CN102604537A - Water-based metal antiseptic paint and preparation method thereof - Google Patents

Water-based metal antiseptic paint and preparation method thereof Download PDF

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Publication number
CN102604537A
CN102604537A CN2012100500840A CN201210050084A CN102604537A CN 102604537 A CN102604537 A CN 102604537A CN 2012100500840 A CN2012100500840 A CN 2012100500840A CN 201210050084 A CN201210050084 A CN 201210050084A CN 102604537 A CN102604537 A CN 102604537A
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powder
water
superfine
silicon
emulsion
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CN2012100500840A
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CN102604537B (en
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郭文录
张秀荣
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Mianyang maxewell Technology Co., Ltd.
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Jiangsu University of Science and Technology
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Abstract

The invention discloses water-based metal antiseptic paint and a development method thereof. The water-based metal antiseptic paint comprises the following components by weight percent: 15-20% of silica sol emulsion, 20-30% of GH-26XB silicon acrylic-acid anticorrosion emulsion, 15-20% of rutile titanium dioxide R-930, 2-4% of alcohol ester 12, 5-10% of superfine talcum powder, 5-10% of superfine mica powder, 5-10% of superfine silica powder, 0.4-0.8% of GH5050 dispersant, 0.5-1% of DA (dispersing agent), 0.1-0.3% of PE-100 wetting agent, 0.5-1% of GHP101 thickening agent, 0.1-0.3% of antiseptic 981, 0.1-0.3% of SN-345 defoaming agent and 5-14% of water. The water-based metal antiseptic paint disclosed by the invention is non-toxic and environment-friendly, has the advantages of excellent waterproof corrosion resistance, high temperature resistance, alkali resistance, weather resistance, scrubbing resistance and artificial aging resistance and is perfect novel water-based metal antiseptic paint.

Description

A kind of waterborne metal anti-corrosive paint and preparation method thereof
Technical field
The present invention relates to a kind of waterborne metal anti-corrosive paint and preparation method thereof, belong to the metal anti-corrosive paint technical field.
Background technology
In recent years, the research of metal anti-corrosive paint has obtained certain achievement, but less to waterborne metal anti-corrosive paint research, and has defectives such as preservative effect is not good.Research trial shows that the novel aqueous metal anti-corrosive paint that adopts silicon sol emulsion and the GH-26XB silicon third anticorrosion emulsion to be used to develop not only can directly be coated in the metallic surface, and preservative effect is splendid, thereby has been overcome the defective of prior art.Because silicon sol emulsion and the GH-26XB silicon third anticorrosion emulsion silicon-containing polymer have extremely strong waterproof anti-corrosion performance, can film with the water-tight corrosion-proof of various fillers and auxiliary agent formation high-weatherability.So the coating of development is nontoxic, environmental protection has advantages such as splendid waterproof anti-corrosion property, high temperature resistant, alkali resistance, weathering resistance, scrub resistance and artificial ageing resistance, is the novel aqueous metal anti-corrosive paint of ideal.
Summary of the invention
The objective of the invention is to overcome existing deficiency and defective, and a kind of waterborne metal anti-corrosive paint and preparation method thereof is provided to above-mentioned existing in prior technology problem.
In order to achieve the above object, the present invention realizes that the technical scheme that purpose is taked is:
A kind of waterborne metal anti-corrosive paint, content is by component by mass percentage: the silicon sol emulsion is 15-20%, and the GH-26XB silicon third anticorrosion emulsion is 20-30%; Rutile titanium white R-930 is 15-20%, and alcohol ester 12 is 2-4%, and superfine talcum powder is 5-10%; Ultra-fine mica powder is 5-10%, and the superfine silicon dioxide powder is 5-10%, and the GH5050 dispersion agent is 0.4-0.8%; The DA dispersion agent is 0.5-1%, and the PE-100 wetting agent is 0.1-0.3%, and the GHP101 thickening material is 0.5-1%; Sanitas 981 is 0.1-0.3%, and the SN-345 skimmer is 0.1-0.3%, and water is that 5-14% forms.
In order to achieve the above object, another technical scheme of the present invention is:
The preparation method of above-mentioned a kind of waterborne metal anti-corrosive paint comprises the steps:
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 10-15min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 40-44min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 30-34min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.
The waterborne metal anti-corrosive paint that the present invention makes is nontoxic, and environmental protection has advantages such as splendid waterproof anti-corrosion property, high temperature resistant, alkali resistance, weathering resistance, scrub resistance and artificial ageing resistance, is more satisfactory novel aqueous metal anti-corrosive paint product.Product reaches and is superior to GB/T9755-2001 and GB18583-2001 national standard, and market outlook are wide.
Specific embodiments
In conjunction with specific examples further explain technical scheme of the present invention.
Embodiment 1
One, matches each component by mass percentage
Silicon sol emulsion 15%,
The GH-26XB silicon third anticorrosion emulsion 30%,
Rutile titanium white powder R-930 15%,
Alcohol ester ten two 2.0%,
Superfine talcum powder 10%,
Ultra-fine mica powder 10%,
Superfine silicon dioxide powder 5.0%,
GH 5050 dispersion agents 0.4%,
DA dispersion agent 1.0%,
PE-100 wetting agent 0.2%,
GHP101 thickening material 0.8%,
Sanitas 981 0.3%,
SN-345 skimmer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 10min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 40min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 30min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.
Embodiment 2
One, matches each component by mass percentage
Silicon sol emulsion 20%,
The GH-26XB silicon third anticorrosion emulsion 20%,
Rutile titanium white R-930 powder 20%,
Alcohol ester ten two 4.0%,
Superfine talcum powder 5.0%,
Ultra-fine mica powder 5.0%,
Superfine silicon dioxide powder 10%,
GH 5050 dispersion agents 0.7%,
DA dispersion agent 0.5%,
PE-100 wetting agent 0.1%,
GHP101 thickening material 0.5%,
Sanitas 981 0.1%,
SN-345 skimmer 0.1%,
Water 14%.
Two, preparation method
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 12min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 41min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 31min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.
Embodiment 3
One, matches each component by mass percentage
Silicon sol emulsion 19%,
The GH-26XB silicon third anticorrosion emulsion 25%,
Rutile titanium white powder R-930 18%,
Alcohol ester ten two 3.0%,
Superfine talcum powder 8.0%,
Ultra-fine mica powder 6.0%,
Superfine silicon dioxide powder 8.0%,
GH 5050 dispersion agents 0.8%,
DA dispersion agent 0.3%,
PE-100 wetting agent 0.3%,
GHP101 thickening material 1.0%,
Sanitas 981 0.3%,
SN-345 skimmer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 13min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 42min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 32min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.
Embodiment 4
One, matches each component by mass percentage
Silicon sol emulsion 17%,
The GH-26XB silicon third anticorrosion emulsion 28%,
Rutile titanium white powder R-930 17%,
Alcohol ester ten two 4.0%,
Superfine talcum powder 7.0%,
Ultra-fine mica powder 7.0%,
Superfine silicon dioxide powder 7.0%,
GH 5050 dispersion agents 0.6%,
DA dispersion agent 0.8%,
PE-100 wetting agent 0.3%,
GHP101 thickening material 0.7%,
Sanitas 981 0.3%,
SN-345 skimmer 0.3%,
Water 10%.
Two, preparation method
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 14min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 43min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 33min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.
Embodiment 5
One, matches each component by mass percentage
Silicon sol emulsion 20%,
The GH-26XB silicon third anticorrosion emulsion 30%,
Rutile titanium white powder R-930 19%,
Alcohol ester ten two 3.0%,
Superfine talcum powder 6.0%,
Ultra-fine mica powder 9.0%,
Superfine silicon dioxide powder 6.0%,
GH 5050 dispersion agents 0.5%,
DA dispersion agent 0.4%,
PE-100 wetting agent 0.2%,
GHP101 thickening material 0.5%,
Sanitas 981 0.2%,
SN-345 skimmer 0.2%,
Water 5.0%.
Two, preparation method
1. respectively water, silicon sol emulsion, the silicon third anticorrosion emulsion, GH5050 dispersion agent, DA dispersion agent, PE-100 wetting agent are added and stir the 15min uniform mixing in the reactor drum.
2. add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 stirring 44min uniform mixing more respectively.
3. add GHP101 thickening material, sanitas 981, SN-345 skimmer stirring 34min more respectively, promptly make waterborne metal anti-corrosive paint.
4. the waterborne metal anti-corrosive paint that step 3 is made gets into sand mill and grinds twice, filters the discharging barrelling.

Claims (2)

1. a waterborne metal anti-corrosive paint is characterized in that, content is by component by mass percentage: the silicon sol emulsion is 15-20%, and the GH-26XB silicon third anticorrosion emulsion is 20-30%; Rutile titanium white powder R-930 is 15-20%, and alcohol ester 12 is 2-4%, and superfine talcum powder is 5-10%; Ultra-fine mica powder is 5-10%, and the superfine silicon dioxide powder is 5-10%, and GH 5050 dispersion agents are 0.4-0.8%; The DA dispersion agent is 0.5-1%, and the PE-100 wetting agent is 0.1-0.3%, and the GHP101 thickening material is 0.5-1%; Sanitas 981 is 0.1-0.3%, and the SN-345 skimmer is 0.1-0.3%, and water is that 5-14% forms.
2. the method for production of a waterborne metal anti-corrosive paint as claimed in claim 1 is characterized in that, comprises the steps:
(1) respectively with water, silicon sol emulsion, the silicon third anticorrosion emulsion,, GH 5050 dispersion agents, DA dispersion agent, PE-100 wetting agent add and stir the 10-15min uniform mixing in the reactor drum;
(2) add rutile titanium white powder R-930, superfine talcum powder, ultra-fine mica powder, superfine silicon dioxide powder, alcohol ester 12 continuation stirring 40-44min uniform mixing respectively;
(3) add GHP101 thickening material, sanitas 981, SN-345 skimmer respectively and continue to stir 30-34min again, promptly make waterborne metal anti-corrosive paint;
(4) waterborne metal anti-corrosive paint that step (3) is made gets into sand mill and grinds twice, filters the discharging barrelling.
CN201210050084.0A 2012-03-01 2012-03-01 Water-based metal antiseptic paint and preparation method thereof Active CN102604537B (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289467A (en) * 2013-04-23 2013-09-11 宁波墨西科技有限公司 Mica inorganic paint and usage method thereof
CN103421364A (en) * 2013-08-23 2013-12-04 南通优尼科化工有限公司 High-efficiency anticorrosive paint
CN105385278A (en) * 2015-12-24 2016-03-09 江苏常明电力设备有限公司 Electric meter box
CN105733382A (en) * 2016-03-07 2016-07-06 广东省建筑材料研究院 Micro-nano reinforcing steel bar anti-rusting agent for autoclaved aerated concrete slab and preparation method of micro-nano reinforcing steel bar anti-rusting agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1431266A (en) * 2003-01-20 2003-07-23 湖南大学 Multi-functional construction external wall nano coating material and its preparing method
CN101525505A (en) * 2009-04-03 2009-09-09 河海大学 Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof
CN102127353A (en) * 2010-01-13 2011-07-20 亚士漆(上海)有限公司 High-pollution-resistant high-silicon coating special for bridges and overhead roads

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1431266A (en) * 2003-01-20 2003-07-23 湖南大学 Multi-functional construction external wall nano coating material and its preparing method
CN101525505A (en) * 2009-04-03 2009-09-09 河海大学 Watery zinc-aluminium heavy-duty coating in compounding squama shape and preparation method thereof
CN102127353A (en) * 2010-01-13 2011-07-20 亚士漆(上海)有限公司 High-pollution-resistant high-silicon coating special for bridges and overhead roads

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103289467A (en) * 2013-04-23 2013-09-11 宁波墨西科技有限公司 Mica inorganic paint and usage method thereof
CN103421364A (en) * 2013-08-23 2013-12-04 南通优尼科化工有限公司 High-efficiency anticorrosive paint
CN105385278A (en) * 2015-12-24 2016-03-09 江苏常明电力设备有限公司 Electric meter box
CN105733382A (en) * 2016-03-07 2016-07-06 广东省建筑材料研究院 Micro-nano reinforcing steel bar anti-rusting agent for autoclaved aerated concrete slab and preparation method of micro-nano reinforcing steel bar anti-rusting agent

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Effective date of registration: 20160421

Address after: 621000 Mianyang City, Sichuan Province County Industrial Park

Patentee after: Mianyang maxewell Technology Co., Ltd.

Address before: 212003 Zhenjiang City, Jiangsu province dream Creek Road, No. 2

Patentee before: Jiangsu University of Science and Technology