CN101402816B - Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction - Google Patents
Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction Download PDFInfo
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- CN101402816B CN101402816B CN2008101620044A CN200810162004A CN101402816B CN 101402816 B CN101402816 B CN 101402816B CN 2008101620044 A CN2008101620044 A CN 2008101620044A CN 200810162004 A CN200810162004 A CN 200810162004A CN 101402816 B CN101402816 B CN 101402816B
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- 238000010276 construction Methods 0.000 title claims abstract description 5
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 title claims description 14
- 239000003973 paint Substances 0.000 title claims description 6
- 239000011248 coating agent Substances 0.000 claims abstract description 45
- 238000000576 coating method Methods 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 239000000945 filler Substances 0.000 claims abstract description 10
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000006254 rheological additive Substances 0.000 claims abstract description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 239000000839 emulsion Substances 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 17
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000006185 dispersion Substances 0.000 claims description 12
- 230000008719 thickening Effects 0.000 claims description 12
- 238000004581 coalescence Methods 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 4
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims description 3
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 229960004217 benzyl alcohol Drugs 0.000 claims description 3
- 235000019445 benzyl alcohol Nutrition 0.000 claims description 3
- 239000010433 feldspar Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 241000195493 Cryptophyta Species 0.000 claims description 2
- 239000003518 caustics Substances 0.000 claims description 2
- -1 poly carboxylic acid ammonium salt Chemical class 0.000 claims description 2
- 150000003673 urethanes Chemical class 0.000 claims description 2
- 239000002518 antifoaming agent Substances 0.000 claims 1
- 235000010446 mineral oil Nutrition 0.000 claims 1
- 238000003916 acid precipitation Methods 0.000 abstract description 3
- 230000032683 aging Effects 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004816 latex Substances 0.000 abstract 2
- 229920000126 latex Polymers 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 239000003619 algicide Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000006260 foam Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 230000003449 preventive effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 238000011109 contamination Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- 238000009472 formulation Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 208000034189 Sclerosis Diseases 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a water elastic coating used for the protection and decoration on the surface of an outer wall of a construction. The current elastic coating mainly aims at solving the stain resistance of the elastic coating, while relates less to the aspects of acid rain resistance and aging resistance. The mass percentage of each component in the coating is as follows: 10 to 20 percent of water, 2 to 4 percent of latent solvent, 0.5 to 1.0 percent of dispersant, 0.2 to 0.4 percent of multifunctional accessory ingredient, 0.2 to 0.5 percent of foam killer, 0.1 to 0.2 percent of preservative, 0.2 to 0.6 percent of mildew preventive and algaecide, 15 to 23 percent of acid resistant pigment, 5 to 18 percent of acid resistant filler, 10 to 15 percent of fluorocarbon latex, 30 to 40 percent of crylic acid elastic latex, 1 to 1.5 percent of film forming additive, 0.3 to 0.8 percent of rheological additive and 0.5 to 1.0 percent of thickening agent. The water elastic coating has the durability, the acid rain resistance and the stain resistance of fluorocarbon coating and simultaneously has the elastic crack resistance of acrylic acid elastic coating.
Description
Technical field
The present invention relates to paint field, specifically a kind of aqueous elastic coating that is used for the building exterior wall surface protection and decorates.
Background technology
Skin is many to be basic unit with the cement sand plaster, and motar reduces the sclerosis crack that produces owing to volume when sclerosis; During temperature variation, the thermal cracking that produces owing to rising-heat contracting-cold; During weather wet variation of the Heavenly Stems, the desciccation crack that the drying shrinkage that rises owing to wetting produces; Winter, rainwater was when the body of wall freeze thawing, the freeze thawing crack that produces owing to the water freezing volumetric expansion; Produce structural cracks etc. during settlement of foundation, cause exterior wall surface protection decorative coveringn cracking, rainwater and air enter body of wall with the crack seepage, deepen the destruction to buildings, as harm buildingss such as steel bar corrosion and concrete carbonizations.Because elastic coating keeps higher elasticity, toughness and elongation in certain temperature range; be coated on the exterior wall substrate surface and form the elastic protective layer; coating can not rupture when basic unit's body of wall cracks, and has waterproofing and anti-leakage leakage property preferably, and therefore elastic coating is greatly developed in recent years.But since present domestic main employing coal fired power generation, content of sulfur dioxide height in the air, each department acid rain takes place frequently, and atmospheric pollution is serious, and it is serious to cause elastic coating surface contamination and acid etching to destroy, and the ornamental and weather resistance of elastic coating is descended greatly.Up to the present, mainly focusing on the contamination resistance that solves elastic coating aspect the elastic coating exploitation, and the acidproof rain and the ageing-resistant aspect of elastic coating seldom related to.
Summary of the invention
Technical problem to be solved by this invention is to overcome the defective that above-mentioned prior art exists; a kind of fluorine-carbon modified aqueous elastic coating is provided; it has elasticity preferably, and it is ageing-resistant to possess anti-contamination, acidproof rain and overlength simultaneously, with protection and the decoration that is used for external wall basic unit.
For this reason, the present invention adopts following technical scheme: the quality percentage composition of each component is as follows in the watersoluble fluorine-carbon modified elastic paint for exterior wall of construction:
Water 10-20%
Solubility promoter 2-4%
Dispersion agent 0.5-1.0%
Multifunctional assistant 0.2-0.4%
Defoamer 0.2-0.5%
Sanitas 0.1-0.2%
Algae agent 0.2-0.6% is prevented in mildew-resistant
Acidproof pigment 15-23%
Acid resistance filler 5-18%
Fluorine carbon emulsion 10-15%
Acrylic elastic emulsion 30-40%
Film coalescence aid 1-1.5%
Auxiliary rheological agents 0.3-0.8%
Thickening material 0.5-1.0%.
Elastic coating of the present invention is made up of main film forming substance, film forming subsidiary material matter, auxiliary film forming matter and water, main film forming substance is meant emulsion, directly influence weather resistance, elasticity and the contamination resistance of coating, the used emulsion of the present invention is that fluorine carbon emulsion and acrylic elastic emulsion are mixed assembly by different ratios, 10 ℃ of fluorine carbon emulsion second-order transition temperatures, solids content 50%, the second-order transition temperature of acrylic elastic emulsion-22 ℃, solids content 50%; Film forming subsidiary material matter is meant acidproof pigment and filler, the performance of pigment has substantial connection with the opacifying power of filming, tint retention, acid resistance and chalking resistance, described pigment is selected Rutile type Titanium Dioxide for use, also can suitably add some coloured pigments, as import mill base (the high-quality aqueous color paste that can select for use companies such as Clariant and Xi Bisi to produce), filler is a kind of pigment extender of less colored power, mainly play coating performance adjustment, film performance change and further reduce the effect of formulation cost, filler is selected process white, ultrafine quartz powder, Feldspar Powder etc. for use; Auxiliary film forming matter is film forming separately, just form to be coated with and play auxiliary effect in the membrane process at coating, as film coalescence aid, solubility promoter, dispersion agent, multifunctional assistant, defoamer, sanitas, various auxiliary agents such as mildew-resistant anti-algae agent, auxiliary rheological agents and thickening material, though their consumptions in coating are little, the storage of coating, the outward appearance of constructing and filming, water tolerance and abrasion resistance are all had a significant effect.The dispersion agent that is added among the present invention is the poly carboxylic acid ammonium salt, can disperse inorganic color stuffing effectively, and be adsorbed on face, filling surface, hydrophilic face, filler are carried out the surface hydrophobicity modification, simultaneously and between the emulsion good consistency is arranged, can improve the water resisting property of elastic coating effectively; Film coalescence aid is mainly alcohol ester-12, phenylcarbinol and butyl glycol ether etc., solubility promoter is propylene glycol, ethylene glycol etc., multifunctional assistant is selected commercially available AMP-95 (2-amino-2-methyl-1-propanol for use, contain 5% water) and analogous products, defoamer is mainly selected mineral oils, organic-silicon-modified mineral oils for use; Sanitas is selected the loose sanitas of card and 1 for use, 2-benzisothiazole-3-ketone (being called for short the BIT sanitas), U.S. ROHM AND HAAS product R-2000 is selected in the anti-algae agent of mildew-resistant for use, and auxiliary rheological agents is a hydrophobically modified urethane rheology modifier, and thickening material is a hydrophobically modified caustic solubility thickening material.
The production process of elastic coating is: add solubility promoter, dispersion agent, multifunctional assistant, 1/2 defoamer, sanitas, mildew-resistant anti-algae agent, pigment and filler in water successively, high speed dispersion is qualified to fineness, add emulsion, 1/2 defoamer, film coalescence aid, auxiliary rheological agents and thickening material then, be adjusted to appropriate viscosity, obtain the finished product elastic coating at last.
The present invention's fluorine carbon emulsion modified acroleic acid elastic emulsion, screen acidproof pigment, acid resistance filler simultaneously, after making the elastic coating of the present invention surperficial formation of plinth course outside coating, possess the weather resistance of fluorocarbon coating, acidproof rain and contamination resistance, the elasticity resistance to cleavage that possesses the vinylformic acid elastic coating simultaneously, the two mutual supplement with each other's advantages; Be aqueous product, reduced the VOC discharging, meet national requirements for environmental protection.
The invention will be further described below in conjunction with embodiment.
Embodiment
Embodiment 1
Formulation for coating material of the present invention is: 200.0g deionized water, 30.0g propylene glycol, 7.0g dispersion agent SN5027,2.0g multifunctional assistant AMP-95,3.0g defoamer NXZ, 1.0g card pine sanitas LXE, the anti-algae agent R-2000 of 2.0g mildew-resistant, 150.0g Rutile type Titanium Dioxide, 180.0g process white, 100.0g fluorine carbon emulsion, 300.0g acrylic elastic emulsion, 10.0g film coalescence aid alcohol ester-12,4.0g auxiliary rheological agents R-2020,8.0g thickening material TT-935.In water, add solubility promoter, dispersion agent, multifunctional assistant, 1/2 defoamer, sanitas, mildew-resistant anti-algae agent, Rutile type Titanium Dioxide and process white successively, high speed dispersion is qualified to fineness, add fluorine carbon emulsion and acrylic elastic emulsion, 1/2 defoamer, film coalescence aid, auxiliary rheological agents and thickening material then, be adjusted to appropriate viscosity, obtain the finished product elastic coating at last.
Embodiment 2
Formulation for coating material of the present invention is: 150.0g deionized water, 25.0g ethylene glycol, 8.0g dispersion agent SN5027,2.5g multifunctional assistant AMP-95,3.5g defoamer DFC165,1.5g BIT sanitas PROXELAQ, the anti-algae agent R-2000 of 4.0g mildew-resistant, 190.0g Rutile type Titanium Dioxide, 110.0g ultrafine quartz powder, 125.0g fluorine carbon emulsion, 350.0g acrylic elastic emulsion, 12.0g film coalescence aid phenylcarbinol, 5.0g auxiliary rheological agents R-2020,7.0g thickening material TT-935.Preparation process is with embodiment 1.
Embodiment 3
Formulation for coating material of the present invention is: 100.0g deionized water, 20.0g propylene glycol, 9.0g dispersion agent SN5027,3.0g multifunctional assistant AMP-95,4.0g defoamer NXZ, 2.0g BIT sanitas PROXELAQ, the anti-algae agent R-2000 of 6.0g mildew-resistant, 230.0g Rutile type Titanium Dioxide, 50.0g Feldspar Powder, 150.0g fluorine carbon emulsion, 400.0g acrylic elastic emulsion, 15.0g film coalescence aid butyl glycol ether, 6.0g auxiliary rheological agents R-2020,6.0g thickening material TT-935.Preparation process is with embodiment 1.
The performance such as the following table of embodiment gained elastic coating:
Elastic coating of the present invention is mainly used in the decoration and the protection of external wall basal plane; can form flat coating layer with supporting priming paint, also can be used as the finish coat that is coated with in elastic napping and the embossment, resist the crack of basic unit better; because of possessing super weather resistance, recommend to be used for the protection of Highrise buildings.
The above only is preferred embodiment of the present invention, is not technical scheme of the present invention is done any pro forma restriction.Every foundation technical spirit of the present invention all falls within the scope of protection of the present invention any simple modification, equivalent variations and modification that above embodiment did.
Claims (10)
1. watersoluble fluorine-carbon modified elastic paint for exterior wall of construction, the quality percentage composition of its each component is as follows: water 10-20%, solubility promoter 2-4%, dispersion agent 0.5-1.0%, multifunctional assistant 0.2-0.4%, defoamer 0.2-0.5%, sanitas 0.1-0.2%, algae agent 0.2-0.6%, acidproof pigment 15-23% are prevented in mildew-resistant, acid resistance filler 5-18%, fluorine carbon emulsion 10-15%, acrylic elastic emulsion 30-40%, film coalescence aid 1-1.5%, auxiliary rheological agents 0.3-0.8%, thickening material 0.5-1.0%.
2. coating according to claim 1 is characterized in that described solubility promoter selects propylene glycol or ethylene glycol for use.
3. coating according to claim 1 is characterized in that described dispersion agent selects the poly carboxylic acid ammonium salt for use.
4. coating according to claim 1 is characterized in that described defoamer selects mineral oils or organic-silicon-modified mineral oil defoaming agent for use.
5. coating according to claim 1 is characterized in that described sanitas selects the loose sanitas of card or 1,2-benzisothiazole-3-ketone for use.
6. coating according to claim 1 is characterized in that described acidproof pigment selects Rutile type Titanium Dioxide for use.
7. coating according to claim 1 is characterized in that described acid resistance filler selects process white, ultrafine quartz powder or Feldspar Powder for use.
8. coating according to claim 1 is characterized in that described film coalescence aid selects alcohol ester-12, phenylcarbinol or butyl glycol ether for use.
9. coating according to claim 1 is characterized in that described auxiliary rheological agents is a hydrophobically modified urethane rheology modifier.
10. coating according to claim 1 is characterized in that described thickening material is a hydrophobically modified caustic solubility thickening material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101620044A CN101402816B (en) | 2008-11-04 | 2008-11-04 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101620044A CN101402816B (en) | 2008-11-04 | 2008-11-04 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101402816A CN101402816A (en) | 2009-04-08 |
| CN101402816B true CN101402816B (en) | 2011-05-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2008101620044A Active CN101402816B (en) | 2008-11-04 | 2008-11-04 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
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Families Citing this family (21)
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| CN102876158A (en) * | 2011-07-11 | 2013-01-16 | 上海富臣化工有限公司 | Soft anti-stain elastic interior wall latex paint and preparation method thereof |
| CN102417772B (en) * | 2011-09-28 | 2013-11-27 | 上海市建筑科学研究院(集团)有限公司 | Environment-friendly type steel structure building fireproof anticorrosion composite coating and preparation method thereof |
| CN103102749A (en) * | 2012-11-13 | 2013-05-15 | 益阳祥瑞科技有限公司 | Waterborne fluorocarbon building coating |
| CN102964940B (en) * | 2012-12-04 | 2015-09-30 | 深圳市广田环保涂料有限公司 | A kind of aqueous elastic fluorocarbon coating and preparation method thereof |
| CN102993946B (en) * | 2012-12-11 | 2015-03-25 | 天津灯塔涂料工业发展有限公司 | Waterborne fluorine silicone resin modified acrylic acid concrete protective coating |
| CN104073083B (en) * | 2014-06-17 | 2016-06-08 | 江苏科技大学 | A kind of aqueous elastic fluorine carbon building coating and its preparation method |
| CN104559592A (en) * | 2014-12-19 | 2015-04-29 | 北京东方雨虹防水技术股份有限公司 | Fluorocarbon elastic paint and preparation method thereof |
| CN104987785B (en) * | 2015-05-07 | 2017-10-24 | 重庆市品胜涂料有限公司 | A kind of fluorocarbon paint for external wall and preparation method thereof |
| CN105062249A (en) * | 2015-09-07 | 2015-11-18 | 无锡市嘉邦电力管道厂 | Water-based fluorocarbon-modified elastic architectural external wall paint and preparation method thereof |
| CN105462314A (en) * | 2015-12-15 | 2016-04-06 | 三棵树涂料股份有限公司 | High-cost-performance and high-stain-resistance elastic flat-coating emulsion paint and preparation method thereof |
| CN106366790A (en) * | 2016-08-31 | 2017-02-01 | 常熟市优德爱涂料有限公司 | Elastic fluorocarbon emulsion paint and preparation method thereof |
| CN106752549A (en) * | 2016-12-03 | 2017-05-31 | 范林虎 | A kind of self-cleaning aqueous coating and preparation method thereof |
| CN107150018A (en) * | 2017-05-12 | 2017-09-12 | 黎茂活 | Infrared curing equipment |
| CN108976935A (en) * | 2018-06-08 | 2018-12-11 | 浙江安吉朝辉新材料有限公司 | A kind of aqueous fluorocarbon coating |
| CN109021832A (en) * | 2018-06-12 | 2018-12-18 | 佛山市华强协兴陶瓷有限公司 | A kind of environmental-friendly construction material of antimycotic antiseptic |
| CN108727980A (en) * | 2018-07-09 | 2018-11-02 | 合肥择浚电气设备有限公司 | A kind of preparation method of coating used for building exterior wall |
| CN111440489A (en) * | 2019-01-17 | 2020-07-24 | 广东顺德三和化工有限公司 | Fluorocarbon-acrylic acid building waterproof coating and preparation method thereof |
| CN110628288A (en) * | 2019-09-23 | 2019-12-31 | 成都彭州立源高分子材料有限公司 | Water-based single-component fluorocarbon paint and preparation method thereof |
| CN111153645A (en) * | 2019-12-28 | 2020-05-15 | 刘万凯 | Preparation method of antibacterial and anticorrosive coating |
| CN111099547B (en) * | 2019-12-31 | 2021-12-21 | 广东润立新材科技有限公司 | Building exterior wall water-based paint process system, paint formula and preparation process thereof |
| CN114836097B (en) * | 2022-06-07 | 2023-06-09 | 广东美涂士建材股份有限公司 | Multifunctional nano building exterior wall coating and preparation method thereof |
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| CN101168627A (en) * | 2006-10-29 | 2008-04-30 | 董善刚 | Single-layer contamination-resisting highly effective water-proof elastic dope |
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2008
- 2008-11-04 CN CN2008101620044A patent/CN101402816B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101168627A (en) * | 2006-10-29 | 2008-04-30 | 董善刚 | Single-layer contamination-resisting highly effective water-proof elastic dope |
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| CN101402816A (en) | 2009-04-08 |
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