CN102964940B - A kind of aqueous elastic fluorocarbon coating and preparation method thereof - Google Patents
A kind of aqueous elastic fluorocarbon coating and preparation method thereof Download PDFInfo
- Publication number
- CN102964940B CN102964940B CN201210512198.2A CN201210512198A CN102964940B CN 102964940 B CN102964940 B CN 102964940B CN 201210512198 A CN201210512198 A CN 201210512198A CN 102964940 B CN102964940 B CN 102964940B
- Authority
- CN
- China
- Prior art keywords
- model
- product
- water
- emulsion
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Landscapes
- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of aqueous elastic fluorocarbon coating and preparation method thereof, and this coating application is convenient, with low cost, has excellent weather-proof, resistant, rotproofness and not easily occurs crackle again.A kind of aqueous elastic fluorocarbon coating, be mixed by each component of following proportioning by weight: water-based fluorine emulsion 20 ~ 25, elastic emulsion 19 ~ 23, rutile titanium white powder 20 ~ 22, stopping composition 10 ~ 20, wetting agent 0.1 ~ 0.3, defoamer 0.3 ~ 0.8, thickening material 0.5 ~ 1, film coalescence aid 1.8 ~ 2.5, ammonia dipersant 0.4 ~ 0.8, water 10.42 ~ 13.32, organic amino 0.14.Aqueous elastic fluorocarbon coating of the present invention has water tolerance, resistance to soiling, chemical resistant properties excellent as oiliness F-C paint, and the paint film after film forming can cover fine cracks, has good elasticity and drawing force.Constructional method is consistent with the constructional method of common exterior coating, product environmental protection, nontoxicity.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of aqueous elastic fluorocarbon coating being applied to skin surface and preparation method thereof.
Background technology
Exterior coating develops into multi-functional trend from traditional decoration functions, and wherein the strength of science and technology plays immeasurable effect.Not only require that coating possesses application property strong, safety and environmental protection.Also need to possess the function such as high durable, the feature of environmental protection simultaneously.At present, exterior coating hydrotropismsization, functionalization, high-performance, high-grade development; So in order to ensure painting effect and the working life of exterior wall paint, increasing engineering have selected high-grade exterior wall paint; As the fluorine resin coating of high-weatherability, obtain good effect for building aspect.Because fluorine resin coating has excellent weathering resistance, weather resistance, chemical-resistant compared with other synthetic resins, as all used fluorine resin coating, then price is costly, and construction trouble, metope after construction easily ftractures, and significantly limit the facing that it is applied to external wall.In order to reach cracking resistance, cover the effect of crackle, in industry, more options use aqueous elastic exterior wall paint, although aqueous elastic exterior wall paint can cover crackle, but its resistance to soiling extreme difference, after for some time, coating surface just there will be the same stain of similar tear stains.
Summary of the invention
The problem to be solved in the present invention there is provided a kind of easy construction, with low cost, has excellent weather-proof, resistant, rotproofness aqueous elastic fluorocarbon coating not easily occurring crackle and preparation method thereof again.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme: a kind of aqueous elastic fluorocarbon coating, is mixed: water-based fluorine emulsion 20-25 by each component of following proportioning by weight, elastic emulsion 19-23, rutile titanium white powder 20-22, stopping composition 10-20, wetting agent 0.1-0.3, defoamer 0.3-0.8, thickening material 0.5-1, film coalescence aid 1.8-2.5, ammonium salt dispersion agent 0.4-0.8, water 10.42-13.32, organic amino 0.14.
Described in a kind of aqueous elastic fluorocarbon coating of the present invention, stopping composition is barium sulfate 5-10, the strong powder 3-6 of magnesium, kaolin 2-4.
A kind of aqueous elastic fluorocarbon coating of the present invention also comprises propylene glycol 2-3.
A kind of aqueous elastic fluorocarbon coating of the present invention also comprises flow agent 0.4-0.8.
A kind of aqueous elastic fluorocarbon coating of the present invention also comprises sanitas 0.14, mould inhibitor 0.4-0.6.
The preferred water-based fluorine emulsion 25 of a kind of aqueous elastic fluorocarbon coating of the present invention, elastic emulsion 20, rutile titanium white powder 22, barium sulfate 7.5, the strong powder 5 of magnesium, wetting agent 0.25, defoamer 0.6, thickening material 0.8, film coalescence aid 2, ammonium salt dispersion agent 0.6, water 10.47, kaolin 3, propylene glycol 2.5, urethane flow agent 0.6, organic amine 0.14, sanitas 0.14, mould inhibitor 0.4.
Water-based fluorine emulsion described in a kind of aqueous elastic fluorocarbon coating of the present invention is the mixture of poly(vinylidene fluoride) and polymethylmethacrylate, solid content %49-51, and Oil repellent is 42%; Described elastic emulsion is for having elastomeric anionic acrylic emulsion, and solid content is 49-51%, and minimum film-forming temperature is 3 DEG C; Described barium sulfate fineness≤50 micron are that the hydrochloric acid instillation of 5% is without bubbling by concentration; Strong powder fineness≤20 micron of described magnesium are that the hydrochloric acid instillation of 5% is without bubbling by concentration; Described kaolin fineness≤50 micron are that the hydrochloric acid instillation of 5% is without bubbling by concentration; Described wetting agent is polyether-modified polydimethylsiloxane solution; Described defoamer is modified polyorganosiloxane polyethers Copolymer defoamer; Described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol list isobutyl ester; Described dispersion agent to be concentration be 40% acrylic copolymer ammonium salt solution; Described flow agent is the nonionic polyurethane flow agent of hydrophobic grouping modification; The mixture that described sanitas is made up of CMIT, MIT and formaldehyde; Described mould inhibitor is the mixture of imines benzene azoles carbamate, Kathon and urea derivative.
The product of to be the model of large King Company the be ZEFFLE SE-310 of water-based fluorine emulsion described in a kind of aqueous elastic of the present invention fluorocarbon coating; Described elastic emulsion is the model of BASF AG is the product of 7026; Described rutile titanium white powder is the model of E.I.Du Pont Company is the product of R706; Described barium sulfate is commercially available 800 object products; The strong powder of described magnesium is commercially available 3000 object products; Described wetting agent is the model of BYK auxiliary agent company is the product of BYK346; Described defoamer is the model of BYK auxiliary agent company is the product of BYK022; Described thickening material is the model of Hai Mingsi company is the product of R430; Described film coalescence aid is the model of Yi Si Man is the product of OE300; Described ammonium salt dispersion agent is the model of Ruo Puke company is the product of SN-5027; Described water is deionized water; Described kaolin is commercially available 4000 object products; Described propylene glycol is commercially available prod; Described urethane flow agent is the model of Rhom and Hass is the product of RM2020; Described organic amine is the model of fresh breeze chemical company is the product of AMP95; Described sanitas is the model of Clariant Corporation is the product of HF-1; Described mould inhibitor is the model of Rhom and Hass is the product of 361.
The preparation method of a kind of aqueous elastic fluorocarbon coating of the present invention, by weight, obtained by following steps: one, in production cylinder, add water 10.42-13.32, with mould wash mixer under the rotating speed of 500-800r/min, add ammonium salt dispersion agent 0.4-0.8, wetting agent 0.1-0.3, defoamer 0.3-0.8, organic amine 0.14, Keep agitation 7-10 minute, to even; Two, the rotating speed of mould wash mixer is carried to 800-1000r/min, add rutile titanium white powder 20-22, barium sulfate 5-10, the strong powder 3-6 of magnesium, kaolin 2-4, urethane flow agent 0.4-0.8, add rear raising rotating speed to 1500-2500r/min, Keep agitation dispersion 15-30min, to fineness of dispersion≤50 micron; Three, reduce the rotating speed of mould wash mixer to 500-800r/min, add mould inhibitor 0.4-0.6, propylene glycol 2-3, film coalescence aid 1.8-2.5, water-based fluorine emulsion 20-25, elastic emulsion 19-23, Keep agitation 15-20min after thickening material 0.5-1, adjust ph is to 7.5-9.Four, add sanitas 0.14 and Keep agitation 10-20min, obtain finished product.
The preparation method of a kind of aqueous elastic fluorocarbon coating of the present invention, preferably adopts water-based fluorine emulsion 25, elastic emulsion 20, rutile titanium white powder 22, barium sulfate 7.5, the strong powder 5 of magnesium, wetting agent 0.25, defoamer 0.6, thickening material 0.8, film coalescence aid 2, ammonium salt dispersion agent 0.6, water 10.47, kaolin 3, propylene glycol 2.5, urethane flow agent 0.6, organic amine 0.14, sanitas 0.14, mould inhibitor 0.4.
Water-based fluorine emulsion is the mixture of poly(vinylidene fluoride) and polymethyl acrylate, poly(vinylidene fluoride) is a kind of thermoplastics of excellent performance, is formed by vinylidene fluoride homopolymerization, has excellent ageing resistance and soda acid performance, chemical stability is high, its fusing point is 165-180 DEG C, and decomposition temperature is more than 350 DEG C, and fusing point Sum decomposition temperature difference is larger, therefore processing temperature is wide, but its degree of crystallinity is high, viscosity is large, not easily processes.Polymethyl acrylate add the degree of crystallinity that can reduce poly(vinylidene fluoride), improve the processing plasticity-of poly(vinylidene fluoride), and the cost of material can be reduced in process of production, therefore film has excellent water tolerance and the feature such as weathering resistance, resistance to soiling, chemical resistant properties of excellence.With acrylic copolymer ammonium salt solution for dispersion agent, the storage of product, dispersion and water tolerance are had greatly improved; The ground that wetting agent can make different substrate materials all have excellence soaks and levelling property, can improve the water tolerance of product, has excellent color developing; Defoamer can eliminate the mechanicalness steam bubble produced in processes such as production, packaging, transport, constructions, enhances productivity, improves stability in storage and application property; Rutile titanium white powder can produce opacifying power, has the weathering resistance of high refractive index, high whiteness and excellence; Stopping composition is barium sulfate, the strong powder of magnesium and kaolin, can improve product anti-pollution characteristic and can application property; Adding of film coalescence aid, the minimum film-forming temperature of emulsion can be reduced, improve the film-forming properties of film, thus extend weathering resistance and the ageing resistance of film.
Add propylene glycol, the film-forming properties of film can be improved, improve the low-temperature storage of coating, shorten time of drying.Add flow agent, can opening effect and the application property of product can be improved.Add sanitas and mould inhibitor, effectively can prevent the growth on film of mould class and algae, extend the work-ing life of film.
Aqueous elastic fluorocarbon coating of the present invention is in preparation process, elastic emulsion as added is greater than 23 parts, then the polluting proofing property of coating and weathering resistance will not reach the standard of aqueous fluorine-carbon paint, and the elastic emulsion as added is less than 19 parts, then the effect of prestressed of fluorocarbon coating will disappear; The water-based fluorine emulsion added is greater than 23 parts, then other performance of coating is all good, but without the effect of cracking resistance.Confirm through experiment, the model of large King Company to be the water-based fluorine emulsion of ZEFFLE SE-310 and the model of BASF AG be 7026 elastic emulsion between consistency best.
Compared with prior art, adopt the aqueous elastic fluorocarbon coating that the inventive method prepares, the mating reaction that the water-based fluorine emulsion used and elastic emulsion and other auxiliary agents produce, aqueous elastic fluorocarbon coating of the present invention is made to have water tolerance, resistance to soiling, chemical resistant properties excellent as oiliness F-C paint, and the paint film after film forming can cover fine cracks, has good elasticity and drawing force.Its water-based speciality makes to brush this coating does not need complicated constructional method, consistent with the constructional method of common exterior coating, product environmental protection, nontoxicity.
Embodiment
Embodiment 1
One, in production cylinder, deionized water 13.32kg is added, with mould wash mixer under the rotating speed of 500r/min, the model adding Ruo Puke company is the ammonium salt dispersion agent 0.4kg of SN-5027, the model of BYK auxiliary agent company is the wetting agent 0.1kg of BYK346, the model of BYK auxiliary agent company is the defoamer 0.3kg of BYK022, the model of fresh breeze chemical company is the organic amine 0.14kg of AMP95, Keep agitation 7 minutes, to even;
Two, the rotating speed of mould wash mixer is carried to 800r/min, the model adding E.I.Du Pont Company is the rutile titanium white powder 20kg of R706, commercially available 800 object barium sulfate 10kg, the strong powder 3kg of commercially available 3000 object magnesium, commercially available 4000 object kaolin 2kg, the model of Rhom and Hass is the urethane flow agent 0.4kg of RM2020, adds rear raising rotating speed to 1500r/min, Keep agitation dispersion 15min, to fineness of dispersion≤50 micron;
Three, the rotating speed of mould wash mixer is reduced to 500r/min, the model adding Rhom and Hass is the mould inhibitor 0.4kg of 361, propylene glycol 2kg, the model of Yi Si Man is the film coalescence aid 1.8kg of OE300, the model of large King Company is the water-based fluorine emulsion 25kg of ZEFFLE SE-310, the model of BASF AG is the elastic emulsion 20kg of 7026, and the model of Hai Mingsi company is Keep agitation 15min after the thickening material 1kg of R430, adjust ph to 7.5.
Four, the model adding Clariant Corporation is the sanitas 0.14kg of HF-1 and Keep agitation 10min, obtains finished product.
Five, bucket is packaged into.
Embodiment 2
One, in production cylinder, deionized water 10.47kg is added, with mould wash mixer under the rotating speed of 700r/min, the model adding Ruo Puke company is the ammonium salt dispersion agent 0.6kg of SN-5027, the model of BYK auxiliary agent company is the wetting agent 0.25kg of BYK346, the model of BYK auxiliary agent company is the defoamer 0.6kg of BYK022, the model of fresh breeze chemical company is the organic amine 0.14kg of AMP95, Keep agitation 8 minutes, to even;
Two, the rotating speed of mould wash mixer is carried to 900r/min, the model adding E.I.Du Pont Company is the rutile titanium white powder 22kg of R706, commercially available 800 object barium sulfate 7.5kg, the strong powder 5kg of commercially available 3000 object magnesium, commercially available 4000 object kaolin 3kg, the model of Rhom and Hass is the urethane flow agent 0.6kg of RM2020, adds rear raising rotating speed to 2000r/min, Keep agitation dispersion 20min, to fineness of dispersion≤50 micron;
Three, the rotating speed of mould wash mixer is reduced to 700r/min, the model adding Rhom and Hass is the mould inhibitor 0.4kg of 361, propylene glycol 2.5kg, the model of Yi Si Man is the film coalescence aid 2kg of OE300, the model of large King Company is the water-based fluorine emulsion 25kg of ZEFFLE SE-310, the model of BASF AG is the elastic emulsion 19kg of 7026, and the model of Hai Mingsi company is Keep agitation 20min after the thickening material 0.8kg of R430, adjust ph to 8.
Four, the model adding Clariant Corporation is the sanitas 0.14kg of HF-1 and Keep agitation 15min, obtains finished product.
Five, bucket is packaged into.
Embodiment 3
One, in production cylinder, deionized water 10.42kg is added, with mould wash mixer under the rotating speed of 800r/min, the model adding Ruo Puke company is the ammonium salt dispersion agent 0.8kg of SN-5027, the model of BYK auxiliary agent company is the wetting agent 0.3kg of BYK346, the model of BYK auxiliary agent company is the defoamer 0.8kg of BYK022, the model of fresh breeze chemical company is the organic amine 0.14kg of AMP95, Keep agitation 10 minutes, to even;
Two, the rotating speed of mould wash mixer is carried to 1000r/min, the model adding E.I.Du Pont Company is the rutile titanium white powder 22kg of R706, commercially available 800 object barium sulfate 5kg, the strong powder 6kg of commercially available 3000 object magnesium, commercially available 4000 object kaolin 4kg, the model of Rhom and Hass is the urethane flow agent 0.8kg of RM2020, adds rear raising rotating speed to 2500r/min, Keep agitation dispersion 30min, to fineness of dispersion≤50 micron;
Three, the rotating speed of mould wash mixer is reduced to 800r/min, the model adding Rhom and Hass is the mould inhibitor 0.6kg of 361, propylene glycol 3kg, the model of Yi Si Man is the film coalescence aid 2.5kg of OE300, the model of large King Company is the water-based fluorine emulsion 20kg of ZEFFLE SE-310, the model of BASF AG is the elastic emulsion 23kg of 7026, and the model of Hai Mingsi company is Keep agitation 25min after the thickening material 0.5kg of R430, adjust ph to 9.
Four, the model adding Clariant Corporation is the sanitas 0.14kg of HF-1 and Keep agitation 20min, obtains finished product.
Five, bucket is packaged into.
Adopt national standard HG/T4104-2009 watersoluble fluorine paint for building and JG/T172-2005 elastic building paint two standards to combine, detect the aqueous elastic fluorocarbon coating that the embodiment of the present invention obtains, its detected result is as table 1.
Table 1
Claims (4)
1. an aqueous elastic fluorocarbon coating, is characterized in that, is mixed: water-based fluorine emulsion 20-25 by each component of following proportioning by weight, elastic emulsion 19-23, rutile titanium white powder 20-22, stopping composition 10-20, wetting agent 0.1-0.3, defoamer 0.3-0.8, thickening material 0.5-1, film coalescence aid 1.8-2.5, ammonium salt dispersion agent 0.4-0.8, water 10.42-13.32, organic amine 0.14; Described stopping composition is barium sulfate 5-10, the strong powder 3-6 of magnesium, kaolin 2-4;
Also comprise propylene glycol 2-3;
Also comprise flow agent 0.4-0.8;
Also comprise sanitas 0.14, mould inhibitor 0.4-0.6;
Described water-based fluorine emulsion is the mixture of poly(vinylidene fluoride) and polymethylmethacrylate, solid content 49-51%, and Oil repellent is 42%; Described elastic emulsion is for having elastomeric anionic acrylic emulsion, and solid content is 49-51%, and minimum film-forming temperature is 3 DEG C;
Described barium sulfate fineness≤50 micron are that the hydrochloric acid instillation of 5% is without bubbling by concentration;
Strong powder fineness≤20 micron of described magnesium are that the hydrochloric acid instillation of 5% is without bubbling by concentration;
Described kaolin fineness≤50 micron are that the hydrochloric acid instillation of 5% is without bubbling by concentration;
Described wetting agent is polyether-modified polydimethylsiloxane solution;
Described defoamer is modified polyorganosiloxane polyethers Copolymer defoamer;
Described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol list isobutyl ester;
Described ammonium salt dispersion agent to be concentration be 40% acrylic copolymer ammonium salt solution;
Described flow agent is the nonionic polyurethane flow agent of hydrophobic grouping modification;
The mixture that described sanitas is made up of CMIT, MIT and formaldehyde;
Described mould inhibitor is the mixture of imines benzene azoles carbamate, Kathon and urea derivative.
2. a kind of aqueous elastic fluorocarbon coating according to claim 1, is characterized in that:
The product of described water-based fluorine emulsion to be the model of large King Company be ZEFFLE SE-310;
Described elastic emulsion is the model of BASF AG is the product of 7026;
Described rutile titanium white powder is the model of E.I.Du Pont Company is the product of R706;
Described barium sulfate is commercially available 800 object products;
The strong powder of described magnesium is commercially available 3000 object products;
Described wetting agent is the model of BYK auxiliary agent company is the product of BYK346;
Described defoamer is the model of BYK auxiliary agent company is the product of BYK022;
Described thickening material is the model of Hai Mingsi company is the product of R430;
Described film coalescence aid is the model of Yi Si Man is the product of OE300;
Described ammonium salt dispersion agent is the model of Ruo Puke company is the product of SN-5027;
Described water is deionized water;
Described kaolin is commercially available 4000 object products;
Described propylene glycol is commercially available prod;
Described flow agent is the model of Rhom and Hass is the product of RM2020;
Described organic amine is the model of fresh breeze chemical company is the product of AMP95;
Described sanitas is the model of Clariant Corporation is the product of HF-1;
Described mould inhibitor is the model of Rhom and Hass is the product of 361.
3. a preparation method for aqueous elastic fluorocarbon coating, is characterized in that, by weight, is obtained by following steps:
One, in production cylinder, add water 10.42-13.32, with mould wash mixer under the rotating speed of 500-800r/min, add ammonium salt dispersion agent 0.4--0.8, wetting agent 0.1-0.3, defoamer 0.3-0.8, organic amine 0.14, Keep agitation 7-10 minute, to even;
Two, the rotating speed of mould wash mixer is carried to 800-1000r/min, add rutile titanium white powder 20-22, barium sulfate 5-10, the strong powder 3-6 of magnesium, kaolin 2-4, urethane flow agent 0.4-0.8, add rear raising rotating speed to 1500-2500r/min, Keep agitation dispersion 15-30min, to fineness of dispersion≤50 micron;
Three, reduce the rotating speed of mould wash mixer to 500-800r/min, add mould inhibitor 0.4-0.6, propylene glycol 2-3, film coalescence aid 1.8-2.5, water-based fluorine emulsion 20-25, elastic emulsion 19-23, Keep agitation 15-20min after thickening material 0.5-1, adjust ph is to 7.5-9;
Four, add sanitas 0.14 and Keep agitation 10-20min, obtain finished product.
4. the preparation method of a kind of aqueous elastic fluorocarbon coating according to claim 3, is characterized in that, water-based fluorine emulsion 25, elastic emulsion 20, rutile titanium white powder 22, barium sulfate 7.5, the strong powder 5 of magnesium, wetting agent 0.25, defoamer 0.6, thickening material 0.8, film coalescence aid 2, ammonium salt dispersion agent 0.6, water 10.47, kaolin 3, propylene glycol 2.5, urethane flow agent 0.6, organic amine 0.14, sanitas 0.14, mould inhibitor 0.4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210512198.2A CN102964940B (en) | 2012-12-04 | 2012-12-04 | A kind of aqueous elastic fluorocarbon coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210512198.2A CN102964940B (en) | 2012-12-04 | 2012-12-04 | A kind of aqueous elastic fluorocarbon coating and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102964940A CN102964940A (en) | 2013-03-13 |
| CN102964940B true CN102964940B (en) | 2015-09-30 |
Family
ID=47795384
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210512198.2A Expired - Fee Related CN102964940B (en) | 2012-12-04 | 2012-12-04 | A kind of aqueous elastic fluorocarbon coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102964940B (en) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103468068B (en) * | 2013-05-22 | 2016-01-20 | 上海三银制漆有限公司 | Aqueous elastic fluorine carbon building coating covering large crackle and its preparation method and application |
| CN103421374B (en) * | 2013-08-23 | 2015-10-21 | 苏州长盛机电有限公司 | A kind of art metal furniture coating |
| CN103483954A (en) * | 2013-09-17 | 2014-01-01 | 三棵树涂料股份有限公司 | APEO-free water-based elastic fluorocarbon exterior-wall paint with adjustable colors |
| CN104311722B (en) * | 2014-11-06 | 2017-02-15 | 任婧 | Acrylic resin used for fluorocarbon coatings |
| CN104559592A (en) * | 2014-12-19 | 2015-04-29 | 北京东方雨虹防水技术股份有限公司 | Fluorocarbon elastic paint and preparation method thereof |
| CN106009968A (en) * | 2016-06-27 | 2016-10-12 | 佛山科学技术学院 | Water-based PVDF (polyvinylidene fluoride) fluorocarbon paint and preparation method thereof |
| CN108003713B (en) * | 2017-12-13 | 2020-02-11 | 苏州拓博琳新材料科技有限公司 | Water-based marking paint and preparation method and construction method thereof |
| CN108948892B (en) * | 2018-05-31 | 2020-03-10 | 江西亚龙美氟科技有限公司 | Fluorocarbon coating for wire drawing and preparation method and application thereof |
| CN109135538A (en) * | 2018-08-01 | 2019-01-04 | 合肥尚涵装饰工程有限公司 | A kind of preparation method of sports equipment coating |
| CN109266141A (en) * | 2018-08-27 | 2019-01-25 | 河北君道涂料有限公司 | A kind of self-clean type stone-like coating and preparation method |
| CN109294347A (en) * | 2018-09-03 | 2019-02-01 | 陈威 | A kind of Gao Baose water paint and production method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1794223A1 (en) * | 1968-09-25 | 1971-10-21 | Basf Ag | Stoving enamels based on aqueous dispersions of acrylic ester copolymers containing reactive groups |
| CN101402816A (en) * | 2008-11-04 | 2009-04-08 | 杭州传化涂料有限公司 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
| CN101845254A (en) * | 2009-03-24 | 2010-09-29 | 上海三银制漆有限公司 | Elastic aqueous fluorocarbon paint for external walls |
-
2012
- 2012-12-04 CN CN201210512198.2A patent/CN102964940B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1794223A1 (en) * | 1968-09-25 | 1971-10-21 | Basf Ag | Stoving enamels based on aqueous dispersions of acrylic ester copolymers containing reactive groups |
| CN101402816A (en) * | 2008-11-04 | 2009-04-08 | 杭州传化涂料有限公司 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
| CN101845254A (en) * | 2009-03-24 | 2010-09-29 | 上海三银制漆有限公司 | Elastic aqueous fluorocarbon paint for external walls |
Non-Patent Citations (3)
| Title |
|---|
| PVDE/PMMA共混挤出流延膜结构与性能研究;李卫等;《化工新型材料》;20090930;第37卷(第9期);第40页左栏第1段及第42页第3段 * |
| 氟碳改性弹性外墙乳胶漆;蔡继权等;《浙江化工》;20111031;第42卷(第10期);第2页右栏第1-3段 * |
| 高耐候弹性乳胶涂料的研究开发;高彤等;《新型建筑材料》;20100331;第37卷(第3期);第82页左栏表1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102964940A (en) | 2013-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102964940B (en) | A kind of aqueous elastic fluorocarbon coating and preparation method thereof | |
| CN1200058C (en) | Water fluorine-carbon nanapaint and producing process thereof | |
| CN104073083B (en) | A kind of aqueous elastic fluorine carbon building coating and its preparation method | |
| CN105199558B (en) | Special coil coating of anodic oxidation special-effect of a kind of aluminium sheet coiled material and preparation method thereof | |
| CN103113796B (en) | Water-based fluorocarbon elasticity anti-soil exterior wall paint | |
| CN108047834B (en) | Easily-oriented high-performance fluorine-silicon composite water-based aluminum powder paint and preparation method thereof | |
| CN102504694A (en) | Water-based naon-sized pre-coated coil top coating and preparation method thereof | |
| CN102911568A (en) | Aqueous fluorine carbon coating material and preparation technology thereof | |
| CN106893423A (en) | Agricultural machinery aqueous amino-stoving varnish and preparation method thereof | |
| CN103351795B (en) | Poly-lucid asparagus car paint and preparation method and application | |
| CN103865341A (en) | Waterborne FEVE (chlorotrifluoroethylene copolymer) fluorocarbon coating and preparation method thereof | |
| CN105273121B (en) | Preparation method of fluorine-containing polyvinylidene chloride emulsion for coating | |
| CN1158348A (en) | Aqueous coating compositions | |
| CN104927504A (en) | Building external wall coating | |
| CN101314684B (en) | Single-component fluorine-carbon-aluminum powder baking varnish, preparation, special thinning agent and use method thereof | |
| CN105385314A (en) | Water-based white polyester coil coating special for aluminum ceiling finish paint and preparation method of water-based white polyester coil coating | |
| CN107629608A (en) | A kind of preparation method and construction technology of elastic roofing waterproof paint | |
| CN105462316A (en) | Ultra-high-dirt-resistance outer wall elastic flat coating emulsion paint and preparation method thereof | |
| CN106065264B (en) | A kind of high dedicated sealing wax of anti-corrosion high durable metal component and preparation method thereof | |
| CN106947338B (en) | A kind of dedicated water paint of tape measure and preparation method thereof | |
| CN115960507B (en) | Multifunctional multi-color putty for batch scraping and preparation method thereof | |
| CN103483962A (en) | Silicone-acrylic outer wall paint and preparation method thereof | |
| CN111073407A (en) | Water-based acrylic coating suitable for rapid off-line packaging and preparation method thereof | |
| CN105949958A (en) | Waterborne epoxy modified polyamine curing agent and waterborne epoxy anti-corrosion primer coating | |
| CN108300126A (en) | A kind of water-base epoxy Self-leveling scratch resistance floor coatings and its preparation process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150930 Termination date: 20201204 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |