CN108976954A - A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead - Google Patents
A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead Download PDFInfo
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- CN108976954A CN108976954A CN201810931635.1A CN201810931635A CN108976954A CN 108976954 A CN108976954 A CN 108976954A CN 201810931635 A CN201810931635 A CN 201810931635A CN 108976954 A CN108976954 A CN 108976954A
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- tin oxide
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2231—Oxides; Hydroxides of metals of tin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Inorganic Chemistry (AREA)
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- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention discloses a kind of preparation methods of roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead, hollow glass microbead is placed in water bath with thermostatic control, constantly agitation, titanium dioxide is added several times, silica solution is uniformly sprayed again in spraying form, constantly agitation bead is subsequently placed in baking oven and dries to constant weight up to drying, and silica solution-titanium dioxide compound coating bead is made;Under the conditions of magnetic agitation, deionized water is added into nano antimony tin oxide, adds dispersing agent, adjusting pH is alkalescent, ultrasonic disperse, ball milling dispersion, filtering, obtained nano-fluid;Film forming matter water-based acrylic resin, nanometer titanium dioxide silica aerogel slurry, dispersing agent, wetting dispersing agent and silica solution-titanium dioxide compound coating bead, nano-fluid high-speed uniform are dispersed, then auxiliary agent and cosolvent are added, high speed dispersion is uniformly mixed, and insulating moulding coating is made.
Description
Technical field
The invention belongs to insulating moulding coating fields, and in particular to a kind of roof insulating water-proof pad nano antimony tin oxide-bead
The preparation method of filling-modified insulating moulding coating.
Background technique
While solar radiation provides continually energy to the earth, also lead to the surface of the objects such as building and interior
Portion's temperature increases, and brings many troubles to the production and living of the mankind.Insulating moulding coating can effectively reduce coating surface and inside
Temperature improves internal thermal environment, has the certain significance to energy-saving.
As low-carbon economy becomes the hot spot in the whole world, energy-saving material is increasingly subject to the favor of people.In building energy conservation,
The light transmission of glass and it is heat-insulated be a very crucial problem, use the building of exterior window and transparent ceiling in large area
The heat radiation of the occasions such as object, automotive window, sunlight will lead to the increase of air conditioning energy consumption, cause the very big energy
Waste.Continuous attention with society to energy conservation and environmental requirement, can be in the heat-protecting glass that different places use
As the common requirements of people, and existing heat-protecting glass there are performances not perfect, complex process or at high cost
The drawbacks of.
Nano antimony tin oxide has good visible light permeability and infrared barrier, is a kind of ideal heat-barrier material.
Nano antimony tin oxide is added to the method that transparent heat insulating dope is made in coating can effectively solve the heat-insulating problem of glass, and same
Class product is compared, and has the advantages that simple process, low in cost, has high application value and vast market prospect.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of roof insulating water-proof pad nano antimony tin oxide-is provided
The preparation method of the filling-modified insulating moulding coating of bead, the insulating moulding coating according to this method production have excellent heat-proof quality,
Film has good mechanical performance.
The present invention is achieved by the following technical solutions:
A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead, feature exist
In including the following steps:
(1) silica solution-titanium dioxide compound coating bead:
30-40 parts of hollow glass microbeads are placed in 50-53 DEG C of water bath with thermostatic control, are constantly stirred, add 10-13 parts of titanium whites several times
Powder, then 10-13 parts of silica solution are uniformly sprayed in spraying form, constantly bead is stirred until drying, is subsequently placed in 105-115 DEG C
It dries to constant weight in baking oven;
(2) nano antimony tin oxide-water nano-fluid:
Under the conditions of magnetic agitation, into 34-45 parts of nano antimony tin oxides, deionized water is added in 1:10-15, adds 0.5-0.7
Part dispersing agent, adjusting pH is 9, and ultrasonic disperse 10-15min, ball milling disperse 14-15h, filtering, obtained nano-fluid;
(3) preparation of modified insulating moulding coating:
By 300-400 parts of film forming matter water-based acrylic resins, 75-100 parts of nanometer titanium dioxide silica aerogel slurries, 4-5 parts points
Resulting material high-speed uniform disperses 15-20min in SF-1,1-2 parts of wetting dispersing agent SR-1 of powder and (1), (2), then adds
Auxiliary agent and cosolvent, high speed dispersion are uniformly mixed, and modified insulating moulding coating is made.
Further, dispersing agent is dispersing agent P30 in step (2).
Further, aerosil water dispersion slurry is prepared using mixing dispersing technology in step (3):
1-2% aqueous dispersion SF-1,1-2% wetting dispersing agent SR-1, deionized water are mixed, with 2000rpm high speed homogenization point
5-10min is dissipated, homogeneous mixture A is obtained;10-15% aerosil, 3-4% stabilizer SW-1 and deionized water are mixed,
Low speed dispersion 5-10min obtains homogeneous mixture B;Under low rotation speed, mixture B is added in mixture A, adjusting pH is 8-
9, ultrasonic disperse 30-35min disperse 3-4h with 3000rpm high speed grinding, aerosil water dispersion slurry are made.
Further, in step (3) auxiliary agent by 2-3 parts of SX-1,2-3 parts of defoaming agent SL-1,1-2 parts of levelling agent thickeners
SZ-1,3-4 parts of curing agent SG-1 compositions;Cosolvent is by 0.5-0.7 parts of dipropylene glycol methyl ethers, 0.5-0.6 parts of dipropylenes
Composition.
The present invention has the advantage that compared with prior art
(1) by carrying out cladding processing to hollow glass microbead, using silica solution-titanium dioxide compound coating, heat-proof quality is made
Excellent pigments and fillers;Covered effect is good, and the intensity of bead enhances with the increase of covering amount, and the thermal coefficient of film then by
It is cumulative big;The modified bead heat-proof quality of compound coating is good, can be used for preparing insulating moulding coating.
(2) it is prepared for nano antimony tin oxide-water nano-fluid of stably dispersing, system stability when dispersion meta-alkalescence
Preferably, most beneficial for the stably dispersing of nano antimony tin oxide nano-fluid;Ultrasonic disperse and ball milling disperse two kinds of dispersing methods and match
It closes and uses, good stably dispersing effect can be reached within the shorter time, improve production efficiency, the grain of particle in system
Diameter distribution is relatively uniform;It is mixed with nano antimony tin oxide-water nano-fluid and film forming matter phase water-based acrylic resin, addition is certain
Thickener and other auxiliary agents are measured, insulating moulding coating of good performance has been made.
(3) aerosil is the minimum solid material of thermal conductivity and has excellent visible light permeability, is one
The excellent transparent heat-insulated material of kind;Using high speed dispersion-ultrasonic disperse-grinding distribution mixing dispersion process means, by dioxy
Slurry is made in SiClx aeroge, and aerosil water dispersion slurry has good dispersion stabilization;Then with aqueous third
Olefin(e) acid resin is film forming matter, and insulating moulding coating is made under the cooperation of auxiliary agent;Appearance of film homogeneous transparent has good mechanicalness
Energy.
Specific embodiment
Embodiment 1
A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead, feature exist
In including the following steps:
(1) silica solution-titanium dioxide compound coating bead:
30 parts of hollow glass microbeads are placed in 50-53 DEG C of water bath with thermostatic control, are constantly stirred, add 10 parts of titanium dioxides several times, then
10 parts of silica solution are uniformly sprayed in spraying form, constantly stir bead until drying, is subsequently placed in 105-115 DEG C of baking oven and dries
To constant weight;
(2) nano antimony tin oxide-water nano-fluid:
Under the conditions of magnetic agitation, into 34 parts of nano antimony tin oxides, deionized water is added in 1:10, adds 0.5 part of dispersing agent,
Adjusting pH is 9, and ultrasonic disperse 10min, ball milling disperse 14h, and nano-fluid is made in filtering;
(3) preparation of modified insulating moulding coating:
By 300 parts of film forming matter water-based acrylic resins, 75 parts of nanometer titanium dioxide silica aerogel slurries, 4 parts of dispersing agent SF-1,1
Resulting material high-speed uniform disperses 15min in part wetting dispersing agent SR-1 and (1), (2), then adds auxiliary agent and cosolvent, high
Fast dispersion mixing is uniform, and modified insulating moulding coating is made.
Further, dispersing agent is dispersing agent P30 in step (2).
Further, aerosil water dispersion slurry is prepared using mixing dispersing technology in step (3):
1% aqueous dispersion SF-1,1% wetting dispersing agent SR-1, deionized water are mixed, with the dispersion of 2000rpm high speed homogenization
5min obtains homogeneous mixture A;10% aerosil, 3% stabilizer SW-1 and deionized water are mixed, low speed dispersion
5min obtains homogeneous mixture B;Under low rotation speed, mixture B is added in mixture A, adjusting pH is 8-9, ultrasonic disperse
30min disperses 3h with 3000rpm high speed grinding, aerosil water dispersion slurry is made.
Further, in step (3) auxiliary agent by 2 parts of defoaming agent SX-1,2 parts of levelling agent SL-1,1 part of thickener SZ-1,3 parts
Curing agent SG-1 composition;Cosolvent is made of 0.5 part of dipropylene glycol methyl ether, 0.5 part of dipropylene.
Embodiment 2
A kind of preparation method of the roof insulating water-proof pad filling-modified insulating moulding coating of nano antimony tin oxide-bead, feature exist
In including the following steps:
(1) silica solution-titanium dioxide compound coating bead:
40 parts of hollow glass microbeads are placed in 50-53 DEG C of water bath with thermostatic control, are constantly stirred, add 13 parts of titanium dioxides several times, then
13 parts of silica solution are uniformly sprayed in spraying form, constantly stir bead until drying, is subsequently placed in 105-115 DEG C of baking oven and dries
To constant weight;
(2) nano antimony tin oxide-water nano-fluid:
Under the conditions of magnetic agitation, into 45 parts of nano antimony tin oxides, deionized water is added in 1:15, adds 0.7 part of dispersing agent,
Adjusting pH is 9, and ultrasonic disperse 15min, ball milling disperse 15h, and nano-fluid is made in filtering;
(3) preparation of modified insulating moulding coating:
By 400 parts of film forming matter water-based acrylic resins, 100 parts of nanometer titanium dioxide silica aerogel slurries, 5 parts of dispersing agent SF-1,2
Resulting material high-speed uniform disperses 20min in part wetting dispersing agent SR-1 and (1), (2), then adds auxiliary agent and cosolvent, high
Fast dispersion mixing is uniform, and modified insulating moulding coating is made.
Further, dispersing agent is dispersing agent P30 in step (2).
Further, aerosil water dispersion slurry is prepared using mixing dispersing technology in step (3):
2% aqueous dispersion SF-1,2% wetting dispersing agent SR-1, deionized water are mixed, with the dispersion of 2000rpm high speed homogenization
10min obtains homogeneous mixture A;15% aerosil, 4% stabilizer SW-1 and deionized water are mixed, low speed dispersion
10min obtains homogeneous mixture B;Under low rotation speed, mixture B is added in mixture A, adjusting pH is 8-9, ultrasonic disperse
35min disperses 4h with 3000rpm high speed grinding, aerosil water dispersion slurry is made.
Further, in step (3) auxiliary agent by 3 parts of defoaming agent SX-1,3 parts of levelling agent SL-1,2 parts of thickener SZ-1,4 parts
Curing agent SG-1 composition;Cosolvent is made of 0.7 part of dipropylene glycol methyl ether, 0.6 part of dipropylene.
According to the method for the present invention production modification insulating moulding coating have excellent heat-proof quality, compound heat-insulation coating it is heat-insulated
The temperature difference is up to 21 DEG C;Film has good mechanical performance, and coating pencil hardness is 2H, and adhesive force is 1 grade.
Claims (4)
1. a kind of preparation method of roof insulating water-proof pad with the filling-modified insulating moulding coating of nano antimony tin oxide-bead, feature
It is, includes the following steps:
(1) silica solution-titanium dioxide compound coating bead:
30-40 parts of hollow glass microbeads are placed in 50-53 DEG C of water bath with thermostatic control, are constantly stirred, add 10-13 parts of titanium whites several times
Powder, then 10-13 parts of silica solution are uniformly sprayed in spraying form, constantly bead is stirred until drying, is subsequently placed in 105-115 DEG C
It dries to constant weight in baking oven;
(2) nano antimony tin oxide-water nano-fluid:
Under the conditions of magnetic agitation, into 34-45 parts of nano antimony tin oxides, deionized water is added in 1:10-15, adds 0.5-0.7
Part dispersing agent, adjusting pH is 9, and ultrasonic disperse 10-15min, ball milling disperse 14-15h, filtering, obtained nano-fluid;
(3) preparation of modified insulating moulding coating:
By 300-400 parts of film forming matter water-based acrylic resins, 75-100 parts of nanometer titanium dioxide silica aerogel slurries, 4-5 parts points
Resulting material high-speed uniform disperses 15-20min in SF-1,1-2 parts of wetting dispersing agent SR-1 of powder and (1), (2), then adds
Auxiliary agent and cosolvent, high speed dispersion are uniformly mixed, and modified insulating moulding coating is made.
2. a kind of roof insulating water-proof pad according to claim 1 filling-modified heat-insulated painting of nano antimony tin oxide-bead
The preparation method of material, which is characterized in that dispersing agent is dispersing agent P30 in step (2).
3. a kind of roof insulating water-proof pad according to claim 1 filling-modified heat-insulated painting of nano antimony tin oxide-bead
The preparation method of material, which is characterized in that aerosil water dispersion slurry is prepared using mixing dispersing technology in step (3)
Material:
1-2% aqueous dispersion SF-1,1-2% wetting dispersing agent SR-1, deionized water are mixed, with 2000rpm high speed homogenization point
5-10min is dissipated, homogeneous mixture A is obtained;10-15% aerosil, 3-4% stabilizer SW-1 and deionized water are mixed,
Low speed dispersion 5-10min obtains homogeneous mixture B;Under low rotation speed, mixture B is added in mixture A, adjusting pH is 8-
9, ultrasonic disperse 30-35min disperse 3-4h with 3000rpm high speed grinding, aerosil water dispersion slurry are made.
4. a kind of roof insulating water-proof pad according to claim 1 filling-modified heat-insulated painting of nano antimony tin oxide-bead
The preparation method of material, which is characterized in that auxiliary agent is by 2-3 parts of SL-1,1-2 parts of levelling agents of SX-1,2-3 parts of defoaming agent in step (3)
SZ-1,3-4 parts of curing agent SG-1 compositions of thickener;Cosolvent is by 0.5-0.7 parts of dipropylene glycol methyl ethers, 0.5-0.6 parts of dipropyls two
Alcohol butyl ether composition.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114163888A (en) * | 2022-01-17 | 2022-03-11 | 苏州皮米新材料科技有限公司 | High-temperature-resistant nano aerogel thermal insulation coating |
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CN104479481A (en) * | 2014-12-16 | 2015-04-01 | 深圳市东维丰电子科技股份有限公司 | Waterborne self-crosslinking acrylic resin thermal-insulation coating and preparation method thereof |
CN104946032A (en) * | 2015-07-13 | 2015-09-30 | 武汉科技大学 | Silica solution/titanium dioxide wrapped hollow glass bead thermal insulating coating and preparing method thereof |
CN105694629A (en) * | 2016-03-07 | 2016-06-22 | 广州市白云化工实业有限公司 | Nano transparent heat-insulating coating and preparation method thereof |
CN107760139A (en) * | 2017-10-25 | 2018-03-06 | 佛山科学技术学院 | A kind of thermal insulation water-proof acrylic acid functional paint and preparation method thereof |
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2018
- 2018-08-16 CN CN201810931635.1A patent/CN108976954A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102391757A (en) * | 2011-07-15 | 2012-03-28 | 山东奔腾漆业有限公司 | Water-borne acrylic thermal insulating coating and preparation method thereof |
CN104479481A (en) * | 2014-12-16 | 2015-04-01 | 深圳市东维丰电子科技股份有限公司 | Waterborne self-crosslinking acrylic resin thermal-insulation coating and preparation method thereof |
CN104946032A (en) * | 2015-07-13 | 2015-09-30 | 武汉科技大学 | Silica solution/titanium dioxide wrapped hollow glass bead thermal insulating coating and preparing method thereof |
CN105694629A (en) * | 2016-03-07 | 2016-06-22 | 广州市白云化工实业有限公司 | Nano transparent heat-insulating coating and preparation method thereof |
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CN114163888A (en) * | 2022-01-17 | 2022-03-11 | 苏州皮米新材料科技有限公司 | High-temperature-resistant nano aerogel thermal insulation coating |
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Application publication date: 20181211 |