CN106497256A - Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof - Google Patents
Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof Download PDFInfo
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- CN106497256A CN106497256A CN201610846289.8A CN201610846289A CN106497256A CN 106497256 A CN106497256 A CN 106497256A CN 201610846289 A CN201610846289 A CN 201610846289A CN 106497256 A CN106497256 A CN 106497256A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/24—Trifluorochloroethene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
Abstract
The heat-insulated radial pattern coating of a kind of colored fluorine carbon, it is characterised in which is prepared from by the following raw material：CTFE, INFRARED ABSORPTION nano-powder, perfluoro methyl vinyl ether, butyl acrylate, DAAM, potassium peroxydisulfate, diphenylcarbazide, calgon, vinyl acetate, butanone, acetic acid, mica powder, pigment, cyclohexanone peroxide, hydroxyethyl cellulose, triethylene glycol butyl ether, vinyl bis-stearamides, appropriate sodium acid carbonate, appropriate absolute ethyl alcohol, appropriate deionized water.The heat-insulated radial pattern coating good heat-insulation effect of colored fluorine carbon of the invention；And with excellent mechanical performance, excellent adhesive force；Excellent weatherability, resistance to water, stain resistance, abrasion resistance etc.；Safety and environmental protection, applied widely.
Description
Technical field
The present invention relates to a kind of coating, more particularly to a kind of heat-insulated radial pattern coating of colored fluorine carbon and preparation method thereof.
Background technology
With developing rapidly for China's building trade and becoming increasingly conspicuous for energy crisis, the energy-saving of building is got over
Send out important.The building energy consumption of China accounts for the 27% of national energy aggregate consumption, occupies first of national all kinds of energy consumptions.
The energy consumption of heating and air-conditioning accounts for the 55% of building total energy consumption, but also increases in the speed with annual 1 percentage point.
Because a little, research and develop insulating mold coating for construction and there is great economic benefit, environmental benefit and social benefit.Make in external wall
The original decoration of coating, protection and the function such as mould proof not only can be realized with the coating with heat insulating function, but also make coating
There is heat-insulated function, keep indoor temperature constant, increase the temperature difference of indoor and outdoor, warm energy consumption is reduced in summer, reduced in the winter time
Heat cost.At present, heat-barrier material is just experiencing the transformation to based on heat-insulating heat-insulated from industry, and this is also heat-insulated material from now on
One of main development direction of material.Insulating moulding coating has the disadvantage that in the market：
1st, poor insulation property：The density of glass microballoon or ceramic fine bead is high with respect to borosilicate hollow glass micropearl, thus in phase
With adding under consumption, the coating acquisition dry film heat insultating cavity using glass microballoon or ceramic fine bead is few, and coating thickness is relatively low, adiabatic
Poor performance；
2nd, poor storage stability：Glass microballoon or ceramic fine bead etc. are through surface treatment and density is relatively low, make coating in storage
During easily produce viscosity increase and the phenomenon for floating；
3rd, construct inconvenient：Using glass microballoon or the insulating moulding coating of ceramic fine bead, in order to prevent that floated during storing to show
As, the usual initial viscosity for improving coating, thus higher paint film can only be obtained by the way of blade coating or batch painting during construction
Thickness.
Author Li little Bing et al. exists《The preparation of multifunctional aqueous nano combined insulating mold coating for construction》In one text, with aqueous poly-
Urethane is film forming agent, with well dispersed talcum powder as filler, the rutile titanium dioxide of high reflection, hollow glass micropearl be every
Hot merit energy color stuffing, adds the sericite of high radiance, improves dispersiveness of the Nano filling in coating, system through high speed dispersion
Standby multifunctional aqueous nano composite heat insulation insulating moulding coating；The multifunctional aqueous nano composite heat insulation insulating moulding coating that is developed, its every
Hot excellent thermal insulation performance and the characteristic with high-quality low-cost.
Content of the invention
For the problems referred to above and demand existing for prior art, it is an object of the invention to provide good heat-insulation effect, storage
Stably, heat-insulated radial pattern coating of the colored fluorine carbon of easy construction and preparation method thereof.
For achieving the above object, technical scheme is as follows：
The heat-insulated radial pattern coating of a kind of colored fluorine carbon, it is characterised in which is prepared from by the raw material of following weight portion：Trifluoro chlorine
200 parts of ethene, INFRARED ABSORPTION nano-powder 30-40 parts, perfluoro methyl vinyl ether 30-40 parts, butyl acrylate 30-40 parts,
DAAM 15-20 parts, potassium peroxydisulfate 3-5 parts, diphenylcarbazide 12-15 parts, calgon 6-8 parts, acetic acid
Ethene 20-30 parts, butanone 120-150 parts, acetic acid 20-30 parts, mica powder 10-12 parts, pigment 10-12 parts, cyclohexanone peroxide
2-3 parts, hydroxyethyl cellulose 8-10 parts, triethylene glycol butyl ether 6-8 parts, vinyl bis-stearamides 8-10 part, sodium acid carbonate are fitted
Amount, appropriate absolute ethyl alcohol, appropriate deionized water.
The heat-insulated radial pattern coating of described colored fluorine carbon, it is characterised in that described INFRARED ABSORPTION nano-powder, by as follows
The raw material of weight portion is prepared from：100 parts of sorbierite, ethylene glycol 60-80 parts, 30 parts of wolframic acid, cesium sulfate 10-15 parts, deionization
Appropriate amount of water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：By sorbierite and second two
Alcohol heating for dissolving in jacket reactor, adds wolframic acid and cesium sulfate, after high-speed stirred 30-40min, pumps into homogenizer and followed
Ring homogenizes, and pumps into product and be heated in 140-150 DEG C of autoclave after 60-80min, by autoclave rotating speed
Be set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, close each valve of autoclave, with 10-15 DEG C/
Temperature of reaction kettle is risen to 350 DEG C by the heating rate of min, and is incubated 10-12h, cools to 140-150 DEG C, is released reaction and is produced
Thing, is added thereto to deionized water, and material is squeezed into filter press, with deionized water, absolute ethanol washing 3-5 time, filter cake is put
Enter vacuum drying oven drying, then carry out mechanical crushing and air-flow crushing, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of described colored fluorine carbon, it is characterised in that the heat-insulated radial pattern coating of described colored fluorine carbon
Which is prepared from by following steps：
（1）Vinyl acetate, butanone and acetic acid are mixed, 50-60 DEG C of agitating heating 20-30min on magnetic stirring apparatus is placed in；Slow
Slow addition mica powder and pigment, after ultrasonic disperse 40-50min, add cyclohexanone peroxide, continue stirring anti-at 50-60 DEG C
Answer 5-6h；High-temperature is risen to 80-90 DEG C, continues stirring reaction 4-6h, by the suspension of gained in 8000r/min after the completion of reaction
Centrifugation, and deionized water and absolute ethyl alcohol respectively wash solid product 3-4 time, to remove the impurity substances in product；Most
Dry in the baking oven that the centrifugation product of gained is put into 80 DEG C afterwards
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 10-12 times of CTFE weight portion,
Be added in reactor, add sodium acid carbonate as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, third
Olefin(e) acid butyl ester and DAAM, high-speed stirred dispersion and emulsion 40-50min obtain emulsion droplets particle diameter treating less than 800nm
Polymerization pre-emulsion；Continue under high velocity agitation in reactor lead to nitrogen, exclude reactor in oxygen concentration to 80ppm with
Under, under nitrogen atmosphere, make the emulsion in reactor be warmed up to 60-70 DEG C, potassium peroxydisulfate is added dropwise and equivalent to potassium peroxydisulfate weight
The solution of the deionized water configuration of 5-6 times of part, controls in 40-60min completion of dropping, 60-70 DEG C of isothermal reaction 5-8h, is warmed up to
75-85 DEG C is continued reaction 1-2h, is cooled to 30 DEG C, is added sodium acid carbonate, adjusts the pH value of emulsion to 6-7；Add hexichol phosphinylidyne
Two hydrazines, 50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add calgon, step（1）Product and hydroxyethyl cellulose, with 1800-
2000rpm stirs 30-60min；Triethylene glycol butyl ether and vinyl bis-stearamides are added, 40- is stirred with 800-1000rpm
50min, obtains final product the heat-insulated radial pattern coating of colored fluorine carbon.
The heat-insulated radial pattern coating of described colored fluorine carbon, it is characterised in that described pigment be iron oxide serial pigment, root
According to needing to be configured to different colours.
Application technical scheme, with following technique effect：
The present invention adds INFRARED ABSORPTION nano-powder, using solvent heat liquid phase method technique, with wolframic acid, cesium sulfate production caesium tungsten bronze
INFRARED ABSORPTION nano-powder；Concentrate on 0.78-2.5 mum wavelengths based on 95% of heat energy in sunshine wave band, and caesium tungsten bronze
Lacking oxygen in INFRARED ABSORPTION nano-powder can produce to absorb to the infrared ray of this section of wavelength makes the electron transition of caesium and tungsten paramount
Energy position, produces the reflection and diffraction of light wave luminous energy, enters basic unit so as to separate heat energy, obtains good effect of heat insulation；This
The fluorocarbon resin that invention is obtained with CTFE and acrylic ester polymerization as film forming agent, then with DAAM and hexichol
Two hydrazine of phosphinylidyne carries out cross-linking modified to fluorocarbon resin, enhances the toughness and weatherability of coating, improve coating wearability and
Adhesion property；It is filler that the present invention adds the strong mica powder of insulating properties, high temperature resistant, acid and alkali-resistance, corrosion-resistant, adhesive force, iron oxide
Serial pigment is function color stuffing, gives the colorful color of insulating moulding coating of the invention and corrosion resistance；The present invention fluorine carbon every
Heat radiation type coating good heat-insulation effect；And with excellent mechanical performance, excellent adhesive force；Excellent weatherability, resistance to water,
Stain resistance, abrasion resistance etc.；Safety and environmental protection, applied widely.
Specific embodiment
The heat-insulated radial pattern coating of the colored fluorine carbon of the present embodiment, it is characterised in which is prepared by the raw material of following weight portion
Form：200 parts of CTFE, 40 parts of INFRARED ABSORPTION nano-powder, 40 parts of perfluoro methyl vinyl ether, butyl acrylate 40
Part, 20 parts of DAAM, 5 parts of potassium peroxydisulfate, 15 parts of diphenylcarbazide, 8 parts of calgon, vinyl acetate 30
Part, 150 parts of butanone, 30 parts of acetic acid, 12 parts of mica powder, 12 parts of pigment, 3 parts of cyclohexanone peroxide, 10 parts of hydroxyethyl cellulose, three
8 parts of butyl glycol ether, 10 parts of vinyl bis-stearamides, appropriate sodium acid carbonate, appropriate absolute ethyl alcohol, appropriate deionized water.
The INFRARED ABSORPTION nano-powder of the present embodiment, is prepared from by the raw material of following weight portion：100 parts of sorbierite, second
60 parts of glycol, 30 parts of wolframic acid, 15 parts of cesium sulfate, appropriate deionized water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano powder
Body, is prepared from by following steps：The heating for dissolving in jacket reactor by sorbierite and ethylene glycol, adds wolframic acid and sulfuric acid
Caesium, after high-speed stirred 40min, pumps into homogenizer and is circulated and homogenize, pump into product and be heated to 150 DEG C after 80min
In autoclave, autoclave rotating speed is set to 200r/min, after above-mentioned material is completely transferred to autoclave, is closed high
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 15 DEG C/min, and is incubated 12h, cooled to by each valve of pressure reactor
150 DEG C, product is released, deionized water is added thereto to, material is squeezed into filter press, washed with deionized water, absolute ethyl alcohol
Wash 5 times, put filter cake into vacuum drying oven drying, then carry out mechanical crushing and air-flow crushing, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of the colored fluorine carbon of the present embodiment its be prepared from by following steps：
（1）Vinyl acetate, butanone and acetic acid are mixed, 60 DEG C of agitating heatings 30min on magnetic stirring apparatus are placed in；It is slowly added to
Mica powder and pigment, after ultrasonic disperse 50min, add cyclohexanone peroxide, continue stirring reaction 6h at 60 DEG C；Rise high-temperature
To 90 DEG C, continue stirring reaction 6h, by the suspension of gained in 8000r/min centrifugations after the completion of reaction, and use deionization
Water and absolute ethyl alcohol respectively wash solid product 4 times, to remove the impurity substances in product；Finally the centrifugation product of gained is put into
Dry in 80 DEG C of baking oven
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 12 times of CTFE weight portion, plus
To in reactor, sodium acid carbonate is added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, propylene
Acid butyl ester and DAAM, high-speed stirred dispersion and emulsion 50min obtain emulsion droplets particle diameter to be polymerized less than 800nm
Pre-emulsion；Continue to lead to nitrogen under high velocity agitation in reactor, the oxygen concentration in exclusion reactor to below 80ppm,
Under blanket of nitrogen, make the emulsion in reactor be warmed up to 70 DEG C, potassium peroxydisulfate and going equivalent to 6 times of potassium peroxydisulfate weight portion is added dropwise
The solution of ionized water configuration, controls in 60min completion of dropping, 70 DEG C of isothermal reaction 5-8h, is warmed up to 85 DEG C and continues reaction 2h, drop
Temperature adds sodium acid carbonate to 30 DEG C, adjusts the pH value of emulsion to 6-7；Diphenylcarbazide is added, 60 DEG C are continued reaction 8h；
（3）To step（2）Product in add calgon, step（1）Product and hydroxyethyl cellulose, with 2000rpm
Stirring 60min；Triethylene glycol butyl ether and vinyl bis-stearamides are added, 50min is stirred with 1000rpm, colored fluorine carbon is obtained final product
Heat-insulated radial pattern coating.
After tested, the temperature difference of coating both sides is more than 10 DEG C, and heat-insulated rate is more than 85%.
Claims (4)
1. the heat-insulated radial pattern coating of a kind of colored fluorine carbon, it is characterised in which is prepared from by the raw material of following weight portion：Trifluoro
200 parts of vinyl chloride, INFRARED ABSORPTION nano-powder 30-40 parts, perfluoro methyl vinyl ether 30-40 parts, butyl acrylate 30-40
Part, DAAM 15-20 parts, potassium peroxydisulfate 3-5 parts, diphenylcarbazide 12-15 parts, calgon 6-8 parts, vinegar
Sour ethene 20-30 parts, butanone 120-150 parts, acetic acid 20-30 parts, mica powder 10-12 parts, pigment 10-12 parts, peroxidating hexamethylene
Ketone 2-3 parts, hydroxyethyl cellulose 8-10 parts, triethylene glycol butyl ether 6-8 parts, vinyl bis-stearamides 8-10 part, sodium acid carbonate
In right amount, appropriate absolute ethyl alcohol, appropriate deionized water.
2. the heat-insulated radial pattern coating of colored fluorine carbon according to claim 1, it is characterised in that described INFRARED ABSORPTION nanometer
Powder, is prepared from by the raw material of following weight portion：100 parts of sorbierite, ethylene glycol 60-80 parts, 30 parts of wolframic acid, cesium sulfate 10-
15 parts, appropriate deionized water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：By mountain
Pears alcohol and ethylene glycol heating for dissolving in jacket reactor, adds wolframic acid and cesium sulfate, after high-speed stirred 30-40min, pumps into
Matter machine is circulated and homogenizes, and pumps into product and be heated in 140-150 DEG C of autoclave, by high pressure after 60-80min
Reactor rotating speed is set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, closes each valve of autoclave,
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 10-15 DEG C/min, and is incubated 10-12h, cool to 140-150 DEG C,
Product is released, deionized water is added thereto to, material is squeezed into filter press, with deionized water, absolute ethanol washing 3-5
Secondary, put filter cake into vacuum drying oven drying, then carry out mechanical crushing and air-flow crushing, that is, obtain INFRARED ABSORPTION nano-powder.
3. the heat-insulated radial pattern coating of colored fluorine carbon according to claim 1, it is characterised in that described colored fluorine carbon is heat-insulated
Radial pattern coating its be prepared from by following steps：
（1）Vinyl acetate, butanone and acetic acid are mixed, 50-60 DEG C of agitating heating 20-30min on magnetic stirring apparatus is placed in；Slow
Slow addition mica powder and pigment, after ultrasonic disperse 40-50min, add cyclohexanone peroxide, continue stirring anti-at 50-60 DEG C
Answer 5-6h；High-temperature is risen to 80-90 DEG C, continues stirring reaction 4-6h, by the suspension of gained in 8000r/min after the completion of reaction
Centrifugation, and deionized water and absolute ethyl alcohol respectively wash solid product 3-4 time, to remove the impurity substances in product；Most
Dry in the baking oven that the centrifugation product of gained is put into 80 DEG C afterwards
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 10-12 times of CTFE weight portion,
Be added in reactor, add sodium acid carbonate as nertralizer, adjust pH value to 6-7, be subsequently adding perfluoro methyl vinyl ether, third
Olefin(e) acid butyl ester and DAAM, high-speed stirred dispersion and emulsion 40-50min obtain emulsion droplets particle diameter treating less than 800nm
Polymerization pre-emulsion；Continue under high velocity agitation in reactor lead to nitrogen, exclude reactor in oxygen concentration to 80ppm with
Under, under nitrogen atmosphere, make the emulsion in reactor be warmed up to 60-70 DEG C, potassium peroxydisulfate is added dropwise and equivalent to potassium peroxydisulfate weight
The solution of the deionized water configuration of 5-6 times of part, controls in 40-60min completion of dropping, 60-70 DEG C of isothermal reaction 5-8h, is warmed up to
75-85 DEG C is continued reaction 1-2h, is cooled to 30 DEG C, is added sodium acid carbonate, adjusts the pH value of emulsion to 6-7；Add hexichol phosphinylidyne
Two hydrazines, 50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add calgon, step（1）Product and hydroxyethyl cellulose, with 1800-
2000rpm stirs 30-60min；Triethylene glycol butyl ether and vinyl bis-stearamides are added, 40- is stirred with 800-1000rpm
50min, obtains final product the heat-insulated radial pattern coating of colored fluorine carbon.
4. the heat-insulated radial pattern coating of colored fluorine carbon according to claim 1,3, it is characterised in that described pigment is oxidation
Iron serial pigment, is configured as needed to different colours.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610846289.8A CN106497256A (en) | 2016-09-23 | 2016-09-23 | Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof |
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| CN201610846289.8A CN106497256A (en) | 2016-09-23 | 2016-09-23 | Heat-insulated radial pattern coating of a kind of colored fluorine carbon and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107383263A (en) * | 2017-08-04 | 2017-11-24 | 安徽博泰氟材料科技有限公司 | Water-based fluororesin coating and its preparation technology |
| WO2024070475A1 (en) * | 2022-09-30 | 2024-04-04 | Ａｇｃ株式会社 | Fluorinated polymer composition for painting materials |
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| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104629576A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-performance water-based wood coating |
| CN105859949A (en) * | 2016-06-27 | 2016-08-17 | 南京信息工程大学 | Soap-free fluorocarbon emulsion prepared from perfluoroalkyl ethylenes through copolymerization and preparation method of soap-free fluorocarbon emulsion |
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- 2016-09-23 CN CN201610846289.8A patent/CN106497256A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN104629576A (en) * | 2015-01-19 | 2015-05-20 | 安徽嘉年华漆业有限公司 | High-performance water-based wood coating |
| CN105859949A (en) * | 2016-06-27 | 2016-08-17 | 南京信息工程大学 | Soap-free fluorocarbon emulsion prepared from perfluoroalkyl ethylenes through copolymerization and preparation method of soap-free fluorocarbon emulsion |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383263A (en) * | 2017-08-04 | 2017-11-24 | 安徽博泰氟材料科技有限公司 | Water-based fluororesin coating and its preparation technology |
| WO2024070475A1 (en) * | 2022-09-30 | 2024-04-04 | Ａｇｃ株式会社 | Fluorinated polymer composition for painting materials |
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Application publication date: 20170315 |