CN109401374A - The aqueous inorganic paint and preparation method thereof of high resistant high rigidity - Google Patents
The aqueous inorganic paint and preparation method thereof of high resistant high rigidity Download PDFInfo
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- CN109401374A CN109401374A CN201811287145.9A CN201811287145A CN109401374A CN 109401374 A CN109401374 A CN 109401374A CN 201811287145 A CN201811287145 A CN 201811287145A CN 109401374 A CN109401374 A CN 109401374A
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- thickener
- aqueous inorganic
- inorganic paint
- high rigidity
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous inorganic paints of high resistant high rigidity, and by weight, formula includes the following raw material component: 10~30 parts of inorganic silicic acid salt resin；Styrene-acrylic emulsion or 5~20 parts of emulsion acrylic resin；1~10 part of silane coupling agent；8~20 parts of titanium dioxide；0.3~0.7 part of dispersing agent；0.5~6.5 part of thickener；Appropriate pure water.Not only high resistance to soiling, high rigidity, covering power are good for the film of aqueous inorganic paint obtained by the present invention, adhesive force is good, also there is fabulous antibacterial to remove aldehyde effect, whiteness, weatherability characteristics.
Description
Technical field
The invention belongs to building coating fields to relate more particularly to a kind of high more particularly to a kind of coating for internal and external wall
The aqueous inorganic paint and preparation method thereof of resistant high rigidity.
Background technique
Current aqueous inorganic paint on the market and traditional coating for internal and external wall performance difference are little, all there is resistance to soiling
Difference, hardness of paint film is general, so that service life is shorter, just needs to renovate recoating, the wastings of resources such as human and material resources after coating several years
Seriously, pollution is also generated to environment.
In order to reduce because of architectural finish number, reduces because of environmental pollution brought by multiple coating, need to develop one
The aqueous inorganic paint of kind anti-pollution high rigidity.
Summary of the invention
In order to solve the above technical problems existing in the prior art, the present invention provides a kind of the aqueous of high resistant high rigidity
Inorganic coating.
Technical purpose of the invention is to be achieved through the following technical solutions:
By weight, the formula of aqueous inorganic paint of the present invention includes the following raw material component:
Further, by weight, the formula of aqueous inorganic paint of the present invention also includes the following raw material component: function
It can be 2~5 parts of auxiliary agent of property.
Further, by weight, the formula of aqueous inorganic paint of the present invention also includes the following raw material component:
Further, by weight, the formula of aqueous inorganic paint of the present invention also includes the following raw material component:
Preferably, inorganic silicic acid salt resin of the present invention is selected from Switzerland vanBaerleINOCOT 330 or rattan is trained in Xiamen
The MOS-1010 of material；The styrene-acrylic emulsion or emulsion acrylic resin are selected from the styrene-acrylic emulsion AcronalECO- of BASF
The acrylic emulsion Archsol 8016 of 502ap or the China of styrene-acrylic emulsion RS-752D or ten thousand chemistry of Ahmedabad richness；It is described silane coupled
Agent is selected from the LT-560 in the new blue sky Z-6030 or Hubei of DOW CORNING.
Preferably, thickener of the present invention includes the first thickener and the second thickener, and first thickener is selected from
The 250HBR of Ya Shilan or carefree BK30；Second thickener is selected from the Vesmody U300 or DOW Chemical of ten thousand China's chemistry
RM2020；The dispersing agent be modified phosphonic acids saline solution, be selected from Switzerland vanBaerleINOCOT 930；The titanium
White powder is selected from rutile titanium dioxide pigment, selected from E.I.Du Pont Company R-706, the R-216 of center titanium white company or one hundred benefit connection of imperial boa
The R996 of group company.
Preferably, the quality of the first thickener and the second thickener of the present invention is (0.2~0.5) than range: (1.5
~4.5)；The functional aid is aldehyde remover and/or fungus and mildew resistance algaecide；Preferably, the aldehyde remover be selected from know it is clear (on
Sea) new material MAP-1000；The fungus and mildew resistance algaecide is selected from the ZOE-2X that dragon desertification is learned；The pigments and fillers are selected from heavy
One or more of calcium carbonate, mica powder, precipitated sulfur, silica flour substance.
Preferably, the pigments and fillers of the present invention are selected from powdered whiting, mica powder, precipitated sulfur and silica flour, heavy
Measure part ratio range 5: 4: 3:(12~16)；The powdered whiting partial size is 600~2000 mesh, the mica powder partial size is
800~3000 mesh, the precipitated sulfur partial size be 800~3000 mesh, the precipitated sulfur partial size be 800~3000 mesh；It is described steady
Determine agent and is selected from Switzerland vanBaerleINOCOT 925 or Clariant Dispersogen SPS；The anti-settling agent is bentonite, choosing
From BASF Attagel 40；The defoaming agent is selected from Switzerland vanBaerle INOCOT 935.
Another technical object of the present invention is to provide a kind of preparation method of the aqueous inorganic paint of high resistant high rigidity, packets
Include following steps:
1) weighs each component raw material by formula ratio；
2) pure water, the first thickener, dispersing agent are uniformly dispersed by, then put into titanium dioxide, high speed dispersion to fineness≤50
Micron, it is spare；
3) adds inorganic silicic acid salt resin, styrene-acrylic emulsion or emulsion acrylic resin, silane coupling agent and the second thickening
Agent, low speed disperse 20~30min, filtering to get.
Further, in step 2) of the present invention, addition dispersing agent adds the defoaming agent simultaneously, and it is same to add the titanium dioxide
Shi Tianjia anti-settling agent and the pigments and fillers；The revolving speed of high speed dispersion is 1200~1500 revs/min；Low speed dispersion revolving speed be
400~600 revs/min.
The present invention is using the above-mentioned attainable beneficial effect of technical solution:
By adding inorganic silicic acid salt resin, so that the aqueous inorganic paint of the high resistant high rigidity is with resistance to well
Time property and hardness, and add the anti-pollution characteristic that silane coupling agent can improve the aqueous inorganic paint product of the high resistant high rigidity
And hardness；By adding functional aid, so that product has antibacterial except performances such as aldehyde.
Specific embodiment
Below by way of specific preferred embodiment, invention is further described in detail, but the present invention be not limited in it is following
Embodiment.
Inorganic silicic acid salt resin, styrene-acrylic emulsion or the emulsion acrylic resin conduct in the coating system that the present invention uses
Film forming matter.Inorganic silicic acid salt resin has very high hardness, endurance and anti-yellowing property, and can be with ground (concrete wall surface)
In mineral substrate generation petrifaction, the silica surface layer of a kind of waterproof and acid-proof is formed, as matrix resin, styrene-acrylic emulsion
Or emulsion acrylic resin has good flexibility and anti-yellowing property, improves inorganic silicic acid salt resin as assisted resin
Brittleness.
Titanium dioxide mainly provides covering power and whiteness in system, and rutile titanium dioxide pigment is to the absorption of ultraviolet light, anti-
Penetrate weaker than anatase titanium dioxide, and covering power and tinting strength, tinting power are preferable, and titanium dioxide of the present invention uses rutile titanium dioxide pigment.System
Used in pigments and fillers primarily serve reduction product cost, adjustment working viscosity and adjustment film performance.Coating is in production and construction
Bubble can be generated in the process, and the presence of bubble will lead to film and generate defect, need defoaming agent to improve, defoaming agent can mention
For good defoaming effect.
Suitable thickener is added in formulation for coating material, and the viscosity and flow leveling of coating can be improved.Stabilizer can make
Viscosity of the coating of the invention tends towards stability, and is not in gelatinization phenomenon.Paint film can be improved using silane coupling agent in the present invention
With the adhesive force of ground, and the consistency of paint film can be improved, to improve the hardness and anti-pollution characteristic of paint film.It is added in the present invention
With antibacterial except the functional aid of aldehyde function makes coating have the function of antibacterial except aldehyde.It is in coating storage and work progress
Anti-settling resist sagging, the present invention add appropriate bentonite anti-settling agent.
One, the aqueous inorganic paint of high resistant high rigidity
The raw material components and formulation by weight (unit: kg) of Examples 1 to 5 and reference examples 1~2 are as shown in table 1.
Each starting components that 1 Examples 1 to 5 of table and reference examples 1~2 are formulated
Two, the preparation method of the aqueous inorganic paint of high resistant high rigidity
The high resistant antibacterial of Examples 1 to 5 removes the preparation method of aldehyde inorganic coating comprising following steps:
Step 1, each component is weighed by 1 weight percent of above table.
Step 2, deionized water, defoaming agent, dispersing agent and the first thickener in component are successively put into and disperses 5 in dispersion cylinder
Minute, then successively put into anti-settling agent, titanium dioxide and other pigments and fillers, 20~30 points of high speed dispersion to fineness≤50 micron, it is standby
With.
Step 3, remaining component successively being put into dispersion cylinder, low speed disperses 20~30 minutes, 200 mesh filter-cloth filterings,
Up to the high resistant high rigidity aqueous inorganic paint.
The preparation method of reference examples 1~2 is referred to the preparation method of Examples 1 to 5.
Three, performance detection
Through detecting, the high resistant high-hardness inorganic coating of Examples 1 to 5 preparation, color appearance is white liquid, solid content
It is 80~120KU (25 DEG C) for 55%~72%, fineness≤50 micron, viscosity.
By the formula of Examples 1 to 5 by aqueous inorganic paint obtained by above-mentioned preparation method, its Physical properties of coating film energy is detected
As shown in table 2, and the Physical properties of coating film energy of reference examples 1~2 is detected, as shown in table 2.
2 Physical properties of coating film test result of table
From table 2 it can be seen that high resistant high-hardness inorganic coating products described in Examples 1 to 5 contaminated resistance (≤
8%；≤ 7%；≤ 6%；≤ 5%；≤ 4%) than reference examples 1~2 (≤20%；It≤25%) will be well very much；Examples 1 to 5
The hardness of paint films (2H, 2H, 3H, 4H, 4H) of the high resistant high-hardness inorganic coating products and weatherability than reference examples 1~2 (H,
H) also well very much, and also have many advantages, such as preferable antibacterial except aldehyde function, adhesive force, covering power, good whiteness, weatherability (0
Grade represents no mould and generates, and 5 grades represent all long moulds).
The above described is only a preferred embodiment of the present invention, be not intended to limit the present invention in any form, therefore
Without departing from the technical solutions of the present invention, to the above embodiments according to the technical essence of the invention any simply to repair
Change, equivalent variations and modification, all of which are still within the scope of the technical scheme of the invention.
Claims (10)
1. a kind of aqueous inorganic paint of high resistant high rigidity, which is characterized in that by weight, formula includes the following raw material
Component:
2. the aqueous inorganic paint of high resistant high rigidity according to claim 1, which is characterized in that by weight, match
Side also includes the following raw material component: 2~5 parts of functional aid.
3. high resistant high rigidity aqueous inorganic paint according to claim 1 or claim 2, which is characterized in that by weight, match
Side also includes the following raw material component:
4. the aqueous inorganic paint of high resistant high rigidity according to claim 3, which is characterized in that by weight,
Formula includes the following raw material component:
5. aqueous inorganic paint described according to claim 1~any one of 4, which is characterized in that the inorganic silicate
Resin is selected from the MOS-1010 of Switzerland vanBaerleINOCOT 330 or Xiamen training rattan material；The styrene-acrylic emulsion or acrylic acid
Resin emulsion is selected from the styrene-acrylic emulsion AcronalECO-502ap of BASF or the styrene-acrylic emulsion RS-752D or Wan Huahua of Ahmedabad richness
Acrylic emulsion Archsol 8016；The silane coupling agent is selected from the LT- in the new blue sky Z-6030 or Hubei of DOW CORNING
560。
6. aqueous inorganic paint described according to claim 1~any one of 4, which is characterized in that the thickener includes
First thickener and the second thickener, first thickener are selected from the 250HBR or carefree BK30 of Ya Shilan；Described second
Thickener is selected from the Vesmody U300 of the ten thousand China's chemistry or RM2020 of DOW Chemical；The dispersing agent be modified phosphonate
Aqueous solution is selected from Switzerland vanBaerleINOCOT 930；The titanium dioxide is selected from rutile titanium dioxide pigment, is selected from Du Pont
The R996 of company R-706, the R-216 of center titanium white company or dragon Mang Baililian group company.
7. aqueous inorganic paint according to claim 3, which is characterized in that the quality of the first thickener and the second thickener
It is (0.2~0.5): (1.5~4.5) than range；The functional aid is aldehyde remover and/or fungus and mildew resistance algaecide；It is preferred that
Ground, the aldehyde remover are selected from the MAP-1000 for knowing clear (Shanghai) new material；The fungus and mildew resistance algaecide is selected from what dragon desertification was learned
ZOE-2X；The pigments and fillers are selected from one or more of powdered whiting, mica powder, precipitated sulfur, silica flour substance.
8. aqueous inorganic paint according to claim 7, which is characterized in that the pigments and fillers are selected from powdered whiting, cloud
Female powder, precipitated sulfur and silica flour, weight range 5: 4: 3: (12~16)；The powdered whiting partial size be 600~
2000 mesh, the mica powder partial size are 800~3000 mesh, the grain that the precipitated sulfur partial size is 800~3000 mesh, the precipitated sulfur
Diameter is 800~3000 mesh；The stabilizer is selected from Switzerland vanBaerleINOCOT 925 or Clariant DispersogenSPS；
The anti-settling agent is bentonite, is selected from BASF Attagel 40；The defoaming agent is selected from Switzerland vanBaerle INOCOT
935。
9. a kind of preparation method for the aqueous inorganic paint for preparing high resistant high rigidity as described in claim 1 it is characterized in that,
Include the following steps:
1) weighs each component raw material by formula ratio；
2) pure water, the first thickener, dispersing agent are uniformly dispersed by, then put into titanium dioxide, and high speed dispersion is micro- to fineness≤50
Rice, it is spare；
3) adds inorganic silicic acid salt resin, styrene-acrylic emulsion or emulsion acrylic resin, silane coupling agent and the second thickener, low
Speed dispersion 20~30min, filtering to get.
10. in preparation method step 2) according to claim 9, addition dispersing agent adds the defoaming agent simultaneously, add
The titanium dioxide adds anti-settling agent and the pigments and fillers simultaneously；The revolving speed of high speed dispersion is 1200~1500 revs/min；Low speed point
Scattered revolving speed is 400~600 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811287145.9A CN109401374A (en) | 2018-10-31 | 2018-10-31 | The aqueous inorganic paint and preparation method thereof of high resistant high rigidity |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811287145.9A CN109401374A (en) | 2018-10-31 | 2018-10-31 | The aqueous inorganic paint and preparation method thereof of high resistant high rigidity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109401374A true CN109401374A (en) | 2019-03-01 |
Family
ID=65470600
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811287145.9A Withdrawn CN109401374A (en) | 2018-10-31 | 2018-10-31 | The aqueous inorganic paint and preparation method thereof of high resistant high rigidity |
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| CN (1) | CN109401374A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266636A (en) * | 2020-11-22 | 2021-01-26 | 湖南省金海科技有限公司 | Development and preparation method of antiviral water-based inorganic coating |
| CN113698817A (en) * | 2021-07-26 | 2021-11-26 | 丹阳市现代实业有限公司 | Stain-resistant water-based coating composition |
| CN115521648A (en) * | 2022-11-03 | 2022-12-27 | 中科路达(福建)交通科技有限公司 | Graphene-modified fireproof, anticorrosive and anti-fouling nano coating and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5317648A (en) * | 1976-08-02 | 1978-02-17 | Nissan Chem Ind Ltd | Process of coating inorganic paint |
| CN108034295A (en) * | 2017-12-28 | 2018-05-15 | 河南宣和钧釉环保材料有限公司 | A kind of inorganic environment-friendly interior wall mould proof antibacterial paint |
-
2018
- 2018-10-31 CN CN201811287145.9A patent/CN109401374A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5317648A (en) * | 1976-08-02 | 1978-02-17 | Nissan Chem Ind Ltd | Process of coating inorganic paint |
| CN108034295A (en) * | 2017-12-28 | 2018-05-15 | 河南宣和钧釉环保材料有限公司 | A kind of inorganic environment-friendly interior wall mould proof antibacterial paint |
Non-Patent Citations (1)
| Title |
|---|
| 张万臣: "《建筑材料与装饰材料》", 30 June 2010, 中国建材工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112266636A (en) * | 2020-11-22 | 2021-01-26 | 湖南省金海科技有限公司 | Development and preparation method of antiviral water-based inorganic coating |
| CN113698817A (en) * | 2021-07-26 | 2021-11-26 | 丹阳市现代实业有限公司 | Stain-resistant water-based coating composition |
| CN115521648A (en) * | 2022-11-03 | 2022-12-27 | 中科路达(福建)交通科技有限公司 | Graphene-modified fireproof, anticorrosive and anti-fouling nano coating and preparation method thereof |
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Application publication date: 20190301 |