CN109294347A - A kind of Gao Baose water paint and production method - Google Patents

A kind of Gao Baose water paint and production method Download PDF

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Publication number
CN109294347A
CN109294347A CN201811019031.6A CN201811019031A CN109294347A CN 109294347 A CN109294347 A CN 109294347A CN 201811019031 A CN201811019031 A CN 201811019031A CN 109294347 A CN109294347 A CN 109294347A
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parts
water
paint
production
water paint
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陈威
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陈威
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses a kind of Gao Baose water paint and production method, Gao Baose water paint includes the Gao Baose water paint of emulsion paint system and/or the Gao Baose water paint of inorganic coating system;Its production method is that each raw material of the Gao Baose water paint by the Gao Baose water paint of emulsion paint system and/or inorganic coating system is added portionwise in blender, it adds water and stirs, it is eventually adding polyvinylidene fluoride lotion and dispersible pigment color paste toning, obtains finished product after defoaming agent stirring is added;The Gao Baose water paint that the present invention obtains has high durable, protects the characteristics of color, and final coating obtained is made to have good colour retention.The weatherability and chemical corrosion resistance that coating can also be enhanced, the shortcomings that especially changing poor current emulsion paint exterior coating weatherability, fugitive color.Be religion temple, kindergarten, outdoor advertising, etc. bright-coloured wall mark ideal chose.Use scope is wide, maintenance is simple, cost performance is high.

Description

A kind of Gao Baose water paint and production method
Technical field
The present invention relates to a kind of inorganic polymer, more particularly to it is a kind of by emulsion paint, it is silicate inorganic coating, poly- The Gao Baose water paint and production method that vinylidene fluoride lotion, dispersible pigment color paste make.
Background technique
Preceding exterior coating mainly uses acrylic emulsion for film-forming binder, adds pigment, solvent, auxiliary agent, through toning External wall decorative material made of matching.Exterior coating plays beauty, cleans, the effect of protection is wide for beautifying, protecting metope It is general to use and promote.But the problem of exterior coating weatherability in the prior art is poor, colour fading is that existing exterior coating can not overcome The problem of.Although good weatherability, there is also fade silicate inorganic coating.Therefore, it is necessary to it is a kind of new it is extra-weather-proof, Gao Baose exterior coating is born.
Summary of the invention
The purpose of the present invention is to above-mentioned the shortcomings of the prior art, a kind of Gao Baose water paint and system are provided Make method, be made by emulsion paint, silicate inorganic coating, polyvinylidene fluoride lotion, dispersible pigment color paste, have high durable, The characteristics of protecting color makes final coating obtained have good colour retention.
To achieve the above object, the invention provides the following technical scheme:
A kind of Gao Baose water paint, be emulsion paint system Gao Baose water paint, including water, wetting agent, dispersing agent, Multifunctional assistant, defoaming agent, hydroxyethyl cellulose, thickener, titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite, propylene Yogurt liquid, polyvinylidene fluoride lotion, dispersible pigment color paste, in terms of mass fraction, 20-25 parts of water, divides 0.08-0.15 parts of wetting agent 0.6-0.8 parts of powder, 0.1 part of multifunctional assistant, 0.2-0.3 parts of defoaming agent, 0.3-0.5 parts of hydroxyethyl cellulose, thickener 0.4-0.6 parts, 1-12 parts of titanium dioxide, 8-10 parts of kaolin, 15-20 parts of calcium carbonate, 4-6 parts of talcum powder, 2-3 parts of wollastonite, third 10-15 parts of olefin(e) acid lotion, 8-15 parts of polyvinylidene fluoride lotion, 0.1-8 parts of dispersible pigment color paste.
The step of present invention simultaneously provides the production method of above-mentioned Gao Baose water paint, the production method are as follows:
S1, base-material production, are successively added water, wetting agent, multifunctional assistant, dispersing agent, defoaming agent, hydroxyl second into blender It is mixed after base cellulose, thickener;
S2, addition titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite continue to stir;
S3, addition acrylic emulsion continue to stir;
S4, dispersible pigment color paste toning is added;The dispersible pigment color paste of different colours is added according to user demand color and is added poly- inclined Difluoroethylene lotion, stirring obtain finished product after being eventually adding defoaming agent stirring.
As improvement to above-mentioned technical proposal, in the step S1, mixing speed is 300 revs/min, mixing time 20 minutes.
As improvement to above-mentioned technical proposal, in the step S2, mixing speed is 1300 revs/min, when stirring Between 30 minutes.
As improvement to above-mentioned technical proposal, in the step S3, mixing speed is 300 revs/min, mixing time 20 minutes.
As improvement to above-mentioned technical proposal, in the step S3, dispersible pigment color paste and polyvinylidene fluoride is added 300 revs/min of mixing speed when lotion, mixing time are 20 minutes;300 revs/min of speed when defoaming agent are added, stirs 10 points Clock.
A kind of Gao Baose water paint is the Gao Baose water paint of inorganic coating system, including water, dispersing agent, defoaming Agent, hydroxyethyl cellulose, thickener, silica solution, potassium silicate, inorganic dispersant, titanium dioxide, kaolin, calcium carbonate, talcum powder, Wollastonite, polyvinylidene fluoride lotion, dispersible pigment color paste, in terms of mass fraction, 20-25 parts of water, 0.6-0.8 parts of dispersing agent, defoaming 0.2-0.3 parts of agent, 0.3-0.5 parts of hydroxyethyl cellulose, 0.4-0.6 parts of thickener, 12-15 parts of silica solution, 8-20 parts of potassium silicate, 0.4-0.6 parts of inorganic dispersant, 1-12 parts of titanium dioxide, 8-10 parts of kaolin, 15-20 parts of calcium carbonate, 4-6 parts of talcum powder, silicon ash 2-3 parts of stone, 8-15 parts of polyvinylidene fluoride lotion, 0.1-8 parts of dispersible pigment color paste.
The step of present invention simultaneously provides the production method of above-mentioned Gao Baose water paint, the production method are as follows:
S5, be successively added into blender water, dispersing agent, defoaming agent, mixed after hydroxyethyl cellulose, thickener Stirring;
S6, addition titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite continue to stir;
S7, addition silica solution, potassium silicate solution, inorganic dispersant continue to stir;
S8, dispersible pigment color paste toning is added;The dispersible pigment color paste of different colours is added according to user demand color and is added poly- inclined Difluoroethylene lotion, stirring obtain finished product after being eventually adding defoaming agent stirring.
As improvement to above-mentioned technical proposal, in the step S5, mixing speed is 300 revs/min, mixing time 20 minutes.
As improvement to above-mentioned technical proposal, in the step S6, mixing speed is 1300 revs/min, when stirring Between 30 minutes.
As improvement to above-mentioned technical proposal, in the step S7, mixing speed is 300 revs/min, mixing time 20 minutes.
As improvement to above-mentioned technical proposal, in the step S8, dispersible pigment color paste and polyvinylidene fluoride is added 300 revs/min of mixing speed when lotion, mixing time are 20 minutes;300 revs/min of speed when defoaming agent are added, stirs 10 points Clock.
As improvement to above-mentioned technical proposal, dispersing agent is preferably (inorganic point of silicate paint quaternary ammonium salt dispersants Powder);The defoaming agent is the composite anti-foaming agent of organosilicon and mineral oil;The thickener can be with polyurethanes and the swollen class of alkali soluble The thickener of compounding;The hydroxyethyl cellulose be viscosity 30,000 hydrophobically modified celluloses, the acrylic emulsion be phenylpropyl alcohol or Silicone acrylic emulsion;The modulus of the potassium silicate is 2.5-4.0, and the silica solution average grain diameter is 7-10nm;The dispersible pigment color paste with Iron oxide series is best;The polyvinylidene fluoride lotion is novel aqueous fluorine-containing latex.
It is Piezoelectricity under polyvinylidene fluoride normality, crystallinity is about 50%.Hitherto reported has α, β, γ, δ and ε Deng 5 kinds of crystal forms, they are formed under different conditions, again can under certain condition (effect of heat, electric field, machinery and radiation energy) To mutually convert.Density 1.75-1.78g/cm3.- 39 DEG C of glass transition temperature, -62 DEG C of brittle temperature, 170 DEG C of fusing point, heat 350 DEG C of decomposition temperature or so, long-term use temperature -40~150 DEG C.Its outstanding feature is high mechanical strength, and radioresistance is good. With good chemical stability, do not corroded at room temperature by acid, alkali, strong oxidizer and halogen.
Characteristic: 1, polyvinylidene fluoride has excellent chemical corrosion resistance, excellent high temperature resistant color distortion and resistance to oxidation Property.2, polyvinylidene fluoride has excellent wearability, flexibility, very high anti-rise intensity and impact resistance intensity.3, gather inclined Difluoroethylene has excellent UV resistant and high-energy radiation.4, polyvinylidene fluoride hydrophily is poor.5, it can project and give as security Fluoride resin (being commonly called as thermoplasticity Teflon) out.6, heat resistance is good and has high dielectric strength.
Using petrochemical industry, the electric and big field of fluorocarbon coating three is concentrated mainly on, due to polyvinylidene fluoride tree Rouge weatherability with super strength, can be used for a long time, service free outdoors, such coating be widely used in power station, airport, Highway, skyscraper etc..In addition polyvinylidene fluoride resin can also be modified with other resin alloys, such as gathers inclined difluoro second Alkene is blended to obtain composite material with acrylonitrile butadiene styrene resin, has been widely used for building, automobile dress Decorations, appliance shell etc..
The present invention is remained poly- inclined using the modified aqueous polyvinylidene fluoride lotion produced of polyvinylidene fluoride resin The characteristics of chemical corrosion resistance of difluoroethylene, excellent high temperature resistant be color distortion and oxidative resistance introduces hydrophilic radical, makes its tool Body hydrophily, is processed into water-based emulsion.It is the excellent film forming matter of water-based exterior wall paint.
Aqueous polyvinylidene fluoride lotion wraps up mill base, shields the oxidisability of mill base.
Performance of the invention is following (silicate base-material):
The project indicator
In a reservoir without agglomeration, uniform state after state stirring;
Fineness≤50 micron;
Application property twice are accessible;
Drying time surface drying≤1h;Do solid work≤12h;
Water resistance (168h) is without blistering, slight crack, peeling, picking;
Alkali resistance (0.5%NaOH solution 168h) is without blistering, slight crack, peeling, picking;
Low temperature and thermodynamic stability are without agglomeration, cohesion, mildew phenomena;
Artificial ageing resistance (2000h) is without blistering, slight crack, peeling, dusting, discoloration.
Compared with prior art, the beneficial effects of the present invention are:
Gao Baose water paint of the invention makes water-based exterior wall paint using polyvinylidene fluoride lotion, mill base, can be with It is widely used in emulsion paint, silicate inorganic coating system, it is poor, fugitive color scarce overcomes current water-based exterior wall paint weatherability Point, has vast market prospect;Have the characteristics that high durable using polyvinylidene fluoride lotion, protect color, makes final obtained Coating has good colour retention.Also there is the spy for keeping former emulsion paint, silicate inorganic coating in addition to greatly enhancing colour retention Property, it is excellent to enhance performances, the unfadings such as fire-retardant, hardness, adhesive force, chemical corrosion resistance, simple process and low cost, and one Lift solve current exterior coating weatherability is poor, defect of fugitive color.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution of the present invention is clearly and completely described, it is clear that institute The embodiment of description is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, Every other embodiment obtained by those of ordinary skill in the art without making creative efforts, it is made any Modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Embodiment 1:
Emulsion paint system
Formula: water 20, wetting agent 0.08, dispersing agent 0.6, multifunctional assistant 0.1, defoaming agent 0.2, hydroxyethyl cellulose 0.3, thickener 0.4, titanium dioxide 1, kaolin 8, calcium carbonate 15, talcum powder 4, wollastonite 2, acrylic emulsion 10, gather inclined difluoro Vac emulsion 8, dispersible pigment color paste 0.1.
Production:
1, base-material makes, and in parts by weight, 20 parts of water, 0.08 part of wetting agent, multi-functional is successively added into blender 0.1 part of auxiliary agent, 0.6 part of dispersing agent, 0.2 part of defoaming agent, 0.3 part of hydroxyethyl cellulose, 0.4 part of thickener, speed It is 300 revs/min, mixing time 20 minutes;
2,1 part of titanium dioxide, 8 parts of kaolin, 15 parts of calcium carbonate, 4 parts of talcum powder, 2 parts of wollastonite is added, mixing speed is 1300 revs/min, mixing time 30 minutes;
3,10 parts of acrylic emulsion are added, part mixing speed is 300 revs/min, mixing time 20 minutes;
4,0.1 part of different mill bases, 8-15 parts of polyvinylidene fluoride lotion, speed 300 are added according to user demand color Rev/min, mixing time is 20 minutes;
5, it is added 0.2 part of defoaming agent, 300 revs/min of speed, is stirred 10 minutes.
Embodiment 2:
Emulsion paint system
Formula: water 25, wetting agent 0.15, dispersing agent 0.8, multifunctional assistant 0.1, defoaming agent 0.3, hydroxyethyl cellulose 0.5, thickener 0.6, titanium dioxide 12, kaolin 10, calcium carbonate 20, talcum powder 6, wollastonite 3, acrylic emulsion 15, gather inclined two Vinyl fluoride lotion 15, dispersible pigment color paste 8.
Production:
1, base-material makes, and in parts by weight, 25 parts 0.15 part of water, wetting agent multifunctional assistant is successively added into blender 0.1 part of agent, 0.8 part of dispersing agent, 0.3 part of defoaming agent, 0.5 part of hydroxyethyl cellulose, 0.6 part of thickener, speed are 300 revs/min, mixing time 20 minutes;
2,12 parts of titanium dioxide, 10 parts of kaolin, 20 parts of calcium carbonate, 6 parts of talcum powder, 3 parts of wollastonite is added, mixing speed is 1300 revs/min, mixing time 30 minutes;
3,15 parts of acrylic emulsion are added, part mixing speed is 300 revs/min, mixing time 20 minutes;
4,8 parts of different mill bases, 15 parts of polyvinylidene fluoride lotion are added according to user demand color, 300 turns of speed/ Point, mixing time is 20 minutes;
5, it is added 0.2 part of defoaming agent, 300 revs/min of speed, is stirred 10 minutes.
Embodiment 3:
Inorganic coating system
Formula: water 20, dispersing agent 0.6, defoaming agent 0.2, hydroxyethyl cellulose 0.3, thickener 0.4, silica solution 12, silicic acid Potassium 8, inorganic dispersant 0.4, titanium dioxide 02, kaolin 8, calcium carbonate 15, talcum powder 4, wollastonite 2, polyvinylidene fluoride lotion 8, dispersible pigment color paste 0.1.
Production:
1, base-material makes, and in parts by weight, 20 parts of water, 0.6 part of dispersing agent, 0.2 part is successively added into blender Defoaming agent, 0.3 part of hydroxyethyl cellulose, 0.4 part of thickener speed be 300 revs/min, mixing time 20 minutes;
2,1 part of titanium dioxide, 8 parts of kaolin, 15 parts of calcium carbonate, 4 parts of talcum powder, 2 parts of wollastonite is added, mixing speed is 1300 revs/min, mixing time 30 minutes;
3, be added 12 parts of silica solution, 8 parts of potassium silicate solution, 0.4 part of inorganic dispersant, mixing speed be 600 turns/ Point, mixing time 20 minutes;
4, it mixes colours, 0.1 part of different mill bases, 8 parts of polyvinylidene fluoride lotion, speed is added according to user demand color 300 revs/min, mixing time is 20 minutes;
5, it is added 0.2 part of defoaming agent, 300 revs/min of speed, is stirred 10 minutes.
Embodiment 4:
Inorganic coating system
Formula: water 25, dispersing agent 0.8, defoaming agent 0.3, hydroxyethyl cellulose 0.5, thickener 0.6, silica solution 15, silicic acid Potassium 20, inorganic dispersant 0.6, titanium dioxide 12, kaolin 10, calcium carbonate 20, talcum powder 6, wollastonite 3, polyvinylidene fluoride cream Liquid 15, dispersible pigment color paste 8.
Production:
1, base-material makes, and in parts by weight, 25 parts of water, -0.8 part of dispersing agent, 0.3 part is successively added into blender Defoaming agent, 0.5 part of hydroxyethyl cellulose, 0.6 part of thickener speed be 300 revs/min, mixing time 20 minutes;
2,12 parts of titanium dioxide, 10 parts of kaolin, 20 parts of calcium carbonate, 6 parts of talcum powder, 3 parts of wollastonite is added, mixing speed is 1300 revs/min, mixing time 30 minutes;
3, be added 15 parts of silica solution, 20 parts of potassium silicate solution, 0.5 part of inorganic dispersant, mixing speed be 600 turns/ Point, mixing time 20 minutes;
4, it mixes colours, 8 parts of different mill bases, 15 parts of polyvinylidene fluoride lotion, speed 300 is added according to user demand color Rev/min, mixing time is 20 minutes;
5, it is added 0.2 part of defoaming agent, 300 revs/min of speed, is stirred 10 minutes.
Finally it should be noted that basic principles and main features of the invention and of the invention have been shown and described above Advantage.It should be understood by those skilled in the art that the present invention is not limited to the above embodiments, in above embodiments and description Description merely illustrates the principles of the invention, and without departing from the spirit and scope of the present invention, the present invention also has various Changes and improvements, these changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention is by institute Attached claims and its equivalent thereof.

Claims (7)

1. a kind of Gao Baose water paint, which is characterized in that the Gao Baose water paint includes the Gao Baose water of emulsion paint system The Gao Baose water paint of property coating and/or inorganic coating system;
The Gao Baose water paint of the emulsion paint system, composition of raw materials include water, wetting agent, dispersing agent, multifunctional assistant, Defoaming agent, thickener, titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite, acrylic emulsion, gathers partially hydroxyethyl cellulose Difluoroethylene lotion, dispersible pigment color paste, in terms of mass fraction, 20-25 parts of water, 0.08-0.15 parts of wetting agent, dispersing agent 0.6-0.8 Part, 0.1 part of multifunctional assistant, 0.2-0.3 parts of defoaming agent, 0.3-0.5 parts of hydroxyethyl cellulose, 0.4-0.6 parts of thickener, titanium white 1-12 parts of powder, 8-10 parts of kaolin, 15-20 parts of calcium carbonate, 4-6 parts of talcum powder, 2-3 parts of wollastonite, acrylic emulsion 10-15 Part, 8-15 parts of polyvinylidene fluoride lotion, 0.1-8 parts of dispersible pigment color paste;
The Gao Baose water paint of the inorganic coating system, composition of raw materials include water, dispersing agent, defoaming agent, ethoxy fibre It ties up element, thickener, silica solution, potassium silicate, inorganic dispersant, titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite, gather partially Difluoroethylene lotion, dispersible pigment color paste, in terms of mass fraction, 20-25 parts of water, 0.6-0.8 parts of dispersing agent, 0.2-0.3 parts of defoaming agent, 0.3-0.5 parts of hydroxyethyl cellulose, 0.4-0.6 parts of thickener, 12-15 parts of silica solution, 8-20 parts of potassium silicate, inorganic dispersant 0.4-0.6 parts, it is 1-12 parts of titanium dioxide, 8-10 parts of kaolin, 15-20 parts of calcium carbonate, 4-6 parts of talcum powder, 2-3 parts of wollastonite, poly- 8-15 parts of vinylidene fluoride lotion, 0.1-8 parts of dispersible pigment color paste.
2. Gao Baose water paint according to claim 1, which is characterized in that the dispersing agent is that silicate paint uses season Ammonium salt dispersing agent;The defoaming agent is the composite anti-foaming agent of organosilicon and mineral oil;The thickener is polyurethanes and alkali soluble The thickener of swollen class compounding;The hydroxyethyl cellulose is the hydrophobically modified celluloses of viscosity 30,000, and the acrylic emulsion is benzene Third or silicone acrylic emulsion;The modulus of the potassium silicate is 2.5-4.0, and the silica solution average grain diameter is 7-10nm;The pigment colour Slurry is the dispersible pigment color paste of iron oxide series;The polyvinylidene fluoride lotion is novel aqueous fluorine-containing latex.
3. a kind of production method of Gao Baose water paint as claimed in claim 1 or 2, it is characterised in that: the production method packet Include the Gao Baose water paint production method of emulsion paint system and/or the Gao Baose water paint production side of inorganic coating system Method;
The Gao Baose water paint production method step of emulsion paint system is:
S1, base-material production, it is fine to be successively added water, wetting agent, multifunctional assistant, dispersing agent, defoaming agent, ethoxy into blender It is mixed after dimension element, thickener;
S2, addition titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite continue to stir;
S3, addition acrylic emulsion continue to stir;
S4, dispersible pigment color paste toning is added;The dispersible pigment color paste of different colours is added according to user demand color and addition gathers inclined difluoro Vac emulsion, stirring obtain finished product after being eventually adding defoaming agent stirring;
The Gao Baose water paint production method step of inorganic coating system is:
S5, be successively added into blender water, dispersing agent, defoaming agent, be mixed after hydroxyethyl cellulose, thickener;
S6, addition titanium dioxide, kaolin, calcium carbonate, talcum powder, wollastonite continue to stir;
S7, addition silica solution, potassium silicate solution, inorganic dispersant continue to stir;
S8, dispersible pigment color paste toning is added;The dispersible pigment color paste of different colours is added according to user demand color and addition gathers inclined difluoro Vac emulsion, stirring obtain finished product after being eventually adding defoaming agent stirring.
4. production method according to claim 3, which is characterized in that in step S1, S5, mixing speed 300 Rev/min, mixing time 20 minutes.
5. production method according to claim 3, which is characterized in that in step S2, S6, mixing speed is 1300 revs/min, mixing time 30 minutes.
6. production method according to claim 3, which is characterized in that in step S3, S7, mixing speed is 300 revs/min, mixing time 20 minutes.
7. production method according to claim 3, which is characterized in that in step S4, S8, dispersible pigment color paste is added With 300 revs/min of mixing speed when polyvinylidene fluoride lotion, mixing time is 20 minutes;The speed 300 when defoaming agent is added Rev/min, it stirs 10 minutes.
CN201811019031.6A 2018-09-03 2018-09-03 A kind of Gao Baose water paint and production method Pending CN109294347A (en)

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CN110318271A (en) * 2019-07-10 2019-10-11 常州雅美特窗饰股份有限公司 It is a kind of for improving the toning size and preparation method thereof of casement face color
CN110669367A (en) * 2019-10-11 2020-01-10 深圳市广田环保涂料有限公司 Easily-colored inorganic wall coating and preparation method thereof
CN111234625A (en) * 2019-07-11 2020-06-05 惠州市维尔康王漆化工有限公司 Organic exterior wall coating and preparation process thereof
CN111268991A (en) * 2020-03-10 2020-06-12 浙江华德新材料有限公司 Compound high-color-retention color decorative mortar

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110318271A (en) * 2019-07-10 2019-10-11 常州雅美特窗饰股份有限公司 It is a kind of for improving the toning size and preparation method thereof of casement face color
CN111234625A (en) * 2019-07-11 2020-06-05 惠州市维尔康王漆化工有限公司 Organic exterior wall coating and preparation process thereof
CN110669367A (en) * 2019-10-11 2020-01-10 深圳市广田环保涂料有限公司 Easily-colored inorganic wall coating and preparation method thereof
CN111268991A (en) * 2020-03-10 2020-06-12 浙江华德新材料有限公司 Compound high-color-retention color decorative mortar

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