CN106854410A - A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping - Google Patents

A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping Download PDF

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Publication number
CN106854410A
CN106854410A CN201611123660.4A CN201611123660A CN106854410A CN 106854410 A CN106854410 A CN 106854410A CN 201611123660 A CN201611123660 A CN 201611123660A CN 106854410 A CN106854410 A CN 106854410A
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minutes
coating
added
colorful
silicon substrate
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孟广科
李强
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Anhui Fuyang Fujian Building Materials Co Ltd
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Anhui Fuyang Fujian Building Materials Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/29Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

Abstract

The invention discloses a kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, silicon dioxide gel is prepared first, then palmityl alcohol palmitic acid laurate is dispersed in colloidal sol under ultrasonication, effectively can disperse to form symmetrical liquid drop, at ultrasonic and suitable temperature, silica wraps up palmityl alcohol palmitic acid bay acid droplet, form microcapsule phase-change humidity adjusting material, particle diameter is small, specific surface area is big, it is added in the preparation of interior wall coating, wet effect is passed with good biography, so as to improve phase transformation humidity, indoor environment comfort level can be improved, reducing energy consumption;The colorful sliver interior wall coating that the present invention is made, except the effect with artificial granite true to nature, and weatherability is good, xanthochromia is difficult, construction is simple, and stores up wet stability with preferable phase transformation, regulation indoor humidity, is a kind of safety and Health environmental protection coating attractive in appearance, is worthy to be popularized.

Description

A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping
Technical field
The present invention relates in technical field of coatings, more particularly to a kind of colorful sliver of titanium dioxide silicon substrate microcapsule phase-change damping Wall coating.
Background technology
Aqueous compound sliver artificial granite paint is also sliver paint, granite mineral varnish, category novel pure Water-borne modification without appointing The sand textured building coating of what solvent-borne type material, is rich in the style of granite, the intension of granite, the noble quality of granite, Hua Gang The grade of rock, is the upgrading kind of traditional natural real stone paint.It is right with extensive use of the new coating in construction market The research that the formula of sliver is combined in building coating is increasingly paid close attention to by numerous research workers.The imitative flower of aqueous compound sliver Hilllock rock coating is formulated with high-quality synthetic resin emulsion, coating colored compound sliver, filler, auxiliary agent etc., is closed with tradition Resin emulsion sand textured coating is compared, and it is excellent that its application property, Low Temperature Thermal deposit stability, water-fast and alkali resistance, coating temperature-change resistance Good, During Initial Stage Construction does not split, impact resistance, stain resistant, and weather-proof, adhesion strength is high, and coating exactly likes natural granite, can be used to build interior The decoration of wall and exterior wall, also can be cladding with the natural granite for substituting matter weight as the finish coat of External Thermal Insulation System, Mitigate building to bear a heavy burden, reduce the protection opened Bian, be conducive to ecological environment of granite ore deposit.
Colorful compound sliver is synthesized by high molecular polymer, therefore with superpower water-fast, weatherability, can be with all kinds of aqueous stones Paint is combined closely.The resistance to tensile strength and pick up of compound sliver determine the quality of compound sliver, so as to determine water paint Quality.《The improvement of composite rock slice prescription in outer wall building coating》It is modified by formula in one text, adds wetting agent, divides Powder, defoamer, thickener, coalescents, fungusproof anti-corrosion agent, pH value conditioning agents, coordinate acrylate and vinyl acetate emulsion to be answered with styrene-acrylic emulsion Match somebody with somebody, be made the compound sliver having excellent weather resistance.Although can be lifted compound with acrylate and vinyl acetate emulsion of styrene-acrylic emulsion is made compound sliver Weatherability, but the lifting for being combined the tensile strength, pick up of sliver is modified limited, it is necessary to further match somebody with somebody to compound sliver Emulsion in side is further modified, to meet the demand of the compound sliver of high-quality, while being carried out to water paint a series of Functional form is modified, to meet demand of the interior wall with colorful sliver paint development.
The content of the invention
The object of the invention is exactly to make up the defect of prior art, there is provided a kind of titanium dioxide silicon substrate microcapsule phase-change damping Colorful sliver interior wall coating.
The present invention is achieved by the following technical solutions:
A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, is made up of the raw material of following weight portion: Waterborne Polyurethane Prepolymer 5-6, appropriate deionized water, Lauryl Alcohol ester 1-1.2, Sodium Polyacrylate 0.45-0.5, citric acid three Monooctyl ester 0.5-0.55, ultra-fine natural color stuffing 60-65, styrene 4-4.5, n-butyl acrylate 6-6.4, potassium peroxydisulfate 0.6- 0.65th, pure-acrylic emulsion 80-85, defoamer NXZ1-1.2, propane diols 2.5-3, butyl glycol ether 4-5, polyvinylpyrrolidone 4- 5th, quartz sand 20-24, tetraethyl orthosilicate 9-10, absolute ethyl alcohol 45-50, palmityl alcohol 1.5-1.7, palmitic acid 1-1.2, laurate 2.5-2.6, silane coupler KH5700.9-1,1mol/L hydrochloric acid is appropriate, 2mol/L ammoniacal liquor is appropriate;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, is made up of step in detail below:
(1)Waterborne Polyurethane Prepolymer is put into reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature The deionized water of amount, with stirring and emulsifying 40-50 minutes under 800-1000 revs/min of speed, is subsequently adding potassium peroxydisulfate again, heats To 80-85 DEG C, insulation reaction 90-120 minutes, discharged after cooling, obtain modifying cinepazid emulsion;Modifying cinepazid emulsion is added and is divided Dissipate in machine, stirred with 1500-1800 revs/min of speed, Lauryl Alcohol ester, Sodium Polyacrylate, citric acid three are added while stirring The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10 The film that thickness is 18-19 microns is made after minute, is dried under the conditions of being 155-160 DEG C in temperature, after product cooling, broken It is broken, then sieved with the 7-9 millimeters of mesh screen of mesh, obtain the colorful compound sliver that is modified;
(2)Tetraethyl orthosilicate is mixed with the deionized water that 9-10 times is measured, absolute ethyl alcohol, silane coupler KH570 is subsequently adding, Stirred 15-20 minutes under 60-70 DEG C of water bath condition, be put into afterwards in ultrasonic cell disruption instrument with the power dispersion of 100W It is 3 with the ammoniacal liquor regulation pH of 2mol/L that the hydrochloric acid of appropriate 1mol/L is added after 15-20 minutes, obtains modified silicon dioxide sol and treats With;By palmityl alcohol, palmitic acid, laurate is well mixed is put into reactor, under 60-70 DEG C of water bath condition dissolving and with 500-600 revs/min of speed is stirred 90-120 minutes, in it is added above-mentioned modified silicon dioxide sol after being uniformly dispersed, together Sample is during stirring is put into ultrasonic cell disruption instrument after 15-20 minutes under the 60-70 DEG C of water bath condition with the power dispersion 45- of 100W 50 minutes, the hydrosol that will be obtained was aged 2-3 hours in 60-70 DEG C of thermostat water bath and obtains gel, is finally placed on gel With 80-90 DEG C of drying in drying box, titanium dioxide silicon substrate palmityl alcohol-palmitic acid-laurate microcapsules humidity adjusting material is obtained;
(3)The 22-24 times of deionized water measured will be added in polyvinylpyrrolidone, 40-50 DEG C is heated to, with 500-600 revs/min Speed stir 15-20 minute after be cooled to room temperature, add pure-acrylic emulsion, propane diols, butyl glycol ether, continuation is with 800-1000 Rev/min speed stir 10-15 minutes after add step(2)Product and remaining residual components, stir 20-30 minutes;
(4)To step in the state of being stirred at 750-1000 revs/min(3)Step is slowly added in the product for obtaining(1)Obtain Be modified colorful compound sliver, is obtained final product after being sufficiently stirred for 10-15 minutes.
It is an advantage of the invention that:The present invention is added in the preparation of styrene-acrylic emulsion first with Waterborne Polyurethane Prepolymer, Without any emulsifying agent, using Waterborne Polyurethane Prepolymer as emulsifying agent, the elongation at break of emulsion, water-fast is improved Property, enhance the tensile strength of compound sliver and reduce pick up, simultaneously because addition trioctyl lemon acid and 12 carbon The mutual cooperation of alcohol ester, improves the shaping shape of compound sliver, non-breakable;The present invention will meet sliver and mutually be tied with pure-acrylic emulsion Close, the interior wall coating artificial granite effect prepared is good, high from heavy and light, bin stability, complete aqueous safety non-toxic, while reducing The exploitation of granite, is conducive to ecological protection.
The method comprises the steps of firstly, preparing silicon dioxide gel, then palmityl alcohol-palmitic acid-laurate is disperseed under ultrasonication In colloidal sol, effectively can disperse to form symmetrical liquid drop, at ultrasonic and suitable temperature, silica is by palmityl alcohol-palm Acid-bay acid droplet parcel, forms microcapsule phase-change humidity adjusting material, and particle diameter is small, specific surface area is big, is added to interior wall coating In preparation, wet effect is passed with good biography, so as to improve phase transformation humidity, indoor environment comfort level can be improved, reduced Energy consumption;The colorful sliver interior wall coating that the present invention is made, except the effect with artificial granite true to nature, and weatherability is good, no Easy xanthochromia, construction is simple, and stores up wet stability with preferable phase transformation, adjusts indoor humidity, is a kind of safety and Health environmental protection Coating attractive in appearance, is worthy to be popularized.
Specific embodiment
A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, by following weight portion(Kilogram)Raw material Preparation is made:Waterborne Polyurethane Prepolymer 5, appropriate deionized water, Lauryl Alcohol ester 1, Sodium Polyacrylate 0.45, citric acid three are pungent Ester 0.5, ultra-fine natural color stuffing 60, styrene 4, n-butyl acrylate 6, potassium peroxydisulfate 0.6, pure-acrylic emulsion 80, defoamer NXZ1, propane diols 2.5, butyl glycol ether 4, polyvinylpyrrolidone 4, quartz sand 20, tetraethyl orthosilicate 9, absolute ethyl alcohol 45, palm fibre Palmitic acid alcohol 1.5, palmitic acid 1, laurate 2.5, silane coupler KH5700.9,1mol/L hydrochloric acid is appropriate, 2mol/L ammoniacal liquor is fitted Amount;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, is made up of step in detail below:
(1)Waterborne Polyurethane Prepolymer is put into reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature The deionized water of times amount, with stirring and emulsifying under 800 revs/min of speed 40 minutes, is subsequently adding potassium peroxydisulfate, is heated to 80 DEG C, Insulation reaction 90 minutes, discharges after cooling, obtains modifying cinepazid emulsion;By modifying cinepazid emulsion add dispersion machine in, with 1500 Rev/min speed stirring, Lauryl Alcohol ester, Sodium Polyacrylate, trioctyl lemon acid and total amount equivalent are added while stirring Deionized water, continues to add ultra-fine natural color stuffing after stirring 10 minutes, and it is 18 microns to continue to be made thickness after stirring 8 minutes Film, dries under the conditions of being 155 DEG C in temperature, after product cooling, is crushed, and is then sieved with 7 millimeters of mesh screens of mesh, obtains To modified colorful compound sliver;
(2)Tetraethyl orthosilicate is mixed with the deionized water of 9 times of amounts, absolute ethyl alcohol, silane coupler KH570 is subsequently adding, Stirred 15 minutes under 60 DEG C of water bath conditions, be put into afterwards in ultrasonic cell disruption instrument after the power dispersion 15 minutes with 100W plus It is 3 to enter the hydrochloric acid of appropriate 1mol/L with the ammoniacal liquor regulation pH of 2mol/L, obtains modified silicon dioxide sol stand-by;By palmityl alcohol, Palmitic acid, laurate are well mixed to be put into reactor, is dissolved under 60 DEG C of water bath conditions and is stirred with 500 revs/min of speed Mix 90 minutes, in it is added above-mentioned modified silicon dioxide sol after being uniformly dispersed, equally stir 15 under 60 DEG C of water bath conditions It is put into ultrasonic cell disruption instrument after minute with the power dispersion 45 minutes of 100W, the hydrosol that will be obtained is in 60 DEG C of thermostatted waters Ageing obtains gel in 2 hours in bath, and finally gel is placed in drying box with 80 DEG C of drying, obtains titanium dioxide silicon substrate palmityl alcohol Palmitic acid laurate microcapsules humidity adjusting material;
(3)22 times of deionized waters of amount will be added in polyvinylpyrrolidone, be heated to 40 DEG C, stirred with 500 revs/min of speed Room temperature is cooled to after 15 minutes, pure-acrylic emulsion, propane diols, butyl glycol ether is added, continues to stir 10 with 800 revs/min of speed Step is added after minute(2)Product and remaining residual components, stir 20 minutes;
(4)To step in the state of being stirred at 750 revs/min(3)Step is slowly added in the product for obtaining(1)What is obtained is modified more The compound sliver of coloured silk, obtains final product after being sufficiently stirred for 10 minutes.
It is uniform after coating stirring obtained in the embodiment of the present invention that without shadow is fast, application property is good, easily spraying, levelability is good, Low tempertaure storage without caking, heat-storage without lump, go mouldy, condense and constituent change, surface drying time is less than 4 hours;Film is resistance to Water, alkaline-resisting 48 hours nothings rise and rouse, ftracture, coming off;Adhesion strength is more than 0.5MPa, meets national standard.

Claims (2)

1. a kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping, it is characterised in that by following weight portion Raw material is made:Waterborne Polyurethane Prepolymer 5-6, appropriate deionized water, Lauryl Alcohol ester 1-1.2, Sodium Polyacrylate 0.45- 0.5th, trioctyl lemon acid 0.5-0.55, ultra-fine natural color stuffing 60-65, styrene 4-4.5, n-butyl acrylate 6-6.4, mistake Potassium sulfate 0.6-0.65, pure-acrylic emulsion 80-85, defoamer NXZ1-1.2, propane diols 2.5-3, butyl glycol ether 4-5, polyethylene Pyrrolidones 4-5, quartz sand 20-24, tetraethyl orthosilicate 9-10, absolute ethyl alcohol 45-50, palmityl alcohol 1.5-1.7, palmitic acid 1- 1.2nd, laurate 2.5-2.6, silane coupler KH5700.9-1,1mol/L hydrochloric acid is appropriate, 2mol/L ammoniacal liquor is appropriate;
The ultra-fine natural color stuffing includes two kinds in calcium carbonate superfine powder, ultra-fine barium sulfate, ultrafine mica powder, microfine diatomaceous Or it is several.
2. a kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping according to claim 1, its feature exists In being made up of step in detail below:
(1)Waterborne Polyurethane Prepolymer is put into reactor, styrene, n-butyl acrylate and total amount 4 are added under normal temperature The deionized water of amount, with stirring and emulsifying 40-50 minutes under 800-1000 revs/min of speed, is subsequently adding potassium peroxydisulfate again, heats To 80-85 DEG C, insulation reaction 90-120 minutes, discharged after cooling, obtain modifying cinepazid emulsion;Modifying cinepazid emulsion is added and is divided Dissipate in machine, stirred with 1500-1800 revs/min of speed, Lauryl Alcohol ester, Sodium Polyacrylate, citric acid three are added while stirring The deionized water of monooctyl ester and total amount equivalent, continues to add ultra-fine natural color stuffing after stirring 10-15 minutes, continues to stir 8-10 The film that thickness is 18-19 microns is made after minute, is dried under the conditions of being 155-160 DEG C in temperature, after product cooling, broken It is broken, then sieved with the 7-9 millimeters of mesh screen of mesh, obtain the colorful compound sliver that is modified;
(2)Tetraethyl orthosilicate is mixed with the deionized water that 9-10 times is measured, absolute ethyl alcohol, silane coupler KH570 is subsequently adding, Stirred 15-20 minutes under 60-70 DEG C of water bath condition, be put into afterwards in ultrasonic cell disruption instrument with the power dispersion of 100W It is 3 with the ammoniacal liquor regulation pH of 2mol/L that the hydrochloric acid of appropriate 1mol/L is added after 15-20 minutes, obtains modified silicon dioxide sol and treats With;By palmityl alcohol, palmitic acid, laurate is well mixed is put into reactor, under 60-70 DEG C of water bath condition dissolving and with 500-600 revs/min of speed is stirred 90-120 minutes, in it is added above-mentioned modified silicon dioxide sol after being uniformly dispersed, together Sample is during stirring is put into ultrasonic cell disruption instrument after 15-20 minutes under the 60-70 DEG C of water bath condition with the power dispersion 45- of 100W 50 minutes, the hydrosol that will be obtained was aged 2-3 hours in 60-70 DEG C of thermostat water bath and obtains gel, is finally placed on gel With 80-90 DEG C of drying in drying box, titanium dioxide silicon substrate palmityl alcohol-palmitic acid-laurate microcapsules humidity adjusting material is obtained;
(3)The 22-24 times of deionized water measured will be added in polyvinylpyrrolidone, 40-50 DEG C is heated to, with 500-600 revs/min Speed stir 15-20 minute after be cooled to room temperature, add pure-acrylic emulsion, propane diols, butyl glycol ether, continuation is with 800-1000 Rev/min speed stir 10-15 minutes after add step(2)Product and remaining residual components, stir 20-30 minutes;
(4)To step in the state of being stirred at 750-1000 revs/min(3)Step is slowly added in the product for obtaining(1)Obtain Be modified colorful compound sliver, is obtained final product after being sufficiently stirred for 10-15 minutes.
CN201611123660.4A 2016-12-08 2016-12-08 A kind of colorful sliver interior wall coating of titanium dioxide silicon substrate microcapsule phase-change damping Pending CN106854410A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502078A (en) * 2017-07-20 2017-12-22 江苏荣鑫铝业科技有限公司 Application aluminium weather resistant luminescent coating and its application method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456965A (en) * 2008-12-30 2009-06-17 江阴国联化工有限公司 Method for preparing dry-type water-soluble colorful rock slices
CN103788285A (en) * 2014-01-20 2014-05-14 华南理工大学 Humidity-controlling microcapsule and preparation method thereof as well as application of humidity-controlling microcapsule in interior wall humidity-controlling coating
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105295600A (en) * 2015-10-21 2016-02-03 安徽工业大学 Interior wall coating having multiple functions of temperature and humidity regulation and photocatalysis and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101456965A (en) * 2008-12-30 2009-06-17 江阴国联化工有限公司 Method for preparing dry-type water-soluble colorful rock slices
CN103788285A (en) * 2014-01-20 2014-05-14 华南理工大学 Humidity-controlling microcapsule and preparation method thereof as well as application of humidity-controlling microcapsule in interior wall humidity-controlling coating
CN105219195A (en) * 2015-09-30 2016-01-06 三棵树涂料股份有限公司 A kind of aqueous colorful compound sliver paint and preparation method thereof
CN105295600A (en) * 2015-10-21 2016-02-03 安徽工业大学 Interior wall coating having multiple functions of temperature and humidity regulation and photocatalysis and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502078A (en) * 2017-07-20 2017-12-22 江苏荣鑫铝业科技有限公司 Application aluminium weather resistant luminescent coating and its application method

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Application publication date: 20170616