CN108410321A - A kind of water-base epoxy graphene inorganic scale anticorrosive paint - Google Patents
A kind of water-base epoxy graphene inorganic scale anticorrosive paint Download PDFInfo
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- CN108410321A CN108410321A CN201810296293.0A CN201810296293A CN108410321A CN 108410321 A CN108410321 A CN 108410321A CN 201810296293 A CN201810296293 A CN 201810296293A CN 108410321 A CN108410321 A CN 108410321A
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- 239000003973 paint Substances 0.000 title claims abstract description 34
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 33
- 229910021389 graphene Inorganic materials 0.000 title claims abstract description 32
- 239000004593 Epoxy Substances 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 5
- 239000011347 resin Substances 0.000 claims abstract description 5
- 239000011521 glass Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 39
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- 239000003822 epoxy resin Substances 0.000 claims description 28
- 229920000647 polyepoxide Polymers 0.000 claims description 28
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 14
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000002518 antifoaming agent Substances 0.000 claims description 10
- 229910052710 silicon Inorganic materials 0.000 claims description 10
- 239000010703 silicon Substances 0.000 claims description 10
- 239000000080 wetting agent Substances 0.000 claims description 10
- 239000006184 cosolvent Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 8
- 241000894007 species Species 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 229920000642 polymer Polymers 0.000 claims description 6
- -1 alcohol ethers Chemical class 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 150000002826 nitrites Chemical class 0.000 claims description 5
- 239000004848 polyfunctional curative Substances 0.000 claims description 5
- 238000006116 polymerization reaction Methods 0.000 claims description 5
- 229910001200 Ferrotitanium Inorganic materials 0.000 claims description 4
- 241000276489 Merlangius merlangus Species 0.000 claims description 4
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 150000002009 diols Chemical class 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- 230000008961 swelling Effects 0.000 claims description 4
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 4
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- 239000004816 latex Substances 0.000 claims description 3
- 229920000126 latex Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000011863 silicon-based powder Substances 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 239000010456 wollastonite Substances 0.000 claims description 3
- 229910052882 wollastonite Inorganic materials 0.000 claims description 3
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 3
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 3
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 210000003205 muscle Anatomy 0.000 claims 1
- 239000000454 talc Substances 0.000 claims 1
- 235000012222 talc Nutrition 0.000 claims 1
- 229910052623 talc Inorganic materials 0.000 claims 1
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000003260 anti-sepsis Effects 0.000 abstract description 4
- 230000035699 permeability Effects 0.000 abstract description 3
- 230000007547 defect Effects 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 239000002585 base Substances 0.000 description 10
- 239000002270 dispersing agent Substances 0.000 description 8
- 230000002421 anti-septic effect Effects 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 240000003936 Plumbago auriculata Species 0.000 description 1
- XUBKPYAWPSXPDZ-UHFFFAOYSA-N [Ba].OS(O)(=O)=O Chemical compound [Ba].OS(O)(=O)=O XUBKPYAWPSXPDZ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 150000003376 silicon Chemical class 0.000 description 1
- QPILZZVXGUNELN-UHFFFAOYSA-M sodium;4-amino-5-hydroxynaphthalene-2,7-disulfonate;hydron Chemical compound [Na+].OS(=O)(=O)C1=CC(O)=C2C(N)=CC(S([O-])(=O)=O)=CC2=C1 QPILZZVXGUNELN-UHFFFAOYSA-M 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to anticorrosive paint technology fields, and in particular to a kind of water-base epoxy graphene inorganic scale anticorrosive paint.Water-base epoxy graphene inorganic scale anticorrosive paint of the present invention has many advantages, such as that intensity is high, heat resistance is good, corrosion resistance is strong, permeability resistance is good, coefficient of thermal expansion is small.Select basalt scale, can be good at solve glass flake existing for brittleness is big, mechanical strength is low, thermal coefficient is low, it is easy to aging fall off, the defect that long-effective corrosion performance is not satisfactory, be greatly improved the performance of scale resin heavy antisepsis material.
Description
Technical field
The present invention relates to anticorrosive paint technology fields, and in particular to a kind of water-base epoxy graphene inorganic scale heavy antisepsis painting
Material.
Background technology
Currently, Environmental protection increasingly pay attention to, exploitation water paint be to be not only the task of top priority, even more coating from
The social responsibility of industry personnel, still, compared with solvent type anticorrosive paint, the performance of water-based anticorrosive paint also difference.This
Invention is intended to the excellent antiseptic property using graphene, passes through the inorganic scale with strong inert, permeability resistance height, good mechanical property
Perfect compounding is carried out, to promote the anti-corrosion ability of water paint.
The special structure of graphene makes it have that mechanical property is good, electric property is excellent and has because of its large specific surface area
There is good impermeabilisation iris action, it is often more important that it can be stably dispersed in water paint, so as to anti-with other
Rotten material plays synergistic effect, improves mutual antiseptic property.
Invention content
The present invention relates to a kind of aqueous heavy anti-corrosion paint, what is be related specifically to is that a kind of intensity is high, heat resistance is good, resistance to
The water-base epoxy basalt scale anticorrosive paint that corrosivity is strong, permeability resistance is good, coefficient of thermal expansion is small.
Technical scheme is as follows：
A kind of water-base epoxy graphene inorganic scale anticorrosive paint, including component A and B component, component A include following heavy
Measure the component of part：30~60 parts of aqueous epoxy resins, 3~5 parts of cosolvent, 0.2~1.0 part of antifoaming agent, 0.3~2 part of dispersant,
Face fills out 5~15 parts of agent, 5~15 parts of antirust material, 0.5~3 part of graphene, 10~40 parts of inorganic scale, wetting agent 0.1~-1.0
Part, 0.2~1.5 part of anti-flash rusting agent, 0.1~1.0 part of anti-settling agent, 0.1~1.0 part of levelling agent, 5~20 parts of deionized water, B component
Including aqueous amine epoxy hardener, component A is 4 with B component mass ratio:1~8:1.
Preferably, the aqueous epoxy resins are watersoluble modified epoxy resin, including E44/E51 low molecular weight epoxy trees
In fat, epoxy resin latex, modified epoxy resin emulsion, aqueous epoxy resins dispersion, watersoluble modified epoxy resin dispersion
One or more compositions.
Preferably, the cosolvent is one or more compositions in alcohols, alcohol ethers, alkoxide；Antifoaming agent
For one or more compositions in mineral oils, organic silicon, polymerization species.
Preferably, the dispersant is one or more groups in inorganic, low molecular weight organic, high polymer class
Close object；
Preferably, color stuffing is titanium dioxide, talcum powder, silica flour, coarse whiting, wollastonite in powder, barium sulfate, kaolin, silicon
One or more compositions in micro mist.
Preferably, the antirust material is one or more groups in ferrotitanium powder, trbasic zinc phosphate, aluminum phosphate, tripolyphosphate
Close object；
Preferably, the graphene number of plies is 2-9 layers, it is 5-50 microns a diameter of；
Preferably, the inorganic scale is one or more combinations in glass flake, basalt scale, sericite
Object；
Preferably, the wetting agent is one or more combinations in organic silicon, polymerization species, acetylenic diols
Object；
Preferably, the anti-flash rusting agent is one or more compositions in nitrites, polymerization species；
Preferably, the anti-settling agent is swelling great soil group, aerosil class, and it is polyamide-based, one in polyurethanes
Kind or a variety of compositions；Levelling agent is one or more compositions in organic silicon, polyacrylate.
Advantageous effect
Watersoluble plumbago alkene modified inorganic scale anticorrosive paint of the present invention, utilizes graphene good heat conductivity, machine
The feature that tool performance is excellent, blocking effect is good, plays with inorganic scale and cooperates with antisepsis, the more inorganic squama of antiseptic property of the coating
Piece anticorrosive paint significantly increases.On the other hand, graphene has good light weight, flexibility, large specific surface area, impermeabilisation effect good
The characteristics of, in the case where reaching same antisepsis, the usage amount of inorganic scale can be reduced, or reduce the thickness of coating
Degree promotes the cost performance of anticorrosion with coat, and the application restriction and defect, what is more important that reduction mastic is brought are evaded significantly
Environmental problem caused by traditional solvent-borne coating, it is environmental-friendly.
Currently, the electrodeless flake anticorrosive paint in China is still based on solvent type, this brings greatly to our environment
Damage, although also there is the invention of aqueous inorganic flake paint, can not evade water-base resin antiseptic property be less than solvent
The problem of type resin, and the addition of grapheme material, mutually promote with inorganic scale material, and antiseptic property is excellent, especially stone
Moisture content is reached base material by the high surface area of black alkene through paint film, and the path to corrode base material improves several times, is equivalent to water
The antiseptic property of property anticorrosive paint improves several times, solves the problems, such as that water paint anti-corrosion ability is weak.
Specific implementation mode
For a better understanding of the present invention, below with specific example come the technical solution that the present invention will be described in detail, but this
Invention is not limited thereto.
Embodiment 1
A kind of water-base epoxy graphene inorganic scale anticorrosive paint, including component A and B component, component A include following heavy
Measure the component of part：30 parts of aqueous epoxy resins, 5 parts of cosolvent, 0.2 part of antifoaming agent, 2 parts of dispersant, face fill out 5 parts of agent, antirust material
15 parts, 0.5 part of graphene, 10 parts of inorganic scale, 0.1 part of wetting agent, 1.5 parts of anti-flash rusting agent, 1.0 parts of anti-settling agent, levelling agent 0.1
Part, 5 parts of deionized water, B component include aqueous amine epoxy hardener, and component A is 5 with B component mass ratio:1.
The aqueous epoxy resins are watersoluble modified epoxy resin, including E44/E51 low-molecular-weight epoxy resins, aqueous are changed
The composition of property epoxy resin dispersion.The cosolvent is alcohols；Antifoaming agent is mineral oils.The dispersant is inorganic
Class；Color stuffing is the composition in titanium dioxide, wollastonite in powder, silicon powder.The antirust material is the group in ferrotitanium powder, tripolyphosphate
Close object；The graphene number of plies is 2-9 layers, 5-50 microns a diameter of；The inorganic scale is glass flake；The wetting agent is
Organic silicon；The anti-flash rusting agent is nitrites, polymerize the composition of species；The anti-settling agent is swelling great soil group, gas phase
Silica-based composition；Levelling agent is organic silicon.
Embodiment 2
A kind of water-base epoxy graphene inorganic scale anticorrosive paint, including component A and B component, component A include following heavy
Measure the component of part：60 parts of aqueous epoxy resins, 3 parts of cosolvent, 1.0 parts of antifoaming agent, 0.3 part of dispersant, face fill out 15 parts of agent, antirust
5 parts of material, 3 parts of graphene, 40 parts of inorganic scale, 1.0 parts of wetting agent, 0.2 part of anti-flash rusting agent, 0.1 part of anti-settling agent, levelling agent 1.0
Part, 20 parts of deionized water, B component include aqueous amine epoxy hardener, and component A is 4 with B component mass ratio:1.
The aqueous epoxy resins are watersoluble modified epoxy resin, including epoxy resin latex, modified epoxy resin emulsion
Composition.The cosolvent be alcohol ethers, alkoxide composition；Antifoaming agent is organic silicon, polymerize the composition of species.
The dispersant be low molecular weight organic, high polymer class composition；Color stuffing is talcum powder, silica flour, coarse whiting, sulfuric acid
Barium, kaolinic composition.The antirust material is the composition in aluminum phosphate, tripolyphosphate；The graphene number of plies is 2-9
Layer, it is 5-50 microns a diameter of；The inorganic scale is the composition of basalt scale, sericite；The wetting agent is polymer
Composition in class, acetylenic diols；
The anti-flash rusting agent is nitrites；The anti-settling agent is polyamide-based, the composition in polyurethanes；Levelling
Agent is polyacrylate.
Embodiment 3
A kind of water-base epoxy graphene inorganic scale anticorrosive paint, including component A and B component, component A include following heavy
Measure the component of part：50 parts of aqueous epoxy resins, 4 parts of cosolvent, 0.5 part of antifoaming agent, 1 part of dispersant, face fill out 10 parts of agent, antirust material
10 parts, 2 parts of graphene, 30 parts of inorganic scale, 0.5 part of wetting agent, 1.0 parts of anti-flash rusting agent, 0.5 part of anti-settling agent, levelling agent 0.8
Part, 10 parts of deionized water, B component include aqueous amine epoxy hardener, and component A is 8 with B component mass ratio:1.
The aqueous epoxy resins are watersoluble modified epoxy resin, including aqueous epoxy resins dispersion, watersoluble modified ring
Composition in oxygen resin dispersion.The cosolvent be alcohols, alcohol ethers composition；Antifoaming agent is mineral oils, organic
The composition of silicon class.The dispersant be low molecular weight organic, high polymer class composition；Color stuffing be talcum powder, coarse whiting,
Composition in barium sulfate, silicon powder.The antirust material is the composition of ferrotitanium powder, trbasic zinc phosphate；The graphene number of plies is 2-9
Layer, it is 5-50 microns a diameter of；The inorganic scale is the composition of basalt scale, sericite；The wetting agent is organosilicon
The composition of class, acetylenic diols；The anti-flash rusting agent is nitrites；The anti-settling agent is swelling great soil group, and levelling agent is to have
Machine silicon class.The performance test results of coating described in 1. 1-3 of the embodiment of the present invention of table
| Project | Establishing criteria | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Adhesive force | GB/T1720 | 1-2 grades | 1-2 grades | 1-2 grades |
| Hardness | GB/T6739 | H | H | H |
| Acid resistance (0.05mol/L) | GB/T9274 | 480h is unchanged | 480h is unchanged | 480h is unchanged |
| Alkali resistance (0.1mol/L) | GB/T9274 | 480h is unchanged | 480h is unchanged | 480h is unchanged |
| Water resistance | GB/T1733 | 480h is unchanged | 480h is unchanged | 480h is unchanged |
| Salt spray resistance | GB/T1771 | 960h is unchanged | 960h is unchanged | 960h is unchanged |
Claims (10)
1. a kind of water-base epoxy graphene inorganic scale anticorrosive paint, which is characterized in that including component A and B component, component A
Include the component of following parts by weight：30~60 parts of aqueous epoxy resins, 3~5 parts of cosolvent, 0.2~-1.0 parts of antifoaming agent, dispersion
5~15 parts of agent, 5~15 parts of antirust material, 0.5~3 part of graphene, 10~40 parts of inorganic scale, wetting agent are filled out in 0.3~2 part of agent, face
0.1~1.0 part, 0.2~1.5 part of anti-flash rusting agent, 0.1~1.0 part of anti-settling agent, 0.1~1.0 part of levelling agent, deionized water 5~20
Part, B component includes aqueous amine epoxy hardener, and component A is 4 with B component mass ratio:1~8:1.
2. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that described aqueous
Epoxy resin is watersoluble modified epoxy resin, including E44/E51 low-molecular-weight epoxy resins, epoxy resin latex, modified epoxy
One or more compositions in resin emulsion, aqueous epoxy resins dispersion, watersoluble modified epoxy resin dispersion.
3. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the hydrotropy
Agent is one or more compositions in alcohols, alcohol ethers, alkoxide；Antifoaming agent is mineral oils, organic silicon, polymer
One or more compositions in class.
4. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the dispersion
Agent is one or more compositions in inorganic, low molecular weight organic, high polymer class；Color stuffing is titanium dioxide, talcum
One or more compositions in powder, silica flour, coarse whiting, wollastonite in powder, barium sulfate, kaolin, silicon powder.
5. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the antirust
Material is one or more compositions in ferrotitanium powder, trbasic zinc phosphate, aluminum phosphate, tripolyphosphate.
6. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the graphite
The alkene number of plies is 2-9 layers, 5-50 microns a diameter of.
7. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that described inorganic
Scale is one or more compositions in glass flake, basalt scale, sericite.
8. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the wetting
Agent is one or more compositions in organic silicon, polymerization species, acetylenic diols.
9. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that the anti-sudden strain of a muscle
Rust agent is one or more compositions in nitrites, polymerization species.
10. water-base epoxy graphene inorganic scale anticorrosive paint according to claim 1, which is characterized in that described anti-
Heavy agent is swelling great soil group, aerosil class, polyamide-based, one or more compositions in polyurethanes；Levelling agent
For one or more compositions in organic silicon, polyacrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810296293.0A CN108410321A (en) | 2018-04-03 | 2018-04-03 | A kind of water-base epoxy graphene inorganic scale anticorrosive paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810296293.0A CN108410321A (en) | 2018-04-03 | 2018-04-03 | A kind of water-base epoxy graphene inorganic scale anticorrosive paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108410321A true CN108410321A (en) | 2018-08-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201810296293.0A Pending CN108410321A (en) | 2018-04-03 | 2018-04-03 | A kind of water-base epoxy graphene inorganic scale anticorrosive paint |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109337519A (en) * | 2018-10-22 | 2019-02-15 | 无锡华东锌盾科技有限公司 | A kind of aqueous glass flake paint and preparation method thereof |
| CN109370424A (en) * | 2018-11-22 | 2019-02-22 | 深圳陶金材料科技有限公司 | A kind of preventing corrosion of dew points coating material and preparation method thereof |
| CN109971309A (en) * | 2019-03-09 | 2019-07-05 | 金华市易途新材料有限公司 | A kind of preparation method of fire resistant water-based anticorrosive paint |
| CN110183941A (en) * | 2019-07-04 | 2019-08-30 | 吴波 | A kind of preparation method of the thermally conductive preventing metal corrosion coating of graphene/basalt |
| CN110437654A (en) * | 2019-08-08 | 2019-11-12 | 深圳航天科技创新研究院 | A kind of aqueous inorganic zinc-rich anti-corrosive paint and preparation method thereof |
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| CN110484090A (en) * | 2019-07-23 | 2019-11-22 | 广州化工研究设计院 | A kind of water corrosion-resistant epoxy paint and preparation method thereof |
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| CN110669413A (en) * | 2019-11-06 | 2020-01-10 | 中国科学院宁波材料技术与工程研究所 | A kind of high build low surface treatment moisture curing primer, its preparation method and use method |
| CN110982373A (en) * | 2018-09-30 | 2020-04-10 | 常州大学 | Water-based heavy-duty anti-corrosion flame-retardant coating for metal substrate and preparation method thereof |
| CN112194952A (en) * | 2019-07-08 | 2021-01-08 | 常州市大使涂料有限公司 | Water-based graphene epoxy aging-resistant coating |
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Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740234A (en) * | 2014-01-20 | 2014-04-23 | 苏州高通新材料科技有限公司 | Waterborne epoxy paint with high strength and high tenacity and preparation method thereof |
| CN104371500A (en) * | 2014-11-24 | 2015-02-25 | 张家港保税区冠祥贸易有限公司 | High-corrosion-resistance metal anti-corrosive paint and preparation method thereof |
| CN105623466A (en) * | 2014-11-28 | 2016-06-01 | 中国科学院金属研究所 | High-conductivity heavy anti-corrosion coating and preparation method therefor |
| CN105733405A (en) * | 2016-03-18 | 2016-07-06 | 信和新材料股份有限公司 | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same |
| CN106366710A (en) * | 2016-09-12 | 2017-02-01 | 中国航空工业集团公司北京航空材料研究院 | Graphene heat-conducting anticorrosive water-based paint, and preparation and application methods thereof |
| CN106978041A (en) * | 2017-03-21 | 2017-07-25 | 东南大学 | A kind of preparation method of water-base epoxy basalt flake anticorrosive paint |
| CN107641445A (en) * | 2017-09-26 | 2018-01-30 | 信和新材料股份有限公司 | A kind of fast-drying aqueous zinc powder shop primer of ultra high solids part being modified based on graphene and preparation method thereof |
-
2018
- 2018-04-03 CN CN201810296293.0A patent/CN108410321A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103740234A (en) * | 2014-01-20 | 2014-04-23 | 苏州高通新材料科技有限公司 | Waterborne epoxy paint with high strength and high tenacity and preparation method thereof |
| CN104371500A (en) * | 2014-11-24 | 2015-02-25 | 张家港保税区冠祥贸易有限公司 | High-corrosion-resistance metal anti-corrosive paint and preparation method thereof |
| CN105623466A (en) * | 2014-11-28 | 2016-06-01 | 中国科学院金属研究所 | High-conductivity heavy anti-corrosion coating and preparation method therefor |
| CN105733405A (en) * | 2016-03-18 | 2016-07-06 | 信和新材料股份有限公司 | Graphene-based enhanced high-solid epoxy anticorrosive coating and method for preparing same |
| CN106366710A (en) * | 2016-09-12 | 2017-02-01 | 中国航空工业集团公司北京航空材料研究院 | Graphene heat-conducting anticorrosive water-based paint, and preparation and application methods thereof |
| CN106978041A (en) * | 2017-03-21 | 2017-07-25 | 东南大学 | A kind of preparation method of water-base epoxy basalt flake anticorrosive paint |
| CN107641445A (en) * | 2017-09-26 | 2018-01-30 | 信和新材料股份有限公司 | A kind of fast-drying aqueous zinc powder shop primer of ultra high solids part being modified based on graphene and preparation method thereof |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN110982373A (en) * | 2018-09-30 | 2020-04-10 | 常州大学 | Water-based heavy-duty anti-corrosion flame-retardant coating for metal substrate and preparation method thereof |
| CN109337519A (en) * | 2018-10-22 | 2019-02-15 | 无锡华东锌盾科技有限公司 | A kind of aqueous glass flake paint and preparation method thereof |
| CN109370424A (en) * | 2018-11-22 | 2019-02-22 | 深圳陶金材料科技有限公司 | A kind of preventing corrosion of dew points coating material and preparation method thereof |
| CN109971309A (en) * | 2019-03-09 | 2019-07-05 | 金华市易途新材料有限公司 | A kind of preparation method of fire resistant water-based anticorrosive paint |
| CN110183941A (en) * | 2019-07-04 | 2019-08-30 | 吴波 | A kind of preparation method of the thermally conductive preventing metal corrosion coating of graphene/basalt |
| CN112194952A (en) * | 2019-07-08 | 2021-01-08 | 常州市大使涂料有限公司 | Water-based graphene epoxy aging-resistant coating |
| CN110484090A (en) * | 2019-07-23 | 2019-11-22 | 广州化工研究设计院 | A kind of water corrosion-resistant epoxy paint and preparation method thereof |
| CN110437654A (en) * | 2019-08-08 | 2019-11-12 | 深圳航天科技创新研究院 | A kind of aqueous inorganic zinc-rich anti-corrosive paint and preparation method thereof |
| CN110454620A (en) * | 2019-08-20 | 2019-11-15 | 蔡樟森 | A kind of anticorrosion water supply line |
| CN110454620B (en) * | 2019-08-20 | 2021-02-23 | 江西省共青城润泉供水有限公司 | Anti-corrosion water supply pipeline |
| CN110564262A (en) * | 2019-09-05 | 2019-12-13 | 天恒涂料有限公司 | Graphene-coated titanium nano heavy-duty anticorrosive paint and preparation method thereof |
| CN112778869A (en) * | 2019-11-05 | 2021-05-11 | 宜兴汉光高新石化有限公司 | Water-based two-component epoxy anticorrosive paint for storage tank weld joint and preparation method thereof |
| CN110669413A (en) * | 2019-11-06 | 2020-01-10 | 中国科学院宁波材料技术与工程研究所 | A kind of high build low surface treatment moisture curing primer, its preparation method and use method |
| CN112552794A (en) * | 2020-12-11 | 2021-03-26 | 安徽强旭塑业科技有限公司 | High-heat-resistance coating for battery case and preparation method thereof |
| CN121450203A (en) * | 2026-01-06 | 2026-02-03 | 武汉九西新材料有限公司 | Water-based industrial antirust paint for steel members and preparation method thereof |
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