CN103351672A - Environment-friendly exterior wall paint and preparation method thereof - Google Patents
Environment-friendly exterior wall paint and preparation method thereof Download PDFInfo
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- CN103351672A CN103351672A CN2013102472515A CN201310247251A CN103351672A CN 103351672 A CN103351672 A CN 103351672A CN 2013102472515 A CN2013102472515 A CN 2013102472515A CN 201310247251 A CN201310247251 A CN 201310247251A CN 103351672 A CN103351672 A CN 103351672A
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- 238000002360 preparation method Methods 0.000 title claims description 7
- 239000003973 paint Substances 0.000 title abstract description 11
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- OFEAOSSMQHGXMM-UHFFFAOYSA-N 12007-10-2 Chemical compound [W].[W]=[B] OFEAOSSMQHGXMM-UHFFFAOYSA-N 0.000 claims abstract description 7
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims abstract description 7
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical compound CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims abstract description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 claims abstract description 7
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 7
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 7
- 239000010456 wollastonite Substances 0.000 claims abstract description 7
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 4
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims abstract description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 15
- 238000004581 coalescence Methods 0.000 claims description 10
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 9
- 230000007613 environmental effect Effects 0.000 claims description 9
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 6
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 6
- -1 polyoxyethylene Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 6
- 230000000630 rising effect Effects 0.000 claims description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- FZQSLXQPHPOTHG-UHFFFAOYSA-N [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 Chemical compound [K+].[K+].O1B([O-])OB2OB([O-])OB1O2 FZQSLXQPHPOTHG-UHFFFAOYSA-N 0.000 claims description 3
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 238000000034 method Methods 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000000280 densification Methods 0.000 abstract 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 1
- 229910052753 mercury Inorganic materials 0.000 abstract 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 abstract 1
- 238000005201 scrubbing Methods 0.000 abstract 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 abstract 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 abstract 1
- 239000003039 volatile agent Substances 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- PVGBHEUCHKGFQP-UHFFFAOYSA-N sodium;n-[5-amino-2-(4-aminophenyl)sulfonylphenyl]sulfonylacetamide Chemical compound [Na+].CC(=O)NS(=O)(=O)C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 PVGBHEUCHKGFQP-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Abstract
The invention discloses an exterior wall paint prepared from the following raw materials in parts by weight: 86-90 parts of waterborne acrylic emulsion, 17-20 parts of styrene-acrylic emulsion, 20-50 parts of wollastonite powder, 2-3 parts of iso-octyl acrylate, 1-2 parts of potassium borate, 0.4-1 part of ethylene glycol dimethacrylate, 3-4 parts of tungsten boride, 1-2 parts of sodium dodecyl sulfate, 0.6-1 part of dibenzoyl peroxide, 3-4 parts of absolute ethyl alcohol, 0.8-1 part of gamma-aminopropyltriethoxysilane, 0.1-0.2 part of polyoxyethylene polyoxypropylene ether, 3-5 parts of coalescing agent and 10-20 parts of deionized water. The paint produced by the invention is low in raw material loss, less in gel generation, simple in process, firm in paint film, good in glossiness, strong in impact force resistance, not easy to crack, soft in texture, strong in decoration, high in weather and scrubbing resistance, strong in adhesive force, long in service life, free of special smell, heavy metals such as mercury, lead and the like and formaldehyde volatiles, and capable of meeting the technical requirement of an environment-friendly paint; and the added coalescing agent has very high stability, efficient adhesiveness and film forming property, so that the density of the paint film is increased, the film forming quality is improved, and a film layer has the advantages of strong adhesive force, no hole and rift, densification, uniformity and the like.
Description
Technical field
The present invention relates generally to a kind of coating, relates in particular to a kind of environmental protection exterior coating and preparation method thereof.
Background technology
In recent years; along with the raising of living standards of the people and the development of society; people are to the selection pay attention to day by day of building decoration coating, and are more simple better to the construction requirement of coating, for particularly in exterior coating; not only rest in the most basic protection to ground; decorative effect to coating is had higher requirement, and exterior coating requires to have water repelling property, requires to have from washing property; it is hard and smooth, dirty once rushing that paint film is wanted.
But the acrylic coating of throwing on the domestic market exists, and gloss is low, poor adhesive force, winter hardiness are poor, not water-fast, water vapour, soda acid, salts solution and organic polar solvent, poor flexibility under the room temperature, the shortcoming such as wear no resistance, and high temperature easily returns sticking, fragile under low temperature splitting, cause coating easily to ftracture, peel off, rainwater etc. easily infiltrate metope, corrosion body of wall, and this not only affects the beautiful decoration of buildings, and will reduce the work-ing life of buildings.
Summary of the invention
The object of the invention is exactly in order to remedy the defective of prior art, exterior coating that a kind of paint film is stable, glossiness is good, tolerance is strong and preparation method thereof to be provided.
The present invention is achieved by the following technical solutions:
A kind of environmental protection exterior coating, it is comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 86-90, benzene emulsion 17-20, wollastonite powder 20-50, Isooctyl acrylate monomer 2-3, potassium tetraborate 1-2, Ethylene glycol dimethacrylate 0.4-1, tungsten boride 3-4, sodium lauryl sulphate 1-2, dibenzoyl peroxide 0.6-1, dehydrated alcohol 3-4, γ-aminopropyl triethoxysilane 0.8-1, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.1-0.2, film coalescence aid 3-5, deionized water 10-20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
A kind of preparation method of environmental protection exterior coating may further comprise the steps:
The Isooctyl acrylate monomer of above-mentioned weight part is joined in the dehydrated alcohol, stirring and dissolving, the rising temperature is to 80-90 ℃, add sodium lauryl sulphate, benzene emulsion, 500-600 rev/min was stirred 6-8 minute, continued the rising temperature to 90-100 ℃, drip above-mentioned Ethylene glycol dimethacrylate, dropwise rear adding dibenzoyl peroxide, stir, be cooled to normal temperature; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again wollastonite powder, tungsten boride, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Advantage of the present invention is:
The coating raw material loss that the present invention produces is few, gel generates few, technique is simple, paint film is hard, glossiness is good, anti-impact force is strong, be not easy cracking, texture is soft, ornamental strong, high weather resisteant is arranged, brushing resistance, strong adhesion, long service life, without special odor, not mercurous, the plumbous heavy metal that waits, formaldehydeless volatile matter, meet the technical requirements of environmental protection coating material, the film coalescence aid of adding has very high stability, efficient binding property, film-forming properties has increased the density of coated membrane, improved quality of forming film, so that rete has strong adhesion, without the cavity, split sunken, the fine and close advantage such as even.
Embodiment
Embodiment 1
A kind of environmental protection exterior coating, it is comprised of the raw material of following weight parts (kilogram):
Aqueous acrylic emulsion 90, benzene emulsion 20, wollastonite powder 40, Isooctyl acrylate monomer 3, potassium tetraborate 2, Ethylene glycol dimethacrylate 0.4, tungsten boride 4, sodium lauryl sulphate 2, dibenzoyl peroxide 1, dehydrated alcohol 4, γ-aminopropyl triethoxysilane 0.8, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.2, film coalescence aid 5, deionized water 20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 40, polyvinyl alcohol 6, vinyltriethoxysilane 10, alkylphenol Polyoxyalkylene ethers 1, benzene emulsion 4, nano-sized carbon 2;
Polyvinyl alcohol is joined in 4 times of water, be steam heated to 100 ℃, stirring and dissolving adds benzene emulsion, reducing temperature is 70 ℃, and constant temperature stirred 4 minutes, adds each raw material of residue, 400 rev/mins of dispersions of low speed 3 minutes, 120 ℃ of insulations were left standstill 2 hours, were cooled to normal temperature, namely got described film coalescence aid.
A kind of preparation method of environmental protection exterior coating may further comprise the steps:
The Isooctyl acrylate monomer of above-mentioned weight part is joined in the dehydrated alcohol, stirring and dissolving, rising temperature to 90 ℃, add sodium lauryl sulphate, benzene emulsion, 600 rev/mins were stirred 8 minutes, continued rising temperature to 100 ℃, drip above-mentioned Ethylene glycol dimethacrylate, dropwise rear adding dibenzoyl peroxide, stir, be cooled to normal temperature; Add aqueous acrylic emulsion, deionized water, 1000 rev/mins were stirred 10 minutes; Add again wollastonite powder, tungsten boride, stirred 20 minutes at 800 rev/mins; Add each raw material of residue, under 700 rev/mins speed, fully stir, add acetic acid or sodium acetate, regulating PH is 9, and stirring is described exterior coating.
Performance test:
Paint film appearance is full, smooth, good without lump, glossiness;
Corrosion resistance test: pass through for 10000 times, paint film is without breakage;
The artificial ageing resistance test: 2000 hours non-foaming, do not peel off, flawless;
Temperature-change resistance (5 circulations): without unusual;
Alkali resistance: 200 hours without unusual.
Claims (2)
1. environmental protection exterior coating is characterized in that what it was comprised of the raw material of following weight parts:
Aqueous acrylic emulsion 86-90, benzene emulsion 17-20, wollastonite powder 20-50, Isooctyl acrylate monomer 2-3, potassium tetraborate 1-2, Ethylene glycol dimethacrylate 0.4-1, tungsten boride 3-4, sodium lauryl sulphate 1-2, dibenzoyl peroxide 0.6-1, dehydrated alcohol 3-4, γ-aminopropyl triethoxysilane 0.8-1, polyoxyethylene polyoxy propyl alcohol amidogen ether 0.1-0.2, film coalescence aid 3-5, deionized water 10-20;
Described film coalescence aid is comprised of the raw material of following weight parts:
Nano silicon 30-40, polyvinyl alcohol 4-6, vinyltriethoxysilane 6-10, alkylphenol Polyoxyalkylene ethers 0.8-1, benzene emulsion 3-4, nano-sized carbon 1-2;
Polyvinyl alcohol is joined in the 4-5 times of water, be steam heated to 95-100 ℃, stirring and dissolving adds benzene emulsion, and reducing temperature is 60-70 ℃, constant temperature stirred 3-4 minute, add each raw material of residue, low speed 300-400 rev/min was disperseed 2-3 minute, and 100-120 ℃ of insulation left standstill 1-2 hour, be cooled to normal temperature, namely get described film coalescence aid.
2. the preparation method of an environmental protection exterior coating as claimed in claim 1 is characterized in that may further comprise the steps:
The Isooctyl acrylate monomer of above-mentioned weight part is joined in the dehydrated alcohol, stirring and dissolving, the rising temperature is to 80-90 ℃, add sodium lauryl sulphate, benzene emulsion, 500-600 rev/min was stirred 6-8 minute, continued the rising temperature to 90-100 ℃, drip above-mentioned Ethylene glycol dimethacrylate, dropwise rear adding dibenzoyl peroxide, stir, be cooled to normal temperature; Add aqueous acrylic emulsion, deionized water, 900-1000 rev/min was stirred 8-10 minute; Add again wollastonite powder, tungsten boride, stirred 15-20 minute at 700-800 rev/min; Add each raw material of residue, under 600-700 rev/min speed, fully stir, add acetic acid or sodium acetate, adjusting PH is 8-9, stirs to be described exterior coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310247251.5A CN103351672B (en) | 2013-06-20 | 2013-06-20 | A kind of environmental protection exterior coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310247251.5A CN103351672B (en) | 2013-06-20 | 2013-06-20 | A kind of environmental protection exterior coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103351672A true CN103351672A (en) | 2013-10-16 |
| CN103351672B CN103351672B (en) | 2016-05-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310247251.5A Active CN103351672B (en) | 2013-06-20 | 2013-06-20 | A kind of environmental protection exterior coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103351672B (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046144A (en) * | 2014-05-23 | 2014-09-17 | 李世跃 | Odorless latex paint |
| CN104119757A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Waterproof paint for exterior wall |
| CN104119756A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Low-temperature-resistant water-resistant paint |
| CN104263122A (en) * | 2014-09-03 | 2015-01-07 | 天长市开林化工有限公司 | Stable paint |
| CN104387879A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Outer wall coating with self-cleaning heat-preservation function and preparation method of outer wall coating |
| CN105505076A (en) * | 2016-01-21 | 2016-04-20 | 上海馨来建筑装饰设计有限公司 | Environment-friendly external wall paint and preparation method thereof |
| CN109021741A (en) * | 2018-06-25 | 2018-12-18 | 滁州麦斯特新型建材有限公司 | Wall emulsion paint and preparation method thereof inside and outside a kind of |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083504A (en) * | 1993-09-10 | 1994-03-09 | 王衡新 | Mutually intersecting network polymer multi-colour water-coluble figure paint |
| CN1233637A (en) * | 1998-12-25 | 1999-11-03 | 童忠良 | Water-soluble composite high molecular polymer out-wall coating |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN101089062A (en) * | 2006-06-15 | 2007-12-19 | 深圳市海川实业股份有限公司 | Paint and its prepn process |
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
-
2013
- 2013-06-20 CN CN201310247251.5A patent/CN103351672B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1083504A (en) * | 1993-09-10 | 1994-03-09 | 王衡新 | Mutually intersecting network polymer multi-colour water-coluble figure paint |
| CN1233637A (en) * | 1998-12-25 | 1999-11-03 | 童忠良 | Water-soluble composite high molecular polymer out-wall coating |
| CN1696219A (en) * | 2004-05-11 | 2005-11-16 | 张海波 | Environmental protection type Nano Coating |
| CN101089062A (en) * | 2006-06-15 | 2007-12-19 | 深圳市海川实业股份有限公司 | Paint and its prepn process |
| CN101486861A (en) * | 2008-01-18 | 2009-07-22 | 深圳市海川实业股份有限公司 | Environment friendly antibacterial waterborne paint and preparation thereof |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104046144A (en) * | 2014-05-23 | 2014-09-17 | 李世跃 | Odorless latex paint |
| CN104046144B (en) * | 2014-05-23 | 2016-06-15 | 李世跃 | A kind of clean taste emulsion paint |
| CN104119757A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Waterproof paint for exterior wall |
| CN104119756A (en) * | 2014-06-26 | 2014-10-29 | 安徽快来防水防腐有限公司 | Low-temperature-resistant water-resistant paint |
| CN104263122A (en) * | 2014-09-03 | 2015-01-07 | 天长市开林化工有限公司 | Stable paint |
| CN104387879A (en) * | 2014-11-11 | 2015-03-04 | 合肥不老传奇保健科技有限公司 | Outer wall coating with self-cleaning heat-preservation function and preparation method of outer wall coating |
| CN105505076A (en) * | 2016-01-21 | 2016-04-20 | 上海馨来建筑装饰设计有限公司 | Environment-friendly external wall paint and preparation method thereof |
| CN105505076B (en) * | 2016-01-21 | 2018-12-04 | 河北晨阳工贸集团有限公司 | A kind of Environment-friendlyexterior exterior wall paint and preparation method thereof |
| CN109021741A (en) * | 2018-06-25 | 2018-12-18 | 滁州麦斯特新型建材有限公司 | Wall emulsion paint and preparation method thereof inside and outside a kind of |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103351672B (en) | 2016-05-04 |
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Denomination of invention: An environmentally friendly exterior wall coating and its preparation method Effective date of registration: 20231026 Granted publication date: 20160504 Pledgee: Lai An county Jinan financing Company limited by guarantee Pledgor: CHUZHOU BEST NEW BUILDING MATERIAL CO.,LTD. Registration number: Y2023980062875 |