CN108178957A - Unburned enamel-like paint and its preparation method and application - Google Patents
Unburned enamel-like paint and its preparation method and application Download PDFInfo
- Publication number
- CN108178957A CN108178957A CN201711235788.4A CN201711235788A CN108178957A CN 108178957 A CN108178957 A CN 108178957A CN 201711235788 A CN201711235788 A CN 201711235788A CN 108178957 A CN108178957 A CN 108178957A
- Authority
- CN
- China
- Prior art keywords
- paint
- agent
- enamel
- unburned
- acid resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of unburned enamel-like paint and its preparation method and application, includes the component of following parts by weight：Organosilicon modified crylic acid resin 28 35, polyurethane organosilicon modified crylic acid resin 26 32, silane coupling agent 35, nano dye 3 30, functional aid 6 10 and mixed solution 10 20.The enamel-like paint, which exempts from calcining, can form similar glaze effect, can not only ensure superhigh intensity, high scratch resistance, the high-wearing feature of coating, but also with excellent outdoor weathe resistance energy.It directly can form complete application with the antirust paints such as epoxy anti-corrosive primer, electrophoretic primer, powdery paints, acrylic paint or the paint collocation of all kinds of bottom surfaces, electric pole, guard rail, light pole, traffic lights, power distribution cabinet, dustbin that can be applied to urban road both sides etc. needs high rigidity, the outdoor infrastructure of high durable requirement, such as the outdoor craftwork of flowerpot, flower stand, bench, animal statue.
Description
Technical field
The present invention relates to ceramic glaze paint technical field, specifically disclosed a kind of unburned enamel-like paint and preparation method thereof and should
With.
Background technology
Ceramic glaze is attached to a kind of silicate glass matter thin layer on ceramic body surface, and the glaze applied on ware is general
Using quartz, feldspar, clay as raw material, after the modulation of ground plus water, coated on billet surface, melted through the roasting of certain temperature
Melt, when the temperature drops, forming the glassy thin layer of ceramic surface.It is strong that it makes ware increase mechanical strength, thermal stability, dielectric
It spends and prevents liquid, the erosion of gas.Glaze also have increase porcelain it is beautiful and convenient for wash wipe, be not sticky with by dust the effects that.We
Ware used in everyday generally all wears smooth, smooth clothes, particularly domestic ceramics all over the body, " clothes " is more said
Study carefully, what is had is as white as polished jade, and what is had is colorful, very beautiful.This clothes of ceramics, are named as " glaze ".Ceramic glaze presses preparation side
Method is classified, and has raw glaze, fritted glaze；Classify by the composition of glaze, there is lime glaze, feldspar glaze, lead glaze, boron glaze, fused salt glaze, clay glaze
Deng；By green body classification of type, there are hard porcelain glaze, porcelain tendre glaze, bristol glaze；Classify by firing temperature, have fusible glaze (less than 1100 DEG C), in
Warm glaze (1100~1250 DEG C) and high-temperature glaze (1250 DEG C or more)；By glaze paint appearance classification, have clear frit, opaque glaze, the prosperous glaze of knot,
Crackle glaze etc..Common classification is first two in production, it can directly reflect the preparation method and performance of glaze.
Glazing process is one kind of antique pottery porcelain Manufacturing Techniques, refers to impose glaze on molding ceramic body surface
Slurry.Glaze is mainly dipped in, glaze is swung, pours glaze, brushing glazing, spills six kinds of methods such as glaze, wheel glaze, by the different shape of green body, thickness, using phase
The enameling method answered.Because glazing process is one kind of antique pottery porcelain Manufacturing Techniques, glazing process is complex, Er Qieji
Originally high-temperature calcination is required for, causes environmental pollution, it is not only bothersome but also largely consume energy.
In recent years, enamel-like paint had obtained in-depth study.Patent CN104231816A disclose a kind of enamel-like paint and
Preparation method, the component containing following parts by weight：Polymer emulsion 500~600, nano zircite 50~150, the imitative glaze
Coating solves the unicity of previous coating characteristic, is significantly obtained in terms of adhesion strength, high temperature resistance, ageing-resistant performance
It improves, and there is the coating excellent appearance to imitate glaze effect, improve the class of coated product.Patent CN105176284A mono-
Kind of water soluble imitation glaze coating and preparation method, the material of material component A and weight proportion are respectively in the water soluble imitation glaze coating：Third
90 parts of olefin(e) acid butyl ester, 45 parts of methyl methacrylate, 1.3 parts of ammonium persulfate, 2.2 parts of Triton X-100, acrylic acid-
1.1 parts of methacrylic acid copolymer ammonium salt, 210 parts of water.The material and weight proportion of material component B be respectively：Emulsion type forms a film
80 parts of object, 7.5 parts of rutile type titanium white, 0.8 part of calgon, 6.2 parts of butyl glycol ether, 61 parts of water.The invention is applicable in
In building inner, external wall and the water soluble imitation glaze coating of roof tiling decoration, have surfacing smooth, glossiness is high, strong adhesive force
Characteristic, there are the good effects such as water-fast, ageing-resistant, acid and alkali-resistance, washability, stain resistance be strong, 100 DEG C or more of height can be resisted
Temperature；Cost is relatively low.Patent CN 106905794A disclose a kind of nontoxic enamel-like paint formula, and raw material composition is：Polycarboxylic acids sweet tea
Dish alkali：25-30 parts；Propane sulfonic acid：3-5 parts；White carbon：5-10 parts；Sodium hydroxide：0.8-1.2 parts；Fluorescent whitening agent：0.7-1
Part；Deionized water：500-600 parts；Precipitated calcium carbonate：40-50 parts；Sierozem power：250-280 parts；Mould inhibitor：0.08-0.12 parts；
Synthetic resin emulsion：10-15 parts；Preservative：0.8-1.2 parts；Stain resistant agent：0.5-1.5 parts；Talcum powder：38-45 parts；Formaldehyde：
15-20 parts；Viscosity stabiliser：0.5-1 parts；Above-mentioned number is mass fraction.Above-mentioned nontoxic enamel-like paint formula, anti-scratch
It washes, it is at low cost, the smooth of metope can be kept.But above-mentioned patented technology product is not in terms of weatherability, cleanablity
Obtain special attention and research.
Invention content
The purpose of the present invention is to provide a kind of unburned enamel-like paint, similar glaze effect can be formed by exempting from calcining, both can be with
Ensure superhigh intensity, high scratch resistance, the high-wearing feature of coating, and there can be excellent outdoor weathe resistance energy.
It is another object of the present invention to provide a kind of preparation methods of unburned enamel-like paint, and preparation process is simple,
Easy high-volume industrialization production, the coating excellent combination property of acquisition.
A further object of the present invention is to provide a kind of unburned enamel-like paint infrastructure and outdoor craftwork outdoors
In application.
The present invention provides a kind of unburned enamel-like paint, includes the component of following parts by weight：Organosilicon modified crylic acid resin
28-35, polyurethane organosilicon modified crylic acid resin 26-32, silane coupling agent 3-5, nano dye 3-30, functional aid 6-
10 and mixed solution 10-20.
Preferably, the organosilicon modified crylic acid resin is with containing by the polyacrylic acid phenol resin containing active group
A kind of modified resin, preferably Changzhou Shi Jianuo organosilicons made of the silicone oligomer reaction of active antelope base (or alkoxy)
The FJNS-4 organosilicon modified crylic acid resins of Co., Ltd.It is by containing four silicon of phenyltriethoxysilane and prestox ring
For modifying agent, the graft reaction under catalyst action synthesizes acrylic resin modified oxygen alkane with acrylic monomers or intermediate, makes
Organosilicon modified crylic acid resin generates three-dimensional netted cross-linked structure, can significantly improve the weatherability of coating, high-low temperature resistant,
Water resistance, gloss retention and durability etc., while can one component room temperature drying.The resin plays the work of film forming matter in product system
With.
Preferably, the polyurethane organosilicon modified crylic acid resin is self-drying type polyurethane organosilicon-modified acrylic
The polyurethane organosilicon modified crylic acid resin SJ-5021 of resin, preferably three gold medal pigment Co., Ltd of Zongyang County.It is main
Be using advanced synthesis technology by the part of hydroxyl in the alkoxy and polyurethane prepolymer in polysiloxane molecule into
Row ester exchange reaction synthesizes, and not only significantly improves the adhesive force of organosilicon, wearability oil resistivity, chemical resistance, but also keeps poly-
Urethane excellent weatherability and mechanicalness, while there is highly cross-linked reticular structure, contain active group on molecule, by pre-
- NCO in polymers reacts generation urea bond ambient cross-linking curing drying and forming-film with the moisture content in air, can guarantee the superelevation of paint film
Hardness.The resin plays modified hardening in product system and promotes the double effects of adhesive force.
Silane coupling agent is a kind of in the molecule while containing there are two types of the organo-silicon compound of different chemical property groups.This
In formula, it can serve as crosslinking agent, improve the bridging property of resin, improve the adhesive force of resin, water-fast flexibility, can significantly carry
Adhesive force, the adhesion property of high coating can improve the bonding force of acrylic latex, sealant, polyurethane and epoxy resin, improve
Film flexibility, water proofing property, wearability, scrub resistance, scratch resistance and chemical-resistant etc., preferably Dow corning company silicon
Alkane coupling agent Z-6040.
Preferably, the nano dye is nano aluminium oxide, nanometer titanium dioxide, the organic middle Huang of nanometer or nanometer are organic
It is bright red, corresponding weight be nano aluminium oxide 3-5, nanometer titanium dioxide 26-30, the organic middle Huang 12-16 of nanometer or
The organic bright red 12-16 of nanometer.Wherein, addition nano aluminium oxide then forms the anti-ceramic wear-resisting varnish of high-hard, transparent, adds nanometer
Titanium dioxide then forms the unburned enamel-like paint of white, and the addition organic middle Huang of nanometer then forms the unburned enamel-like paint of yellow, adds nanometer
It is organic bright red, form red unburned enamel-like paint.
Preferably, functional aid includes the one of antifoaming agent, levelling agent, dispersant, anti-pollution auxiliary agent and uvioresistant auxiliary agent
Kind is a variety of.
Preferably, the antifoaming agent is 810 antifoaming agent of Di Gao companies of Germany, which defoams for polyether silicone class
Agent.The levelling agent is Efka EFKA-3700 levelling agents, which is the polyacrylate flow agent of high fluorine carbon content,
With very strong drop surface tension, excellent nonshrink hole, good ground soaks and promotes facade levelling.The dispersant is
The 650U dispersants of Britain, the dispersant are acrylic acid dispersants, can disperse organic inorganic pigment.The anti-pollution auxiliary agent is3700；1130 UV absorbers and antioxidant of the preferred BASF of uvioresistant auxiliary agent
292,1130 be hydroxybenzotriazole fluid-like state UV absorbers, and 292 be liquid hindered amine class light stabilizer, and two kinds of compoundings make
With coating plays the role of extraordinary ultraviolet light.
Preferably, a variety of mixtures of the mixed solvent in water soluble alcohols solvent, water-soluble ether solvent.
The water soluble alcohols solvent is n-butanol, isobutanol, ethyl alcohol etc.；The water solubility ether solvent can be dipropylene glycol diformazan
Ether, butyl, dipropylene etc..The solvent of selection is the water-soluble solvent that can be dissolved in water, such solvent ratio
Organic solvent benzene,toluene,xylene is more environmentally-friendly, and effect harmless to the human body will not pollute environment, has very high
The feature of environmental protection.
Preferably, mixed solvent for n-butanol, dimethyl ether mixture, mass ratio 1:1-1.2.N-butanol
Play the role of stabilizer in coating, prevent coating gelatinization, extend coating storage time, dimethyl ether plays molten
Solution and adjustment paint drying time, surface tension is reduced, helps the effect to form a film.
The present invention also provides the preparation method of above-mentioned unburned enamel-like paint, when the nano dye of addition need not be ground,
Step is：Organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, part mixed solvent, functional aid are mixed
It closes, be stirred uniformly, finally adjust viscosity, filtering with remaining mixed solvent；When the nano dye of addition needs grinding,
Its step is：By organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, nano dye, part mixed solvent, work(
Can the mixing of property auxiliary agent, be stirred uniformly, go to grinding process and be ground using sand mill and be dispersed to fineness and meet the requirements, most
Afterwards viscosity, filtering are adjusted with remaining mixed solvent.
The unburned enamel-like paint of the present invention is spontaneously dried using tide curing, forms the film of ultrahigh hardness, moisture solidification
Cardinal principle is that-NCO the reactivities in main film forming matter-prepolymer in product are very big, can be made with the moisture content in air
With reaction generation urea bond, ambient cross-linking curing drying and forming-film, product will be dried under appropriate temperature and humidity.Temperature
At 25-27 DEG C, humidity is suitble to the most in 75-80%.It sprinkles water or sprays water on ground when necessary, to improve indoor humidity, from
And film tide is promoted to cure drying.The process costs are cheap, energy consumption is small and easy to operate, do not need to high-temperature calcination and high temperature dries
It is roasting, belong to high energy saving, high-environmental product, be suitble to industrialized production.
The present invention provides above-mentioned unburned enamel-like paint infrastructure and the application in outdoor craftwork outdoors.
The present invention unburned enamel-like paint can directly with epoxy anti-corrosive primer, electrophoretic primer, powdery paints, acrylic paint
Antirust paints or the paint collocation of all kinds of bottom surfaces is waited to form complete application, can be applied to the electric pole of urban road both sides, guard rail,
Light pole, traffic lights, power distribution cabinet, dustbin etc. need high rigidity, the outdoor infrastructure of high durable requirement, as flowerpot,
The open air such as flower stand, bench, animal statue craftwork.
Beneficial effects of the present invention have：
1st, not only construction technology is simple for the unburned enamel-like paint of the present invention, but also exempts to calcine tide curing natural drying 48 hours i.e.
Similar glaze effect can be formed, greatly reduces the energy consumed to fire glaze；Simultaneously the preparation method for coating it is simple, cost compared with
Low, form of construction work is also simple, and utilization rate is high, avoids causing to waste, has saved production and construction cost.
2nd, organosilicon modified crylic acid resin and self-drying type polyurethane organosilicon modified crylic acid resin compounding are refined
Enamel-like paint, through tide curing spontaneously dry after form paint film, film forming coatings have：A, high rigidity, coating table after film-forming
Surface hardness can reach 9H (Mitsubishi's pencil)；B, high-low temperature resistant, is resistant to 500 DEG C or more high temperature and -40 DEG C of low temperature and coating is not crisp
Change；C, high-wearing feature, has super-high wear-resistant, and wearability can compare favourably with ceramics；D, there is good adhesive force, at various bottoms
Adhesive force on material can reach 0 grade；E, weatherability is fabulous, is particularly suitable for outdoor with waterproof and dampproof, uvioresistant requirement
It is used on base material, normal use not aging in 30 years.
3rd, the low-surface-energy of coating characteristic, outstanding lipophobic hydrophobic and anti-scribble performance easy to clean can be kept for a long time.
4th, the solvent selected is the water-soluble solvent that can be dissolved in water, such solvent is than organic solvent benzene,toluene,xylene
More environmentally-friendly, effect harmless to the human body will not pollute environment, have the very high feature of environmental protection.
Specific embodiment
This hair can be further well understood by the specific embodiment and comparing embodiment of invention now given below
It is bright, but they are not limitation of the invention.It is to use not have the part described in detail in specific embodiment and comparing embodiment
What the prior art, known technology means and professional standard obtained.
Unless otherwise specified, the conventional hand that the technological means employed in embodiment is well known to those skilled in the art
Section, used reagent and product are also available commercial.The source of agents useful for same, trade name are with it is necessary to list its group
Into ingredient person, indicate on the first appearance.
Unless otherwise indicated, the percentage employed in the present invention is weight percent.
Main test method is used in the specific embodiment of the invention or instrument is as follows：
It surveys and applies film thickness：German import Knicks (Qanix8500) calibrator (film thickness gauge), suitable for measuring aluminum bronze magnesium zinc-iron
Wait ferrous metals and nonferrous metal part base material thickness, the nonmetallic digital display calibrators of PosiTector200, suitable for measuring plastic bottom
The substrate coatings thickness such as material, timber, concrete, magnesia.
Pencil hardness：Guangzhou mark brother reaches the combined pencil hardometer of Laboratory Instruments articles for use Co., Ltd.
Adhesive force：Guangzhou mark brother reaches the paint film lattice drawing device (cross-cut tester) of Laboratory Instruments articles for use Co., Ltd.
Humidity resistance：Taiwan crowd's will CZ-A-150D programmable constant temperature and moisture test machine set temperature humidity simultaneously sets test
Time 800h wet-heat resisting test condition is tested.
Gloss：The intelligent triangular degree glossometer BGD516 of Guangzhou mark brother up to Laboratory Instruments articles for use Co., Ltd carries out accurate
Test.
Aberration：The CI6X spectrophotometers of U.S. Ai Seli (Asia-Pacific) Co., Ltd carry out precision measurement.
Salt fog resistance：Guangzhou mark brother is rotten up to 881 continous way brine spray salt fogs of Laboratory Instruments articles for use Co., Ltd BGD
Wave gas etching tester, set temperature humidity simultaneously set testing time 800h salt spray resistance test condition and are tested.
Artificial weathering ageing resistance：The Q-SUN-XE-3 type photo-stability testings case setting light of Q=LAB companies of U.S. production
Wave is surveyed in 340nm, irradiation level 0.51W/m2,63 DEG C of illumination temperature, humidity 80% into Line Continuity artificial weathering ageing resistance
Try 1200h, after with Guangzhou mark brother up to Laboratory Instruments articles for use Co., Ltd intelligent triangular degree glossometer BGD516 and the U.S. like
The CI6X spectrophotometers of beautiful (Asia-Pacific) Co., Ltd of color carry out glossiness and chromatic aberration test.
Embodiment 1
The clear varnish of unburned imitative glaze includes each component of following parts by weight：32.5 weight of organosilicon modified crylic acid resin
Measure part, polyurethane-modified 32 parts by weight of organic siliconresin, 4.5 parts by weight of silane coupling agent, 5.0 parts by weight of nano aluminium oxide, work(
9.5 parts by weight of energy property auxiliary agent, mixed solvent (n-butanol：Dimethyl ether=1:1) 16.5 parts by weight.
Its production method, includes the following steps：
With input organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, mixed solvent, silane in paint can
Coupling agent, dispersant, antifoaming agent, nano aluminium oxide are stirred evenly with blender, and the rotating speed of blender is 1000 rpms, is stirred
Levelling agent, anti-pollution auxiliary agent and the uvioresistant auxiliary agent in functional aid are sequentially added after mixing substantially uniformity, are again stirring for
Uniformly, blender rotating speed is 800 rpms, then viscosity is adjusted to painting 25 ± 22S of 4# cups (25 DEG C) with mixed solvent, to be tested
It with 200 mesh filter screen filtrations and is packed after qualification.
Its construction method is as follows：
Spraying or the unburned enamel-like paint of roller coating：Pail pack is opened, stirring evenly can construct, using aerial spraying, roller coating
Or it brushes.
Embodiment 2
Unburned imitative glaze white coating includes each component of following parts by weight：28.3 weight of organosilicon modified crylic acid resin
Part, polyurethane-modified 26 parts by weight of organic siliconresin, 4.0 parts by weight of silane coupling agent, 2.0 parts by weight of nano aluminium oxide, nanometer
26 parts by weight of titanium dioxide, 8.5 parts by weight of functional aid, mixed solvent (n-butanol：Dimethyl ether=1:1)15.9
Parts by weight.
Its production method, includes the following steps：
With input top half organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, mixing in paint can
Solvent, silane coupling agent, dispersant, antifoaming agent, nano aluminium oxide, nano-titanium dioxide are stirred evenly with blender, blender
Rotating speed for 1000 rpms, be stirred to after substantially uniformity and be ground to fineness≤20um with big flow high efficiency sand mill, after
By lower half portion synthesizing organo-silicon is acrylic resin modified, the levelling agent in polyurethane-modified organic siliconresin, functional aid,
Anti-pollution auxiliary agent and uvioresistant auxiliary agent sequentially add, be again stirring for uniformly, blender rotating speed be 800 rpms, then with mix
Viscosity is adjusted to apply 22 ± 2S of 4# cups (25 DEG C) by solvent, with 200 mesh filter screen filtrations and is packed after qualification to be tested.
Embodiment 3
Unburned imitative glaze yellow paint includes each component of following parts by weight：29.2 weight of organosilicon modified crylic acid resin
Part, polyurethane-modified 26 parts by weight of organic siliconresin, 4.0 parts by weight of silane coupling agent, 2.2 parts by weight of nano aluminium oxide, nanometer
Organic 12 parts by weight of middle bloom, 8.5 parts by weight of functional aid, mixed solvent (n-butanol：Dimethyl ether=1:1)
14.3 parts by weight.
Its production method, includes the following steps：
With input organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, mixed solvent, silane in paint can
Coupling agent, antifoaming agent, dispersant, nano aluminium oxide, the organic middle bloom of nanometer are stirred evenly, the rotating speed of blender with blender
Be 1000 rpms, be stirred to after substantially uniformity and be ground to fineness≤20um with big flow high efficiency sand mill, after will be transferred to
With in paint can, adding in lower half portion organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, functional aid
Levelling agent, anti-pollution auxiliary agent and uvioresistant auxiliary agent sequentially add, be again stirring for uniformly, blender rotating speed be 800 rpms,
Viscosity is adjusted to mixed solvent again to apply 22 ± 2S of 4# cups (25 DEG C), with 200 mesh filter screen filtrations and is packed after qualification to be tested.
Comparative example 1
Conventional ceramic baking vanish includes each component of following parts by weight：33 parts by weight of thermosetting acrylic resin, mixed solvent
(n-butanol：Dimethylbenzene=1:1) 13 parts by weight, 1 parts by weight of wetting dispersing agent, 0.3 parts by weight of antifoaming agent, 20 weight of iron oxide red
Part, 11 parts by weight of filler, 0.4 parts by weight of anti-settling agent, 14 parts by weight of amino resins (582-2), 6 parts by weight of saturated polyester resin,
0.4 parts by weight of levelling agent, 0.4 parts by weight of uvioresistant auxiliary agent.
Its production method, includes the following steps：
With input thermosetting acrylic resin, mixed solvent, anti-settling agent, wetting dispersing agent, antifoaming agent, gold in paint can
It after red stone-type titanium dioxide, filler, is stirred evenly with blender, the rotating speed of blender is 1000 rpms, is stirred to completely
It is ground to fineness≤20um after even, after fineness of grind qualification, is transferred to in paint can, adding amino resins, saturated polyester
Resin, levelling agent, uvioresistant auxiliary agent, cooling agent, be again stirring for uniformly, blender rotating speed be 800 rpms, then with mix
Viscosity is adjusted to apply 22 ± 2S of 4# cups (25 DEG C) by solvent, with 200 mesh filter screen filtrations and is packed after qualification to be tested.
The unburned enamel-like paint of above-mentioned each embodiment and comparative example is tested, obtained the performance test results are as follows
Shown in table 1.
The performance test results of 1 unburned enamel-like paint of table
It is above disclosed to be merely a preferred embodiment of the present invention, the right of the present invention cannot be limited with this certainly
Range, therefore the equivalent variations made according to scope of the present invention patent, are still within the scope of the present invention.
Claims (10)
1. a kind of unburned enamel-like paint, it is characterised in that：Include the component of following parts by weight：Organosilicon modified crylic acid resin
28-35, polyurethane organosilicon modified crylic acid resin 26-32, silane coupling agent 3-5, nano dye 3-30, functional aid 6-
10 and mixed solution 10-20.
2. unburned enamel-like paint according to claim 1, it is characterised in that：The organosilicon modified crylic acid resin is
By contain phenyltriethoxysilane and octamethylcy-clotetrasiloxane for modifying agent with acrylic monomers or intermediate in catalyst
The lower graft reaction of effect synthesizes acrylic resin modified.
3. unburned enamel-like paint according to claim 1, it is characterised in that：The polyurethane organosilicon-modified acrylic
Resin is self-drying type polyurethane organosilicon modified crylic acid resin.
4. unburned enamel-like paint according to claim 1, it is characterised in that：The nano dye for nano aluminium oxide,
The organic middle yellow or nanometer of nanometer titanium dioxide, nanometer is organic bright red, and corresponding weight is nano aluminium oxide 3-5, is received
Rice titanium dioxide 26-30, the nanometer organic middle Huang 12-16 or organic bright red 12-16 of nanometer.
5. unburned enamel-like paint according to claim 1, it is characterised in that：Functional aid include antifoaming agent, levelling agent,
Dispersant, anti-pollution auxiliary agent and uvioresistant auxiliary agent it is one or more.
6. unburned enamel-like paint according to claim 5, it is characterised in that：The antifoaming agent is Di Gao companies 810 of Germany
Antifoaming agent, the levelling agent are Efka EFKA-3700 levelling agents, and the dispersant is the 650U dispersants of Britain, described
Anti-pollution auxiliary agent be- SILCLEAN 3700,1130 UV absorbers of the preferred BASF of uvioresistant auxiliary agent
It is compounded with antioxidant 292.
7. unburned enamel-like paint according to claim 1, it is characterised in that：It is molten that the mixed solvent is selected from water soluble alcohols
A variety of mixtures in agent, water-soluble ether solvent.
8. unburned enamel-like paint according to claim 7, it is characterised in that：The water soluble alcohols solvent for n-butanol,
Isobutanol, ethyl alcohol；The water solubility ether solvent is dimethyl ether, butyl, dipropylene.
9. a kind of preparation method of unburned enamel-like paint described in claim 1 to 8, it is characterised in that：When the nanometer face of addition
When material need not be ground, step is：By organosilicon modified crylic acid resin, polyurethane-modified organic siliconresin, partly mix it is molten
Agent, is stirred uniformly functional aid mixing, finally adjusts viscosity, filtering with remaining mixed solvent；
When the nano dye of addition needs grinding, step is：By organosilicon modified crylic acid resin, polyurethane-modified organic
Silicones, part mixed solvent, functional aid mixing, is stirred uniformly nano dye, goes to grinding process using sand milling
Machine, which is ground, to be dispersed to fineness and meets the requirements, and finally adjusts viscosity, filtering with remaining mixed solvent.
10. a kind of unburned enamel-like paint described in any item of the claim 1 to 8 is outdoors in infrastructure and outdoor craftwork
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711235788.4A CN108178957B (en) | 2017-11-30 | 2017-11-30 | Baking-free glaze-imitating coating and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711235788.4A CN108178957B (en) | 2017-11-30 | 2017-11-30 | Baking-free glaze-imitating coating and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108178957A true CN108178957A (en) | 2018-06-19 |
| CN108178957B CN108178957B (en) | 2021-06-15 |
Family
ID=62545332
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711235788.4A Active CN108178957B (en) | 2017-11-30 | 2017-11-30 | Baking-free glaze-imitating coating and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108178957B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109897483A (en) * | 2019-01-16 | 2019-06-18 | 深圳市欧科力科技有限公司 | A kind of preparation method of the modified acrylic coating material of resistance to UV aging energy |
| CN110723987A (en) * | 2019-10-17 | 2020-01-24 | 南京博物院 | Application of XW-HB water-based two-component self-drying paint as porcelain repairing glaze-imitating material |
| CN111393025A (en) * | 2020-03-30 | 2020-07-10 | 景德镇陶瓷大学 | Ceramic glaze material with antibacterial effect and ceramic |
| CN111484354A (en) * | 2020-06-05 | 2020-08-04 | 嘉应学院 | High-hardness long-afterglow luminescent coating for enamel ceramic product and preparation method thereof |
| CN113024282A (en) * | 2021-03-05 | 2021-06-25 | 德化县嘉吉陶瓷有限公司 | High-strength crack glaze, high-strength crack glaze ceramic product and preparation method thereof |
| CN113956077A (en) * | 2021-11-26 | 2022-01-21 | 佛山市东鹏陶瓷发展有限公司 | Decorative ceramic tile using baking-free glaze and manufacturing process thereof |
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125753A (en) * | 1994-12-29 | 1996-07-03 | 北京华典新技术公司 | Weather-resisting liquid porcelain and its preparation method |
| CN102464784A (en) * | 2010-11-19 | 2012-05-23 | 北京佳盛世纪科技有限公司 | Synthesis method of organic silicon modified acrylate copolymer |
| CN103012714A (en) * | 2012-12-26 | 2013-04-03 | 江苏柏鹤涂料有限公司 | High-flexibility aqueous acrylic acid polyurethane elastic resin and coating thereof |
| CN105176284A (en) * | 2015-09-14 | 2015-12-23 | 黄建丽 | Water-based glaze-imitation paint and preparing method thereof |
| CN105694702A (en) * | 2016-03-15 | 2016-06-22 | 中科院广州化学有限公司南雄材料生产基地 | Single-component moisture-curable organic silicon modified polyurethane waterproof paint and preparation method |
-
2017
- 2017-11-30 CN CN201711235788.4A patent/CN108178957B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1125753A (en) * | 1994-12-29 | 1996-07-03 | 北京华典新技术公司 | Weather-resisting liquid porcelain and its preparation method |
| CN102464784A (en) * | 2010-11-19 | 2012-05-23 | 北京佳盛世纪科技有限公司 | Synthesis method of organic silicon modified acrylate copolymer |
| CN103012714A (en) * | 2012-12-26 | 2013-04-03 | 江苏柏鹤涂料有限公司 | High-flexibility aqueous acrylic acid polyurethane elastic resin and coating thereof |
| CN105176284A (en) * | 2015-09-14 | 2015-12-23 | 黄建丽 | Water-based glaze-imitation paint and preparing method thereof |
| CN105694702A (en) * | 2016-03-15 | 2016-06-22 | 中科院广州化学有限公司南雄材料生产基地 | Single-component moisture-curable organic silicon modified polyurethane waterproof paint and preparation method |
Non-Patent Citations (3)
| Title |
|---|
| 李群英: "《涂装工快速入门》", 30 April 2007, 国防工业出版社 * |
| 王锡娇: "《涂料与颜料标准应用手册 上册》", 30 April 2005, 军事谊文出版社 * |
| 贾红兵 等: "《高分子材料》", 30 November 2009, 南京大学出版社 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109897483A (en) * | 2019-01-16 | 2019-06-18 | 深圳市欧科力科技有限公司 | A kind of preparation method of the modified acrylic coating material of resistance to UV aging energy |
| CN110723987A (en) * | 2019-10-17 | 2020-01-24 | 南京博物院 | Application of XW-HB water-based two-component self-drying paint as porcelain repairing glaze-imitating material |
| CN111393025A (en) * | 2020-03-30 | 2020-07-10 | 景德镇陶瓷大学 | Ceramic glaze material with antibacterial effect and ceramic |
| CN111484354A (en) * | 2020-06-05 | 2020-08-04 | 嘉应学院 | High-hardness long-afterglow luminescent coating for enamel ceramic product and preparation method thereof |
| CN113024282A (en) * | 2021-03-05 | 2021-06-25 | 德化县嘉吉陶瓷有限公司 | High-strength crack glaze, high-strength crack glaze ceramic product and preparation method thereof |
| CN113024282B (en) * | 2021-03-05 | 2022-05-31 | 德化县嘉吉陶瓷有限公司 | High-strength crack glaze, high-strength crack glaze ceramic product and preparation method thereof |
| CN113956077A (en) * | 2021-11-26 | 2022-01-21 | 佛山市东鹏陶瓷发展有限公司 | Decorative ceramic tile using baking-free glaze and manufacturing process thereof |
| CN113956077B (en) * | 2021-11-26 | 2023-03-10 | 佛山市东鹏陶瓷发展有限公司 | Decorative ceramic tile using baking-free glaze and manufacturing process thereof |
| CN116161987A (en) * | 2023-04-21 | 2023-05-26 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
| CN116161987B (en) * | 2023-04-21 | 2024-01-05 | 佛山市东鹏陶瓷有限公司 | Composite decorative porcelain product and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108178957B (en) | 2021-06-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108178957A (en) | Unburned enamel-like paint and its preparation method and application | |
| CN102532965B (en) | Coating composition and decorative material | |
| CN102617104B (en) | Inorganic powder sandy paint and production method thereof | |
| WO2017028471A1 (en) | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof | |
| CN101230222B (en) | Title-imitating coating and preparation method thereof | |
| CN101255301A (en) | Exterior deep base paint formulation | |
| CN104031508A (en) | Three-resistance type real stone paint and preparation method thereof | |
| CN110527378A (en) | A kind of bottom surface unification water burnt-in sand coating and preparation method thereof | |
| CN102051115A (en) | Ultraviolet light curing colored paint and preparation method thereof | |
| CN109897503A (en) | A kind of normal temperature cure modifying epoxy resin by organosilicon coating and the preparation method and application thereof | |
| CN109868015B (en) | Organic-inorganic composite water-based aluminum powder paint and preparation method thereof | |
| CN102745966B (en) | Anti-cracking color retention VOC-free (Volatile Organic Compounds) and zero-alkali-return aqueous dry powder building colored coating | |
| CN105001731A (en) | Creative environment-friendly dry powder paint for wall decoration | |
| CN101265391A (en) | Colorful drying powder wall paint with marble effect | |
| CN108727922A (en) | One kind exempting from cover and imitates lime mineral varnish and preparation method thereof | |
| CN101230237B (en) | Marble-imitated natural mica paint and preparation method thereof | |
| CN110724421A (en) | Water-based tile anti-slip cover and preparation method and application thereof | |
| CN101723705A (en) | Fully water based granite multicolor paint | |
| JP2019155919A (en) | Surface material | |
| CN111484780A (en) | Method for manufacturing composite marble-imitated coating based on elastic multicolor paint | |
| TWI647288B (en) | Non-burning imitation glaze coating and preparation method and application thereof | |
| CN105670404A (en) | Aqueous stone-like coating | |
| CN104710932B (en) | Full-visual-angle high-imitation stone paint and preparation method thereof | |
| JP5215021B2 (en) | Painting method | |
| JP6693914B2 (en) | Film forming method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |