coupling agent 0.2～0.5%;
Fluorine-containing auxiliary agent 0.2～0.5%;
Thickening material 0.5～2.0%;
Biocide mildewcide 0.2～0.4%;
Skimmer 0.2～0.5%;
PH regulator agent 0.1～0.5%;
Deionized water 18～30%.
Organic polymer emulsion according to the invention is for gathering in (cinnamic acrylic ester) copolymer emulsion, polyacrylate emulsion or the silicone-modified polyacrylate emulsion one or more; The sparkling temperature of said organic polymer emulsion is 0 ~ 20 ℃, and the carboxyl mass percent is 0.5 ~ 1.0%.
The median size of silicon sol according to the invention is 7 ~ 30nm.
Far infrared ceramic powder according to the invention is a ceramic, and said far infrared ceramic powder infrared rate at normal temperatures is 0.85 ~ 0.92, and the median size of said far infrared ceramic powder is 325 ~ 3000 orders.
The median size of ceramic microsphere according to the invention is 1～40 μ m.
The median size of wood fibre according to the invention is 500 ~ 1000 orders.
Silane coupling agent according to the invention is an organo-siloxane, comprises one or more mixtures in γ-An Bingjisanyiyangjiguiwan, octyltri-ethoxysilane, amino-methoxy functional silane, the γ-glycidyl ether oxygen propyl trimethoxy silicane.
Fluorine-containing auxiliary agent according to the invention is one or more mixtures in ethoxy base class non-ionic type fluorocarbon surfactant, water-soluble phosphate anionoid type fluorocarbon surfactant or the polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant.
Wetting agent according to the invention is TX10 class nonionogenic tenside and/or polyether-modified ZGK 5 wetting agent; Said dispersion agent is one or more in polycarboxylate sodium's dispersion agent, poly carboxylic acid ammonium salt dispersion agent or the Sodium hexametaphosphate 99; Said film coalescence aid is propylene glycol monomethyl ether, Ucar 35 butyl ether, dipropylene glycol methyl ether, Diethylene Glycol butyl ether or 2,2,4-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate; Said frostproofer is one or both in terepthaloyl moietie or the Ucar 35; Said white titanium pigment is a Rutile type Titanium Dioxide; Said talcous median size is 1250 orders, and kaolinic median size is 4000 orders; Said thickening material is one or more in Natvosol, hydroxypropylcellulose, polyurethanes thickening material or the alkali swelling type thickening material; Said biocide mildewcide is one or more in pentachlorophenol, 5-chloro-2 methyl-4 isothiazoline-3 ketone, 2-methyl-4 isothiazoline-3 ketone, benzothiazolinone, iodo propinyl butyl carbamate, the Salicylanlide; Said skimmer is a silicone antifoam agent, one or more in organic silicon modified by polyether skimmer and the mineral oil antifoam agent, and wherein the staple of silicone antifoam agent is YSR 3286, emulsifying agent, dispersion agent and tensio-active agent; The staple of mineral oil antifoam agent is metallic soap of stearic acid, emulsifying agent, dispersion agent and tensio-active agent; The staple of polyether antifoam agent is T 46155 oxygen propyl group glycerine, emulsifying agent, dispersion agent and tensio-active agent; The staple of organic silicon modified by polyether skimmer is polyether-modified YSR 3286, emulsifying agent, dispersion agent and tensio-active agent; Said pH regulator agent is one or more in 2-amino-2-methyl-1-propanol, ammoniacal liquor, sodium hydroxide, diethylolamine or the triethylamine.
The present invention also provides the preparation method of the compound heat-insulation and heat-preservation aqueous architectural coating of a kind of organic/inorganic, may further comprise the steps:
(1) according to formula ratio film coalescence aid, frostproofer, wetting agent, dispersion agent, skimmer, silane coupling agent, thickening material and silicon sol are joined in 13 ~ 18 parts of deionized waters, under the rotating speed of 300～500r/min, stir 3～10min and obtain mixture;
(2) white titanium pigment, far infrared ceramic powder, ceramic microsphere, wood fibre, talcum powder and the kaolin of adding formula ratio in the mixture that step (1) obtains disperse 15 ~ 60min to obtain the mixed system of fineness≤60 μ m under the rotating speed of 1000～2000r/min;
(3) under 300～600r/min rotating speed; In the mixed system that step (2) obtains, add biocide mildewcide, organic polymer emulsion, hollow glass micropearl, skimmer, 5 ~ 12 parts of deionized waters, pH regulator agent and thickening materials of formula ratio successively, stir, the viscosity of regulating mixed system is 11000 ~ 13000mpa/s; Stop to stir; Leave standstill, filter, obtain the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The present invention compared with prior art has following advantage:
(1) the present invention adopts ceramic microsphere and hollow glass micro-ball, and its sunshine reflectivity is higher than other common fillers, and they have synergy, makes coating of the present invention have very high sunshine reflectivity, hemispherical emissivity is high; Hollow glass micro-ball is a kind of hollow, thin-walled, hard, light-weight spheroid, has extremely low thermal conductivity, can reduce the thermal conductivity of coating; Sun luminous reflectance factor ≧ 0.85 of coating of the present invention; Ban ball Fa She Shuais ≧ and 0.85, heat insulation Wen is Cha ≧ and 12 ℃, heat insulation temperature difference Shuai Jian ≦ 12 ℃;
(2) the present invention has added a large amount of silicon sol and has substituted the organic polymer emulsion in base-material; Adopt organic polymer and the composite basic physics chemical property that not only improves coating of silicon sol; Because the organic/inorganic composite emulsion has excellent film forming properties, the combination of flexibility of filming and hardness have not only been improved the effect of heat insulation of coating; Also give coating excellent weathering resistance, abrasion resistance and water resistance, its washable Shua Xing ≧ 10000 time;
(3) the present invention has added fluorine-containing auxiliary agent, has further improved the hydrophobic and oleophobic property of coating, and giving coating better weather, water tolerance and contamination resistance can;
(4) the present invention has reduced the content of organic polymer in the coating through organic/inorganic is compound, thereby has reduced the usage quantity of film coalescence aid in the coating, has not only reduced the VOC content of coating, and has reduced the cost of coating;
(5) the present invention has adopted the far infrared ceramic powder that has the high IR emittance under the normal temperature, and this far-infrared functional material not only has good effect of heat insulation, can also play the effect of certain health care.
Embodiment
Below in conjunction with specific embodiment, the present invention is further explained, but the scope that the present invention requires to protect is not limited to this.
Embodiment 1
(1) by percentage to the quality; Add 15 parts of deionized waters, 1.5 parts terepthaloyl moietie, 0.1 part of polyoxyethylene nonylphenol wetting agent, 0.5 part of polycarboxylate sodium's dispersion agent, 0.1 part YSR 3286 skimmer, γ-glycidyl ether oxygen propyl trimethoxy silicane of 0.3 part, 15.7 parts silicon sol earlier; Under the rotating speed of 500r/min, stir 5min; Add 0.3 part of Natvosol thickening material again, the rotating speed of 500r/min stirs 5min down;
(2) in (1), add 20 parts rutile titanium white powder, 15 parts 3000 order far infrared ceramic powders, 8 parts ceramic microsphere, 0.3 part wood fibre, 4 parts talcum powder successively, high speed dispersion 20min is to fineness 60 μ m under the speed of 1500r/min;
(3), the speed of 700r/min in (2), adds 0.2 part of iodo propinyl butyl carbamate, 0.2 part of pentachlorophenol, 0.2 part Natvosol thickening material under stirring successively; 8.5 part deionized water, 10.4 parts polyacrylate emulsion, 0.3 portion of fluorine auxiliary agent ethoxy base class non-ionic type fluorocarbon surfactant; 0.1 the metallic soap of stearic acid skimmer of part and 0.3 part of 2-amino-2-methyl-1-propanol are regulated the pH value, stir; Adjustment viscosity is to 12000mpa/s; Leave standstill, filter, obtain the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 1 is made carries out performance test, and the result is as shown in table 1:
Table 1
Embodiment 2
(1) by weight percentage; Add 16 parts of deionized waters, 1.0 parts terepthaloyl moietie, 0.2 part of polyoxyethylene nonylphenol wetting agent, 0.5 part of polycarboxylate sodium's dispersion agent, 0.2 part YSR 3286 skimmer, γ-glycidyl ether oxygen propyl trimethoxy silicane of 0.2 part, 16 parts silicon sol earlier; Under the speed of 400r/min, stir 5min; Add 0.3 part of Natvosol thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 22 parts rutile titanium white powder, 9 parts 3000 order far infrared ceramic powders, 6 parts ceramic microsphere, 0.1 part wood fibre, 4 parts talcum powder successively; 5 parts mica powder, high speed dispersion 20min is to fineness 60 μ m under the speed of 2000r/min.
(3), the speed of 500r/min in (2), adds 0.2 part of 5-chloro-2 methyl-4 isothiazoline-3 ketone successively successively, 0.2 part of 2-methyl-4 isothiazoline-3 ketone, 0.2 part Natvosol thickening material under stirring; 8 parts of deionized waters, 10 parts polyacrylate emulsion, 0.3 part fluorine auxiliary agent ethoxy base class non-ionic type fluorocarbon surfactant; 0.3 the metallic soap of stearic acid skimmer of part and 0.3 part of 2-amino-2-methyl-1-propanol are regulated the pH value; Stir, adjustment viscosity leaves standstill to 13000mpa/s; Filter, obtain the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 2 is made carries out performance test, and the result is as shown in table 2:
Table 2
Embodiment 3
(1) by weight percentage; Add earlier 13 parts of deionized waters, 0.1 part terepthaloyl moietie, 0.5 part of polyoxyethylene octylphenol ether wetting agent, 0.2 part of polycarboxylate sodium's dispersion agent, 0.1 part Sodium hexametaphosphate 99; 0.15 the T 46155 oxygen propyl group glycerine skimmer of part, 0.3 part γ-An Bingjisanyiyangjiguiwan, 22 parts silicon sol; Under the speed of 300r/min, stir 5min, add 0.4 part of Natvosol thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 17 parts rutile titanium white powder, 5 parts 800 order far infrared ceramic powders, 8 parts kaolin, 10 parts talcum powder, high speed dispersion 15min is to fineness 60 μ m under the speed of 2000r/min.
(3), the speed of 700r/min in (2), adds the benzothiazolinone that adds 0.15 part successively, 0.15 part Salicylanlide, 5.4 parts of deionized waters under stirring successively successively; 12 parts phenylpropyl alcohol acrylic ester emulsion; 3 parts of hollow glass micro-balls, 0.3 part fluorine auxiliary agent ethoxy base class non-ionic type fluorocarbon surfactant, 0.15 part metallic soap of stearic acid skimmer; 0.2 the polyurethane thickener of part and 0.1 part of ammoniacal liquor are regulated the pH value, stir.Adjustment viscosity leaves standstill to 13000mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 3 is made carries out performance test, and the result is as shown in table 3:
Table 3
Embodiment 4
(1) by weight percentage; Add 18 parts of deionized waters, 1.2 parts Ucar 35,0.5 part of dipropylene glycol methyl ether, 0.2 part of polyoxyethylene octylphenol ether wetting agent, 1.0 parts of poly carboxylic acid ammonium salt dispersion agents, 0.15 part polyether-modified YSR 3286 skimmer, 0.2 part octyltri-ethoxysilane, 17.5 parts silicon sol earlier; Under the speed of 500r/min, stir 4min; Add 0.5 part of Natvosol thickening material again, under the speed of 500r/min, stir 4min.
(2) in (1), add 17 parts rutile titanium white powder, 5 parts 325 order far infrared ceramic powders, 8 parts ceramic microsphere, 0.5 part wood fibre, 8 parts talcum powder successively, high speed dispersion 20min is to fineness 60 μ m under the speed of 1000r/min.
(3), the speed of 800r/min in (2), adds 0.2 part of 5-chloro-2 methyl-4 isothiazoline-3 ketone successively successively, 0.2 part of 2-methyl-4 isothiazoline-3 ketone, 10.5 parts of deionized waters under stirring; 9.5 the phenylpropyl alcohol acrylic ester emulsion of part; 0.1 portion water-soluble phosphate anionoid type fluorocarbon surfactant, 0.15 part metallic soap of stearic acid skimmer, 0.5 part Natvosol thickening material; Regulate the pH value with 0.1 part of ammoniacal liquor, stir.Adjustment viscosity leaves standstill to 12000mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 4 is made carries out performance test, and the result is as shown in table 4:
Table 4
Embodiment 5
(1) by weight percentage; Add 18 parts of deionized waters, 1.2 parts Ucar 35,1.5 parts of Diethylene Glycol butyl ether earlier; 0.1 part polyether-modified ZGK 5 wetting agent wetting agent, 0.5 part of polycarboxylate sodium's dispersion agent, 0.15 part metallic soap of stearic acid skimmer, γ-glycidyl ether oxygen propyl trimethoxy silicane of 0.2 part, 17.5 parts silicon sol; Under the speed of 500r/min, stir 5min; Add 0.5 part of Natvosol thickening material again, under the speed of 500r/min, stir 3min.
(2) in (1), add 15 parts rutile titanium white powder, 12 parts 1000 order far infrared ceramic powders, 4 parts ceramic microsphere, 1.0 parts wood fibre, 5 parts talcum powder, 5 parts kaolin, high speed dispersion 20min is to fineness 60 μ m under the speed of 1500r/min.
(3), the speed of 700r/min in (2), adds 0.2 part of iodo propinyl butyl carbamate successively successively under stirring; 0.2 part Salicylanlide, 7.2 parts of deionized waters, 9.5 parts silicon third acrylic ester emulsion; 0.4 part fluorine auxiliary agent water-soluble phosphate anionoid type fluorocarbon surfactant; 0.15 the polyether-modified YSR 3286 skimmer of part, 0.2 part alkali swelling type thickening material and 0.2 part of 2-amino-2-methyl-1-propanol are regulated the pH value, stir.Adjustment viscosity leaves standstill to 11500mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 5 is made carries out performance test, and the result is as shown in table 5:
Table 5
Embodiment 6
(1) by weight percentage; Add 15 parts of deionized waters, 1.2 parts Ucar 35,1.0 parts propylene glycol monomethyl ether, 0.2 part of polyoxyethylene octylphenol ether wetting agent, 0.2 part of polycarboxylate sodium's dispersion agent, 0.1 part of Sodium hexametaphosphate 99,0.15 part YSR 3286 skimmer, amino-methoxy functional silane of 1.0 parts, 15.5 parts silicon sol earlier; Under the speed of 500r/min, stir 5min; Add 0.4 part of Natvosol thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 25 parts rutile titanium white powder, 5 parts 800 order far infrared ceramic powders, 5 parts hollow glass micro-ball, 0.2 part wood fibre, 12 parts talcum powder, high speed dispersion 18min is to fineness 60 μ m under the speed of 1500r/min.
(3), the speed of 500r/min in (2), adds 0.15 part of benzothiazolinone successively successively, 0.15 part of Salicylanlide, 6 parts of deionized waters under stirring; 10.5 the phenylpropyl alcohol acrylic ester emulsion of part; 5 parts of hollow glass micro-balls, 0.2 part fluorine auxiliary agent water-soluble phosphate anionoid type fluorocarbon surfactant, 0.1 part T 46155 oxygen propyl group glycerine skimmer; 0.2 the alkali swelling type thickening material of part and 0.5 part of diethylolamine are regulated the pH value, stir.Adjustment viscosity leaves standstill to 12500mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 6 is made carries out performance test, and the result is as shown in table 6:
Table 6
Embodiment 7
(1) by weight percentage; Add 13 parts of deionized waters, 1.0 parts Ucar 35,1.5 parts Ucar 35 butyl ether, 0.5 part of polyether-modified ZGK 5 wetting agent wetting agent, 0.8 part of polycarboxylate sodium's dispersion agent, 0.15 part metallic soap of stearic acid skimmer, γ-glycidyl ether oxygen propyl trimethoxy silicane of 0.3 part, 15 parts silicon sol earlier; Under the speed of 500r/min, stir 5min; Add 0.4 part of Natvosol thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 15 parts rutile titanium white powder, 5 parts 800 order far infrared ceramic powders, 0.3 part wood fibre, 15 parts talcum powder, 8 parts kaolin, high speed dispersion 15min is to fineness 60 μ m under the speed of 2000r/min.
(3), the speed of 500r/min in (2), adds 0.1 part of 5-chloro-2 methyl-4 isothiazoline-3 ketone, 0.1 part of 2-methyl-4 isothiazoline-3 ketone, 5 parts of deionized waters successively successively under stirring; 0.4 the Natvosol thickening material of part; 15 parts phenylpropyl alcohol acrylic ester emulsion, 3 parts of hollow glass micro-balls, 0.4 part fluorine auxiliary agent polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant; 0.1 the YSR 3286 skimmer of part and 0.5 part of diethylolamine are regulated the pH value, stir.Adjustment viscosity leaves standstill to 11000mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 7 is made carries out performance test, and the result is as shown in table 7:
Table 7
Embodiment 8
(1) by weight percentage; Add earlier 15 parts of deionized waters, 1.0 parts terepthaloyl moietie, 0.7 part 2; 2; 4-trimethylammonium-1,3-pentanediol mono isobutyrate, 0.5 part of polyoxyethylene nonylphenol wetting agent, 0.1 part of polycarboxylate sodium's dispersion agent, 0.1 part of Sodium hexametaphosphate 99,0.1 part T 46155 oxygen propyl group glycerine skimmer, 0.3 part octyltri-ethoxysilane, 15 parts silicon sol stir 5min under the speed of 500r/min; Add 0.8 part of hydroxypropylcellulose thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 15 parts of rutile titanium white powder, 5 part of 1000 order far infrared ceramic powder, 12 parts of talcum powder, 10 parts of kaolin, high speed dispersion 18min is to fineness 60 μ m under the speed of 1500r/min.
(3), the speed of 700r/min in (2), adds 0.2 part benzothiazolinone, 0.15 part iodo propinyl butyl carbamate successively successively, 5 parts of deionized waters, 15 parts phenylpropyl alcohol acrylic ester emulsion under stirring; 0.15 the metallic soap of stearic acid skimmer of part; 4 parts of hollow glass micro-balls, 0.4 portion of fluorine auxiliary agent polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant, 0.4 part polyurethane thickener; Regulate the pH value with 0.15 part of triethylamine, stir.Adjustment viscosity leaves standstill to 12400mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 8 is made carries out performance test, and the result is as shown in table 8:
Table 8
Embodiment 9
(1) by weight percentage; Add earlier 13 parts of deionized waters, 1.0 parts terepthaloyl moietie, 1.0 part 2; 2; 4-trimethylammonium-1,3-pentanediol mono isobutyrate, 0.5 part of polyether-modified ZGK 5 wetting agent wetting agent, 0.5 part of poly carboxylic acid ammonium salt dispersion agent, 0.15 part of YSR 3286 skimmer, 0.3 part of γ-An Bingjisanyiyangjiguiwan, 15 parts of silicon sol stir 5min under the speed of 500r/min; Add 0.4 part of Natvosol thickening material again, under the speed of 500r/min, stir 5min.
(2) in (1), add 15 parts of rutile titanium white powder, 5 part of 325 order far infrared ceramic powder, 15 parts of talcum powder, 8 parts of kaolin, high speed dispersion 20min is to fineness 60 μ m under the speed of 1500r/min.
(3), the speed of 700r/min in (2), adds 0.3 part benzothiazolinone, 5.5 parts of deionized waters successively successively under stirring; 15 parts of phenylpropyl alcohol acrylic ester emulsions; 0.15 part metallic soap of stearic acid skimmer, 4 parts of hollow glass micro-balls, 0.1 portion of fluorine auxiliary agent polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant; 0.5 part polyurethane thickener and 0.1 part of ammoniacal liquor are regulated the pH value, stir.Adjustment viscosity leaves standstill to 11700mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 9 is made carries out performance test, and the result is as shown in table 9:
Table 9
Embodiment 10
(1) by weight percentage; Add 15 parts of deionized waters, 1.0 parts Ucar 35,0.2 part of polyoxyethylene nonylphenol wetting agent, 1.0 parts of poly carboxylic acid ammonium salt dispersion agents, 0.15 part YSR 3286 skimmer, 0.3 part γ-An Bingjisanyiyangjiguiwan, 18 parts silicon sol earlier; Under the speed of 500r/min, stir 5min; Add 1.0 parts of hydroxypropylcellulose thickening materials again, under the speed of 500r/min, stir 5min.
(2) in (1), add 18 parts rutile titanium white powder, 5 parts 3000 order far infrared ceramic powders, 10 parts ceramic microsphere, 0.2 part wood fibre, 5 parts talcum powder, 6 parts kaolin successively, high speed dispersion 20min is to fineness 60 μ m under the speed of 1500r/min.
(3), the speed of 700r/min in (2), adds 0.2 part of 5-chloro-2 methyl-4 isothiazoline-3 ketone successively successively under stirring; 0.2 part 2-methyl-4 isothiazoline-3 ketone, 5.8 parts of deionized waters, 12 parts phenylpropyl alcohol acrylic ester emulsion; 0.1 the fluorine auxiliary agent water-soluble phosphate anionoid type fluorocarbon surfactant of part; 0.15 the polyether-modified YSR 3286 skimmer of part, 1.0 parts hydroxypropylcellulose thickening material and 0.3 part of triethylamine are regulated the pH value, stir.Adjustment viscosity leaves standstill to 11600mpa/s, filters, and obtains the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
The compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic that embodiment 10 is made carries out performance test, and the result is as shown in table 10:
Table 10
Claims (10)
1. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic is characterized in that, by weight percentage, the prescription of said trade sales coating is following:
Organic polymer emulsion 9.5～15%;
Silicon sol 15～22%;
Far infrared ceramic powder 5～15%;
White titanium pigment 15～25%;
Hollow glass micropearl 0～5%;
Ceramic microsphere 0～10%;
Wood fibre 0～1%;
Talcum powder 4～15%;
Kaolin 0～10%;
Wetting agent 0.1～0.5%;
Dispersion agent 0.2～1.0%;
Film coalescence aid 0～1.5%;
Frostproofer 0.5～1.5%;
Silane coupling agent 0.2～0.5%;
Fluorine-containing auxiliary agent 0.2～0.5%;
Thickening material 0.5～1.0%;
Biocide mildewcide 0.2～0.4%;
Skimmer 0.2～0.5%;
PH regulator agent 0.1～0.5%;
Deionized water 18～30%.
2. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 1; It is characterized in that said organic polymer emulsion is for gathering in (cinnamic acrylic ester) copolymer emulsion, polyacrylate emulsion or the silicone-modified polyacrylate emulsion one or more;
The second-order transition temperature of said organic polymer emulsion is 0 ~ 20 ℃, and the carboxyl mass percent is 0.5 ~ 1.0%.
3. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 2 is characterized in that the median size of said silicon sol is 7 ~ 30nm.
4. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 3; It is characterized in that; Said far infrared ceramic powder is a ceramic; Said far infrared ceramic powder infrared rate at normal temperatures is 0.85 ~ 0.92, and the median size of said far infrared ceramic powder is 325 ~ 3000 orders.
5. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 4 is characterized in that, the median size of said ceramic microsphere is 1～40 μ m.
6. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 5 is characterized in that the median size of said wood fibre is 500 ~ 1000 orders.
7. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 6; It is characterized in that said silane coupling agent is one or more mixtures in γ-An Bingjisanyiyangjiguiwan, octyltri-ethoxysilane, amino-methoxy functional silane, the γ-glycidyl ether oxygen propyl trimethoxy silicane.
8. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 7; It is characterized in that said fluorine-containing auxiliary agent is one or more in ethoxy base class non-ionic type fluorocarbon surfactant, water-soluble phosphate anionoid type fluorocarbon surfactant or the polyoxyethylene groups ethers non-ionic type fluorocarbon surfactant.
9. the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic according to claim 8 is characterized in that, said wetting agent is TX10 class nonionogenic tenside and/or polyether-modified ZGK 5 wetting agent; Said dispersion agent is one or more in polycarboxylate sodium's dispersion agent, poly carboxylic acid ammonium salt dispersion agent or the Sodium hexametaphosphate 99; Said film coalescence aid is propylene glycol monomethyl ether, Ucar 35 butyl ether, dipropylene glycol methyl ether, Diethylene Glycol butyl ether or 2,2,4-trimethylammonium-1, one or more in the 3-pentanediol mono isobutyrate; Said frostproofer is one or both in terepthaloyl moietie or the Ucar 35; Said white titanium pigment is a Rutile type Titanium Dioxide; Said talcous median size is 1250 orders, and kaolinic median size is 4000 orders; Said thickening material is one or more in Natvosol, hydroxypropylcellulose, polyurethanes thickening material or the alkali swelling type thickening material; Said biocide mildewcide is one or more in pentachlorophenol, 5-chloro-2 methyl-4 isothiazoline-3 ketone, 2-methyl-4 isothiazoline-3 ketone, benzothiazolinone, iodo propinyl butyl carbamate, the Salicylanlide; Said skimmer is a silicone antifoam agent, one or more in organic silicon modified by polyether skimmer and the mineral oil antifoam agent, and wherein the staple of silicone antifoam agent is YSR 3286, emulsifying agent, dispersion agent and tensio-active agent; The staple of mineral oil antifoam agent is metallic soap of stearic acid, emulsifying agent, dispersion agent and tensio-active agent; The staple of polyether antifoam agent is T 46155 oxygen propyl group glycerine, emulsifying agent, dispersion agent and tensio-active agent; The staple of organic silicon modified by polyether skimmer is polyether-modified YSR 3286, emulsifying agent, dispersion agent and tensio-active agent; Said pH regulator agent is one or more in 2-amino-2-methyl-1-propanol, ammoniacal liquor, sodium hydroxide, diethylolamine or the triethylamine.
10. the preparation method of the compound heat-insulation and heat-preservation aqueous architectural coating of the described organic/inorganic of one of claim 1 ~ 9 is characterized in that, may further comprise the steps:
(1) according to formula ratio film coalescence aid, frostproofer, wetting agent, dispersion agent, skimmer, silane coupling agent, thickening material and silicon sol are joined in 13 ~ 18 parts of deionized waters, under the rotating speed of 300～500r/min, stir 3～10min and obtain mixture;
(2) white titanium pigment, far infrared ceramic powder, ceramic microsphere, wood fibre, talcum powder and the kaolin of adding formula ratio in the mixture that step (1) obtains disperse 15 ~ 60min to obtain the mixed system that fineness is 40 ~ 60 μ m under the rotating speed of 1000～2000r/min;
(3) under 300～600r/min rotating speed; In the mixed system that step (2) obtains, add biocide mildewcide, organic polymer emulsion, hollow glass micropearl, skimmer, 5 ~ 12 parts of deionized waters, pH regulator agent and thickening materials of formula ratio successively, stir, obtain the mixed system that viscosity is 11000 ~ 13000mpa/s; Stop to stir; Leave standstill, filter, obtain the compound heat-insulation and heat-preservation aqueous architectural coating of organic/inorganic.
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