CN103351680A - Multifunctional nano exterior wall coating and preparation method thereof - Google Patents
Multifunctional nano exterior wall coating and preparation method thereof Download PDFInfo
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- CN103351680A CN103351680A CN2013102476111A CN201310247611A CN103351680A CN 103351680 A CN103351680 A CN 103351680A CN 2013102476111 A CN2013102476111 A CN 2013102476111A CN 201310247611 A CN201310247611 A CN 201310247611A CN 103351680 A CN103351680 A CN 103351680A
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- 239000011248 coating agent Substances 0.000 title claims abstract description 27
- 238000000576 coating method Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000008367 deionised water Substances 0.000 claims abstract description 10
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims abstract description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 7
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims abstract description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 5
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 4
- PZZYQPZGQPZBDN-UHFFFAOYSA-N aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims abstract description 4
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 15
- 238000004581 coalescence Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 6
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 229940059574 pentaerithrityl Drugs 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 6
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 238000005336 cracking Methods 0.000 abstract description 2
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- RZRNZDQNXWVZNY-UHFFFAOYSA-N [B].[B].[B].[Cr].[Cr].[Cr].[Cr].[Cr] Chemical compound [B].[B].[B].[Cr].[Cr].[Cr].[Cr].[Cr] RZRNZDQNXWVZNY-UHFFFAOYSA-N 0.000 abstract 1
- -1 ethoxylated alkyl phenol ammonium sulfate Chemical compound 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 abstract 1
- 239000011787 zinc oxide Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses exterior wall coating composed of the following raw materials in parts by weight: 70-80 parts of aqueous acrylic emulsion, 20-30 parts of styrene-acrylic emulsion, 10-20 parts of nano calcium carbonate, 14-20 parts of nano aluminium silicate, 13-20 parts of nano titanium dioxide, 2-3 parts of nano zinc oxide, 2-3 parts of butyl acrylate, 2-4 parts of pentaerythritol, 0.5-1 part of ethoxylated alkyl phenol ammonium sulfate, 1-2 parts of penta-chromium triboride, 0.6-1 part of sodium persulfate, 0.8-1 part of propyl trimethoxy silane, 0.1-0.2 part of tributyl phosphate, 3-5 parts of coalescing agent and 10-20 parts of deionized water. The coating produced by the invention is small in raw material loss, small in gel generation, simple in process, firm in paint film, good in glossiness, strong in impact resistance, unlikely to crack, soft in texture, good in decoration, high in weather resistance and scrub resistance, strong in adhesive force, long in service life, free of special smell, free of such heavy metals as mercury and lead and free of formaldehyde volatile, thereby meeting the technical demands of environmentally-friendly coating, and the added coalescing agent has high stability and high adhesion efficiency and film-forming property, increases the density of the coating film and perfects the film forming quality, so that the film layer has the advantages of strong adhesive force, non-cavity or cracking and good density and uniformity, and the like.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of nano multifunctional outer wall coating and preparation method thereof.
Background technology
In recent years; along with the raising of living standards of the people and the development of society; people are to the selection pay attention to day by day of building decoration coating, and are more simple better to the construction requirement of coating, for particularly in exterior coating; not only rest in the most basic protection to ground; decorative effect to coating is had higher requirement, and exterior coating requires to have water repelling property, requires to have from washing property; it is hard and smooth, dirty once rushing that paint film is wanted.
But the acrylic coating of throwing on the domestic market exists, and gloss is low, poor adhesive force, winter hardiness are poor, not water-fast, water vapour, soda acid, salts solution and organic polar solvent, poor flexibility under the room temperature, the shortcoming such as wear no resistance, and high temperature easily returns sticking, fragile under low temperature splitting, cause coating to ftracture easily, peel off, rainwater etc. infiltrate metope, corrosion body of wall easily, and this not only affects the beautiful decoration of buildings, and will reduce the work-ing life of buildings.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of prior art, exterior coating that a kind of paint film is stable, glossiness is good, tolerance is strong and preparation method thereof to be provided.
The present invention is achieved by the following technical solutions:
A kind of nano multifunctional outer wall coating, it is comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 70-80, benzene emulsion 20-30, nano-calcium carbonate 10-20, nanometer pure aluminium silicate 14-20, nanometer titanium dioxide 13-20, nano zine oxide 2-3, butyl acrylate 2-3, tetramethylolmethane 2-4, ethoxylated alkylphenol ammonium sulfate 0.5-1, three boronations, five chromium 1-2, Sodium Persulfate 0.6-1, propyl trimethoxy silicane 0.8-1, tributyl phosphate 0.1-0.2, film coalescence aid 3-5, deionized water 10-20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
A kind of preparation method of nano multifunctional outer wall coating may further comprise the steps:
The ethoxylated alkylphenol ammonium sulfate of above-mentioned weight part is joined in the deionized water of 50-60% weight, stirring and dissolving, add butyl acrylate, Sodium Persulfate, the rising temperature is to 70-80 ℃, and 500-600 rev/min was stirred 10-20 minute, and be cooled to normal temperature, add benzene emulsion, nano zine oxide, stir, add aqueous acrylic emulsion, remaining deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again wollastonite powder, triglycol, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Advantage of the present invention is:
The coating raw material loss that the present invention produces is few, gel generates few, technique is simple, paint film is hard, glossiness is good, anti-impact force is strong, be not easy cracking, texture is soft, ornamental strong, high weather resisteant is arranged, brushing resistance, strong adhesion, long service life, without special odor, not mercurous, the plumbous heavy metal that waits, formaldehydeless volatile matter, meet the technical requirements of environmental protection coating material, the film coalescence aid of adding has very high stability, efficient binding property, film-forming properties has increased the density of coated membrane, improved quality of forming film, so that rete has strong adhesion, without the cavity, split sunken, the fine and close advantage such as even.
Embodiment
Embodiment 1
A kind of nano multifunctional outer wall coating, it is comprised of the raw material of following weight parts (kilogram):
Aqueous acrylic emulsion 80, benzene emulsion 30, nano-calcium carbonate 20, nanometer pure aluminium silicate 20, nanometer titanium dioxide 20, nano zine oxide 3, butyl acrylate 3, tetramethylolmethane 4, ethoxylated alkylphenol ammonium sulfate 0.5, three boronations, five chromium 2, Sodium Persulfate 0.6, propyl trimethoxy silicane 0.8, tributyl phosphate 0.2, film coalescence aid 5, deionized water 20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 40, polyvinyl alcohol 6, vinyltriethoxysilane 10, alkylphenol Polyoxyalkylene ethers 0.8, benzene emulsion 4, nano-sized carbon 2;
Polyvinyl alcohol is joined in 5 times of water, be steam heated to 100 ℃, stirring and dissolving adds benzene emulsion, reducing temperature is 70 ℃, and constant temperature stirred 3 minutes, adds each raw material of residue, 400 rev/mins of dispersions of low speed 3 minutes, 120 ℃ of insulations were left standstill 2 hours, were cooled to normal temperature, namely got described film coalescence aid.
A kind of preparation method of nano multifunctional outer wall coating may further comprise the steps:
The ethoxylated alkylphenol ammonium sulfate of above-mentioned weight part is joined in the deionized water of 60% weight, stirring and dissolving, add butyl acrylate, Sodium Persulfate, rising temperature to 80 ℃, 600 rev/mins were stirred 20 minutes, and were cooled to normal temperature, add benzene emulsion, nano zine oxide, stir, add aqueous acrylic emulsion, remaining deionized water, 1000 rev/mins were stirred 10 minutes; Add again wollastonite powder, triglycol, stirred 20 minutes at 800 rev/mins; Add each raw material of residue, under 700 rev/mins speed, fully stir, add acetic acid or sodium acetate, regulating PH is 9, and stirring is described exterior coating.
Performance test:
Paint film appearance is full, smooth, good without lump, glossiness;
Corrosion resistance test: pass through for 10000 times, paint film is without breakage;
The artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless;
Temperature-change resistance (5 circulations): without unusual;
Alkali resistance: 200 hours without unusual.
Claims (2)
1. nano multifunctional outer wall coating is characterized in that what it was comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 70-80, benzene emulsion 20-30, nano-calcium carbonate 10-20, nanometer pure aluminium silicate 14-20, nanometer titanium dioxide 13-20, nano zine oxide 2-3, butyl acrylate 2-3, tetramethylolmethane 2-4, ethoxylated alkylphenol ammonium sulfate 0.5-1, three boronations, five chromium 1-2, Sodium Persulfate 0.6-1, propyl trimethoxy silicane 0.8-1, tributyl phosphate 0.1-0.2, film coalescence aid 3-5, deionized water 10-20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
2. the preparation method of a nano multifunctional outer wall coating as claimed in claim 1 is characterized in that may further comprise the steps:
The ethoxylated alkylphenol ammonium sulfate of above-mentioned weight part is joined in the deionized water of 50-60% weight, stirring and dissolving, add butyl acrylate, Sodium Persulfate, the rising temperature is to 70-80 ℃, and 500-600 rev/min was stirred 10-20 minute, and be cooled to normal temperature, add benzene emulsion, nano zine oxide, stir, add aqueous acrylic emulsion, remaining deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again wollastonite powder, triglycol, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310247611.1A CN103351680B (en) | 2013-06-20 | 2013-06-20 | A kind of nano multifunctional outer wall coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310247611.1A CN103351680B (en) | 2013-06-20 | 2013-06-20 | A kind of nano multifunctional outer wall coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103351680A true CN103351680A (en) | 2013-10-16 |
| CN103351680B CN103351680B (en) | 2016-05-04 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250497A (en) * | 2014-09-26 | 2014-12-31 | 无锡七点建材有限公司 | Nano thermal insulation exterior wall paint and preparation method thereof |
| CN104263154A (en) * | 2014-09-22 | 2015-01-07 | 句容亿格纳米材料厂 | Nano ceramic simulating coating and preparation method thereof |
| CN104327565A (en) * | 2014-10-23 | 2015-02-04 | 招远鸿瑞印染有限公司 | Preparation of water-based paint |
| CN105505021A (en) * | 2015-12-30 | 2016-04-20 | 辛范范 | Exterior wall coating and preparation method thereof |
| CN104263154B (en) * | 2014-09-22 | 2017-01-04 | 句容亿格纳米材料厂 | A kind of nanometer imitation porcelain coating and preparation method thereof |
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| CN101857752A (en) * | 2010-05-28 | 2010-10-13 | 中华制漆（深圳）有限公司 | Aqueous exterior wall coating material with high solid content and low viscosity |
| KR20110005445A (en) * | 2009-07-10 | 2011-01-18 | 정승수 | Composition and manufacturing method of insulating solution, insulation film and manufacturing method thereof takes advantage of it, and insulation film for plastic greenhouse |
| CN101974273A (en) * | 2010-10-09 | 2011-02-16 | 广州市枫源化工有限公司 | Exterior wall coating and preparation method thereof |
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2013
- 2013-06-20 CN CN201310247611.1A patent/CN103351680B/en active Active
Patent Citations (4)
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| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
| KR20110005445A (en) * | 2009-07-10 | 2011-01-18 | 정승수 | Composition and manufacturing method of insulating solution, insulation film and manufacturing method thereof takes advantage of it, and insulation film for plastic greenhouse |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104263154A (en) * | 2014-09-22 | 2015-01-07 | 句容亿格纳米材料厂 | Nano ceramic simulating coating and preparation method thereof |
| CN104263154B (en) * | 2014-09-22 | 2017-01-04 | 句容亿格纳米材料厂 | A kind of nanometer imitation porcelain coating and preparation method thereof |
| CN104250497A (en) * | 2014-09-26 | 2014-12-31 | 无锡七点建材有限公司 | Nano thermal insulation exterior wall paint and preparation method thereof |
| CN104327565A (en) * | 2014-10-23 | 2015-02-04 | 招远鸿瑞印染有限公司 | Preparation of water-based paint |
| CN105505021A (en) * | 2015-12-30 | 2016-04-20 | 辛范范 | Exterior wall coating and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103351680B (en) | 2016-05-04 |
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Denomination of invention: A nano multifunctional exterior wall coating and its preparation method Effective date of registration: 20231026 Granted publication date: 20160504 Pledgee: Lai An county Jinan financing Company limited by guarantee Pledgor: CHUZHOU BEST NEW BUILDING MATERIAL CO.,LTD. Registration number: Y2023980062875 |
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