CN1364838A - Water-thinned Normal temperature hardening fluorosilicious paint with metal texture - Google Patents
Water-thinned Normal temperature hardening fluorosilicious paint with metal texture Download PDFInfo
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- CN1364838A CN1364838A CN 02110780 CN02110780A CN1364838A CN 1364838 A CN1364838 A CN 1364838A CN 02110780 CN02110780 CN 02110780 CN 02110780 A CN02110780 A CN 02110780A CN 1364838 A CN1364838 A CN 1364838A
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- water
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- fluorosilicious
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Abstract
The water-thinned normal temperature hardening fluorosilicious paint with metal texture is mainly used in painting inner and outer wall in building and may be used in painting concrete, gypsum board, lignocellulose board and metal in order fields. It consists of water-thinned fluorocarbon emulsion, self-crosslinked organosilicon modified acrylic acid emulsion and acrylic acid emulsion as filming and adhering material, and pigments as supplementary material to produce metal texture. The water-thinned resin combination of the present invention has excellent weather resistance, strong pollution resistance, high air permeability, VOC value near zero and other advantages. The nano transparent ferric oxide system pigment and mica pigment combinatino produces metal texture and rich color.
Description
Technical field
Water-thinned Normal temperature hardening fluorosilicious paint with metal texture of the present invention relates to a kind of coating material, is mainly used in the application of building inner, external wall, also can be applicable to the application of concrete, plasterboard, wood fibre board and metal.
Background technology
Existing metal-like coating is mainly the solvent-borne type product, and the film forming fluorocarbon resin coating of high bake is arranged, and it can only be used for the application of the metal curtain wallboard that batch production makes, and the color dullness, costs an arm and a leg; Other baking-types and normal temperature cured type resin are made, be commonly referred to the product of metal flash paint, also be used for metal or the application of little skill product more, its high flash of light gloss is difficult to adapt to large-area architectural finish, and the ventilation property of filming is poor, be used for construction wall the easy peeling of covering with paint coating, peel off, the solvent load of its preparation is big, noxious solvent volatilization contaminate environment endangers biology, influences human beings'health.The building coating developing direction of generally acknowledging is a Water-borne modification; but obtain the pigment of metal-like such as aluminium silver powder, copper bronze etc. usually because of its metal active; under the aqueous medium effect; chemical reaction very easily takes place; oxidizedization variable color, deepening, lose metal-like, thereby the water-based metal texture coating Products Development research that actual application value arranged is still in difficult carrying out.
Summary of the invention
The objective of the invention is to: provide a kind of single component, ambient cure that is main film forming glue ramming material with organic-silicon-modified ACRYLIC EMULSION of water-base fluorocarbon emulsion and self-crosslinking or acrylic emulsions to become film coating to have the water-based metal texture coating of permanent metal-like that continues and good ventilation property.
The object of the invention can be achieved through the following technical solutions: with water-base fluorocarbon emulsion and self-cross linking type organosilicon-modified acrylic emulsion and ACRYLIC EMULSION composition film forming binding material, mix the pigment that produces metal-like.Wherein, the pigment of described generation metal-like comprises metal-like pigment, nano effect pigment, makes through grinding, dispersing technology.
On the technique scheme basis, described metal-like pigment is mica-based pigment, particle diameter 5-200 μ m; Described nano effect pigment is nano transparent iron oxide pigment, particle diameter 0.01-0.015 μ m, and a kind of in the molecular level metal complex pigment and more than one.
The selected water-base resin combination of the present invention has excellent super-weathering resistance and strong stain resistance, the coating good permeability, incrust, the VOC value is near zero, useful environmental protection and people's health, and the mica-based pigment of selecting for use has splendid chemical stability in aqueous medium, nano transparent iron oxide pigment has extremely excellent shielding sorption to UV-light, weather-proof, the ageing-resistant performance of coating are promoted greatly, with nanometer transparent iron oxide pigment and mica-based pigment combination, can show metal-like true to nature, have profuse color simultaneously.
Each component of the present invention is by weight percentage:
Water 0.00-20.00
Polyoxyethylene tetrafluoro carbon ether 0.01-0.05
Poly amic acid 0.10-0.40
Isothiazolinone 0.10-0.40
2-amino-2-methyl-1-propanol 0.00-0.10
Non-silicone mineral oil 0.20-0.40
Mica-based pigment (particle diameter 5-200 μ m) 2.0-15.00
Nano transparent iron oxide pigment (particle diameter 0.01-0.015 μ m)
0.00-2.50
Water-base fluorocarbon emulsion (solid content 40-55%)
10.00-20.00
Self-crosslinking organosilicon-modified acrylic class emulsion (solid content 30-50%)
50.00-75.00
Acrylic emulsions (solid content 30-50%)
0.00-20.00
Propylene soda acid swelling emulsion 0.00-0.40
Functional stuffing 0.00-4.00
Special addition agent 0.10-1.50
In the present invention's prescription, described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin; Described special addition agent be polyether-modified siloxanes, nonionic polyurethane and other can see through visible light reflect with the light penetrability material that absorbs the visible light wave range UV light in one or more. Described this kind light permeable material comprises nano titanium oxide.
Preparation process of the present invention is as follows:
The first step adds in container by weight
Water 0.00-20.00
Polyoxyethylene tetrafluoro carbon ether 0.01-0.05
Poly amic acid 0.10-0.40
Isothiazolinone 0.10-0.40
Non-silicone mineral oil 0.10-0.20 transfers to 500-600 rev/min with stirrer speed, drops into following material under whipped state successively:
Nano transparent iron oxide pigment (particle diameter 0.01-0.015 μ m)
0.00-2.50
Functional stuffing 0.00-4.00 transfers to zero with stirrer speed, and material in the container is carried out high speed dispersion, ground 10-15 minute with specific equipment, and extremely special material heating is shut down to about 40 ℃.
Second step was back to aforementioned dispersed with stirring technology, and stirrer speed transfers to 500-600 rev/min, drops into following material successively:
Water-base fluorocarbon emulsion (solid content 40-55%)
10.00-20.00
Self-crosslinking organosilicon-modified acrylic class emulsion (solid content 30-50%)
50.00-75.00
Acrylic emulsions (solid content 30-50%)
0.00-20.00
Propylene soda acid swelling emulsion 0.00-0.40
Special addition agent 0.10-1.50
Mica-based pigment (particle diameter 5-200 μ m) 2.0-15.00
Non-silicone mineral oil 0.10-0.20 feeds intake and finishes, and continues dispersed with stirring 30-40 minute, and material is uniformly dispersed, and uses 40-60 order nylon net cloth bag filtration again, packing.
Embodiment
Embodiment 1, a kind of silvery white water-thinned Normal temperature fluorine silicon metallized coating, and the each component weight percent is:
Water-base fluorocarbon emulsion (solid content 50%) 10.00
Self-crosslinking organosilicon-modified acrylic class emulsion (solid content 48%)
65.00
Polyoxyethylene tetrafluoro carbon ether 0.03
Nonionic polyurethane 0.15
2-amino-2-methyl-1-propanol 0.08
Non-silicone mineral oil 0.20
Polyether-modified siloxanes 0.37
Isothiazolinone 0.10
Mica-based silvery white pearly pigment (particle diameter 10-40 μ m) 11.20
Mica-based silvery white pearly pigment (particle diameter 5-25 μ m) 11.20
Wax powder (particle diameter 4-6 μ m) 1.32
Nano titanium oxide 0.3.
Embodiment 2, a kind of golden water-thinned Normal temperature hardening fluorosilicious paint with metal texture, and the each component weight percent is:
Water 8.00
Water-base fluorocarbon emulsion (solid content 50%) 16.00
Self-crosslinking organosilicon-modified acrylic class emulsion (solid content 48%)
62.00
Polyoxyethylene tetrafluoro carbon ether 0.03
Nonionic polyurethane 0.20
Polyacrylic acid amine salt (solid content 30%) 0.10
Non-silicone mineral oil 0.20
Polyether-modified siloxanes 0.40
Isothiazolinone 0.10
Nano transparent iron oxide yellow (particle diameter 0.01-0.015 μ m)
0.62
Nano titanium oxide 0.35
The golden pearly pigment of mica-based (particle diameter 10-100 μ m) 10.00
The golden pearly pigment of mica-based (particle diameter 40-200 μ m) 2.00.
Claims (5)
1, water-thinned Normal temperature hardening fluorosilicious paint with metal texture has water-base fluorocarbon emulsion, is characterised in that: by water-base fluorocarbon emulsion, self-cross linking type organosilicon-modified acrylic emulsion and ACRYLIC EMULSION is the film forming binding material, is aided with the pigment that produces metal-like.
2, water-thinned Normal temperature hardening fluorosilicious paint with metal texture according to claim 1 is characterised in that: the pigment of described generation metal-like comprises metal-like pigment, nano effect pigment.
3, according to claim 1,2 described water-thinned Normal temperature hardening fluorosilicious paint with metal texture, be characterised in that: described metal-like pigment is mica-based pigment; Described nano effect pigment is a kind of in nano transparent iron oxide pigment and the molecular level metal complex pigment and more than one.
4, water-thinned Normal temperature hardening fluorosilicious paint with metal texture according to claim 3 is characterised in that each composition is by weight percentage:
Water 0.00-20.00
Polyoxyethylene tetrafluoro carbon ether 0.01-0.05
Poly amic acid 0.10-0.40
Isothiazolinone 0.10-0.40
2-amino-2-methyl-1-propanol 0.00-0.10
Non-silicone mineral oil 0.20-0.40
Mica-based pigment (particle diameter 5-200 μ m) 2.0-15.00
Nano transparent iron oxide pigment (particle diameter 0.01-0.015 μ m)
0.00-2.50
Water-base fluorocarbon emulsion (solid content 40-55%)
10.00-20.00
Self-crosslinking organosilicon-modified acrylic class emulsion (solid content 30-50%)
50.00-75.00
Acrylic emulsions (solid content 30-50%)
0.00-20.00
Propylene soda acid swelling emulsion 0.00-0.40
Functional stuffing 0.00-4.00
Special addition agent 0.10-1.50
5, water-thinned Normal temperature hardening fluorosilicious paint with metal texture according to claim 4 is characterised in that: described functional stuffing is one or more in wax powder, silicon-dioxide, the urine-methyl alcohol resin; Described special addition agent is that polyether-modified siloxanes, nonionic polyurethane and other can see through visible light and reflect and the light penetrability material that absorbs the visible light wave range UV light; Described this kind light permeable material comprises nano titanium oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02110780 CN1364838A (en) | 2002-02-05 | 2002-02-05 | Water-thinned Normal temperature hardening fluorosilicious paint with metal texture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02110780 CN1364838A (en) | 2002-02-05 | 2002-02-05 | Water-thinned Normal temperature hardening fluorosilicious paint with metal texture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1364838A true CN1364838A (en) | 2002-08-21 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02110780 Pending CN1364838A (en) | 2002-02-05 | 2002-02-05 | Water-thinned Normal temperature hardening fluorosilicious paint with metal texture |
Country Status (1)
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|---|---|
| CN (1) | CN1364838A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100551980C (en) * | 2007-09-18 | 2009-10-21 | 深圳市明远氟涂料有限公司 | A kind of normal temperature solidifying fluorine-carbon coating for rubber roller |
| CN101457114B (en) * | 2008-12-30 | 2011-04-13 | 江阴国联化工有限公司 | Method for preparing hydrophilic fluorine carbon metal paint |
| CN103709855A (en) * | 2013-12-25 | 2014-04-09 | 连云港冠钰精密工业有限公司 | Corrosion-resistant wear-resistant water-based automobile paint |
| CN104327627A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Aqueous transparent heat insulation coating for glass doors, and its preparation method |
| CN104497764A (en) * | 2014-12-26 | 2015-04-08 | 嘉兴北大华丰新能源有限公司 | High-quality waterborne fluorosilicone metal paint production process |
| CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
| JP6040773B2 (en) * | 2010-11-15 | 2016-12-07 | 日産化学工業株式会社 | Thermosetting resin softening particles |
| CN110724414A (en) * | 2019-10-08 | 2020-01-24 | 武汉长弢新材料有限公司 | Stain-resistant high-temperature-resistant water-based paint and preparation method thereof |
-
2002
- 2002-02-05 CN CN 02110780 patent/CN1364838A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100551980C (en) * | 2007-09-18 | 2009-10-21 | 深圳市明远氟涂料有限公司 | A kind of normal temperature solidifying fluorine-carbon coating for rubber roller |
| CN101457114B (en) * | 2008-12-30 | 2011-04-13 | 江阴国联化工有限公司 | Method for preparing hydrophilic fluorine carbon metal paint |
| JP6040773B2 (en) * | 2010-11-15 | 2016-12-07 | 日産化学工業株式会社 | Thermosetting resin softening particles |
| CN103709855A (en) * | 2013-12-25 | 2014-04-09 | 连云港冠钰精密工业有限公司 | Corrosion-resistant wear-resistant water-based automobile paint |
| CN104327627A (en) * | 2014-10-14 | 2015-02-04 | 马鞍山市恒毅机械制造有限公司 | Aqueous transparent heat insulation coating for glass doors, and its preparation method |
| CN104497764A (en) * | 2014-12-26 | 2015-04-08 | 嘉兴北大华丰新能源有限公司 | High-quality waterborne fluorosilicone metal paint production process |
| CN105440827A (en) * | 2015-12-28 | 2016-03-30 | 杭州名匠建筑装饰工程有限公司 | Water-based normal-temperature-curing fluorine-silicon composite texture paint |
| CN110724414A (en) * | 2019-10-08 | 2020-01-24 | 武汉长弢新材料有限公司 | Stain-resistant high-temperature-resistant water-based paint and preparation method thereof |
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