CN108046672A - A kind of aqueous cover protective agent of pervious concrete - Google Patents

A kind of aqueous cover protective agent of pervious concrete Download PDF

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Publication number
CN108046672A
CN108046672A CN201810012022.8A CN201810012022A CN108046672A CN 108046672 A CN108046672 A CN 108046672A CN 201810012022 A CN201810012022 A CN 201810012022A CN 108046672 A CN108046672 A CN 108046672A
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CN
China
Prior art keywords
parts
pervious concrete
agent
aqueous
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810012022.8A
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Chinese (zh)
Inventor
林英男
林建二
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenzhen Weitenai New Material Co Ltd
Original Assignee
Shenzhen Weitenai New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenzhen Weitenai New Material Co Ltd filed Critical Shenzhen Weitenai New Material Co Ltd
Priority to CN201810012022.8A priority Critical patent/CN108046672A/en
Publication of CN108046672A publication Critical patent/CN108046672A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/005Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing gelatineous or gel forming binders, e.g. gelatineous Al(OH)3, sol-gel binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00034Physico-chemical characteristics of the mixtures
    • C04B2111/00146Sprayable or pumpable mixtures
    • C04B2111/00155Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of aqueous cover protective agents of pervious concrete, it is made of following content of component:800 1100 parts of cementitious material, functional 0.2 3 parts of additive, 0.01 0.1 parts of material combination power additive, 0.1 1.5 parts of thickener, 50 150 parts of deionized water.The aqueous cover protection materials of pervious concrete of the present invention are organically to combine inorganic active material and organic bonding material by double charge protection and coupling protocols; organic resin is modified by inorganic material; and double charge protection is carried out to inorganic material surface by functional additive; stability of the inorganic material in organic system is added, so as to improve the intensity of system and crocking resistance.

Description

A kind of aqueous cover protective agent of pervious concrete
Technical field
The present invention relates to the pervious concrete cover protective agent technical field of engineering material technology, which is mainly used for Water coagulation soil surface finishing is protected, and can also be used as other building structure surface protecting materials.
Background technology
Cement concrete is a kind of porous material, in addition to macroscopic macropore, also there are substantial amounts of capillary micropore, These micropores easily absorb water through capillary action, and the harmful chemicals such as chlorion and sulfate also can enter cement with dampening to be mixed Solidifying soil is internal, causes the various erosions and destruction of concrete and reinforcing bar, reduces concrete service life.
At present, the attention that does not also obtain relevant departments is protected concrete, only for the extra large work in corrosive environment Concrete is clearly proposed and concrete protected using concrete as related specifications such as the clear-water concretes of final decorative cover Requirement.The concrete outer surface of many urban interchanges is brushed, and largely uses common exterior coating, this Coating not only it is easy to appear peeling and obscission, can also interfere the gas permeability of concrete, make the moisture of inside concrete not Easily effusion, can aggravate the generation of concrete diseases, influence the service life of concrete structure instead.Currently, pervious concrete cover Face protection materials are broadly divided into oily material.The protectant advantage of oiliness pervious concrete cover is:It is bright in luster, bulk strength It is high.Chinese invention patent CN102675999A discloses a kind of aqueous fluorocarbon coating for silicate concrete curb, former Material formula includes the component of following mass percents:Water-base fluorocarbon emulsion 48.0%~78.1%;Pigment 13.5~30.1%;Profit Hygroscopic water powder 0.2~2.3%;Neutralizer 0~0.52%;Organic silicon defoamer 0.1~0.5%;Preservative 0~0.5%;Thickening Agent 0.1~3.2%;Coalescents 1.0~5.1%;Antifreezing agent 1.0~4.2%;Aqueous interfacial agents 1.1~5.7% and water 0.5~10.2%;The pH of the coating is 8.0~9.5.The coating imparts silicate concrete curb decoration and protection Function, weatherability, temperature-change resistance, but its composition is excessively complicated, dispensing difficulty is big, and preparation method is also excessively cumbersome, of high cost; Be unfavorable for carry out mass production and scene modulate, complicated construction technique, at the same its coating penetration depth deficiency, protection effect compared with Difference;And this aqueous fluorocarbon coating weatherability, durability effect unobvious, coating penetration depth deficiency.And the combination on basis Force difference, protection effect is poor, also has certain environmental pollution.
The content of the invention
The technical problem to be solved by the present invention is to:It is proposed a kind of intensity of raising system and crocking resistance, raising system With the aqueous cover protective agent of pervious concrete of the weatherability and durability of the adhesive property and raising system of base concrete.
To achieve the above object, the technical solution adopted by the present invention is:
A kind of aqueous cover protective agent of pervious concrete, it is made of following content of component:
800-1100 parts of cementitious material, functional 0.2-3 parts of additive, 0.01-0.1 parts of material combination power additive, increasing Thick dose 0.1-1.5 parts, 50-150 parts of deionized water.
The mass parts composition of the currently preferred cementitious material is as follows:350-450 parts of waterborne PUA, Ludox 400- 600 parts, active 50-150 parts of metakaolin.
Currently preferred functionality additive is 0.1-1.0 parts of wetting agent, 0.1-1.0 parts of dispersant, antifoaming agent 0-1 Part.
More preferably, the aqueous cover protective agent of pervious concrete, it is characterised in that:Include the component of following parts by weight:
350~450 parts of waterborne PUA;400~600 parts of Ludox;
0.1~1.0 part of dispersant;0.1-1.0 parts of wetting agent;
0.05~1.0 part of antifoaming agent;0.1-1.5 parts of thickener;
50-150 parts of deionized water.
More preferably, the aqueous cover protective agent of pervious concrete, it is characterised in that:Include the component of following parts by weight:
350~450 parts of waterborne PUA;400~600 parts of Ludox;
0.1~1.0 part of dispersant;0.1-1.0 parts of wetting agent;
0.05~1.0 part of antifoaming agent;50-150 parts of deionized water;
Active metakaolin 50-100 parts;0.1-1.5 parts of thickener.
More preferably, a kind of impact-resisting wear-resisting mortar, it is characterised in that:Include the component of following parts by weight:
350~450 parts of waterborne PUA;400~600 parts of Ludox;
0.1~1.0 part of dispersant;0.1-1.0 parts of wetting agent;
0.05~1.0 part of antifoaming agent;50-150 parts of deionized water.
Active metakaolin 50-100 parts, 0.01-0.1 parts of coupling agent;
0.1-1.5 parts of thickener.
Currently preferred waterborne PUA is fit for polyurethane and acrylate bond, solid content 30%-50%, pH value For 7-8.
Currently preferred Ludox is alkaline silica sol, and solid content 30%-40%, silica grain size is 5nm- 10nm。
Presently preferred dispersing agent of the present invention is powdery polycarboxylic acid water-reducing agent, Amino-sulfonic Acid-based Water-reducer, naphthalene series high-efficiency One kind or arbitrary several compound in water-reducing agent.
Currently preferred antifoaming agent is in powdery polyethers antifoaming agent, silicon class antifoaming agent and polyether-modified silicon class antifoaming agent Any one.
Currently preferred wetting agent includes polyoxyethylated alkyl phenol, polyoxyethylene fat for nonionic surface active agent Fat alcohol ether, the embedding block copolymer of polyoxyethylene polyoxypropylene etc..
Currently preferred coupling agent is silane coupling agent, including KH-560, KH-602 etc..
Currently preferred thickener is hydroxyethyl cellulose.
The advantageous effect of technical solution using the present invention is:
1st, the aqueous cover protection materials of pervious concrete of the invention are to lead to inorganic active material and organic bonding material It crosses double charge protection and coupling protocols organically combines, organic resin is modified by inorganic material and passes through function Property additive to inorganic material surface carry out double charge protection, add stability of the inorganic material in organic system, so as to The intensity and crocking resistance of raising system.
2nd, after the aqueous cover protective agent of pervious concrete of the invention sprays to concrete surface, since concrete is to use Portland cement manufactures, and there are substantial amounts of hydrated product Ca (OH) 2, Ludox and active metakaolin will carry out therewith on surface Chemical reaction produces aqueous silicic acid calcium and drated calcium aluminate thin layer, and sprayed coating is made to form the chemistry of high intensity with substrate concrete With reference to;Meanwhile the crack resistance of hydrated product thin layer is poor, is easily cracked, the good extension possessed using waterborne PUA firming body Property, use the crack resistance of waterborne PUA raising hydrated product thin layer.
3rd, coupling agent, thickener are mixed and be used in conjunction in the present invention, not only ensured the cohesiveness of slurry, but also can control inorganic The combination power of material and organic material, modified compound can penetrate into inside concrete, prevent from being layered and improve system and basis The adhesive property of concrete and the weatherability and durability for improving system;Self-leveling under the effect of gravity simultaneously, construction Simply, construction cost has been saved.
Specific embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
A kind of aqueous cover protective agent of pervious concrete, it is made of following content of component:
800-1100 parts of cementitious material, functional 0.2-3 parts of additive, 0.01-0.1 parts of material combination power additive, increasing Thick dose 0.1-1.5 parts, 50-150 parts of deionized water.
The mass parts composition of the currently preferred cementitious material is as follows:350-450 parts of waterborne PUA, Ludox 400- 600 parts, active 50-150 parts of metakaolin.
Currently preferred functionality additive is 0.1-1.0 parts of wetting agent, 0.1-1.0 parts of dispersant, antifoaming agent 0-1 Part.
Currently preferred material combination power additive is coupling agent.
Currently preferred thickener is cellulose ether.
The raw material composition and data of embodiment 1-6 is shown in Table 1.
Table 1
The mass parts composition of cementitious material is shown in Table 2 in embodiment 1-5.
Table 2
The mass parts composition of functional additive is shown in Table 3 in embodiment 1-5.
Table 3
After concrete surface uses the aqueous cover protective agent of above-mentioned pervious concrete, ground performance is surveyed in construction and after drying Test result is as follows:
As can be seen from the above embodiments, by inorganic material organic resin is modified and by functionality outside Agent is added to carry out double charge protection to inorganic material surface, stability of the inorganic material in organic system is added, so as to improve The intensity and crocking resistance of system.

Claims (6)

1. a kind of aqueous cover protective agent of pervious concrete, which is characterized in that it is made of following content of component:
800-1100 parts of cementitious material, functional 0.2-3 parts of additive, 0.01-0.1 parts of material combination power additive, thickener 0.1-1.5 parts, 50-150 parts of deionized water.
2. the aqueous cover protective agent of pervious concrete according to claim 1, which is characterized in that the quality of the cementitious material Part composition is as follows:350-450 parts of waterborne PUA, 400-600 parts of Ludox, active 50-150 parts of metakaolin.
3. the aqueous cover protective agent of pervious concrete according to claim 2, which is characterized in that it is described functionality additive be 0.1-1.0 parts of wetting agent, 0.1-1.0 parts of dispersant, 0-1 parts of antifoaming agent.
4. the aqueous cover protective agent of pervious concrete according to claim 1, which is characterized in that the material combination power is additional Agent is coupling agent.
5. the aqueous cover protective agent of pervious concrete according to claim 1, which is characterized in that the thickener is ethoxy Cellulose.
6. the aqueous cover protective agent of pervious concrete according to claim 3, which is characterized in that the pervious concrete is aqueous The protectant mass parts composition of cover is as follows:
400 parts of waterborne PUA, active 100 parts of metakaolin, 400 parts of Ludox, 100 parts of deionized water, wetting agent 0.6 part, point 0.5 part of powder, 0.06 part of material combination power additive, 0.8 part of thickener, 0.5 part of antifoaming agent.
CN201810012022.8A 2018-01-05 2018-01-05 A kind of aqueous cover protective agent of pervious concrete Pending CN108046672A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201810012022.8A CN108046672A (en) 2018-01-05 2018-01-05 A kind of aqueous cover protective agent of pervious concrete

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CN108046672A true CN108046672A (en) 2018-05-18

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114538818A (en) * 2022-03-28 2022-05-27 厦门防水博士新材料有限公司 Preparation method of concrete reinforcing agent and product

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1670096A (en) * 2005-03-16 2005-09-21 上海市建筑科学研究院有限公司 Monocomponent high elastic aqueous polyurethane/acrylate waterproof paint and process for preparing same
CN102399483A (en) * 2011-12-22 2012-04-04 华南理工大学 Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof
CN104193289A (en) * 2014-08-27 2014-12-10 辽宁一一三(集团)化工有限责任公司 Hydrophobic protective paint and preparation method thereof
CN104829207A (en) * 2015-04-07 2015-08-12 安徽朗凯奇防水科技股份有限公司 Polymer cement waterproof coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1670096A (en) * 2005-03-16 2005-09-21 上海市建筑科学研究院有限公司 Monocomponent high elastic aqueous polyurethane/acrylate waterproof paint and process for preparing same
CN102399483A (en) * 2011-12-22 2012-04-04 华南理工大学 Organic/inorganic composite heat-insulating heat-preserving water-based building coating and preparation method thereof
CN104193289A (en) * 2014-08-27 2014-12-10 辽宁一一三(集团)化工有限责任公司 Hydrophobic protective paint and preparation method thereof
CN104829207A (en) * 2015-04-07 2015-08-12 安徽朗凯奇防水科技股份有限公司 Polymer cement waterproof coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114538818A (en) * 2022-03-28 2022-05-27 厦门防水博士新材料有限公司 Preparation method of concrete reinforcing agent and product

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Application publication date: 20180518