CN106479233B - Composite coating and mark - Google Patents

Composite coating and mark Download PDF

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Publication number
CN106479233B
CN106479233B CN201610899864.0A CN201610899864A CN106479233B CN 106479233 B CN106479233 B CN 106479233B CN 201610899864 A CN201610899864 A CN 201610899864A CN 106479233 B CN106479233 B CN 106479233B
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China
Prior art keywords
parts
back cover
composite coating
cover layer
layer
Prior art date
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Active
Application number
CN201610899864.0A
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Chinese (zh)
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CN106479233A (en
Inventor
朱艳霞
黄烁
于爽
徐剑
郭莹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
State Grid Corp of China SGCC
State Grid Beijing Electric Power Co Ltd
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State Grid Corp of China SGCC
State Grid Beijing Electric Power Co Ltd
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Publication date
Application filed by State Grid Corp of China SGCC, State Grid Beijing Electric Power Co Ltd filed Critical State Grid Corp of China SGCC
Priority to CN201610899864.0A priority Critical patent/CN106479233B/en
Publication of CN106479233A publication Critical patent/CN106479233A/en
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Publication of CN106479233B publication Critical patent/CN106479233B/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • GPHYSICS
    • G09EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09FDISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Theoretical Computer Science (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The present invention provides a kind of composite coating and marks.The composite coating includes back cover layer and rough layer, and back cover layer is covered on base material, and the raw material of back cover layer include by weight 36~77 parts 0.9~2.2 part of the first pH adjusting agent of water, 22~61 parts of toughener;Rough layer is located at the side of the separate base material of back cover layer, and the number of projections of coarse layer surface is 25~45/cm2.Above-mentioned back cover layer tearing toughness with higher can significantly improve the tear resistance of Bulk coat, and have good breakage-proof performance using the anticollision of coating mark.And the number of projections of coarse layer surface is 25~45/cm2, this just makes coating surface have apparent roughness, and as mark in use, small advertisement is not easy to be pasted onto mark surface, and the small advertisement for being pasted onto surface is also very easy to by whole Zhang Qingchu.It is thus able to solve the stickup for identifying upper small advertisement and understands problem.

Description

Composite coating and mark
Technical field
The present invention relates to power domains, in particular to a kind of composite coating and mark.
Background technique
Existing electric pole is identified using thin PVC material adhesive type anticollision, is easy to be pasted by small advertisement, sanitationman removes It is more easily damaged when small advertisement, it is higher so as to cause existing anticollision mark breakage rate.
Summary of the invention
The main purpose of the present invention is to provide a kind of composite coating and marks, higher to solve existing mark breakage rate And be easy to be stuck small advertisement the problem of.
To achieve the goals above, one aspect of the invention provides a kind of composite coating comprising: back cover layer, covering On base material, and the raw material of back cover layer includes 36~77 parts of 0.9~2.2 part of water of the first pH adjusting by weight Agent, 22~61 parts of toughener;And rough layer, positioned at the side of the separate base material of back cover layer, the protrusion of coarse layer surface Number is 25~45/cm2
Further, back cover layer further includes 0.9~2.2 part of alcohol ester-12 by weight.
Further, the raw material of rough layer includes 90~440 parts of water, 450~990 parts of sand particles by weight And 0.9~2.2 part of the second pH adjusting agent;Preferably, rough layer further includes 4.5~16.5 parts of alcohol ester-12.
Further, the raw material of rough layer further include by weight 0.9~3.3 part the first defoaming agent and 9~22 parts Thickener.
Further, composite coating further includes finish coat, and finish coat is located at the side of the separate back cover layer of rough layer.
Further, the raw material of finish coat includes 110~440 parts of water, 1.1~2.2 parts of the 3rd pH by weight Regulator, the glass microballoon that 450~880 parts of partial size is 300~600 mesh;Preferably, the raw material of finish coat is gone back by weight Including 16.5~44 parts of alcohol ester-12.
Further, the raw material of finish coat further includes 0.9~44 part of the second defoaming agent by weight.
Further, the first pH adjusting agent, the second pH adjusting agent and third pH adjusting agent be separately selected from ammonium hydroxide and/ Or lime.
Further, toughener is selected from alkaline-resisting latex and/or silica solution;It is preferred that the raw material of back cover layer includes by weight 18~44 parts of alkaline-resisting latex and 4.5~16.5 parts of silica solution.
Further, the first defoaming agent and the second defoaming agent are separately selected from higher alcohols, polyethers defoaming agent and silicon One of class defoaming agent is a variety of.
Further, thickener is selected from one of methylcellulose, organobentonite and polyurethane thickener or a variety of.
According to another aspect of the present invention, a kind of mark is provided comprising above-mentioned composite coating.
It applies the technical scheme of the present invention, the back cover layer tearing toughness with higher of composite coating, therefore, Neng Gouming The aobvious tear resistance for improving Bulk coat, and there is good breakage-proof performance using the anticollision of coating mark.Above-mentioned painting Layer further includes the rough layer above back cover layer, and the number of projections on surface is 25~45/cm2.This just makes coating surface With apparent roughness, as mark in use, small advertisement is not easy to be pasted onto mark surface, and it is pasted onto the small wide of surface It accuses and is also very easy to by whole Zhang Qingchu.It is thus able to solve the stickup for identifying upper small advertisement and understands problem.
Specific embodiment
It should be noted that in the absence of conflict, the features in the embodiments and the embodiments of the present application can phase Mutually combination.Below in conjunction with embodiment, the present invention will be described in detail.
As described in background technique, it is higher and be easy to be stuck small that existing mark breakage rate exists in the prior art The problem of advertisement.In order to solve the above-mentioned technical problems, the present invention provides a kind of composite coatings comprising: back cover layer and coarse Layer, wherein back cover layer is covered on base material, and rough layer is located at the side of the separate base material of back cover layer;The original of back cover layer Material by weight including 36~77 parts 0.9~2.2 part of the first pH adjusting agent of water, 22~61 parts of toughener;Rough layer The number of projections on surface is 25~45/cm2
In above-mentioned composite coating provided by the invention, the raw material of back cover layer includes the of 0.9~2.2 part of water of 36~77 parts One pH adjusting agent, 22~61 parts of toughener.This layer is directly in contact with coated base material, tear-proof with higher Therefore intensity can significantly improve the tear resistance of coating, have good breakage-proof using the anticollision mark of the coating Energy.Above-mentioned coating further includes the rough layer above back cover layer, and the number of projections on surface is 25~45/cm2.This just makes Coating surface has apparent roughness, as mark in use, small advertisement is not easy to be pasted onto mark surface, and is pasted onto table The small advertisement in face is also very easy to by whole Zhang Qingchu.It is thus able to solve the stickup for identifying upper small advertisement and understands problem.
In a kind of preferred embodiment, back cover layer further includes 0.9~2.2 part of alcohol ester-12 by weight.By the use Back cover layer raw material is added in the alcohol ester-12 of amount, can further improve the temperature tolerance of back cover layer, to make coating lower or higher At a temperature of lear energy still with higher, make anticollision mark can under the more cold or higher weather condition of temperature With.
In a kind of preferred embodiment, the raw material of rough layer include by weight 90~440 parts water, 450~990 The sand particles and 0.9~2.2 part of the second pH adjusting agent of part.Back cover layer adhesive property with higher itself, use are above-mentioned The rough layer that raw material is formed can preferably be adhered to the surface of back cover layer.Preferably, the partial size of sand particles is 0.5~1mm.
It is highly preferred that rough layer further includes 4.5~16.5 parts of alcohol ester-12.Similarly, the alcohol ester-12 of the dosage, energy is added Enough heat resistances for further improving coating, make mark have more excellent heat resistance.
In a kind of preferred embodiment, the raw material of rough layer further includes 0.9~3.3 part of the first defoaming by weight Agent and 9~22 parts of thickener.The first defoaming agent of above-mentioned dosage is added, the foam of coating can be eliminated, improves rough layer and applies Filming performance during covering.And the thickener that above-mentioned dosage is added then can further improve the filming performance of rough layer.
In actual application, it is preferable that further include pigment in back cover layer and rough layer.In this way when making mark, The pigment of different colours can be directly added in different coarse coatings, be spaced in after being coated on back cover layer, form color It is spaced the coated indicia of (common black Huang is alternate in such as traffic mark).
In a kind of preferred embodiment, composite coating further includes finish coat, and finish coat is located at the separate back cover of rough layer The side of layer.Setting finish coat can make mark have reflective function, to play the role of anticollision mark at night.
In a kind of preferred embodiment, the raw material of finish coat include by weight 110~440 parts water, 1.1~ 2.2 parts of third pH adjusting agent, the glass microballoon that 450~880 parts of partial size is 300~600 mesh.The Lacquer finish that above-mentioned raw materials are formed Layer has more preferably reflective function.Preferably, the raw material of finish coat further includes 16.5~44 parts of alcohol ester-12 by weight. Similarly, this can further increase the heat resistance of coating.
In a kind of preferred embodiment, the raw material of finish coat further includes 0.9~44 part of the second defoaming by weight Agent.The bubble in finish coat can be removed using the second defoaming agent, make its filming performance more preferably.
In a kind of preferred embodiment, the first pH adjusting agent, the second pH adjusting agent and third pH adjusting agent are independently Ground is selected from ammonium hydroxide and/or lime.
In a kind of preferred embodiment, toughener is selected from alkaline-resisting latex and/or silica solution.Using alkaline-resisting latex and/or Toughener of the silica solution as back cover layer, in addition to that can be other than coating has higher tear resistance, additionally it is possible to improve and apply The corrosion resistance of layer.Preferably, the raw material of back cover layer includes 18~44 parts of alkaline-resisting latex and 4.5~16.5 by weight The silica solution of part.Alkaline-resisting latex and silica solution are used simultaneously, and the dosage for making the two is within the above range, can further increase The tear resistance of coating improves the breakage-proof ability of mark.
Defoaming agent, the thickener used in above-mentioned raw materials can be type commonly used in the art.In a kind of preferred implementation In example, the first defoaming agent and the second defoaming agent are separately in higher alcohols, polyethers defoaming agent and silicon class defoaming agent It is one or more.Thickener is selected from one of methylcellulose, organobentonite and polyurethane thickener or a variety of.Using upper The defoaming agent and thickener of type are stated, the filming performance of coating is more preferably.
Each layer is specifically sprayed on base material by the preparation method of above-mentioned coating in order using spray coating method, After cured, i.e., plastic.
In addition, mark includes above-mentioned composite coating the present invention also provides a kind of mark.In actual application In, directly use above-mentioned composite coating as mark.
Above-mentioned mark provided by the invention includes above-mentioned composite coating.The raw material of back cover layer includes 36~77 parts of water 0.9~2.2 part of the first pH adjusting agent, 22~61 parts of toughener.The base material that this layer is directly attached with mark is in contact, Therefore tearing toughness with higher can significantly improve the tear resistance of coating, the coating is used to identify as anticollision With good breakage-proof performance.Above-mentioned coating further includes the rough layer above back cover layer, and the number of projections on surface is 25~45/cm2.This just makes coating surface have apparent roughness, as mark in use, small advertisement is not easy to be pasted onto Surface is identified, and the small advertisement for being pasted onto surface is also very easy to by whole Zhang Qingchu.It is thus able to solve and identifies upper small advertisement Paste and understand problem.
Below in conjunction with specific embodiment, present invention is further described in detail, these embodiments should not be understood as limitation originally Invent range claimed.
The detection of composite coating:
Tear-proof degree: the tear-proof degree of each layer of coating is carried out using the digital tearing instrument instrument of YG033B model Detection;
Temperature tolerance: each layer to composite coating is carried out at high temperature using the digital tearing instrument instrument of YG033B model Temperature tolerance of the tear-proof test to obtain is detected;
Reflecting effect: using SS-ST-102 model portable light illumination instrument instrument to the reflective degree of composite coating into Row detection.
Part test raw material is as shown in the table:
Alkaline-resisting latex China Resources emulsion paint (water based emulsion)
Silica solution The vertical letter JN5-20/3 of moral
Alcohol ester-12 Hundred hues
Embodiment 1 to 6
Composite coating manufacture craft:
The raw material dope of configuration back cover layer, rough layer and finish coat is existed using electric pole as base material using spraying method Back cover coating is sprayed on base material.After cured, coarse coating is further sprayed.After rough layer solidification, further Finish coat coating is sprayed, composite coating is formed by curing.
The coating material of each embodiment is as shown in Table 1:
Table one
It is as shown in Table 2 to the performance characterization result of each layer of the composite coating in embodiment 1 to 6:
Table two
It can be seen from the above description that the above embodiments of the present invention realized the following chievements: above-mentioned implementation The composite coating prepared in example, each layer tear resistance with higher.Meanwhile can have anti-small advertisement paste performance, it is small wide It accuses paster to be not easy to cover, and can whole removing noresidue easily.It is therefore shown that the composite coating in the present invention is as anticollision mark Know, there is good breakage-proof performance and anti-small advertisement paste performance.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (6)

1. a kind of composite coating, which is characterized in that the composite coating includes:
Back cover layer, is covered on base material, and the raw material of the back cover layer include by weight 36~77 parts water, 0.9 ~2.2 parts of the first pH adjusting agent, 22~61 parts of toughener, 0.9~2.2 part of alcohol ester-12;
Rough layer, positioned at the side far from the base material of the back cover layer, the number of projections of the coarse layer surface is 25~45/cm2,
The raw material of the rough layer includes 90~440 parts of water, 450~990 parts of sand particles, 0.9~2.2 by weight Second pH adjusting agent, 4.5~16.5 parts of alcohol ester-12,0.9~3.3 part of the first defoaming agent and 9~22 parts of thickening of part Agent,
The composite coating further includes finish coat, and the finish coat is located at the side far from the back cover layer of the rough layer, The raw material of the finish coat include by weight 110~440 parts of water, 1.1~2.2 parts of third pH adjusting agent, 450~ 880 parts of partial size is glass microballoon, 16.5~44 parts of the alcohol ester-12 of 300~600 mesh,
Toughener in the raw material of the back cover layer include by weight 18~44 parts alkaline-resisting latex and 4.5~16.5 parts Silica solution.
2. composite coating according to claim 1, which is characterized in that the raw material of the finish coat further includes by weight 0.9~44 part of the second defoaming agent.
3. composite coating according to claim 1 or 2, which is characterized in that first pH adjusting agent, the 2nd pH tune Section agent and the third pH adjusting agent are separately selected from ammonium hydroxide and/or lime.
4. composite coating according to claim 2, which is characterized in that first defoaming agent and the second defoaming agent difference are only On the spot it is selected from one of higher alcohols, polyethers defoaming agent and silicon class defoaming agent or a variety of.
5. composite coating according to claim 1, which is characterized in that the thickener is selected from methylcellulose, organic bentonite One of profit soil and polyurethane thickener are a variety of.
6. a kind of mark, which is characterized in that the mark includes composite coating described in any one of claims 1 to 5.
CN201610899864.0A 2016-10-14 2016-10-14 Composite coating and mark Active CN106479233B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN106479233B true CN106479233B (en) 2019-09-10

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Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108485545A (en) * 2018-03-13 2018-09-04 昆山市聚光装饰材料有限公司 The preparation method of house ornamentation PVC wallpaper

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531084A (en) * 2009-03-23 2009-09-16 罗煜 An anti-paste material and its manufacturing method
CN102399483A (en) * 2011-12-22 2012-04-04 华南理工大学 Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof
CN104212275A (en) * 2014-08-22 2014-12-17 北京卫星制造厂 Waterborne thermal-insulation coating system for building with double-layer structure
CN204754014U (en) * 2015-06-23 2015-11-11 浙江泰基涂料有限公司 Layer structure is scribbled to hydrophobicity finishing coat

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101531084A (en) * 2009-03-23 2009-09-16 罗煜 An anti-paste material and its manufacturing method
CN102399483A (en) * 2011-12-22 2012-04-04 华南理工大学 Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof
CN104212275A (en) * 2014-08-22 2014-12-17 北京卫星制造厂 Waterborne thermal-insulation coating system for building with double-layer structure
CN204754014U (en) * 2015-06-23 2015-11-11 浙江泰基涂料有限公司 Layer structure is scribbled to hydrophobicity finishing coat

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