CN104073083B - A kind of aqueous elastic fluorine carbon building coating and its preparation method - Google Patents

A kind of aqueous elastic fluorine carbon building coating and its preparation method Download PDF

Info

Publication number
CN104073083B
CN104073083B CN201410271184.5A CN201410271184A CN104073083B CN 104073083 B CN104073083 B CN 104073083B CN 201410271184 A CN201410271184 A CN 201410271184A CN 104073083 B CN104073083 B CN 104073083B
Authority
CN
China
Prior art keywords
ether
emulsion
ultrafine
fluorine carbon
stir
Prior art date
Application number
CN201410271184.5A
Other languages
Chinese (zh)
Other versions
CN104073083A (en
Inventor
郭文录
闫秀芬
王超
Original Assignee
江苏科技大学
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 江苏科技大学 filed Critical 江苏科技大学
Priority to CN201410271184.5A priority Critical patent/CN104073083B/en
Publication of CN104073083A publication Critical patent/CN104073083A/en
Application granted granted Critical
Publication of CN104073083B publication Critical patent/CN104073083B/en

Links

Abstract

The present invention discloses a kind of aqueous elastic fluorine carbon building coating and its preparation method, described coating by mass percentage content by component: water is 16-31%, self-control elastic fluorocarbon building emulsion is 40-60%, and efficient film coalescence aid JS-PPH (302) is 2-6%, ultra-fine rutile TiO2For 5-10%, superfine talcum powder is 1-5%, ultrafine quartz powder is 1-5%, ultrafine kaolin is 1-5%, ultrafine heavy calcium powder is 1-5%, and high force dispersion agent is 0.1��0.5%, and multi-functional thickening material is 0.1-0.5%, silicone antifoam agent JS-2010S is 0.1��0.4%, and strong disinfecting sanitas 981 is 0.1-0.4% composition. Described preparation method is first preparation self-control elastic fluorocarbon building emulsion, then prepares aqueous elastic fluorine carbon building coating. The coating environmental protection of the present invention, have that the weathering resistance of overlength, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, snappiness are good, the advantage such as scrubbing resistance, elongation at break, tensile strength, preparation technology of the present invention is simple, easy to operate, preparation efficiency height, production cost is low, and the market competitiveness is strong.

Description

A kind of aqueous elastic fluorine carbon building coating and its preparation method
Technical field
The invention belongs to technical field of coatings, it relates to a kind of building coating, more specifically relate to a kind of aqueous elastic fluorine carbon building coating and its preparation method. The coating of the present invention is mainly used in outer wall building coating field.
Background technology
At present at building field, the brushing of newly-built external walls of building coating and the maintenance of aging blocks room refresh in the painting process of exterior coating, normally used are mostly fluorine carbon building coating. Existing this kind of coating due to its snappiness poor; when being subject to when affecting of the unfavorable factors such as outside climatic, its building surface often can produce crack phenomenon, and along with strengthening further gradually in its crack of time lengthening; thus buildings can be had a negative impact, even adverse consequences. Therefore, this is extremely paid close attention to and payes attention to by the scientific research personnel relevant to building field, one to since thirst for a kind of snappiness that can improve existing fluorine carbon building coating of development, novel aqueous elastic fluorine carbon building coating, thus overcome and solve the phenomenon that body of wall is covered with paint, lacquer, colour wash, etc. rear coating and easily ftractureed. And the aqueous elastic fluorine carbon building coating not only environmental protection requiring this novel, the more important thing is that the weathering resistance with overlength, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, snappiness are good, the advantage such as scrubbing resistance, elongation at break, tensile strength.
Summary of the invention
It is an object of the invention to as overcoming and solve the poor defect of snappiness and the problem that existing fluorine carbon building coating exists, it is provided that a kind of aqueous elastic fluorine carbon building coating and its preparation method. The not only environmental protection of this coating, the more important thing is that the weathering resistance with overlength, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, snappiness are good, the advantage such as scrubbing resistance, elongation at break, tensile strength.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of aqueous elastic fluorine carbon building coating, content is by component by mass percentage: water is 16-31%, and self-control elastic fluorocarbon building emulsion is 40-60%, and efficient film coalescence aid JS-PPH (302) is 2-6%, ultra-fine rutile TiO2For 5-10%, superfine talcum powder is 1-5%, ultrafine quartz powder is 1-5%, ultrafine kaolin is 1-5%, ultrafine heavy calcium powder is 1-5%, and high force dispersion agent is 0.1��0.5%, and multi-functional thickening material is 0.1-0.5%, silicone antifoam agent JS-2010S is 0.1��0.4%, and strong disinfecting sanitas 981 is 0.1-0.4% composition.
Wherein, described self-control elastic fluorocarbon building emulsion by mass percentage content by component: deionized water is 38%, vinylidene fluoride is 20%, trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, N hydroxymethyl acrylamide is 0.8%, ethylene glycol monoallyl ether is 1%, and vinyl propyl ether is 5%, and isopropyl-ethylene base ether is 4.2%, sodium lauryl sulphate is 0.8%, polyoxyethylene nonylphenol ether OP-10 is 1.5%, and Ammonium Persulfate 98.5 is 0.2%, and sodium bisulfite is 0.5% composition.
Described ultra-fine rutile TiO2, superfine talcum powder, ultrafine quartz powder, ultrafine kaolin, the particle diameter of ultrafine heavy calcium powder is 1250 order sieves.
For achieving the above object, another technical scheme that the present invention takes is:
The preparation method of a kind of aqueous elastic fluorine carbon building coating of the present invention, comprises the following steps:
The preparation method of step 1, described self-control elastic fluorocarbon building emulsion, concrete steps are:
(1) by formula metering by 1/2 deionized water, the hydroxyethyl methylacrylate of 1/2, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsification emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, when the high-speed stirring of 1000-2700r/min, add deionized water and whole ammonium persulphates and the sodium bisulfite of remaining 1/2 respectively, lead to nitrogen in a kettle. to stir for 4-8 time after evenly, it is warming up to 65-75 DEG C, add the hydroxyethyl methylacrylate of remaining 1/2 more respectively, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 stirs 50-60min, pH �� 7-8,
(3) then whole vinylidene fluorides and trifluorochloroethylene is added respectively again by formula metering, it is raised to 90-110 DEG C in temperature, reactor pressure is stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h, namely obtains aqueous elastic fluorine carbon building emulsion.
The preparation of step 2, described aqueous elastic fluorine carbon building coating, concrete steps are:
(1) when stirring with the rotating speed of 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO2, superfine talcum powder add in container, stir 20-25min;
(2) when stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added to stir 35-40min in container more even;
(3) add multi-functional thickening material more respectively, high force dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stir 40-50min, namely obtain aqueous elastic fluorine carbon building coating.
The advantage that the present invention has compared with prior art and useful effect be mainly:
1, the coating of the present invention not only environmental protection, the more important thing is that the weathering resistance with overlength, artificial ageing resistance, acid and alkali-resistance, resistance to soiling, chemical-resistant, strong adhesion, snappiness are good, the advantage such as scrubbing resistance, elongation at break, tensile strength.
2, the Paint preparation technology of the present invention is simple, and easy to operate, preparation efficiency height, production cost is low, and the market competitiveness is strong.
Embodiment
The technical scheme of the present invention is further described below in conjunction with specific embodiment:
The source of each component: water, elastic fluorocarbon building emulsion (self-control), efficient film coalescence aid JS-PPH (302) (Shanghai Jin Shan Chemical Co., Ltd. technical grade product), ultra-fine rutile TiO21250 orders (Langfang Lan Ke Chemical Co., Ltd. technical grade product), ultrafine quartz powder 1250 order (sea otter Wei Fen factory of Henan Province technical grade product), superfine talcum powder 1250 order (Changxing Qing Shenggai industry company limited technical grade product), ultrafine kaolin (Yangzhou Di Lan industrial chemicals company limited technical grade product), ultrafine heavy calcium powder (Sheng Hua fine chemistry industry technical grade product), multi-functional thickening material (Beijing Gongda Weiye Sci-Tech Research Center's technical grade product), high force dispersion agent (Beijing Gongda Weiye Sci-Tech Research Center's technical grade product), strong disinfecting sanitas 981 (Shanghai Ji Yi Chemical Co., Ltd. technical grade product), silicone antifoam agent JS-2010S (Shanghai Jin Shan Chemical Co., Ltd. technical grade product).
One, the mass percent content of embodiment 15 recipe ingredient is as shown in the table:
Two, the preparation method of embodiment 15, step is as follows:
The preparation method of step 1, described self-control elastic fluorocarbon building emulsion, concrete steps are:
(1) being 38% by formulation deionised water, vinylidene fluoride is 20%, and trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, and N hydroxymethyl acrylamide is 0.8%, and ethylene glycol monoallyl ether is 1%, vinyl propyl ether is 5%, isopropyl-ethylene base ether is 4.2%, and sodium lauryl sulphate is 0.8%, and polyoxyethylene nonylphenol ether OP-10 is 1.5%, Ammonium Persulfate 98.5 is 0.2%, and sodium bisulfite is 0.5%. First by wherein 1/2 deionized water, the hydroxyethyl methylacrylate of 1/2, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsification emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, when the high-speed stirring of 1000-2700r/min, add deionized water and whole ammonium persulphates and the sodium bisulfite of remaining 1/2 respectively, lead to nitrogen in a kettle. to stir for 4-8 time after evenly, it is warming up to 65-75 DEG C, add the hydroxyethyl methylacrylate of remaining 1/2 more respectively, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 stirs 50-60min, pH �� 7-8,
(3) then whole vinylidene fluorides and trifluorochloroethylene is added respectively again by formula metering, it is raised to 90-110 DEG C in temperature, reactor pressure is stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h, namely obtains aqueous elastic fluorine carbon building emulsion.
The preparation of step 2, described aqueous elastic fluorine carbon building coating, concrete steps are:
(1) when stirring with the rotating speed of 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO2, superfine talcum powder add in container, stir 20-25min;
(2) when stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added to stir 35-40min in container more even;
(3) add multi-functional thickening material more respectively, high force dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stir 40-50min, namely obtain aqueous elastic fluorine carbon building coating.
Three, embodiment 15 products obtained therefrom performance test results is as shown in the table:

Claims (3)

1. an aqueous elastic fluorine carbon building coating, it is characterised in that, content is by component by mass percentage: water is 16-31%, and self-control elastic fluorocarbon building emulsion is 40-60%, and efficient film coalescence aid JS-PPH (302) is 2-6%, ultra-fine rutile TiO2For 5-10%, superfine talcum powder is 1-5%, ultrafine quartz powder is 1-5%, ultrafine kaolin is 1-5%, ultrafine heavy calcium powder is 1-5%, and high force dispersion agent is 0.1��0.5%, and multi-functional thickening material is 0.1-0.5%, silicone antifoam agent JS-2010S is 0.1��0.4%, and strong disinfecting sanitas 981 is 0.1-0.4% composition;
Wherein, described self-control elastic fluorocarbon building emulsion by mass percentage content by component: deionized water is 38%, vinylidene fluoride is 20%, trifluorochloroethylene is 10%, hydroxyethyl methylacrylate is 10%, methyl methacrylate is 8%, N hydroxymethyl acrylamide is 0.8%, ethylene glycol monoallyl ether is 1%, and vinyl propyl ether is 5%, and isopropyl-ethylene base ether is 4.2%, sodium lauryl sulphate is 0.8%, polyoxyethylene nonylphenol ether OP-10 is 1.5%, and ammonium persulphate is 0.2%, and sodium bisulfite is 0.5% composition, and by first press formula metering by 1/2 deionized water, the hydroxyethyl methylacrylate of 1/2, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsion, then the emulsion after emulsification is poured in reactor, when the high-speed stirring of 1000-2700r/min, add deionized water and whole ammonium persulphates and the sodium bisulfite of remaining 1/2 respectively, lead to nitrogen in a kettle. to stir for 4-8 time after evenly, it is warming up to 65-75 DEG C, add the hydroxyethyl methylacrylate of remaining 1/2 more respectively, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 stirs 50-60min, pH=7-8, adding whole vinylidene fluorides and trifluorochloroethylene respectively again by formula metering again, be raised to 90-110 DEG C in temperature, reactor pressure is stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h obtains self-control elastic fluorocarbon building emulsion.
2. a kind of aqueous elastic fluorine carbon building coating according to claim 1, it is characterised in that, described ultra-fine rutile TiO2, superfine talcum powder, ultrafine quartz powder, the particle diameter of ultrafine kaolin and ultrafine heavy calcium powder is 1250 order sieves.
3. the preparation method of an aqueous elastic fluorine carbon building coating according to claim 1, it is characterised in that, comprise the following steps:
Step one, self-control elastic fluorocarbon building emulsion, step is:
(1) by formula metering by 1/2 deionized water, the hydroxyethyl methylacrylate of 1/2, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 adds in emulsification container, with the rotating speed stirring at low speed 25-30min of 700-900r/min, obtain emulsion;
(2) emulsion after step (1) emulsification is poured in reactor, when the high-speed stirring of 1000-2700r/min, add deionized water and whole ammonium persulphates and the sodium bisulfite of remaining 1/2 respectively, lead to nitrogen in a kettle. to stir for 4-8 time after evenly, it is warming up to 65-75 DEG C, add the hydroxyethyl methylacrylate of remaining 1/2 more respectively, the methyl methacrylate of 1/2, the N hydroxymethyl acrylamide of 1/2, the ethylene glycol monoallyl ether of 1/2, the vinyl propyl ether of 1/2, the isopropyl-ethylene base ether of 1/2, the sodium lauryl sulphate of 1/2, the polyoxyethylene nonylphenol ether OP-10 of 1/2 stirs 50-60min, pH=7-8,
(3) then whole vinylidene fluorides and trifluorochloroethylene is added respectively again by formula metering, it is raised to 90-110 DEG C in temperature, reactor pressure is stir under 0.7-1.0MPa, and cooling decompression after insulation reaction 10-152h, namely obtains aqueous elastic fluorine carbon building emulsion;
Step 2, preparing aqueous elastic fluorine carbon building coating, step is:
1) when stirring with the rotating speed of 700-900r/min, by formula metering respectively by water, ultra-fine rutile TiO2, superfine talcum powder add in container, stir 20-25min;
2) when stirring with 1000-2700r/min rotating speed, by formulating of recipe amount, self-control elastic fluorocarbon building emulsion is added in container, continue to stir 30-35min, then respectively ultrafine quartz powder, ultrafine kaolin, ultrafine heavy calcium powder, efficient film coalescence aid JS-PPH (302) are added to stir 35-40min in container more even;
3) add multi-functional thickening material more respectively, high force dispersion agent, silicone antifoam agent JS-2010S, strong disinfecting sanitas 981, stir 40-50min, namely obtain aqueous elastic fluorine carbon building coating.
CN201410271184.5A 2014-06-17 2014-06-17 A kind of aqueous elastic fluorine carbon building coating and its preparation method CN104073083B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201410271184.5A CN104073083B (en) 2014-06-17 2014-06-17 A kind of aqueous elastic fluorine carbon building coating and its preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201410271184.5A CN104073083B (en) 2014-06-17 2014-06-17 A kind of aqueous elastic fluorine carbon building coating and its preparation method

Publications (2)

Publication Number Publication Date
CN104073083A CN104073083A (en) 2014-10-01
CN104073083B true CN104073083B (en) 2016-06-08

Family

ID=51594701

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201410271184.5A CN104073083B (en) 2014-06-17 2014-06-17 A kind of aqueous elastic fluorine carbon building coating and its preparation method

Country Status (1)

Country Link
CN (1) CN104073083B (en)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062249A (en) * 2015-09-07 2015-11-18 无锡市嘉邦电力管道厂 Water-based fluorocarbon-modified elastic architectural external wall paint and preparation method thereof
CN105462388A (en) * 2016-01-09 2016-04-06 安徽万诚达新型材料有限公司 Weather resistance type elastic waterborne fluorocarbon coating and preparation method thereof
CN106497253A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of a kind of energy-saving fluorine carbon and preparation method thereof
CN106380950A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Ultrahigh-durability fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106497256A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof
CN106380949A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Fluorocarbon heat insulation radiation type paint and preparation method thereof
CN106519826A (en) * 2016-09-23 2017-03-22 安徽吉思特智能装备有限公司 Waterproof heat-insulating radiation fluorocarbon coating material and preparation method thereof
CN106519827A (en) * 2016-09-23 2017-03-22 安徽吉思特智能装备有限公司 Self-cleaning fluorine-carbon heat-insulation radiation type coating material and preparation method thereof
CN106380946A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Antibacterial fluorocarbon heat insulation radiation type paint and preparation method thereof
CN106519824A (en) * 2016-09-23 2017-03-22 安徽吉思特智能装备有限公司 Alcoholic hydroxyl group-resisting fluoro-carbon heat-radiation-isolating coating material and preparation method thereof
CN106497254A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of a kind of corrosion resistant fluorine carbon and preparation method thereof
CN106497255A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the fluorine carbon of a kind of glass fiber reinforcement and preparation method thereof
CN106380947A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Nano-silicon-nitride-modified fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106497251A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the fluorine carbon of a kind of modified zinc oxide and preparation method thereof
CN106519825A (en) * 2016-09-23 2017-03-22 安徽吉思特智能装备有限公司 Fly ash microsphere-based fluorocarbon thermal insulation radiation coating and preparation method thereof
CN106497252A (en) * 2016-09-23 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the modified fluorine carbon of a kind of atlapulgite and preparation method thereof
CN106380948A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Wear-resistant fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106479286A (en) * 2016-09-23 2017-03-08 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked and preparation method thereof
CN106479289A (en) * 2016-09-23 2017-03-08 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the strong fluorine carbon of a kind of adhesive force and preparation method thereof
CN106380951A (en) * 2016-09-23 2017-02-08 安徽吉思特智能装备有限公司 Sun-resistant fluorocarbon heat-insulation radiation-type paint and preparation method thereof
CN106497257A (en) * 2016-09-27 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the enhanced fluorine carbon of a kind of Titanium Dioxide and preparation method thereof
CN106497258A (en) * 2016-09-27 2017-03-15 安徽吉思特智能装备有限公司 Heat-insulated radial pattern coating of the fluorine carbon of a kind of low-surface-energy and preparation method thereof
CN106752605A (en) * 2016-11-17 2017-05-31 上海衡峰氟碳材料有限公司 A kind of novel aqueous fluorocarbon coating
CN107418341A (en) * 2017-09-26 2017-12-01 安徽喜宝高分子材料有限公司 A kind of resistant fluorine carbon wall finiss and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2668157B1 (en) * 1990-10-19 1993-01-08 Atochem Fluorinable curable copolymer, manufacturing method thereof and application thereof in varnishes and paints.
CN1861648A (en) * 2006-06-16 2006-11-15 青岛宏丰氟硅科技有限公司 Mfg. process and tech. of fluorine carbon emulsion for paint
CN101121841A (en) * 2007-09-11 2008-02-13 江苏科技大学 Water exterior wall paint and its preparing process
CN101402816B (en) * 2008-11-04 2011-05-18 杭州传化涂料有限公司 Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction

Also Published As

Publication number Publication date
CN104073083A (en) 2014-10-01

Similar Documents

Publication Publication Date Title
CN103436136B (en) Waterborne anti-corrosive primer for the application of crane outside surface of a kind of ambient temperature curable and preparation method thereof
CN103319965B (en) A kind of automobile water-based property metal flash paint and preparation method thereof
CN104558447B (en) Inorganic nano composite anti-doodling resin and preparation method thereof
CN101215438B (en) Anti-soiling aging-resisting stainless steel paint and preparation method thereof
CN106433364A (en) Superhydrophobicity coating based on waterborne emulsion and preparing method and application thereof
CN103254710B (en) A kind of batch of scratch-type water-in-water multicolor coating and preparation method thereof
CN101735700B (en) Heat-reflecting insulating coating for outer surface of building and preparation method thereof
CN103483895A (en) Powder paint capable of increasing coating rate for dead angle of metal workpiece and preparation method of powder paint
CN103788787A (en) Single-component water-based natural drying finishing coat for construction crane and preparation method thereof
CN102675998B (en) Water-based fluorocarbon top coat for wind-powered blades and method for preparing water-based fluorocarbon top coat
CN104941894B (en) Aluminum profile spraying technology
CN104313608A (en) Environment-friendly aluminum cleaning agent and preparation method thereof
CN1460697A (en) Weatherability self-cleaning external wall coating material and its preparation method
CN103602183A (en) Fast-curing indentation-proof water-based paint for galvanized sheet and preparation method thereof
CN104419315A (en) Waterborne metal anticorrosive coating
WO2013020345A1 (en) All-in-one water-borne inorganic-organic hybrid architectural coating and method for preparing same
CN104334657B (en) Prepare the method for polychrome dispersion and by its obtained polychrome dispersion
CN106118365B (en) A kind of shock resistance Cold resistant paint and preparation method thereof based on graphene powder
CN103333596B (en) Fluorinated silicone modified acrylic cathodic electrophoretic coating of a kind of automatically cleaning and preparation method thereof
CN101659825B (en) Double-component aqueous nano scratch resistant wood coating and method for producing same
CN104231901B (en) A kind of aqueous elastic handfeel paint and preparation method thereof
CN104962143B (en) A kind of water-based fluorocarbon antifouling flush paint and its preparation method and application
CN102627903B (en) Environment-friendly water-based static electricity conductive corrosion-resistant coating and preparation method thereof
CN101560078B (en) External wall heat-insulating coating
CN104087089A (en) Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180913

Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: 212003 Mengxi Road, Jingkou District, Zhenjiang, Jiangsu Province, No. 2

Patentee before: Jiangsu University of Science and Technology

Effective date of registration: 20180913

Address after: No. 1, Chengyang street, Xushui District, Baoding, Hebei

Patentee after: Hebei Chenyang IndustrialL&trade Group Co., Ltd.

Address before: 212003 Mengxi Road, Jingkou District, Zhenjiang, Jiangsu Province, No. 2

Patentee before: Jiangsu University of Science and Technology

PP01 Preservation of patent right
PP01 Preservation of patent right

Effective date of registration: 20200929

Granted publication date: 20160608