CN103113796B - Water-based fluorocarbon elasticity anti-soil exterior wall paint - Google Patents
Water-based fluorocarbon elasticity anti-soil exterior wall paint Download PDFInfo
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- CN103113796B CN103113796B CN201110363852.3A CN201110363852A CN103113796B CN 103113796 B CN103113796 B CN 103113796B CN 201110363852 A CN201110363852 A CN 201110363852A CN 103113796 B CN103113796 B CN 103113796B
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- 239000003973 paint Substances 0.000 title claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 23
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 239000002689 soil Substances 0.000 title claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000839 emulsion Substances 0.000 claims abstract description 15
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 14
- 238000004132 cross linking Methods 0.000 claims abstract description 10
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 8
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 8
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- -1 acrylic acid amine salt Chemical class 0.000 claims description 6
- 239000003429 antifungal agent Substances 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000002270 dispersing agent Substances 0.000 claims description 6
- 239000003755 preservative agent Substances 0.000 claims description 6
- 230000002335 preservative effect Effects 0.000 claims description 6
- 239000000080 wetting agent Substances 0.000 claims description 6
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical group CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 5
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical group CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 4
- 229920006243 acrylic copolymer Polymers 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- MIZLGWKEZAPEFJ-UHFFFAOYSA-N 1,1,2-trifluoroethene Chemical group FC=C(F)F MIZLGWKEZAPEFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 claims description 2
- MCZYARLEFAYGTA-UHFFFAOYSA-N 3,4-dichloro-1,2-thiazole 1-oxide Chemical group ClC1=CS(=O)N=C1Cl MCZYARLEFAYGTA-UHFFFAOYSA-N 0.000 claims description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 2
- 239000004693 Polybenzimidazole Substances 0.000 claims description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 239000003002 pH adjusting agent Substances 0.000 claims 2
- 239000000126 substance Substances 0.000 abstract description 15
- 235000010215 titanium dioxide Nutrition 0.000 abstract description 7
- 239000007788 liquid Substances 0.000 abstract description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 4
- 235000013618 yogurt Nutrition 0.000 abstract description 4
- 238000003916 acid precipitation Methods 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 230000003670 easy-to-clean Effects 0.000 abstract description 2
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 239000004816 latex Substances 0.000 description 6
- 229920000126 latex Polymers 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 238000010276 construction Methods 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- CZKYLWACZPRYOR-UHFFFAOYSA-N [S].OS(O)(=O)=O Chemical compound [S].OS(O)(=O)=O CZKYLWACZPRYOR-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- KQNPFQTWMSNSAP-UHFFFAOYSA-N isobutyric acid Chemical compound CC(C)C(O)=O KQNPFQTWMSNSAP-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
Abstract
The invention provides a kind of water-based fluorocarbon elasticity anti-soil exterior wall paint, component including following weight portion: water 16～20 weight portion, self-crosslinking elastomeric propylene yogurt liquid 15～27 weight portion, water-base fluorocarbon emulsion 12～22 weight portion, titanium dioxide 15～20 parts, barium sulfate 12～18 parts and calcined kaolin 4～8 parts and film former 1～1.4 parts.The present invention is the requirement that main base material reaches anti-crack with self-crosslinking elastomeric propylene yogurt liquid, it is equipped with the good water-base fluorocarbon emulsion of the compatibility modified simultaneously, paint film is made to have lower surface free energy, give the oil repellency that paint film is good, the paint film formed is finer and close, thus reach to make paint film be susceptible to spot and pollute, also it is more easy to clean up after being polluted by spot simultaneously, the weatherability of film is improved in combination with weather-proof rutile titanium white, chemicals-resistant (acid rain, salt etc.) corrosivity, thus film guarantor's color gloss retention is good, for a kind of new high-performance water-based fluorine carbon elasticity anti-soil exterior wall paint.
Description
Technical field
The present invention relates to a kind of exterior wall latex paint.
Background technology
Exterior wall latex paint has been ripe technology, because the advantages such as low cost, easily construction, environmental protection so that it is in building
The decoration of exterior wall protection of thing becomes a kind of conventional material.Along with popularizing of exterior wall latex paint, answering at high performance requirements
Also some problems are also had to have to be solved in: crackle, metope the most then to occur easily by the pollution of some airborne contaminants after construction
Can not scrub, the film color in area (as big in acid rain, seashore salt) of environment rather harsh and mat finish fast.
Summary of the invention
It is an object of the invention to provide a kind of water-based fluorocarbon elasticity anti-soil exterior wall paint, above-mentioned with overcome prior art to exist
Defect.
The water-based fluorocarbon elasticity anti-soil exterior wall paint of the present invention, including the component of following weight portion:
Water 16～20 weight portion, self-crosslinking elastomeric propylene yogurt liquid 15～27 weight portion, water-base fluorocarbon emulsion 12～22 weight
Amount part, titanium dioxide 15～20 parts, barium sulfate 12～18 parts and calcined kaolin 4～8 parts and film former 1～1.4 parts；
Preferably, the water-based fluorocarbon elasticity anti-soil exterior wall paint of the present invention, also include dispersant, wetting agent, defoamer, antifreeze
Agent, antifungus agent, preservative, cellulose, PH regulator and thickening agent；
Preferably, the water-based fluorocarbon elasticity anti-soil exterior wall paint of the present invention, including the component of following weight portion:
In above-mentioned raw material, the chemical name of each component is as follows:
The chemical name of described dispersant is acrylic acid amine salt, and can use DOWS company of the U.S. trade mark is the product of 963；
The chemical name of described wetting agent is alkyl phenol vinyl Ether, and can use DOWS company of the U.S. trade mark is CF-10's
Product；
The chemical name of described defoamer is methylsiloxane, and can use NOPOCO company of the Japan trade mark is SN-154's
Product, or Germany's CONGNIS company trade mark is the product of A-10, or both mixture, when using mixture, weight
Amount ratio is 1: 0.5～1.5；
The chemical name of described film former is 2,2,4-trimethyl-1, and 3-pentanediol mono isobutyrate can use the U.S.
The EASTMAN company trade mark is the product of TEXANOL；
The chemical name of described antifungus agent is dichloro isothiazolone, and can use DOWS company of the U.S. trade mark is 361
Product；
The chemical name of described preservative is poly-benzimidazole, and can use U.S.'s DOWS trade mark is the product of LXE；
Described titanium dioxide uses DUPPONT company of the U.S. trade mark to be the product of R-706；
The product that described barium sulfate uses the Jiangxi Guang Yuan chemical company trade mark to be 2000 mesh barium sulfate；
Described calcined kaolin uses the Shanxi Heng Yuan company trade mark to be the product of HS-801A；
The chemical name of described cellulose is hydroxyethyl cellulose, and CLARIANT company of the employing Germany trade mark is
The product of HS30000；
The chemical name of described PH regulator is 2-amino-2-methyl-1-propanol, and DOWS company of the employing U.S. trade mark is
The product of AMP-95；
The chemical name of described self-crosslinking elastic emulsion is acrylic copolymer, and DOWS company of the employing U.S. trade mark is
The product of 2468；
The chemical name of described fluorine carbon emulsion is trifluoro-ethylene acrylic copolymer, and employing Changxing, Taiwan company trade mark is
The product of 4312；
The chemical name of described thickening agent is polyurethane acroleic acid, and using DOWS company of the U.S. trade mark is the product of RM-8W
Product, or DOWS company of the U.S. trade mark is the product of RM-2020, or both mixture, when using mixture, weight
Ratio is 1: 0.5～1.5；
The preparation method of the water-based fluorocarbon elasticity anti-soil exterior wall paint of the present invention, for conventional physical mixing processes, by each
Component stirring mixing, with 100 mesh sock filtration, can obtain product.
The present invention is directed to tripartite's surface technology difficult problem that prior art exists, start with from latex paint formulation raw material, by series
Experiment, is the requirement that main base material reaches anti-crack with self-crosslinking elastomeric propylene yogurt liquid, is equipped with the aqueous fluorine that the compatibility is good simultaneously
Carbon emulsion is modified, makes paint film have lower surface free energy, gives the oil repellency that paint film is good, the emulsion shape of self-crosslinking in addition
The paint film become is finer and close thus reaches to make paint film be susceptible to spot and pollutes, and is also more easy to clean up after being polluted by spot simultaneously,
Improve the weatherability of film, chemicals-resistant (acid rain, salt etc.) corrosivity in combination with weather-proof rutile titanium white, thus film is protected
Color gloss retention is good, it is thus achieved that a kind of new high-performance water-based fluorine carbon elasticity anti-soil exterior wall paint.
Detailed description of the invention
Embodiment 1
Formula:
(1) 12.0 kilograms of water
(2) 0.5 kilogram of U.S. DOWS of dispersant, 963
(3) 0.3 kilogram of U.S. DOWS of wetting agent, CF-10
(4) 0.2 kilogram of Japanese NOPOCO of defoamer A, SN-154
(5) antifreezing agent propylene glycol 2.0 kilograms
(6) 1.2 kilograms of U.S. EASTMAN of film former, TEXANOL
(7) 0.3 kilogram of U.S. DOWS of antifungus agent, 361
(8) 0.12 kilogram of U.S. DOWS of preservative, LXE
(9) titanium dioxide 18.0 kilograms, U.S. DUPPONT R-706
(10) 2,000 15.0 kilograms of mesh barium sulfate Jiangxi Guang Yuan Chemical Co., Ltd.s
(11) 6.0 kilograms of Shanxi Heng Yuan Kaolin company limited HS-801A of calcined kaolin
(12) 0.15 kilogram of German CLARIANT of cellulose, HS30000
(13) 2.5 kilograms of water
(14) PH, 0.12 kilogram of U.S. DOWS of regulator, AMP-95
(15) 1.5 kilograms of water
(16) 21.5 kilograms of U.S. DOWS of self-crosslinking elastic emulsion, 2468
(17) Changxing, 17.0 kilograms of Taiwan of fluorine carbon emulsion, 4312
(18) 0.3 kilogram of U.S. DOWS of thickening agent A, RM-8W
(19) 0.2 kilogram of U.S. DOWS of thickening agent B, RM-2020
(20) the German CONGNIS company of defoamer B 0.3 kilogram, A-10
(21) 0.81 kilogram of water
Total consumption of water is 16.81 kilograms.
Preparation method:
1, component (1) is added in dispersion cylinder, rotating speed 350 revs/min, add while stirring component (2), (3), (4),
(5), (6), (7) and (8), stir 7 minutes；
2, under the rotating speed of 700～800 revs/min, add component (9), (10) and (11), be subsequently adding component (13) and
The mixture of component (12), is subsequently added into component (14), is adding component (15), 1450 revs/min, is disperseing 25 minutes, reach
The fineness of 45 microns；
3, under the rotating speed of 750 revs/min, component (16), (17), (18), (19), (20) and (21) is added, 450
Rev/min rotating speed under, add component (20), disperse 25 minutes, with 100 mesh sock filtration, product can be obtained.
Product is constructed in the weather not rained.After generally converting the tap water of 10% (weight ratio), construct with roller applications
On external wall, construction together, is dried more than 2 hours, then second of constructing, and after construction completion, is dried about 4 hours, film
Performance is the most conventional；Can not also be watered, directly construct together on external wall by airless spraying mode, be dried about 6 hours, be coated with
Film properties is the most conventional.
Testing result is as follows:
1) key property presses the test of GB/T9757-2009 resin latex dope
| Project | High-class product index | Result |
| Condition in container | Without lump, in uniform state after stirring | Meet |
| Application property | Brush two roads accessible | Meet |
| Low-temperature stability (3 circulations) | Never degenerate | Meet |
| Drying time (surface drying)/hour ,≤ | 2 | 40 minutes |
| Contrast ratio, >= | 0.93 | 0.94 |
| Resistance to 5% sodium chloride (48 hours) | Without exception | 48 hours without exception |
| Resistance to 5% sulfur sulphuric acid (48 hours) | Without exception | 48 hours without exception |
| Scrub resistance (secondary), >= | 5000 | More than 50000 times |
| Alkaline-resisting (48 hours) | Without exception | 48 hours without exception |
| Ageing-resistant (1000 hours) | Without efflorescence, variable color 1 grade | Meet |
2) elastic JGT 172-2005 elastic building paint of pressing is tested
| Project | Exterior wall requirement | Result |
| Hot strength/MPa | 1.0 | 1.2 |
| Elongation at break % under mark state | 200% | 280% |
| Stain resistant | Less than 15% | 8% |
Embodiment 2
Formula:
(1) 14.0 kilograms of water
(2) 0.4 kilogram of U.S. DOWS of dispersant
(3) 0.2 kilogram of U.S. DOWS of wetting agent
(4) 0.3 kilogram of Japanese NOPOCO of defoamer A
(5) antifreezing agent propylene glycol 2.16 kilograms
(6) 1.4 kilograms of U.S. EASTMAN of film former, TEXANOL
(7) 0.4 kilogram of U.S. DOWS of antifungus agent, 361
(8) 0.1 kilogram of U.S. DOWS of preservative, LXE
(9) titanium dioxide 15.0 kilograms, U.S. DUPPONT
(10) 2,000 12.0 kilograms of mesh barium sulfate Jiangxi Guang Yuan Chemical Co., Ltd.s
(11) 8 kilograms of Shanxi Heng Yuan Kaolin company limited HS-801A of calcined kaolin
(12) 0.2 kilogram of German CLARIANT of cellulose, HS30000
(13) 3 kilograms of water
(14) PH, 0.14 kilogram of U.S. DOWS of regulator, AMP-95
(15) 2 kilograms of water
(16) 18 kilograms of U.S. DOWS of self-crosslinking elastic emulsion, 2468
(17) Changxing, 22 kilograms of Taiwan of fluorine carbon emulsion, 4312
(18) 0.4 kilogram of U.S. DOWS of thickening agent A, RM-8W
(19) 0.1 kilogram of U.S. DOWS of thickening agent B, RM-2020
(20) the German CONGNIS company of defoamer B 0.2 kilogram, A-10
(21) 1 kilogram of water
Preparation method is with embodiment 1, and testing result is as follows:
1) key property presses the test of GB/T9757-2009 resin latex dope
| Project | High-class product index | Result |
| Condition in container | Without lump, in uniform state after stirring | Meet |
| Application property | Brush two roads accessible | Meet |
| Low-temperature stability (3 circulations) | Never degenerate | Meet |
| Drying time (surface drying)/hour ,≤ | 2 | 40 minutes |
| Contrast ratio, >= | 0.93 | 0.93 |
| Resistance to 5% sodium chloride (48 hours) | Without exception | 48 hours without exception |
| Resistance to 5% sulfur sulphuric acid (48 hours) | Without exception | 48 hours without exception |
| Scrub resistance (secondary), >= | 5000 | More than 50000 times |
| Alkaline-resisting (48 hours) | Without exception | 48 hours without exception |
| Ageing-resistant (1000 hours) | Without efflorescence, variable color 1 grade | Meet |
2) elastic JGT 172-2005 elastic building paint of pressing is tested
| Project | Exterior wall requirement | Result |
| Hot strength/MPa | 1.0 | 1.05 |
| Elongation at break % under mark state | 200% | 350% |
| Stain resistant | Less than 15% | 6% |
Claims (1)
1. water-based fluorocarbon elasticity anti-soil exterior wall paint, it is characterised in that include the component of following weight portion:
Water 16～20 parts
Dispersant 0.4～0.6 part
Wetting agent 0.2～0.4 part
Defoamer 0.3 ~ 0.7 part
Antifreezing agent propylene glycol 1.5～2.5 parts
Film former 1～1.4 parts
Antifungus agent 0.2～0.4 part
Preservative 0.10～0.14 part
Titanium dioxide 15～20 parts
Barium sulfate 12～18 parts
Calcined kaolin 4～8 parts
Cellulose 0.1～0.2 part
PH adjusting agent 0.1～0.14 part
Self-crosslinking elastic emulsion 15～27 parts
Fluorine carbon emulsion 12～22 parts
Thickening agent 0.3～0.7 part；
Described dispersant is acrylic acid amine salt；
Described wetting agent is alkyl phenol vinyl Ether；
Described defoamer is methylsiloxane；
Described film former is 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate；
Described antifungus agent is dichloro isothiazolone；
Described preservative is poly-benzimidazole；
Described cellulose is hydroxyethyl cellulose；
Described pH adjusting agent is 2-amino-2-methyl-1-propanol；
Described self-crosslinking elastic emulsion is acrylic copolymer；
Described fluorine carbon emulsion is trifluoro-ethylene acrylic copolymer；
Described thickening agent is polyurethane acroleic acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110363852.3A CN103113796B (en) | 2011-11-16 | 2011-11-16 | Water-based fluorocarbon elasticity anti-soil exterior wall paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201110363852.3A CN103113796B (en) | 2011-11-16 | 2011-11-16 | Water-based fluorocarbon elasticity anti-soil exterior wall paint |
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| Publication Number | Publication Date |
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| CN103113796A CN103113796A (en) | 2013-05-22 |
| CN103113796B true CN103113796B (en) | 2016-08-10 |
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| CN103483954A (en) * | 2013-09-17 | 2014-01-01 | 三棵树涂料股份有限公司 | APEO-free water-based elastic fluorocarbon exterior-wall paint with adjustable colors |
| CN103805054B (en) * | 2014-03-04 | 2016-05-25 | 北京市市政工程研究院 | A kind of concrete exterior wall protective agent and preparation method thereof |
| CN104559592A (en) * | 2014-12-19 | 2015-04-29 | 北京东方雨虹防水技术股份有限公司 | Fluorocarbon elastic paint and preparation method thereof |
| CN105778636A (en) * | 2014-12-25 | 2016-07-20 | 铂恩塞尔新材料（上海）股份有限公司 | Environment-friendly exterior wall elastic styling paint and preparation method thereof |
| CN104877504A (en) * | 2015-06-15 | 2015-09-02 | 合肥启华环保科技有限公司 | Graphene added anticorrosion latex paint for outer wall and preparation method thereof |
| CN105017915A (en) * | 2015-08-03 | 2015-11-04 | 蓝星（成都）新材料有限公司 | Water-based paint for outer wall |
| CN105176232A (en) * | 2015-08-31 | 2015-12-23 | 天长市银狐漆业有限公司 | Weather-resistant and waterproof exterior wall emulsion paint |
| EP3511381B1 (en) * | 2016-09-06 | 2021-10-27 | Agc Inc. | Anti-biofouling coating material |
| CN106566442A (en) * | 2016-10-28 | 2017-04-19 | 天长市永泰密封材料有限公司 | Dustproof stain-resistant container water-based sealant and preparation method thereof |
| WO2021051303A1 (en) * | 2019-09-18 | 2021-03-25 | 河北比尔尼克新材料科技股份有限公司 | Waterborne fluorocarbon paint and preparation method therefor and application thereof |
| CN110698929A (en) * | 2019-10-25 | 2020-01-17 | 安徽开林新材料股份有限公司 | Ship anticorrosive paint capable of improving bonding strength and preparation method thereof |
| CN112795246A (en) * | 2021-01-15 | 2021-05-14 | 湖州和悦新材料科技股份有限公司 | Water-based fluorocarbon outdoor paint and preparation method thereof |
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| CN103113796A (en) | 2013-05-22 |
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Address after: 201700 on the south side of Shanghai Road, Qingpu Industrial Park Applicant after: Shanghai Zhanchen Paint Co., Ltd. Applicant after: Zhanchen Coatings Group Co., Ltd. Applicant after: Beijing Zhanchen Chemical Industry Co., Ltd. Address before: 8555 No. 201707 Shanghai city Qingpu District Songze Avenue Applicant before: Shanghai Fuchen Chemical Co., Ltd. Applicant before: Zhanchen Coatings Group Co., Ltd. Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd. |
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Address after: 201700 on the south side of Shanghai Road, Qingpu Industrial Park Applicant after: Shanghai Zhanchen Paint Co., Ltd. Applicant after: CHINA ZHANCHEN PAINTS GROUP LTD. Applicant after: Beijing Zhan Chen novel material company limited Address before: 201700 on the south side of Shanghai Road, Qingpu Industrial Park Applicant before: Shanghai Zhanchen Paint Co., Ltd. Applicant before: Zhanchen Coatings Group Co., Ltd. Applicant before: Beijing Zhanchen Chemical Industry Co., Ltd. |
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