CN102604537B - Water-based metal antiseptic paint and preparation method thereof - Google Patents
Water-based metal antiseptic paint and preparation method thereof Download PDFInfo
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- CN102604537B CN102604537B CN201210050084.0A CN201210050084A CN102604537B CN 102604537 B CN102604537 B CN 102604537B CN 201210050084 A CN201210050084 A CN 201210050084A CN 102604537 B CN102604537 B CN 102604537B
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Abstract
The invention discloses water-based metal antiseptic paint and a development method thereof. The water-based metal antiseptic paint comprises the following components by weight percent: 15-20% of silica sol emulsion, 20-30% of GH-26XB silicon acrylic-acid anticorrosion emulsion, 15-20% of rutile titanium dioxide R-930, 2-4% of alcohol ester 12, 5-10% of superfine talcum powder, 5-10% of superfine mica powder, 5-10% of superfine silica powder, 0.4-0.8% of GH5050 dispersant, 0.5-1% of DA (dispersing agent), 0.1-0.3% of PE-100 wetting agent, 0.5-1% of GHP101 thickening agent, 0.1-0.3% of antiseptic 981, 0.1-0.3% of SN-345 defoaming agent and 5-14% of water. The water-based metal antiseptic paint disclosed by the invention is non-toxic and environment-friendly, has the advantages of excellent waterproof corrosion resistance, high temperature resistance, alkali resistance, weather resistance, scrubbing resistance and artificial aging resistance and is perfect novel water-based metal antiseptic paint.
Description
Technical field
The present invention relates to a kind of waterborne metal anti-corrosive paint and preparation method thereof, belong to metal anti-corrosive paint technical field.
Background technology
In recent years, the research of metal anti-corrosive paint has obtained certain achievement, but less to waterborne metal anti-corrosive paint research, and has the defects such as preservative effect is not good.Research trial shows, adopts silicon sol emulsion and the anticorrosion emulsion of the GH-26XB silicon third novel aqueous metal anti-corrosive paint for developing, and not only can directly be coated in metallic surface, and preservative effect is splendid, thereby has overcome the defect of prior art.Because the anticorrosion emulsion silicon-containing polymer of silicon sol emulsion and GH-26XB silicon third, has extremely strong waterproof anti-corrosion performance, can form with various fillers and auxiliary agent the water-tight corrosion-proof film of high-weatherability.So the coating of development is nontoxic, environmental protection, has the advantages such as splendid waterproof anti-corrosion, high temperature resistant, alkali resistance, weathering resistance, scrub resistance and artificial ageing resistance, is desirable novel aqueous metal anti-corrosive paint.
Summary of the invention
The object of the invention is, for the existing problem of above-mentioned prior art, to overcome existing deficiency and defect, and a kind of waterborne metal anti-corrosive paint and preparation method thereof is provided.
In order to achieve the above object, the present invention realizes the technical scheme that object takes and is:
A kind of waterborne metal anti-corrosive paint, content is by component by mass percentage: silicon sol emulsion is 15-20%, the anticorrosion emulsion of GH-26XB silicon third is 20-30%, rutile titanium white R-930 is 15-20%, alcohol ester 12 is 2-4%, superfine talcum powder is 5-10%, ultrafine mica powder is 5-10%, superfine silicon dioxide powder is 5-10%, GH5050 dispersion agent is 0.4-0.8%, DA dispersion agent is 0.5-1%, PE-100 wetting agent is 0.1-0.3%, GHP101 thickening material is 0.5-1%, sanitas 981 is 0.1-0.3%, SN-345 defoamer is 0.1-0.3%, water is 5-14% composition.
In order to achieve the above object, another technical scheme of the present invention is:
The preparation method of above-mentioned a kind of waterborne metal anti-corrosive paint, comprises the steps:
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 10-15min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 40-44min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 30-34min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
The waterborne metal anti-corrosive paint that the present invention makes is nontoxic, and environmental protection has the advantages such as splendid waterproof anti-corrosion, high temperature resistant, alkali resistance, weathering resistance, scrub resistance and artificial ageing resistance, is more satisfactory novel aqueous metal anti-corrosive paint product.Product reaches and is better than GB/T9755-2001 and GB18583-2001 national standard, and market outlook are wide.
Specific embodiments
In conjunction with specific examples, further describe technical scheme of the present invention.
Embodiment 1
One, match by mass percentage each component
Silicon sol emulsion 15%,
The anticorrosion emulsion 30% of GH-26XB silicon third,
Rutile titanium white powder R-930 15%,
Alcohol ester ten two 2.0%,
Superfine talcum powder 10%,
Ultrafine mica powder 10%,
Superfine silicon dioxide powder 5.0%,
GH 5050 dispersion agents 0.4%,
DA dispersion agent 1.0%,
PE-100 wetting agent 0.2%,
GHP101 thickening material 0.8%,
Sanitas 981 0.3%,
SN-345 defoamer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 10min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 40min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 30min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
Embodiment 2
One, match by mass percentage each component
Silicon sol emulsion 20%,
The anticorrosion emulsion 20% of GH-26XB silicon third,
Rutile titanium white R-930 powder 20%,
Alcohol ester ten two 4.0%,
Superfine talcum powder 5.0%,
Ultrafine mica powder 5.0%,
Superfine silicon dioxide powder 10%,
GH 5050 dispersion agents 0.7%,
DA dispersion agent 0.5%,
PE-100 wetting agent 0.1%,
GHP101 thickening material 0.5%,
Sanitas 981 0.1%,
SN-345 defoamer 0.1%,
Water 14%.
Two, preparation method
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 12min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 41min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 31min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
Embodiment 3
One, match by mass percentage each component
Silicon sol emulsion 19%,
The anticorrosion emulsion 25% of GH-26XB silicon third,
Rutile titanium white powder R-930 18%,
Alcohol ester ten two 3.0%,
Superfine talcum powder 8.0%,
Ultrafine mica powder 6.0%,
Superfine silicon dioxide powder 8.0%,
GH 5050 dispersion agents 0.8%,
DA dispersion agent 0.3%,
PE-100 wetting agent 0.3%,
GHP101 thickening material 1.0%,
Sanitas 981 0.3%,
SN-345 defoamer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 13min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 42min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 32min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
Embodiment 4
One, match by mass percentage each component
Silicon sol emulsion 17%,
The anticorrosion emulsion 28% of GH-26XB silicon third,
Rutile titanium white powder R-930 17%,
Alcohol ester ten two 4.0%,
Superfine talcum powder 7.0%,
Ultrafine mica powder 7.0%,
Superfine silicon dioxide powder 7.0%,
GH 5050 dispersion agents 0.6%,
DA dispersion agent 0.8%,
PE-100 wetting agent 0.3%,
GHP101 thickening material 0.7%,
Sanitas 981 0.3%,
SN-345 defoamer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 14min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 43min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 33min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
Embodiment 5
One, match by mass percentage each component
Silicon sol emulsion 20%,
The anticorrosion emulsion 30% of GH-26XB silicon third,
Rutile titanium white powder R-930 19%,
Alcohol ester ten two 3.0%,
Superfine talcum powder 6.0%,
Ultrafine mica powder 9.0%,
Superfine silicon dioxide powder 6.0%,
GH 5050 dispersion agents 0.5%,
DA dispersion agent 0.4%,
PE-100 wetting agent 0.2%,
GHP101 thickening material 0.5%,
Sanitas 981 0.2%,
SN-345 defoamer 0.2%,
Water 5.0%.
Two, preparation method
1. respectively water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and in reactor, stir 15min and evenly mix.
2. adding respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to stir 44min evenly mixes again.
3. add respectively again GHP101 thickening material, sanitas 981, SN-345 defoamer to stir 34min, make waterborne metal anti-corrosive paint.
4. waterborne metal anti-corrosive paint step 3 being made enters sand mill and grinds twice, filters discharging barrelling.
Claims (2)
1. a waterborne metal anti-corrosive paint, it is characterized in that, content is by component by mass percentage: silicon sol emulsion is 15-20%, the anticorrosion emulsion of GH-26XB silicon third is 20-30%, rutile titanium white powder R-930 is 15-20%, alcohol ester 12 is 2-4%, superfine talcum powder is 5-10%, ultrafine mica powder is 5-10%, superfine silicon dioxide powder is 5-10%, GH5050 dispersion agent is 0.4-0.8%, DA dispersion agent is 0.5-1%, PE-100 wetting agent is 0.1-0.3%, GHP101 thickening material is 0.5-1%, sanitas 981 is 0.1-0.3%, SN-345 defoamer is 0.1-0.3%, water is 5-14% composition.
2. a method of production for waterborne metal anti-corrosive paint as claimed in claim 1, is characterized in that, comprises the steps:
﹙ 1 ﹚ adds water, silicon sol emulsion, the anticorrosion emulsion of silicon third, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent respectively and in reactor, stirs 10-15min and evenly mix;
﹙ 2 ﹚ add respectively rutile titanium white powder R-930, superfine talcum powder, ultrafine mica powder, superfine silicon dioxide powder, alcohol ester 12 to continue to stir 40-44min and evenly mix;
﹙ 3 ﹚ add respectively GHP101 thickening material, sanitas 981, SN-345 defoamer to continue to stir 30-34min again, make waterborne metal anti-corrosive paint;
The waterborne metal anti-corrosive paint that ﹙ 4 ﹚ make step (3) enters sand mill and grinds twice, filters discharging barrelling.
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CN103289467B (en) * | 2013-04-23 | 2014-07-02 | 宁波墨西科技有限公司 | Mica inorganic paint and usage method thereof |
CN103421364A (en) * | 2013-08-23 | 2013-12-04 | 南通优尼科化工有限公司 | High-efficiency anticorrosive paint |
CN105385278A (en) * | 2015-12-24 | 2016-03-09 | 江苏常明电力设备有限公司 | Electric meter box |
CN105733382B (en) * | 2016-03-07 | 2018-05-04 | 广东省建筑材料研究院 | A kind of micro-nano reinforced steel bar rust preventing agent and preparation method thereof of autoclaved aerated concrete slab |
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CN1431266A (en) * | 2003-01-20 | 2003-07-23 | 湖南大学 | Multi-functional construction external wall nano coating material and its preparing method |
CN101525505A (en) * | 2009-04-03 | 2009-09-09 | 河海大学 | Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof |
CN102127353A (en) * | 2010-01-13 | 2011-07-20 | 亚士漆(上海)有限公司 | High-pollution-resistant high-silicon coating special for bridges and overhead roads |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN1431266A (en) * | 2003-01-20 | 2003-07-23 | 湖南大学 | Multi-functional construction external wall nano coating material and its preparing method |
CN101525505A (en) * | 2009-04-03 | 2009-09-09 | 河海大学 | Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof |
CN102127353A (en) * | 2010-01-13 | 2011-07-20 | 亚士漆(上海)有限公司 | High-pollution-resistant high-silicon coating special for bridges and overhead roads |
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Effective date of registration: 20160421 Address after: 621000 Mianyang City, Sichuan Province County Industrial Park Patentee after: Mianyang maxewell Technology Co., Ltd. Address before: 212003 Zhenjiang City, Jiangsu province dream Creek Road, No. 2 Patentee before: Jiangsu University of Science and Technology |