CN106479286A - Heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked and preparation method thereof - Google Patents
Heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked and preparation method thereof Download PDFInfo
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- CN106479286A CN106479286A CN201610846278.XA CN201610846278A CN106479286A CN 106479286 A CN106479286 A CN 106479286A CN 201610846278 A CN201610846278 A CN 201610846278A CN 106479286 A CN106479286 A CN 106479286A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/24—Trifluorochloroethene
- C08F214/245—Trifluorochloroethene with non-fluorinated comonomers
- C08F214/247—Trifluorochloroethene with non-fluorinated comonomers with non-fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/32—Radiation-absorbing paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked, it is characterised in which is prepared from by the following raw material：CTFE, INFRARED ABSORPTION nano-powder, perfluorobutyl ethylene, amyl group vinyl ethers, DAAM, ammonium persulfate, cumyl peroxide, tributyl phosphate, neopentyl glycol, trimethylolpropane, absolute ethyl alcohol, carbon nanopowder, diisocyanate, calgon, γ mercaptopropyltriethoxysilane, hydroxyethyl cellulose, prenol, NPE, appropriate sodium carbonate, appropriate deionized water.The heat-insulated radial pattern coating good heat-insulation effect of the fluorine carbon not being cracked of the present invention；And with excellent mechanical performance, excellent adhesive force；Excellent weatherability, resistance to water, stain resistance, abrasion resistance etc.；Safety and environmental protection, applied widely.
Description
Technical field
The present invention relates to a kind of coating, the heat-insulated radial pattern coating of the more particularly to a kind of fluorine carbon not being cracked and its preparation side
Method.
Background technology
With developing rapidly for China's building trade and becoming increasingly conspicuous for energy crisis, the energy-saving of building is got over
Send out important.The building energy consumption of China accounts for the 27% of national energy aggregate consumption, occupies first of national all kinds of energy consumptions.
The energy consumption of heating and air-conditioning accounts for the 55% of building total energy consumption, but also increases in the speed with annual 1 percentage point.
Because a little, research and develop insulating mold coating for construction and there is great economic benefit, environmental benefit and social benefit.Make in external wall
The original decoration of coating, protection and the function such as mould proof not only can be realized with the coating with heat insulating function, but also make coating
With heat-insulated function, keep indoor temperature constant, increase the temperature difference of indoor and outdoor, reduce warm energy consumption in summer, reduce in the winter time
Heat cost.At present, heat-barrier material is just experiencing transformation to heat-insulating based on heat-insulated from industry, and this is also heat-insulated material from now on
One of main development direction of material.Insulating moulding coating has the disadvantage that in the market：
1st, poor insulation property：The density of glass microballoon or ceramic fine bead is high with respect to borosilicate hollow glass micropearl, thus in phase
With adding under consumption, the coating acquisition dry film heat insultating cavity using glass microballoon or ceramic fine bead is few, and coating thickness is relatively low, adiabatic
Poor performance；
2nd, poor storage stability：Glass microballoon or ceramic fine bead etc. are through surface treatment and density is relatively low, make coating in storage
During easily produce the phenomenon that viscosity increases and floats；
3rd, construct inconvenient：Using glass microballoon or the insulating moulding coating of ceramic fine bead, in order to prevent that floated during storing to show
As generally improving the initial viscosity of coating, thus higher paint film can only be obtained using by the way of blade coating or batch painting during construction
Thickness.
Author Li little Bing et al. exists《The preparation of multifunctional aqueous nano combined insulating mold coating for construction》In one text, with aqueous poly-
Urethane be film forming agent, with well dispersed talcum powder as filler, the rutile titanium dioxide of high reflection, hollow glass micropearl be every
Hot merit energy color stuffing, adds the sericite of high radiance, improves dispersiveness of the Nano filling in coating, system through high speed dispersion
Standby multifunctional aqueous nano composite heat insulation insulating moulding coating；The multifunctional aqueous nano composite heat insulation insulating moulding coating that is developed, its every
Hot excellent thermal insulation performance and the characteristic with high-quality low-cost.
Content of the invention
For the problems referred to above existing for prior art and demand, it is an object of the invention to provide good heat-insulation effect, storage
Stably, heat-insulated radial pattern coating of the fluorine carbon not being cracked of easy construction and preparation method thereof.
For achieving the above object, technical scheme is as follows：
The heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked, it is characterised in which is prepared from by the raw material of following weight portion：Three
200 parts of fluorine vinyl chloride, INFRARED ABSORPTION nano-powder 30-40 part, perfluorobutyl ethylene 30-40 part, amyl group vinyl ethers 30-40
Part, DAAM 15-20 part, ammonium persulfate 3-5 part, cumyl peroxide 12-15 part, tributyl phosphate 6-8 part,
Neopentyl glycol 12-15 part, trimethylolpropane 8-10 part, absolute ethyl alcohol 150-200 part, carbon nanopowder 15-20 part, two isocyanic acids
Ester 15-20 part, calgon 5-6 part, gamma-mercaptopropyltriethoxysilane 8-10 part, hydroxyethyl cellulose 8-10 part, isoamyl
Enol 6-8 part, NPE 8-10 part, appropriate sodium carbonate, appropriate deionized water.
The heat-insulated radial pattern coating of the described fluorine carbon not being cracked, it is characterised in that described INFRARED ABSORPTION nano-powder, by
The raw material of following weight portion is prepared from：100 parts of sorbierite, ethylene glycol 60-80 part, 30 parts of wolframic acid, cesium sulfate 10-15 part, go
Ion appropriate amount of water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：By sorbierite and
Ethylene glycol heating for dissolving in the jacket reactor, adds wolframic acid and cesium sulfate, after high-speed stirred 30-40min, pumps into homogenizer and enter
Row circulation homogenizes, and pumps into product and is heated in 140-150 DEG C of autoclave, by autoclave after 60-80min
Rotating speed is set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, closes each valve of autoclave, with 10-
Temperature of reaction kettle is risen to 350 DEG C by the heating rate of 15 DEG C/min, and is incubated 10-12h, cools to 140-150 DEG C, is released anti-
Product is answered, deionized water is added thereto to, material is squeezed into filter press, with deionized water, absolute ethanol washing 3-5 time, will filter
Vacuum drying oven drying put into by cake, then carries out mechanical crushing and air-flow crushing, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of the described fluorine carbon not being cracked, it is characterised in that the heat-insulated spoke of the described fluorine carbon not being cracked
Emitting coating its be prepared from by following steps：
（1）Neopentyl glycol, trimethylolpropane, carbon nanopowder are added in absolute ethyl alcohol, 60-75 DEG C is warming up to, stirring point
Scattered 40-50min, then, adds diisocyanate, calgon, stirs 40-60min, then be warming up to 85-95 DEG C, add
Gamma-mercaptopropyltriethoxysilane, stirs 3-4h, is cooled to room temperature, grinds 30-40min, stand-by；
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 10-12 times of CTFE weight portion,
Be added in reactor, sodium carbonate added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluorobutyl ethylene, amyl group ethene
Base ether and DAAM, high-speed stirred dispersion and emulsion 40-50min, obtain emulsion droplets particle diameter to be polymerized less than 800nm
Pre-emulsion；Continue to lead to nitrogen under high velocity agitation in reactor, the oxygen concentration in exclusion reactor to below 80ppm,
Under blanket of nitrogen, make the emulsion in reactor that 60-70 DEG C is warmed up to, drip ammonium persulfate and equivalent to ammonium persulfate weight portion 5-6
The solution of deionized water configuration again, controls in 40-60min completion of dropping, 60-70 DEG C of isothermal reaction 5-8h, is warmed up to 75-85
DEG C continue reaction 1-2h, 30 DEG C are cooled to, sodium carbonate is added, the pH value of emulsion is adjusted to 6-7；Add cumyl peroxide,
50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add tributyl phosphate, step（1）Product and hydroxyethyl cellulose, with 1800-
2000rpm stirs 30-60min；Prenol and NPE is added, 40-50min is stirred with 800-1000rpm,
Obtain final product the heat-insulated radial pattern coating of the fluorine carbon not being cracked.
Application technical scheme, with following technique effect：
The present invention adds INFRARED ABSORPTION nano-powder, using solvent heat liquid phase method technique, produces caesium tungsten bronze with wolframic acid, cesium sulfate
INFRARED ABSORPTION nano-powder；Concentrate on 0.78-2.5 mum wavelength based on 95% of heat energy in sunshine wave band, and caesium tungsten bronze
Lacking oxygen in INFRARED ABSORPTION nano-powder can produce to absorb to the infrared ray of this section of wavelength makes the electron transition of caesium and tungsten paramount
Energy position, produces reflection and the diffraction of light wave luminous energy, enters basic unit so as to separate heat energy, obtains good effect of heat insulation；This
Invention is polymerized the fluorocarbon resin for obtaining as film forming agent with CTFE, perfluorobutyl ethylene and amyl group vinyl ethers, then with double
Acetone acrylamide and cumyl peroxide carry out cross-linking modified to fluorocarbon resin, enhance toughness and the weatherability of coating,
Improve wearability and the adhesion property of coating；The present invention is using carbon nanopowder as filler, and γ-mercapto propyl triethoxy
Silane and diisocyanate crosslinking are coated on carbon nanopowder surface, be uniformly dispersed, increase the compactness of coating in fluorocarbon resin,
Improve insulating moulding coating adhesive force and crack resistance energy；The heat-insulated radial pattern coating good heat-insulation effect of the fluorine carbon of the present invention；And have
Excellent mechanical performance, excellent adhesive force；Excellent weatherability, resistance to water, stain resistance, abrasion resistance etc.；Safety and environmental protection,
Applied widely.
Specific embodiment
The heat-insulated radial pattern coating of the fluorine carbon not being cracked of the present embodiment, which is prepared from by the raw material of following weight portion：Three
200 parts of fluorine vinyl chloride, 40 parts of INFRARED ABSORPTION nano-powder, 40 parts of perfluorobutyl ethylene, 40 parts of amyl group vinyl ethers, diacetone third
20 parts of acrylamide, 5 parts of ammonium persulfate, 15 parts of cumyl peroxide, 8 parts of tributyl phosphate, 15 parts of neopentyl glycol, trihydroxy methyl
10 parts of propane, 200 parts of absolute ethyl alcohol, 20 parts of carbon nanopowder, 20 parts of diisocyanate, 6 parts of calgon, γ-mercapto propyl group three
10 parts of Ethoxysilane, 10 parts of hydroxyethyl cellulose, 8 parts of prenol, 10 parts of NPE, appropriate sodium carbonate,
Appropriate deionized water.
The INFRARED ABSORPTION nano-powder of the present embodiment, is prepared from by the raw material of following weight portion：100 parts of sorbierite, second
60 parts of glycol, 30 parts of wolframic acid, 15 parts of cesium sulfate, appropriate deionized water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano powder
Body, is prepared from by following steps：By sorbierite and ethylene glycol in the jacket reactor heating for dissolving, add wolframic acid and sulfuric acid
Caesium, after high-speed stirred 40min, pumps into homogenizer and is circulated and homogenize, pump into product and be heated to 150 DEG C after 80min
In autoclave, autoclave rotating speed is set to 200r/min, after above-mentioned material is completely transferred to autoclave, closes high
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 15 DEG C/min, and is incubated 12h, cools to by each valve of pressure reactor
150 DEG C, product is released, deionized water is added thereto to, material is squeezed into filter press, washed with deionized water, absolute ethyl alcohol
Wash 5 times, filter cake is put into vacuum drying oven drying, then mechanical crushing and air-flow crushing is carried out, that is, obtain INFRARED ABSORPTION nano-powder.
The heat-insulated radial pattern coating of the fluorine carbon not being cracked of the present embodiment its be prepared from by following steps：
（1）Neopentyl glycol, trimethylolpropane, carbon nanopowder are added in absolute ethyl alcohol, 75 DEG C are warming up to, dispersed with stirring
50min, then, adds diisocyanate, calgon, stirs 60min, then be warming up to 95 DEG C, add γ-three second of mercapto propyl group
TMOS, stirs 4h, is cooled to room temperature, grinds 40min, stand-by；
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 12 times of CTFE weight portion, plus
To in reactor, sodium carbonate is added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluorobutyl ethylene, amyl group vinyl
Ether and DAAM, high-speed stirred dispersion and emulsion 50min, obtain to be polymerized pre- breast of the emulsion droplets particle diameter less than 800nm
Liquid；Continue to lead to nitrogen in reactor under high velocity agitation, the oxygen concentration in reactor is excluded to below 80ppm, in nitrogen
Under atmosphere, make the emulsion in reactor that 70 DEG C are warmed up to, drip ammonium persulfate and the deionization equivalent to 6 times of ammonium persulfate weight portion
The solution of water configuration, controls in 60min completion of dropping, 70 DEG C of isothermal reaction 8h, is warmed up to 85 DEG C and continues reaction 2h, cools to 30
DEG C, sodium carbonate is added, and the pH value of emulsion is adjusted to 6-7；Cumyl peroxide is added, 60 DEG C are continued reaction 8h；
（3）To step（2）Product in add tributyl phosphate, step（1）Product and hydroxyethyl cellulose, with 2000rpm
Stirring 60min；Prenol and NPE is added, 50min is stirred with 1000rpm, obtains final product the fluorine carbon not being cracked
Heat-insulated radial pattern coating.
After tested, the temperature difference of coating both sides is more than 10 DEG C, and heat-insulated rate is more than 85%.
Claims (3)
1. the heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked, it is characterised in which is prepared from by the raw material of following weight portion：
200 parts of CTFE, INFRARED ABSORPTION nano-powder 30-40 part, perfluorobutyl ethylene 30-40 part, amyl group vinyl ethers 30-40
Part, DAAM 15-20 part, ammonium persulfate 3-5 part, cumyl peroxide 12-15 part, tributyl phosphate 6-8 part,
Neopentyl glycol 12-15 part, trimethylolpropane 8-10 part, absolute ethyl alcohol 150-200 part, carbon nanopowder 15-20 part, two isocyanic acids
Ester 15-20 part, calgon 5-6 part, gamma-mercaptopropyltriethoxysilane 8-10 part, hydroxyethyl cellulose 8-10 part, isoamyl
Enol 6-8 part, NPE 8-10 part, appropriate sodium carbonate, appropriate deionized water.
2. the heat-insulated radial pattern coating of the fluorine carbon not being cracked according to claim 1, it is characterised in that described INFRARED ABSORPTION
Nano-powder, is prepared from by the raw material of following weight portion：100 parts of sorbierite, ethylene glycol 60-80 part, 30 parts of wolframic acid, cesium sulfate
10-15 part, appropriate deionized water, appropriate absolute ethyl alcohol；Described INFRARED ABSORPTION nano-powder, is prepared from by following steps：
By sorbierite and ethylene glycol in the jacket reactor heating for dissolving, add wolframic acid and cesium sulfate, after high-speed stirred 30-40min, pump
Enter homogenizer and be circulated to homogenize, product is pumped into after 60-80min and be heated in 140-150 DEG C of autoclave, will
Autoclave rotating speed is set to 180-200r/min, after above-mentioned material is completely transferred to autoclave, closes autoclave each
Temperature of reaction kettle is risen to 350 DEG C with the heating rate of 10-15 DEG C/min, and is incubated 10-12h, cools to 140- by valve
150 DEG C, product is released, deionized water is added thereto to, material is squeezed into filter press, washed with deionized water, absolute ethyl alcohol
Wash 3-5 time, filter cake is put into vacuum drying oven drying, then mechanical crushing and air-flow crushing is carried out, that is, obtain INFRARED ABSORPTION nano powder
Body.
3. the heat-insulated radial pattern coating of the fluorine carbon not being cracked according to claim 1, it is characterised in that described be not cracked
The heat-insulated radial pattern coating of fluorine carbon its be prepared from by following steps：
（1）Neopentyl glycol, trimethylolpropane, carbon nanopowder are added in absolute ethyl alcohol, 60-75 DEG C is warming up to, stirring point
Scattered 40-50min, then, adds diisocyanate, calgon, stirs 40-60min, then be warming up to 85-95 DEG C, add
Gamma-mercaptopropyltriethoxysilane, stirs 3-4h, is cooled to room temperature, grinds 30-40min, stand-by；
（2）By CTFE, INFRARED ABSORPTION nano-powder, the deionized water equivalent to 10-12 times of CTFE weight portion,
Be added in reactor, sodium carbonate added as nertralizer, adjust pH value to 6-7, be subsequently adding perfluorobutyl ethylene, amyl group ethene
Base ether and DAAM, high-speed stirred dispersion and emulsion 40-50min, obtain emulsion droplets particle diameter to be polymerized less than 800nm
Pre-emulsion；Continue to lead to nitrogen under high velocity agitation in reactor, the oxygen concentration in exclusion reactor to below 80ppm,
Under blanket of nitrogen, make the emulsion in reactor that 60-70 DEG C is warmed up to, drip ammonium persulfate and equivalent to ammonium persulfate weight portion 5-6
The solution of deionized water configuration again, controls in 40-60min completion of dropping, 60-70 DEG C of isothermal reaction 5-8h, is warmed up to 75-85
DEG C continue reaction 1-2h, 30 DEG C are cooled to, sodium carbonate is added, the pH value of emulsion is adjusted to 6-7；Add cumyl peroxide,
50-60 DEG C is continued reaction 6-8h；
（3）To step（2）Product in add tributyl phosphate, step（1）Product and hydroxyethyl cellulose, with 1800-
2000rpm stirs 30-60min；Prenol and NPE is added, 40-50min is stirred with 800-1000rpm,
Obtain final product the heat-insulated radial pattern coating of the fluorine carbon not being cracked.
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| CN201610846278.XA CN106479286A (en) | 2016-09-23 | 2016-09-23 | Heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked and preparation method thereof |
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| CN201610846278.XA CN106479286A (en) | 2016-09-23 | 2016-09-23 | Heat-insulated radial pattern coating of a kind of fluorine carbon not being cracked and preparation method thereof |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN105131772A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Self-cleaning antifouling inter wall paint |
| CN105238153A (en) * | 2015-09-22 | 2016-01-13 | 安徽皖东化工有限公司 | Anti-cracking marine coating and manufacturing method thereof |
-
2016
- 2016-09-23 CN CN201610846278.XA patent/CN106479286A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073083A (en) * | 2014-06-17 | 2014-10-01 | 江苏科技大学 | Water-based elastic fluorocarbon building coating and preparation method thereof |
| CN104192910A (en) * | 2014-08-14 | 2014-12-10 | 宁波今心新材料科技有限公司 | Preparation method of cesium tungstate nanopowder |
| CN105131772A (en) * | 2015-09-06 | 2015-12-09 | 天长市银狐漆业有限公司 | Self-cleaning antifouling inter wall paint |
| CN105238153A (en) * | 2015-09-22 | 2016-01-13 | 安徽皖东化工有限公司 | Anti-cracking marine coating and manufacturing method thereof |
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Application publication date: 20170308 |