CN105694629A - Nano transparent heat-insulating coating and preparation method thereof - Google Patents
Nano transparent heat-insulating coating and preparation method thereof Download PDFInfo
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- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
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- 239000004408 titanium dioxide Substances 0.000 claims description 34
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a nano transparent heat-insulating coating and a preparation method thereof. The nano transparent heat-insulating coating comprises raw materials in parts by weight as follows: 20-25 parts of deionized water, 15-25 parts of nano-silica aerogel slurry, 40-50 parts of water-based acrylic resin, 0.5-1.2 parts of a defoaming agent, 0.6-1.4 parts of a thickening agent, 2-3 parts of a dispersing agent A, 1-2 parts of a leveling agent, 0.05-0.1 parts of dipropylene glycol methyl ether and 0.05-0.1 parts of dipropylene glycol monobutyl ether. The single nano-silica aerogel slurry with excellent performance is added to the nano transparent heat-insulating coating and modified with the optimized dispersing agent, the problems that the nano transparent heat-insulating coating is prone to agglomeration and is difficult to disperse are solved, the ideal nano transparent heat-insulating coating is prepared through optimization of the other raw materials, ratio, processing steps, parameters and the like, the cost is saved, and the construction technology is simplified.
Description
Technical field
The present invention relates to Material Field, particularly relate to a kind of nano transparent insulating coating and preparation method thereof。
Background technology
Along with carrying out and implementing of new " economizing energy law " revised, saving the energy is the long-range strategy and policy that China develops the economy。At present, China's building energy consumption accounts for about the 1/3 of energy wastage in bulk or weight, and construction unit area heating energy consumption is 2 times-3 times of the international close developed country of weather conditions。Therefore, the research and development of new architectural energy saving techniques and the popularization and application of new product, be the effective way promoting Building Energy-saving Work。
Nano material because of the nano effect of its uniqueness, can give, after being usually added in traditional coating dispersion and former coating being modified, the performance that coating is excellent。The coating that it is disperse medium with water that water paint refers to, organic solvent volatilization is less, pollution-free, safety non-toxic, is the main flow direction of modern coatings development。So, nano material modifiying owing to its importance in environmental protection is particularly very powerful and exceedingly arrogant in recent years water paint。How to make nano material really with nano-scale dispersion in water paint, play its nano effect, it is thus achieved that high-performance, good stability water-thinned nanometer paint there is highly important using value。
If can successfully nano transparent insulating coating be applied on building glass, can effectively intercept the sun infra-red radiation by clear glass, allow and absorbed by human body in visible ray inlet chamber, and the long wave that indoor object radiates can be retained in indoor, open up a new approach for building energy conservation。Chinese patent CN101186781A (a kind of transparent heat insulating dope and preparation method thereof) adopts and adds several different nano material silicon dioxide, titanium dioxide, tin indium oxide, fullerene C60Mixing carries out ultrasonic disperse 20～30 times, and nano material is natively because its unique properties, and grain refine dispersion rear surface is long-pending to increase, and surface free energy increases accordingly, and surface activity strengthens, and causes that the dispersion of nano-particle difficulty is easily reunited；Add multiple nano material, technology difficulty and jitter time will be substantially increased。Chinese patent CN1844281A (environment-friendly antifouling weather-resistant heat-reflecting thermal-insulating coating and preparation method thereof) adopts interpolation titanium dioxide, ball-type closed perlite, pulverized limestone, hollow glass, several different inorganic fillers to carry out ball milling dispersion, dispersing technology is simple, but it is inconspicuous in heat-proof quality, the applicator transparency is also had a great impact, improves cost simultaneously。
Summary of the invention
Based on this, it is necessary for the problems referred to above, a kind of nanometer water transparent heat insulating dope and preparation method thereof is provided, the present invention can relate to the coating as building glass and vehicle glass, for the coating variety of difference in functionality/type that the multiple fields such as heat-insulation and heat-preservation, environmental protection and energy saving, high temperature resistant, chemical resistance are suitable for。
For realizing above-mentioned technical purpose, concrete technical scheme is as follows:
A kind of nano transparent insulating coating, its raw material forms with parts by weight, including:
Wherein, the raw material of described nanometer titanium dioxide silica aerogel slurry forms with parts by weight, including:
Nanometer titanium dioxide silica aerogel of the present invention has porous network structure, and heat conductivity can be low to moderate 0.001W.m-1.k-1。
Wherein in some embodiments, described dispersant A is macromolecule dispersing agent；Described dispersant B is silane coupler and/or macromolecule dispersing agent。The preferred KH-570 of above-mentioned silane coupler；The preferred acrylic acid series polymer dispersants of above-mentioned macromolecule dispersing agent, such as 1053 nano-dispersing agent。The preferred above-mentioned dispersant of the present invention can well disperse nanometer titanium dioxide silica aerogel, and does not reunite after dispersion。Nano silicon aerogel powder particle can be made to be distributed within the scope of 30～90nm, and do not destroy its internal structure so that it is premium properties is well played。
Wherein in some embodiments, described water-borne acrylic resin solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)。Outside the main absworption peak of light is in solar spectrum by currently preferred above-mentioned resin, there is particularly excellent light resistance and resistance to outdoor aging with its coating made, and color is shallow, water-white is transparent, fast light weatherability is good, heat-resistant antifriction loses, and acid, alkali, salt, oils and fats, detergent etc. are had good repellence, is well suited on glass coating and applies。
Wherein in some embodiments, described defoamer is the non-ionic defoamer of mineral oils。The non-ionic defoamer of currently preferred mineral oils requires that its active component is 100%。Preferred De Qian company model is the defoamer DP-082 of 082。Defoamer selected by the present invention can well eliminate the difficult problem that nano material bubble is many。
Wherein in some embodiments, described thickening agent is modified polyacrylic acid thickening agent。The model of preferred De Qian company is WT-102 thickening agent。
Wherein in some embodiments, described levelling agent is modified polyurethane levelling agent。Preferred De Qian company model is the levelling agent DP-495 of 495。Levelling agent preferred for this invention, it is possible to what make that film becomes is uniform, smooth。
The preparation method that the present invention also provides for a kind of above-mentioned nano transparent insulating coating, comprises the following steps:
(1) preparation of nanometer titanium dioxide silica aerogel slurry:
Take described dispersant B, wetting dispersing agent, deionized water and nanometer titanium dioxide silica aerogel, mixing, regulating pH value is 7.5～8.5, disperses on dispersion machine, it is subsequently placed in grinding machine for grinding, prepares powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm；
(2) preparation of transparent heat insulating dope:
Take described water-borne acrylic resin, nanometer titanium dioxide silica aerogel slurry, dispersant A, defoamer, levelling agent, thickening agent, dipropylene glycol methyl ether and dipropylene that deionized water, step (1) obtain, mixing, regulating pH value is 7.5～8.5, dispersion machine disperses, it is placed in grinding machine for grinding, to obtain final product。
Wherein in some embodiments, the jitter time in described step (1) is 15～20min, rotating speed 1150～1250rpm；Milling time is 2～3h, rotating speed 2900～3100rpm。
Wherein in some embodiments, the jitter time in described step (2) is 15～20min, and rotating speed is 1150～1250rpm；Milling time is 1～2h, and grinding rate is 2400～2600rpm。
The present invention is in the technological difficulties overcoming the dispersion of existing nano material difficulty easily to reunite, it is provided that one is not only transparent but also heat insulation, and preparation method is simple simultaneously, easy construction, can from the well-illuminated insulating moulding coating of one nanometer of dry low cost。
Heat transmission is by conduction, convection current, three kinds of modes of radiation。Reach good heat-proof quality, be necessary for above-mentioned 3 kinds of modes are taked measure targetedly。Air has only small heat conductivity, if can manage to make in solid containing air static in a large number, then this solid will have good heat-proof quality。And aerogel material is owing to having the hole of the nanometer scale in space, grain skeleton is very very thin, and the gas heat-transfer for the gentle inside of the contact heat conductien of solid-state all has very big inhibition undoubtedly。That is aeroge is a kind of excellent ground thermal conducting material。
Nano-meter SiO_2 of the present invention2Aeroge has the nanostructured of uniqueness, and bore hole size and particle diameter range are nanometer scale (1-100nm), and form open nanometer porous structure and continuous print three-dimensional net structure, its high-specific surface area (200～1000m2/ g), high porosity (80%～99.8%) and low-density (3～600kg/m3), make Nano-meter SiO_22The network skeleton granule of aeroge reaches nanoscale and it has also reached nanometer scale in pore structure, aerogel material is thus made to have nanoscale and nano-pore structure double grading, it is highly desirable nanocatalyst, adsorbent and catalyst carrier material, its catalysis activity and selectivity is significantly larger than conventional catalyst, and it also has excellent heat stability, the generation of side reaction can be efficiently reduced, increase the service life。
The present invention utilizes Nano-meter SiO_22The aeroge selectivity characteristic to solar spectrum, with Nano-meter SiO_22Aeroge is primary raw material, and selection transparent resin is film forming matter, the two is mixed with other auxiliary aid prepared transparent heat insulating dope, is applied to the glass surface of building, does not change the light transmission of glass, can effectively shield infrared emanation and intercept ultraviolet。Also there is the functions such as antistatic, anti-dazzle, suppression ultraviolet radiation destruction。Simultaneously, coating of the present invention, while ensureing visible light-transmissive, goes back the room heater heat radiation that reflection wavelength is longer, is conducive to heating effect and stops that indoor heat is leaked by glass door and window conduction, reduce the loss of indoor energy in winter, to reach the energy-saving effect of " cool in summer and warm in winter "。
Coating of the present invention adopts Nano-meter SiO_22Aeroge is major function filler, and its heat-proof quality is excellent。It is a kind of desirably heat-insulation transparent material。The fields such as solar energy is heat insulation, solar heating, detector surface insulation can be widely used in, use scope wide, and the requirement of environmental protection can be reached and improve the coating life-span。
But polarity and the granule granular due to nano material itself, there is great specific surface area and higher specific surface energy, it is made not easily to disperse in apolar medium, polarizable medium is easily reunited, directly affect the performance of they performances, during final utilization, lose the specific performance that nanoparticle possesses。The dispersion of general nano material is natively not easy, and very easily reunites after a period of time after reaching certain dispersion effect, so that its performance can not get fully playing。And transparent heat insulating dope is on the coating thickness of 5-25 μm, it is necessary to its good heat-proof quality just can make it be coated on glass and play good heat insulating function。
The present inventor team is for Nano-meter SiO_22Aeroge particularity in an aqueous medium, it is preferable that maximally effective dispersant is to Nano-meter SiO_22Aeroge carries out disperseing and surface modification, further according to factor impacts on the stability of nano material water slurry such as dispersing mode (mechanical agitation, grinding etc.), the consumption of dispersant, pH value, nano material consumptions, determine most suitable dispersing technology and condition, prepare desirable nano silicon slurry。
After preparing above-mentioned nano silicon slurry, inventor team is scattered in the technology of preparing in water paint and allied processes by the modified nano material of research further, suitable raw material and proportioning is selected to improve bin stability and the contaminated resistance of this water-thinned nanometer paint, analyze the modified nanoparticle slurry best formation condition in water paint and the affecting laws to coating properties, determine its optimum addition, finally prepare nano transparent insulating coating of the present invention。
The advantage of hinge structure of the present invention and having the beneficial effect that
(1) the nanometer titanium dioxide silica aerogel of single function admirable is added, and by preferred dispersants etc., nanometer titanium dioxide silica aerogel is modified, eliminate its not easily scattered problem of easily reuniting, and preferably all the other raw materials and proportioning, processing step, parameter etc., prepare desirable nano transparent insulating coating, and save cost and simplify construction technology。
(2) existing general heat reflection plated film on the market, low reflection plated film or general nano transparent insulating coating is overcome to have a heat-proof quality and visible light transmissivity is not high or both performances are all undesirable, it is possible to make to be applied glass and reach good transparent heat-insulated performance。
(3) bar spreader, wet film preparing device can be used or manually brush, coated film, it is not necessary to heating, drying, can certainly do by self-curing, be easy to use people and be coated with voluntarily, technique is simple, convenient and easy。
(4) there is good environmental friendliness function, without solvent composition, nontoxic pollution-free。
Detailed description of the invention
Below with reference to specific embodiment, the present invention will be further described。
The raw material that the embodiment of the present invention adopts is commercially available convenient source, wherein:
Water-borne acrylic resin is purchased from DOW Chemical；
1053 dispersants are purchased from Shanghai Yong Yan Chemical Industry Science Co., Ltd；
Nanometer titanium dioxide silica aerogel is purchased from Changsha Xingna Aerogel Co., Ltd.；
Wetting dispersing agent PE-100 is purchased from Shanghai Yong Yan Chemical Industry Science Co., Ltd；
Silane coupling reagent KH-570 is purchased from Shanghai Yong Yan Chemical Industry Science Co., Ltd；
Thickening agent WT-102 is purchased from De Qian company；
Defoamer DP-082 is purchased from De Qian company；
Levelling agent DP-495 is purchased from De Qian company；
Dipropylene glycol methyl ether and dipropylene are purchased from Dow Chemical；
The formula table of the nanometer titanium dioxide silica aerogel slurry used in embodiment:
Embodiment 1
Certain gymnasium, in order to improve heat-proof quality, reduces power consumption, adopts the nano transparent heat-insulating material External Wall glass of the embodiment of the present invention 1 to be coated。
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 45KG, (sequence number 1 formula material mixes nanometer titanium dioxide silica aerogel slurry 25KG, regulate pH value 7.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 2h on grinder, rotating speed is 3000rpm, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。), 1053 dispersants (dispersant A) 3KG, defoamer DP-0821.2KG, thickening agent WT-1021.4KG, levelling agent DP-4952KG, dipropylene glycol methyl ether 0.1KG, dipropylene 0.1KG, deionized water 25KG。
Preparation method is:
By above-mentioned mixing of materials, regulating pH value 7.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 1h on grinder, and rotating speed is 2500rpm, obtains nano transparent insulating coating。
With specialty cleaning agent and instrument, outer window glass is thoroughly cleaned before construction, nano transparent insulating coating Special coating device is coated in glass surface (coating thickness is 10～25 μm)；Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured；Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。In summer shop, temperature can reduce by 6～12 DEG C when not turning on the aircondition, use in air-conditioning situation can power saving 30%～40%, energy-conservation 35%～45% can be realized generally。
Embodiment 2
Certain megastore, in order to increase light transmission while improving heat-proof quality, adopts the embodiment of the present invention 2 nano transparent heat-insulating material External Wall glass to be coated。
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 50KG, (sequence number 2 formula material mixes nanometer titanium dioxide silica aerogel slurry, regulate pH value 7.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 3h on grinder, rotating speed is 3000rpm, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 15KG, 1053 dispersants (dispersant A) 2KG, defoamer DP-0820.5KG, thickening agent WT-1020.6KG, levelling agent DP-4951KG, dipropylene glycol methyl ether 0.08KG, dipropylene 0.08KG, deionized water 20KG。
Preparation method is:
By above-mentioned mixing of materials, regulating pH value 7.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 2h on grinder, and rotating speed is 2500rpm, obtains nano transparent insulating coating。
With specialty cleaning agent and instrument, outer window glass is thoroughly cleaned before construction, nano transparent insulating coating Special coating device is coated in glass surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured；Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。In summer market, temperature can reduce by 8～14 DEG C when not turning on the aircondition, use in air-conditioning situation can power saving 35%～45%, and light transmittance is greatly improved than patch thermal isolation film, can realize energy-conservation 35%～45% generally, reduce cost 50%～60%。
Embodiment 3
Certain school, improves Students ' Learning environment in order to summer is heat insulation, adopts the nano transparent heat-insulating material External Wall glass of the embodiment of the present invention 3 to be coated。
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 50KG, (sequence number 3 formula material mixes nanometer titanium dioxide silica aerogel slurry, regulate pH value 8.0, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 2h on grinder, rotating speed is 3000rpm, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 20KG, 1053 dispersants (dispersant A) 2.5KG, defoamer DP-0821KG, thickening agent WT-1021KG, levelling agent DP-4951.5KG, dipropylene glycol methyl ether 0.1KG, dipropylene 0.1KG, deionized water 23KG。
Preparation method is:
By above-mentioned mixing of materials, regulating pH value 8.0, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 2h on grinder, and rotating speed is 2500rpm, obtains nano transparent insulating coating。
With specialty cleaning agent and instrument, outer window glass is thoroughly cleaned before construction, nano transparent insulating coating Special coating device is coated in glass surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured。Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。In summer classroom, temperature can reduce by 6～12 DEG C。
Embodiment 4
Certain residential houses district, in order to increase light transmission while improving heat-proof quality, adopts the nano transparent heat-insulating material External Wall glass of the embodiment of the present invention 4 to be coated。
Formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 45KG, (sequence number 4 formula material mixes nanometer titanium dioxide silica aerogel slurry, regulate pH value 8.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 2h on grinder, rotating speed is 3000rpm, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 20KG, 1053 dispersants (dispersant A) 3KG, defoamer DP-0820.9KG, thickening agent WT-1020.8KG, levelling agent DP-4951.2KG, dipropylene glycol methyl ether 0.1KG, dipropylene 0.1KG, deionized water 22KG。
Preparation method is:
By above-mentioned mixing of materials, regulating pH value 7.5, high speed dispersion 15min on dispersion machine, rotating speed is 1200rpm, then grinds 1h on grinder, and rotating speed is 2500rpm, obtains nano transparent insulating coating。
With specialty cleaning agent and instrument, outer window glass is thoroughly cleaned before construction, main for nano transparent insulating coating paint Special coating device is coated in glass surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured；Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。In summer room, temperature can reduce by 5～10 DEG C when not turning on the aircondition, and under using air-conditioning situation can power saving 35%～45%, energy-conservation 40%～45%. can be realized generally
Embodiment 5
Certain newly-built high-grade office building, in order to increase light transmission while improving heat-proof quality, adopts the nano transparent heat-insulating material External Wall glass of the embodiment of the present invention 5 to be coated。
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 50KG, nanometer titanium dioxide silica aerogel slurry (sequence number 3 formula, preparation method, with embodiment 3, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 20KG, 1053 dispersants (dispersant A) 2KG, defoamer DP-0821.1KG, thickening agent WT-1021.2KG, levelling agent DP-4951.8KG, dipropylene glycol methyl ether 0.1KG, dipropylene 0.1KG, deionized water 21KG。
Preparation method, with embodiment 3, obtains nano transparent heat-insulating material。
With specialty cleaning agent and instrument, outer window glass is thoroughly cleaned before construction, nano transparent insulating coating Special coating device is coated in glass surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured；Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through；In summer building, temperature can reduce by 7～14 DEG C when not turning on the aircondition, and under using air-conditioning situation can power saving 35%～45%, energy-conservation 40%～45% can be realized generally。
Coating of the present invention is mainly applied as external wall glass, plays good heat-blocking action, also has other purposes simultaneously:
Embodiment 6
Adopt the nano transparent heat-insulating material of the embodiment of the present invention 6 as vehicle glass coating。
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 40KG, nanometer titanium dioxide silica aerogel slurry (sequence number 1 formula, preparation method, with embodiment 1, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 20KG, 1053 dispersants (dispersant A) 3KG, defoamer DP-0820.5KG, thickening agent WT-1020.8KG, levelling agent DP-4952KG, dipropylene glycol methyl ether 0.08KG, dipropylene 0.08KG, deionized water 24KG。
Preparation method, with embodiment 1, obtains nano transparent heat-insulating material。
With specialty cleaning agent and instrument, vehicle glass is thoroughly cleaned before construction, main for nano transparent insulating coating paint Special coating device is coated in glass surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Do not clean in two days, in order to coating is fully cured。Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。Motor space is less, and heat insulation and preservation effect easily reaches。Summer, the vehicle interior temperature rear temperature difference before coating reached 10～15 DEG C。This coating products can have from dry, heat insulation, be incubated, function and the feature such as weather-proof。
Embodiment 7
Adopt the nano transparent heat-insulating material of the embodiment of the present invention 7 as gasoline tank coating
Concrete formula is as follows: water-borne acrylic resin (solid content 50～55%, viscosity is 1100～1600mPa.s (25 DEG C)) 45KG, nanometer titanium dioxide silica aerogel slurry (sequence number 3 formula, preparation method, with embodiment 3, obtains powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm。) 20KG, 1053 dispersants (dispersant A) 3KG, defoamer DP-0821KG, thickening agent WT-1021KG, levelling agent DP-4951KG, dipropylene glycol methyl ether 0.08KG, dipropylene 0.08KG, deionized water 25KG。
Preparation method, with embodiment 3, obtains nano transparent heat-insulating material。
With specialty cleaning agent and instrument, storage tank is thoroughly cleaned before construction, main for nano transparent insulating coating paint Special coating device is coated in reservoir surface (coating thickness is 10～25 μm)。
Coating of the present invention is one-component normal temperature cure self-drying type, and 0.5h surface drying, 2h does solid work；Not cleaning in two days, coating is fully cured。Recheck again after two months, glass surface coating uniform, without peeling off, be firmly bonded, without scratch and show-through。In summer storage tank temperature before coating after the temperature difference reach 10～15 DEG C。This coating products can have from dry, heat insulation, be incubated, function and the feature such as weather-proof。
The performance of gained nano transparent insulating coating of the present invention:
From the foregoing, it will be observed that the water nano transparent heat insulating dope of the present invention, function admirable, various cooling, heat insulation device or building can be widely used in。
The particle size distribution in nano transparent insulating coating of the present invention of the nanometer titanium dioxide silica aerogel in the embodiment of the present invention is measured with ZetasizerNanoZS90 nanometer particle size potentiometric analyzer, show that the mean diameter after nanometer titanium dioxide silica aerogel slurry of the present invention dispersion at below 100nm and presents unimodal, reached the dispersion effect of Nano grade。
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, the all possible combination of each technical characteristic in above-described embodiment is not all described, but, as long as the combination of these technical characteristics is absent from contradiction, all it is considered to be the scope that this specification is recorded。
Embodiment described above only have expressed the several embodiments of the present invention, and it describes comparatively concrete and detailed, but can not therefore be construed as limiting the scope of the patent。It should be pointed out that, for the person of ordinary skill of the art, without departing from the inventive concept of the premise, it is also possible to making some deformation and improvement, these broadly fall into protection scope of the present invention。Therefore, the protection domain of patent of the present invention should be as the criterion with claims。
Claims (9)
1. a nano transparent insulating coating, it is characterised in that its raw material forms with parts by weight, including:
Wherein, the raw material of described nanometer titanium dioxide silica aerogel slurry forms with parts by weight, including:
2. nano transparent insulating coating according to claim 1, it is characterised in that described dispersant A is macromolecule dispersing agent；Described dispersant B is silane coupler and/or macromolecule dispersing agent。
3. nano transparent insulating coating according to claim 1, it is characterised in that described water-borne acrylic resin solid content 50～55%, viscosity is 1100～1600mPa.s。
4. nano transparent insulating coating according to claim 1, it is characterised in that described defoamer is the non-ionic defoamer of mineral oils。
5. nano transparent insulating coating according to claim 1, it is characterised in that described thickening agent is modified polyacrylic acid thickening agent。
6. the nano transparent insulating coating according to any one of Claims 1 to 5, it is characterised in that described levelling agent is modified polyurethane levelling agent。
7. the preparation method of the nano transparent insulating coating according to any one of claim 1～6, it is characterised in that comprise the following steps:
(1) preparation of nanometer titanium dioxide silica aerogel slurry:
Take described dispersant B, wetting dispersing agent, deionized water and nanometer titanium dioxide silica aerogel, mixing, regulating pH value is 7.5～8.5, disperses on dispersion machine, it is subsequently placed in grinding machine for grinding, prepares powder diameter nanometer titanium dioxide silica aerogel slurry within the scope of 30～90nm；
(2) preparation of transparent heat insulating dope:
Take described water-borne acrylic resin, nanometer titanium dioxide silica aerogel slurry, dispersant A, defoamer, levelling agent, thickening agent, dipropylene glycol methyl ether and dipropylene that deionized water, step (1) obtain, mixing, regulating pH value is 7.5～8.5, dispersion machine disperses, it is placed in grinding machine for grinding, to obtain final product。
8. preparation method according to claim 7, it is characterised in that the jitter time in described step (1) is 15～20min, rotating speed 1150～1250rpm；Milling time is 2～3h, rotating speed 2900～3100rpm。
9. preparation method according to claim 7, it is characterised in that the jitter time in described step (2) is 15～20min, rotating speed is 1150～1250rpm；Milling time is 1～2h, and grinding rate is 2400～2600rpm。
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| CN106590262A (en) * | 2016-12-28 | 2017-04-26 | 苏州宇希新材料科技有限公司 | Thermal-insulating transparent coating |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1908099A (en) * | 2006-08-15 | 2007-02-07 | 广州市白云化工实业有限公司 | Fluorination modified organosilicon nano coating and preparation method thereof |
| CN101649147A (en) * | 2009-08-27 | 2010-02-17 | 广州市白云化工实业有限公司 | Water transparent heat insulation paint and preparation method thereof |
| CN103059670A (en) * | 2012-11-23 | 2013-04-24 | 高凡 | Preparation method of novel nano transparent heat-insulation paint |
| KR20140089687A (en) * | 2013-01-07 | 2014-07-16 | 최영재 | Water-soluble heat-resistance insulation paint composition |
-
2016
- 2016-03-07 CN CN201610128805.3A patent/CN105694629B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1908099A (en) * | 2006-08-15 | 2007-02-07 | 广州市白云化工实业有限公司 | Fluorination modified organosilicon nano coating and preparation method thereof |
| CN101649147A (en) * | 2009-08-27 | 2010-02-17 | 广州市白云化工实业有限公司 | Water transparent heat insulation paint and preparation method thereof |
| CN103059670A (en) * | 2012-11-23 | 2013-04-24 | 高凡 | Preparation method of novel nano transparent heat-insulation paint |
| KR20140089687A (en) * | 2013-01-07 | 2014-07-16 | 최영재 | Water-soluble heat-resistance insulation paint composition |
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