CN104261529A - Nano titanium dioxide coating flocculant and preparation method thereof - Google Patents

Nano titanium dioxide coating flocculant and preparation method thereof Download PDF

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Publication number
CN104261529A
CN104261529A CN201410484817.0A CN201410484817A CN104261529A CN 104261529 A CN104261529 A CN 104261529A CN 201410484817 A CN201410484817 A CN 201410484817A CN 104261529 A CN104261529 A CN 104261529A
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parts
titanium dioxide
nanometer titanium
powder coating
flocculation agent
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CN201410484817.0A
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CN104261529B (en
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潘峥嵘
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JURONG YIGE NANO MATERIAL FACTORY
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JURONG YIGE NANO MATERIAL FACTORY
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/14Paint wastes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The invention discloses a nano titanium dioxide coating flocculant, comprising the following raw components in parts by weight: 5-9 parts of nano titanium dioxide, 3-8 parts of nanometer magnesia, 25-35 parts of polyacrylamide, 5-8 parts of citric acid, 9-12 parts of dioctyl phthalate, 1-2 parts of nanosilicon dioxide, 2-5 parts of lignin, 0.1-0.2 part of ethanediamine, 0.8-1.5 parts of hydroxyethyl cellulose, 0.2-0.5 part of polyaluminium chloride and 50-80 parts of water. The nano titanium dioxide coating flocculant disclosed by the invention is high in flocculation speed, long in settling time, small in drug dosage and stable in operation, and is capable of relatively stably coagulating common components in an oil pant, and reducing the wastewater treatment cost.

Description

A kind of Nanometer Titanium Dioxide powder coating flocculation agent and preparation method thereof
Technical field
The present invention relates to a kind of coating flocculation agent, be specifically related to a kind of Nanometer Titanium Dioxide powder coating flocculation agent and preparation method thereof.
Background technology
Paint flocculant also known as varnish remover, slag former, lacquer mist coagulant, for detaching coating cloud in Drencher spray booth recirculated water.Paint flocculant prepares the conventional material of coating sewage, but existing Paint flocculant rate of set is slow, sedimentation time is long, and input amount is large, poor to some the composition condensation effect in paint.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the invention provides a kind of Nanometer Titanium Dioxide powder coating flocculation agent.
Technical scheme: for achieving the above object, Nanometer Titanium Dioxide powder coating flocculation agent provided by the invention, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 5 ~ 9 parts, nano magnesia 3 ~ 8 parts, polyacrylamide 25 ~ 35 parts, citric acid 5 ~ 8 parts, dioctyl phthalate (DOP) 9 ~ 12 parts, nano silicon 1 ~ 2 part, 2 ~ 5 parts, xylogen, quadrol 0.1 ~ 0.2 part, Natvosol 0.8 ~ 1.5 part, poly aluminium chloride 0.2 ~ 0.5 part, 50 ~ 80 parts, water.
Preferably, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 5 ~ 7 parts, nano magnesia 3 ~ 5 parts, polyacrylamide 25 ~ 30 parts, citric acid 5 ~ 6 parts, dioctyl phthalate (DOP) 9 ~ 10 parts, nano silicon 1 ~ 2 part, 2 ~ 4 parts, xylogen, quadrol 0.1 ~ 0.2 part, Natvosol 0.8 ~ 1.2 part, poly aluminium chloride 0.2 ~ 0.5 part, 50 ~ 60 parts, water.
Preferably, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 6 parts, nano magnesia 4 parts, polyacrylamide 28 parts, citric acid 6 parts, dioctyl phthalate (DOP) 10 parts, nano silicon 2 parts, 3 parts, xylogen, quadrol 0.2 part, Natvosol 0.9 part, poly aluminium chloride 0.4 part, 55 parts, water.
The preparation method of above-mentioned Nanometer Titanium Dioxide powder coating flocculation agent, its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
Beneficial effect: Nanometer Titanium Dioxide powder coating flocculation agent provided by the invention, flocculation rate is fast, and sedimentation time is long, and dosage is little, conventional composition in condensation paint that can be comparatively stable, stable, reduces cost for wastewater treatment.
Embodiment
Below in conjunction with embodiment, the present invention is further described.
Embodiment 1:
A kind of Nanometer Titanium Dioxide powder coating flocculation agent, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 9 parts, nano magnesia 3 parts, polyacrylamide 25 parts, citric acid 5 parts, dioctyl phthalate (DOP) 9 parts, nano silicon 1 part, 2 parts, xylogen, quadrol 0.1 part, Natvosol 0.8 part, poly aluminium chloride 0.2 ~ 0.5 part, 80 parts, water.
The preparation method of above-mentioned Nanometer Titanium Dioxide powder coating flocculation agent, its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
Embodiment 2:
A kind of Nanometer Titanium Dioxide powder coating flocculation agent, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 5 parts, nano magnesia 8 parts, polyacrylamide 35 parts, citric acid 8 parts, dioctyl phthalate (DOP) 12 parts, nano silicon 2 parts, 5 parts, xylogen, quadrol 0.2 part, Natvosol 1.5 parts, poly aluminium chloride 0.2 ~ 0.5 part, 50 parts, water.
The preparation method of above-mentioned Nanometer Titanium Dioxide powder coating flocculation agent, its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
Embodiment 3:
A kind of Nanometer Titanium Dioxide powder coating flocculation agent, its raw materials consists of the following composition nanometer titanium dioxide 7 parts by weight percentage, nano magnesia 5 parts, polyacrylamide 30 parts, citric acid 6 parts, dioctyl phthalate (DOP) 10 parts, nano silicon 2 parts, 4 parts, xylogen, quadrol 0.2 part, Natvosol 1.2 parts, poly aluminium chloride 0.3 part, 60 parts, water.
The preparation method of above-mentioned Nanometer Titanium Dioxide powder coating flocculation agent, its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
Embodiment 4:
A kind of Nanometer Titanium Dioxide powder coating flocculation agent, its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 6 parts, nano magnesia 4 parts, polyacrylamide 28 parts, citric acid 6 parts, dioctyl phthalate (DOP) 10 parts, nano silicon 2 parts, 3 parts, xylogen, quadrol 0.2 part, Natvosol 0.9 part, poly aluminium chloride 0.4 part, 55 parts, water.
The preparation method of above-mentioned Nanometer Titanium Dioxide powder coating flocculation agent, its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
Product performance prepared by embodiment 1 ~ 4 see the following form:
Shown in upper table, this patent product possesses better flocculating effect.
Only the preferred embodiment of the present invention described in upper; be noted that for those skilled in the art; under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (4)

1. a Nanometer Titanium Dioxide powder coating flocculation agent, it is characterized in that: its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 5 ~ 9 parts, nano magnesia 3 ~ 8 parts, polyacrylamide 25 ~ 35 parts, citric acid 5 ~ 8 parts, dioctyl phthalate (DOP) 9 ~ 12 parts, nano silicon 1 ~ 2 part, 2 ~ 5 parts, xylogen, quadrol 0.1 ~ 0.2 part, Natvosol 0.8 ~ 1.5 part, poly aluminium chloride 0.2 ~ 0.5 part, 50 ~ 80 parts, water.
2. Nanometer Titanium Dioxide powder coating flocculation agent according to claim 1, it is characterized in that: its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 5 ~ 7 parts, nano magnesia 3 ~ 5 parts, polyacrylamide 25 ~ 30 parts, citric acid 5 ~ 6 parts, dioctyl phthalate (DOP) 9 ~ 10 parts, nano silicon 1 ~ 2 part, 2 ~ 4 parts, xylogen, quadrol 0.1 ~ 0.2 part, Natvosol 0.8 ~ 1.2 part, poly aluminium chloride 0.2 ~ 0.5 part, 50 ~ 60 parts, water.
3. a kind of Nanometer Titanium Dioxide powder coating flocculation agent according to claim 1, it is characterized in that: its raw materials consists of the following composition by weight percentage: nanometer titanium dioxide 6 parts, nano magnesia 4 parts, polyacrylamide 28 parts, citric acid 6 parts, dioctyl phthalate (DOP) 10 parts, nano silicon 2 parts, 3 parts, xylogen, quadrol 0.2 part, Natvosol 0.9 part, poly aluminium chloride 0.4 part, 55 parts, water.
4. a preparation method for Nanometer Titanium Dioxide powder coating flocculation agent according to claim 1, is characterized in that: its preparation process comprises the following steps: take corresponding feed composition by weight; By disposable for above-mentioned compound input in reactor, start agitator, at 68 ~ 78 DEG C, stir evenly 3h ~ 5h discharging.
CN201410484817.0A 2014-09-19 2014-09-19 A kind of Nanometer Titanium Dioxide powder coating flocculation agent and preparation method thereof Active CN104261529B (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037634A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Preparation method of bi-component liquid dust agglutinant
CN106115813A (en) * 2016-07-29 2016-11-16 周圣聪 A kind of chemical engineering sewage intensive treatment agent and its preparation method and application
CN106145216A (en) * 2016-07-29 2016-11-23 周圣聪 One breeding enterprise sewage-treating agent and its preparation method and application
CN110921729A (en) * 2018-09-19 2020-03-27 南京卡邦科技有限公司 Water treatment agent containing isothiazolinone and preparation method thereof
CN112108500A (en) * 2020-09-14 2020-12-22 安徽清扬水处理设备科技有限公司 High-efficiency treatment process for landfill leachate
CN114604947A (en) * 2022-03-21 2022-06-10 衡阳市建衡实业有限公司 Titanium-containing composite ferric polysulfate flocculant and preparation method and application thereof
CN115572011A (en) * 2018-08-20 2023-01-06 青岛众诚三兄弟环境工程有限公司 Paint wastewater treatment agent composition and paint wastewater treatment method

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JP2000000404A (en) * 1998-06-16 2000-01-07 Tayca Corp Titanium-containing flocculant for water treatment
CN1385375A (en) * 2002-06-06 2002-12-18 大庆油田有限责任公司 Flocculant for oil-containing sewage low-temp. treatment in oil field
KR20040010791A (en) * 2004-01-02 2004-01-31 정종민 The green tide killer
CN1626452A (en) * 2003-12-10 2005-06-15 曾智勇 Nano coagulant for swimming pool
CN101519237A (en) * 2008-02-25 2009-09-02 四平海特环保设备有限公司 Compound high-efficiency flocculating agent
CN102101711A (en) * 2010-12-10 2011-06-22 杭州荣升环保科技有限公司 Method for preparing metal polysilicate flocculant
CN102351286A (en) * 2011-07-07 2012-02-15 盐城工学院 Preparation and application of high-efficiency paint mist coagulant
CN102838197A (en) * 2012-10-09 2012-12-26 重庆理工大学 Method for preparing novel composite flocculant PSAFS (poly-silicate aluminum ferrous sulfate)
CN102942245A (en) * 2012-11-13 2013-02-27 常州大学 Purifying agent for water treatment
CN103864177A (en) * 2014-04-03 2014-06-18 林祝亮 Oil-containing wastewater treatment agent and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000000404A (en) * 1998-06-16 2000-01-07 Tayca Corp Titanium-containing flocculant for water treatment
CN1385375A (en) * 2002-06-06 2002-12-18 大庆油田有限责任公司 Flocculant for oil-containing sewage low-temp. treatment in oil field
CN1626452A (en) * 2003-12-10 2005-06-15 曾智勇 Nano coagulant for swimming pool
KR20040010791A (en) * 2004-01-02 2004-01-31 정종민 The green tide killer
CN101519237A (en) * 2008-02-25 2009-09-02 四平海特环保设备有限公司 Compound high-efficiency flocculating agent
CN102101711A (en) * 2010-12-10 2011-06-22 杭州荣升环保科技有限公司 Method for preparing metal polysilicate flocculant
CN102351286A (en) * 2011-07-07 2012-02-15 盐城工学院 Preparation and application of high-efficiency paint mist coagulant
CN102838197A (en) * 2012-10-09 2012-12-26 重庆理工大学 Method for preparing novel composite flocculant PSAFS (poly-silicate aluminum ferrous sulfate)
CN102942245A (en) * 2012-11-13 2013-02-27 常州大学 Purifying agent for water treatment
CN103864177A (en) * 2014-04-03 2014-06-18 林祝亮 Oil-containing wastewater treatment agent and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105037634A (en) * 2015-08-27 2015-11-11 保护伞环保科技成都有限公司 Preparation method of bi-component liquid dust agglutinant
CN106115813A (en) * 2016-07-29 2016-11-16 周圣聪 A kind of chemical engineering sewage intensive treatment agent and its preparation method and application
CN106145216A (en) * 2016-07-29 2016-11-23 周圣聪 One breeding enterprise sewage-treating agent and its preparation method and application
CN115572011A (en) * 2018-08-20 2023-01-06 青岛众诚三兄弟环境工程有限公司 Paint wastewater treatment agent composition and paint wastewater treatment method
CN110921729A (en) * 2018-09-19 2020-03-27 南京卡邦科技有限公司 Water treatment agent containing isothiazolinone and preparation method thereof
CN112108500A (en) * 2020-09-14 2020-12-22 安徽清扬水处理设备科技有限公司 High-efficiency treatment process for landfill leachate
CN114604947A (en) * 2022-03-21 2022-06-10 衡阳市建衡实业有限公司 Titanium-containing composite ferric polysulfate flocculant and preparation method and application thereof

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