CN105801071A - Formula of primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and making technology - Google Patents
Formula of primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and making technology Download PDFInfo
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- CN105801071A CN105801071A CN201610148727.3A CN201610148727A CN105801071A CN 105801071 A CN105801071 A CN 105801071A CN 201610148727 A CN201610148727 A CN 201610148727A CN 105801071 A CN105801071 A CN 105801071A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00525—Coating or impregnation materials for metallic surfaces
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/26—Corrosion of reinforcement resistance
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
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Abstract
The invention discloses a formula of a primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and a making technology.A small quantity of an organosilicon polymer solution and water-based inorganic film former silicate are adopted as base materials, an anti-rust agent, a rust conversion agent, multiple pigments and fillers and auxiliaries are added, and after dispersion, grinding and blending, the paint is obtained.The single-component paint achieves primer-topcoat combination and has the advantages of rust conversion, passivation and construction with rust and the advantages of being resistant to high temperature, free of toxins or smells, large in adhesive force, good in anti-rust effect and capable of achieving construction easiness and convenience.The situation that for a traditional bi-component anti-rust paint, matching products such as a thinning agent and a curing agent are needed is changed; the adhesive force, weather resistance and use universality are improved; complex processes such as strict polishing or shot blasting or chemical derusting needed by a base face are omitted; the defects of toxicity and harmfulness, environmental pollution and the like are overcome; the complex process of primer coating, middle coating and top coating is simplified.
Description
Technical field
The present invention relates to inorganic coating high molecular polymer field, particularly relate to bottom surface and unify inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology.
Background technology
Antirusting paint of the prior art divides oiliness and aqueous two kinds.Oily antirust varniss makes the greasy removal difficulty of material surface.Oily antirust varniss is easy to use, cheap, but because containing the noxious substance such as nitrite, chromate, operator's harm is relatively big, and country has limited use, and these type of properties of product are single, it is impossible to meet the antirust requirement of magnetic alloy material.Water-based metal antirust paint adopts polyurethane, acrylic acid, silicate etc. to add Plumbum preparatium, zinc powder, ferrum oxide etc. for film forming matter and makes double-component or multi-component coating, need the complex process such as primary coat, middle painting, topcoating, use narrow scope, basal plane requirement is strict, use before basal plane have to pass through the derusting process such as strict sandblasting, ball blast, pickling, construction requirement time length, cost are high, poisonous and harmful.Although also there is the product calling oneself inorganic antirusting paint in market, also it is only a kind of add the hybridization coating of zinc powder or iron oxide red etc. with silicate and substantial amounts of acrylic compounds or resin for film forming matter by analysis, water-resistance property of coating is poor, easy to crack and occurs returning the phenomenons such as rust, and these are all the difficult problems that existing antirusting paint cannot overcome.
Summary of the invention
The purpose of the present invention is that provides bottom surface to unify inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology to solve the problems referred to above.
The present invention is achieved through the following technical solutions above-mentioned purpose:
The present invention comprises the following steps:
(1) with parts by weight, in blender, the water of addition 14 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the coalescents of 0.5 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant are stirred successively, mixing speed is 300 revs/min, mixing time 15 minutes；
(2) adding the color stuffing stirring of 20 parts, mixing speed is 1300 revs/min, mixing time 15 minutes；
(3) adding 15 parts of antirusting powder stirrings, mixing speed is 1300 revs/min, stirs 15 minutes；
(4) adding 5 parts and turn rust passivator stirring, mixing speed 1300 revs/min, mixing time is 15 minutes；
(5) the organosilicon polymer solution of addition 10 parts, the thickening agent of 0.6 part, the defoamer of 0.2 part, 0.8 part anti-dodge rust agent, mixing speed 300 revs/min, stir 10 minutes, filter to obtain antirusting paint after grinding.
Further, the modulus of described Lithium metasilicate solution is 3.6-4.0, and the modulus of described potassium silicate solution is 2.5-3.0, and the mean diameter of described Ludox is 7-10nm.
Specifically, described organosilicon polymer solution is the GBER-1 that brother Bayer limited company produces, and described inorganic dispersant is DISPERSOGENSPS silicate paint dispersant, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Anti-sudden strain of a muscle rust agent is U.S. F-179；Described antirusting powder is the novel environment-friendly water-based antirust iron powder of the proud woods in Wuhan, and described turn of rust passivating material is modified zinc phosphate, modified phosphate aluminum.
Specifically, described color stuffing is made up of rutile titanium white lead, washing barium sulfate, micronized talc powder, ultra-fine mica splitting powder and ultra-fine wollastonite in powder.
The beneficial effects of the present invention is:
The present invention is that inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology is unified in bottom surface, and compared with prior art, the present invention adopts GBER-1 organic silicon solution to instead of the organic binder such as acrylic acid or resin to make film forming solidfied material become full-inorganic；Composite between silicate solutions, and with Ludox blending and modifying, make the final coating prepared have good water proofing property, stability, hardness and heat-resisting quantity；Use the shortcoming that inorganic dispersant overcomes silicate paint poor storage stability；By adding the functional material such as antirusting powder, aluminum phosphate, zinc sulfate, mica splitting, the face passivation that makes to become rusty, film are hard and improve the salt spray resistance of film, make rust-proof effect be greatly improved；The inorganic rush-resisting material excellent performance adopted, VOC content is extremely low, without harmful substances such as formaldehyde, stupid, heavy metals, i.e. environmental protection but also there is excellent rustless property；This Recipe is simple, with low cost.Polishing, the wiping ripe rust of removing, old coat of paint is only needed to construct before construction.
Detailed description of the invention
The invention will be further described below:
The present invention comprises the following steps:
(1) with parts by weight, in blender, the water of addition 14 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the coalescents of 0.5 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant are stirred successively, mixing speed is 300 revs/min, mixing time 15 minutes；
(2) adding the color stuffing stirring of 20 parts, mixing speed is 1300 revs/min, mixing time 15 minutes；
(3) adding 15 parts of antirusting powder stirrings, mixing speed is 1300 revs/min, stirs 15 minutes；
(4) adding 5 parts and turn rust passivator stirring, mixing speed 1300 revs/min, mixing time is 15 minutes；
(5) the GBER-1 organic silicon solution of addition 10 parts, the thickening agent of 0.6 part, the defoamer of 0.2 part, 0.8 part anti-dodge rust agent, mixing speed 300 revs/min, stir 10 minutes, filter to obtain antirusting paint after grinding.
Further, the modulus of described Lithium metasilicate solution is 3.6-4.0, and the modulus of described potassium silicate solution is 2.5-3.0, and the mean diameter of described Ludox is 7-10nm.
Specifically, described in have GBER-1 be the organic silicon solution that brother Bayer coating company limited produces, described inorganic dispersant is DISPERSOGENSPS silicate paint dispersant, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Anti-sudden strain of a muscle rust agent is U.S. F-179；Described antirusting powder is the novel aqueous antirust iron powder AL-E-500 that Wuhan Ao Lin Chung Inc. produces, and described turn of rust passivating material is modified zinc phosphate, modified phosphate aluminum.
Specifically, described color stuffing is made up of rutile titanium white lead, washing barium sulfate, micronized talc powder, ultra-fine mica splitting powder and ultra-fine wollastonite in powder.
The present invention adopts Lithium metasilicate, potassium silicate, Ludox, modifiies with organic silicon solution and makes coating, is a kind of purely inorganic coating, overcome traditional paint and contain the noxious substance such as nitrite, chromate, operator's harm is relatively big, and these type of properties of product are single, it is impossible to meet the market demand；Traditional double component coating needs the complex process such as primary coat, middle painting, topcoating, use narrow scope, basal plane requirement is strict, use before basal plane have to pass through the derusting process such as strict sandblasting, ball blast, pickling, the shortcoming such as construction requirement time length, cost height, poisonous and harmful.The antirusting powder AL-E-500 adopted, is the heavy metals such as a kind of NEW TYPE OF COMPOSITE rust resisting pigment, not leaded, chromium, nontoxic, pollution-free, it is possible to replace the tradition rust resisting pigments such as Plumbum preparatium comprehensively.People and animals are also had no stimulation, good rustless property when consumption is less, can be reached；The rust passivator that turns adopted is the poisonous metals such as modified aluminium triphosphate and zinc phosphate, avirulence, not leaded, chromium, can effectively replace the harmful pigment of the tradition such as Plumbum preparatium, zinc yellow.Its maximum feature of modified zinc phosphate is exactly high covering power and the tinting strength, tinting power that the antirust, anti-corrosive performance of existing zinc phosphate has again titanium dioxide.The barium sulfate that color stuffing is import titanium dioxide, mica splitting powder, needle shape wollastonite powder, stable in properties adopted, after film forming, film is fine and close, and hydrone not easily permeates.The purely inorganic capable of coating with rust turn of rust Rustproof high-temperature resisting coating weatherability nonpoisonous and tasteless with it, superpower of aqueous one-component bottom surface unification, high temperature resistant, excellent rust-preventing characteristic, adhesive force are good, particularly can band rust application property, save substantial amounts of construction cost, cause the extensive concern of people.Raw material used arises directly from nature, and abundance is cheap.Therefore, unification purely inorganic capable of coating with rust turn of rust Rustproof high-temperature resisting coating in aqueous one-component bottom surface possesses wide market prospect.
The ultimate principle of the present invention is as follows: silicate is also referred to as waterglass, and the formula of waterglass molecular formula is M2O.mSiO2.nH2O, M can be sodium, potassium, lithium and 4 kinds of ions of ammonium, and m is modulus.(ammonium waterglass price is too high, sodium silicate cheap, but resistance to water is very poor, it is generally required to external reinforcement agent could meet the demand of reality.) membrane formation mechanism is waterglass and the CO2 in air reacts formation silica sol, evaporation along with moisture, dehydration forms inorganic silica link network shape macromole, but it is dispersed in the form of an ion in film due to alkali metal, when film meets water, film can destroy because of the dissociation of alkali metal ion, namely causes the poor water resistance of film.Conventional method of modifying has: the acid of waterglass is modified and the blending and modifying etc. of synthetic resin emulsion compound use, different types of waterglass.The present invention adopts organic silicon solution to modifiy, and efficiently solves this difficult problem.
Ludox is with the aqueous dispersions of silica sol for film forming matter, its membrane formation mechanism is, when Ludox dries out, monomeric silicic acid is polymerized gradually, along with moisture evaporates, colloid molecules increases, and can form firmly Si-O-Si keyboard between SiO2 particle, then form silica chain network structure, become continuous film.Owing in Ludox, the salt content of solubility is low, thus film is made to have good resistance to water, but, it is due to pore effect, and independent Ludox is as film forming matter, it is easy to occurs that coating adhesion is poor, ftracture or even the phenomenon such as efflorescence.By being added with GBER-1 machine silicon solution, effectively raise the compatibility that organic-inorganic is biphase, make organic binder and inorganic filming substance form effective mutual network structure of interting, further increase coating to the adhesive force of ground, water proofing property and breathability.These materials are resistant to the high temperature of more than 800 degree.
Its rust-proof mechanism is that in aluminium triphosphate, tripolyphosphate radical ion P3O105-can have higher chelating ability with each metal ion species, the passivating film of brilliance is formed on coated article surface, the corrosion of iron and steel and light metal etc. had extremely strong inhibitory action, film adhesive be can effectively improve, salt fog resistance, anticorrosive property and anti-foaming improved.
Zinc phosphate and ferric ion have very strong complexing power; the anion of this zinc phosphate is reacted with iron anode; the protecting film based on iron phosphate can be formed; the purification membrane of this densification is water insoluble; hardness is high; adhesive force excellence presents the rustless property of brilliance, owing to zinc phosphate itself has fine activity, can generate complex with a lot of Action of Metal Ions.
Novel antirust powder is, by multiple organic additive, superfine powder and surface of pigments are carried out high-temperature process, it is made to form the clad of densification in surface of pigments, effectively intercept hydrone, oxygen and the erosion to iron and steel of other gas, greatly enhance the pigment adhesive force at steel surface, thus having possessed excellent antirust ability.
Wet method flaky mica powder is compared with dry ground muscovite mica, its laminated structure is complete, adds needle shape wollastonite powder and multiple ultra-fine color stuffing, has filled up gap between mica sheet, forming multiple dense film, so the layer structure of formation can effectively intercept going deep into of moisture and gas.
In sum, the inorganic antirusting paint of novel environment friendly provided by the invention is with organic silicon solution, alkali silicate, Ludox is main film forming substance, total soluble-salt content in inorganic filming substance is reduced, avoid Ludox independent film forming and pore effect occurs, thus improving the adhesive force of coating, resistance to water and early stage film property, and keep coating ultimate cost cheap, modifiied by a small amount of organic silicon solution simultaneously, improve the early stage resistance to water of coating further, hardness and heat-resisting quantity, the coating making final preparation keeps ultrahigh hardness, weather-proof, high temperature resistant, good breathability；The addition of aluminium triphosphate, can significantly improve the anode polarization degree of coating so that it is anodic attack process is subject to obvious retardance, is a kind of anodic corrosion inhibitor；The diffusion of aluminium triphosphate and reaction needed regular hour in film, its later stage corrosion inhibition is notable, makes antirust function be greatly improved；Zinc phosphate and ferric ion have very strong complexing power, and the anion of this zinc phosphate is reacted with iron anode, can form the protecting film based on iron phosphate; the purification membrane of this densification is water insoluble; hardness is high, and adhesive force is excellent, presents the rustless property of brilliance.Owing to zinc phosphate itself has fine activity, complex can be generated with a lot of Action of Metal Ions.Novel antirust powder is, by multiple organic additive, superfine powder and surface of pigments are carried out high-temperature process, it is made to form the clad of densification in surface of pigments, effectively intercept hydrone, oxygen and the erosion to iron and steel of other gas, greatly enhance the pigment adhesive force at steel surface, thus having possessed excellent antirust ability.Wet method flaky mica powder is compared with dry ground muscovite mica, and its laminated structure is complete, and film forming is fine and close, add needle shape wollastonite powder and fill up gap between mica sheet, the layer structure so formed can effectively intercept going deep into of moisture and gas, therefore, has good rust-proof effect.The addition of inorganic dispersant, increases SiO2 aggregate surface sterically hindered, it is possible to effectively prevent coating store or thermal histories in further condensation and gel, substantially prolongs effective storage time of coating.
The performance of the present invention such as following table:
| Project | Index |
| State in a reservoir | Without caking, uniform state after stirring |
| High temperature resistant | ≥800℃ |
| Application property | Twice are accessible |
| Coating thickness | ≥50 |
| Solid content | >=50 |
| Appearance of film | Normally |
| Drying time | Surface drying≤1h does solid work≤3h |
| Resistance to salt water (5%NaCI solution 168h) | Without exception |
| Alkali resistance (0.5%NaOH solution 168h) | Without exception |
| Adhesive force (pulls open method) MPa | >=5 |
| Salt spray resistance 300h | Non-foaming \ do not fall off \ non-corrosive |
| Artificial ageing resistance 300h | Non-foaming \ do not fall off \ \ not efflorescence of not ftractureing |
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.Skilled person will appreciate that of the industry; the present invention is not restricted to the described embodiments; described in above-described embodiment and description is that principles of the invention is described; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements both fall within the claimed scope of the invention.Claimed scope is defined by appending claims and equivalent thereof.
Claims (4)
1. inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology are unified in a bottom surface, it is characterised in that comprise the following steps:
(1) with parts by weight, in blender, the water of addition 14 parts, the wetting agent of 0.1 part, the dispersant of 0.3 part, the defoamer of 0.2 part, the coalescents of 0.5 part, the antifreezing agent of 0.5 part, the thickening agent of 0.3 part, the Ludox of 22 parts, the Lithium metasilicate solution of 5 parts, the potassium silicate solution of 5 parts, 0.5 part of inorganic dispersant are stirred successively, mixing speed is 300 revs/min, mixing time 15 minutes；
(2) adding the color stuffing stirring of 20 parts, mixing speed is 1300 revs/min, mixing time 15 minutes；
(3) adding 15 parts of antirusting powder stirrings, mixing speed is 1300 revs/min, stirs 15 minutes；
(4) adding 5 parts and turn rust passivator stirring, mixing speed 1300 revs/min, mixing time is 15 minutes；
(5) the organosilicon polymer solution of addition 10 parts, the thickening agent of 0.6 part, the defoamer of 0.2 part, 0.8 part anti-dodge rust agent, mixing speed 300 revs/min, stir 10 minutes, filter to obtain antirusting paint after grinding.
2. inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology are unified in bottom surface according to claim 1, it is characterized in that: the modulus of described Lithium metasilicate solution is 3.6-4.0, the modulus of described potassium silicate solution is 2.5-3.0, and the mean diameter of described Ludox is 7-10nm.
3. inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology are unified in bottom surface according to claim 1, it is characterized in that: described organosilicon polymer solution is brother Beyer Co., Ltd GBER-1, described inorganic dispersant is DISPERSOGENSPS silicate paint dispersant, and described wetting agent model is BYK-346；Described dispersant model is 324；Described defoamer model is 367；Described coalescents is dipropylene and dipropylene glycol methyl ether acetate；Described antifreezing agent is ethylene glycol；Described thickening agent is gold group alkali swollen thickener 4280；Anti-sudden strain of a muscle rust agent is U.S. F-179；Described antirusting powder is waterborne anti-rust iron powder (red, black, white etc.)；Described turn of rust passivating material is modified zinc phosphate, modified phosphate aluminum.
4. inorganic turn of rust high-temperature resistant rustproof paint formula and manufacturing technology are unified in bottom surface according to claim 1, it is characterised in that: described color stuffing is made up of rutile titanium white lead, washing barium sulfate, micronized talc powder, ultra-fine mica splitting powder and ultra-fine wollastonite in powder.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610148727.3A CN105801071A (en) | 2016-03-16 | 2016-03-16 | Formula of primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and making technology |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610148727.3A CN105801071A (en) | 2016-03-16 | 2016-03-16 | Formula of primer-topcoat combined inorganic rust conversion high-temperature-resistant anti-rust paint and making technology |
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| CN106866095A (en) * | 2017-01-21 | 2017-06-20 | 河南省豫星华晶微钻有限公司 | A kind of new ceramics coating containing nanometer diamond alkene and preparation method thereof |
| CN106928791A (en) * | 2017-01-06 | 2017-07-07 | 河北晨阳工贸集团有限公司 | A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof |
| WO2019119645A1 (en) * | 2017-12-22 | 2019-06-27 | 江苏怡成屏障科技有限公司 | Eco-friendly low-carbon automatic rust conversion coating and preparation method thereof |
| CN113429817A (en) * | 2021-08-07 | 2021-09-24 | 简达康 | Three-in-one inorganic anticorrosive paint for primary coating, middle coating and top coating |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106928791A (en) * | 2017-01-06 | 2017-07-07 | 河北晨阳工贸集团有限公司 | A kind of environment-friendly water-based acrylic modified alkyd protective paint for spray coating mechanical equipment and material and preparation method thereof |
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| WO2019119645A1 (en) * | 2017-12-22 | 2019-06-27 | 江苏怡成屏障科技有限公司 | Eco-friendly low-carbon automatic rust conversion coating and preparation method thereof |
| CN113429817A (en) * | 2021-08-07 | 2021-09-24 | 简达康 | Three-in-one inorganic anticorrosive paint for primary coating, middle coating and top coating |
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Application publication date: 20160727 |