CN104263154B - A kind of nanometer imitation porcelain coating and preparation method thereof - Google Patents
A kind of nanometer imitation porcelain coating and preparation method thereof Download PDFInfo
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- CN104263154B CN104263154B CN201410488192.5A CN201410488192A CN104263154B CN 104263154 B CN104263154 B CN 104263154B CN 201410488192 A CN201410488192 A CN 201410488192A CN 104263154 B CN104263154 B CN 104263154B
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- nanometer
- porcelain coating
- imitation porcelain
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- 238000000576 coating method Methods 0.000 title claims abstract description 23
- 229910052573 porcelain Inorganic materials 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000843 powder Substances 0.000 claims abstract description 22
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000011248 coating agent Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- BJQHLKABXJIVAM-UHFFFAOYSA-N Bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims abstract description 11
- 229920005610 lignin Polymers 0.000 claims abstract description 11
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 11
- PIICEJLVQHRZGT-UHFFFAOYSA-N 1,2-ethanediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 claims abstract description 10
- PZZYQPZGQPZBDN-UHFFFAOYSA-N Aluminium silicate Chemical compound O=[Al]O[Si](=O)O[Al]=O PZZYQPZGQPZBDN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 10
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 10
- 239000011575 calcium Substances 0.000 claims abstract description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims description 6
- 230000000875 corresponding Effects 0.000 claims description 6
- 238000007599 discharging Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K Aluminium chloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims 2
- 239000002253 acid Substances 0.000 claims 1
- 230000032683 aging Effects 0.000 abstract description 4
- 150000003839 salts Chemical class 0.000 abstract description 4
- 239000011780 sodium chloride Substances 0.000 abstract description 4
- 239000007921 spray Substances 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 description 5
- 241000209094 Oryza Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
Abstract
The open a kind of nanometer imitation porcelain coating of the present invention, it is prepared raw materials by weight and consists of the following composition: nanometer titanium dioxide 35 ~ 39 parts, nano oxidized calcium powder 33 ~ 48 parts, acryloid cement 25 ~ 35 parts, citric acid 5 ~ 8 parts, dioctyl phthalate 9 ~ 12 parts, 1 ~ 2 part of nanometer aluminium silicate powder, lignin 2 ~ 5 parts, ethylenediamine 0.1 ~ 0.2 part, polyaluminium chloride 0.2 ~ 0.5 part, defoamer 0.2 ~ 0.4 part, 50 ~ 80 parts of water.The nanometer imitation porcelain coating that the present invention provides, cold-hot, salt spray resistance, resistance to water and life aging relatively prior art are all greatly enhanced.
Description
Technical field
The present invention relates to a kind of coating, be specifically related to a kind of nanometer imitation porcelain coating and preparation method thereof.
Background technology
Imitation porcelain coating is the one of numerous functional paint, is usually used on architectural engineering exterior wall or interior wall, and quality is hard.But
Its cold-hot, salt spray resistance, resistance to water and life aging are poor.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the present invention provides a kind of nanometer imitation porcelain coating.
Technical scheme: for achieving the above object, a kind of nanometer imitation porcelain coating that the present invention provides, it prepares raw material by weight
Percentage ratio consists of the following composition: nanometer titanium dioxide 35～39 parts, nano oxidized calcium powder 33～48 parts, acryloid cement
25～35 parts, citric acid 5～8 parts, dioctyl phthalate 9～12 parts, nanometer aluminium silicate powder 1～2 parts, lignin
2～5 parts, ethylenediamine 0.1～0.2 part, polyaluminium chloride 0.2～0.5 part, defoamer 0.2～0.4 part, water 50～80 parts.
Further, it is prepared raw materials by weight and consists of the following composition: nanometer titanium dioxide 35～37 parts, nanometer
Calcium oxide powder 33～38 parts, acryloid cement 25～30 parts, citric acid 5～6 parts, dioctyl phthalate 9～11
Part, nanometer aluminium silicate powder 1～2 parts, lignin 2～5 parts, ethylenediamine 0.1～0.2 part, polyaluminium chloride 0.2～0.5 part, disappear
Infusion 0.2～0.4 part, water 50～70 parts.
Further, it is prepared raw materials by weight and consists of the following composition: nanometer titanium dioxide 36 parts, nano oxygen
Change calcium powder 36 parts, acryloid cement 27 parts, citric acid 6 parts, dioctyl phthalate 11 parts, nanometer silicic acid
Aluminium powder 2 parts, lignin 3 parts, ethylenediamine 0.15 part, polyaluminium chloride 0.3 part, defoamer 0.2～0.4 part, 60 parts of water.
The preparation method of above-mentioned nanometer imitation porcelain coating, its preparation process comprises the following steps: weigh corresponding by weight
Raw material components；Above-mentioned compound is disposably thrown in reactor, starts agitator, at 68～78 DEG C, stir evenly 3h～5h
Discharging.
Beneficial effect: the nanometer imitation porcelain coating that the present invention provides, cold-hot, salt spray resistance, resistance to water and life aging are relatively
Prior art is all greatly enhanced.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
A kind of nanometer imitation porcelain coating, it prepares raw materials by weight and consists of the following composition: nanometer titanium dioxide 39 parts,
Nano oxidized calcium powder 33 parts, acryloid cement 25 parts, citric acid 5 parts, dioctyl phthalate 9 parts, nanometer
Aluminium silicate powder 1 part, lignin 2 parts, ethylenediamine 0.1 part, polyaluminium chloride 0.2 part, defoamer 0.2 part, 50 parts of water.
The preparation method of above-mentioned nanometer imitation porcelain coating, its preparation process comprises the following steps: weigh corresponding by weight
Raw material components；Above-mentioned compound is disposably thrown in reactor, starts agitator, at 68～78 DEG C, stir evenly 3h～5h
Discharging.
Embodiment 2:
A kind of nanometer imitation porcelain coating, it prepares raw materials by weight and consists of the following composition: nanometer titanium dioxide 35 parts,
Nano oxidized calcium powder 48 parts, acryloid cement 35 parts, citric acid 8 parts, dioctyl phthalate 12 parts, receive
Rice aluminium silicate powder 2 parts, lignin 5 parts, ethylenediamine 0.2 part, polyaluminium chloride 0.5 part, defoamer 0.4 part, water 80
Part.
The preparation method of above-mentioned nanometer imitation porcelain coating, its preparation process comprises the following steps: weigh corresponding by weight
Raw material components；Above-mentioned compound is disposably thrown in reactor, starts agitator, at 68～78 DEG C, stir evenly 3h～5h
Discharging.
Embodiment 3:
A kind of nanometer imitation porcelain coating, it prepares raw materials by weight and consists of the following composition: nanometer titanium dioxide 37 parts,
Nano oxidized calcium powder 38 parts, acryloid cement 30 parts, citric acid 6 parts, dioctyl phthalate 11 parts, receive
Rice aluminium silicate powder 2 parts, lignin 4 parts, ethylenediamine 0.1 part, polyaluminium chloride 0.3 part, defoamer 0.4 part, water 55
Part.
The preparation method of above-mentioned nanometer imitation porcelain coating, its preparation process comprises the following steps: weigh corresponding by weight
Raw material components；Above-mentioned compound is disposably thrown in reactor, starts agitator, at 68～78 DEG C, stir evenly 3h～5h
Discharging.
Embodiment 4:
A kind of nanometer imitation porcelain coating, it prepares raw materials by weight and consists of the following composition: nanometer titanium dioxide 36 parts,
Nano oxidized calcium powder 36 parts, acryloid cement 27 parts, citric acid 6 parts, dioctyl phthalate 11 parts, receive
Rice aluminium silicate powder 2 parts, lignin 3 parts, ethylenediamine 0.15 part, polyaluminium chloride 0.3 part, defoamer 0.2～0.4 part,
60 parts of water.
The preparation method of above-mentioned nanometer imitation porcelain coating, its preparation process comprises the following steps: weigh corresponding by weight
Raw material components；Above-mentioned compound is disposably thrown in reactor, starts agitator, at 68～78 DEG C, stir evenly 3h～5h
Discharging.
Properties of product prepared by embodiment 1～4 see table:
Shown in upper table, this patent product possesses preferable cold-hot, salt spray resistance, resistance to water and life aging.
It is only the preferred embodiment of the present invention described on, it should be pointed out that: to those of ordinary skill in the art,
Under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should be regarded as
Protection scope of the present invention.
Claims (4)
1. a nanometer imitation porcelain coating, it is characterised in that: it is prepared raw material and consists of the following composition by weight: nanometer
Titanium dioxide 35～39 parts, nano oxidized calcium powder 33～48 parts, acryloid cement 25～35 parts, citric acid 5～8 parts, adjacent
Dioctyl phthalate 9～12 parts, nanometer aluminium silicate powder 1～2 parts, lignin 2～5 parts, ethylenediamine 0.1～0.2 part, poly-
Aluminum chloride 0.2～0.5 part, defoamer 0.2～0.4 part, water 50～80 parts.
Nanometer imitation porcelain coating the most according to claim 1, it is characterised in that: its prepare raw material by weight by with
Lower one-tenth is grouped into: nanometer titanium dioxide 35～37 parts, nano oxidized calcium powder 33～38 parts, acryloid cement 25～30 parts,
Citric acid 5～6 parts, dioctyl phthalate 9～11 parts, nanometer aluminium silicate powder 1～2 parts, lignin 2～5 parts, second
Diamidogen 0.1～0.2 part, polyaluminium chloride 0.2～0.5 part, defoamer 0.2～0.4 part, water 50～70 parts.
A kind of nanometer imitation porcelain coating the most according to claim 1, it is characterised in that: it prepares raw material by weight
Consist of the following composition: nanometer titanium dioxide 36 parts, nano oxidized calcium powder 36 parts, acryloid cement 27 parts, Fructus Citri Limoniae
Acid 6 parts, dioctyl phthalate 11 parts, 2 parts of nanometer aluminium silicate powder, lignin 3 parts, ethylenediamine 0.15 part,
Polyaluminium chloride 0.3 part, defoamer 0.2～0.4 part, 60 parts of water.
4. the preparation method of the nanometer imitation porcelain coating described in a claim 1, it is characterised in that: its preparation process bag
Include following steps: weigh corresponding raw material components by weight；Above-mentioned compound is disposably thrown in reactor, opens
Dynamic agitator, stirs evenly 3h～5h discharging at 68～78 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410488192.5A CN104263154B (en) | 2014-09-22 | A kind of nanometer imitation porcelain coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410488192.5A CN104263154B (en) | 2014-09-22 | A kind of nanometer imitation porcelain coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104263154A CN104263154A (en) | 2015-01-07 |
| CN104263154B true CN104263154B (en) | 2017-01-04 |
Family
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168640A (en) * | 2007-11-26 | 2008-04-30 | 北京京卫宏远工贸有限公司 | Environment-friendly type antifreeze emulsion paint and preparation method thereof |
| CN103351680A (en) * | 2013-06-20 | 2013-10-16 | 滁州麦斯特新型建材有限公司 | Multifunctional nano exterior wall coating and preparation method thereof |
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168640A (en) * | 2007-11-26 | 2008-04-30 | 北京京卫宏远工贸有限公司 | Environment-friendly type antifreeze emulsion paint and preparation method thereof |
| CN103351680A (en) * | 2013-06-20 | 2013-10-16 | 滁州麦斯特新型建材有限公司 | Multifunctional nano exterior wall coating and preparation method thereof |
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| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190716 Address after: 071000 Hebei city of Baoding province Xushui Chenyang Street No. 1 Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd. Address before: 212400 Jurong City, Zhenjiang Province, the town of white rabbit after the village of the town of Jiangsu No. 888 Patentee before: Jurong Yige Nano Material Factory |
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| PP01 | Preservation of patent right |
Effective date of registration: 20200929 Granted publication date: 20170104 |
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| PD01 | Discharge of preservation of patent |
Date of cancellation: 20210902 Granted publication date: 20170104 |