CN106118263A - A kind of Nano-meter SiO_22modified heat-insulating waterproof coating of butadiene-styrene rubber and preparation method thereof - Google Patents

A kind of Nano-meter SiO_22modified heat-insulating waterproof coating of butadiene-styrene rubber and preparation method thereof Download PDF

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Publication number
CN106118263A
CN106118263A CN201610559193.3A CN201610559193A CN106118263A CN 106118263 A CN106118263 A CN 106118263A CN 201610559193 A CN201610559193 A CN 201610559193A CN 106118263 A CN106118263 A CN 106118263A
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heat
nano
meter sio
waterproof coating
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乔启信
金自海
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Anhui Lencaqi Building Material Co ltd
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Anhui Lencaqi Building Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • C09D109/08Latex
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/28Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • C09D7/62Additives non-macromolecular inorganic modified by treatment with other compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

A kind of Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is made up of the raw material of following weight portion: SBR emulsion 100 parts, neoprene latex 8 10 parts, hydroxyethyl methylacrylate 15 20 parts, alkyl resorcinol formaldehyde resin 8 10 parts, HMMM 12 parts, titanium dioxide 35 parts, Pulvis Talci 35 parts, sodium tripolyphosphate 12 parts, tributyl phosphate 23 parts, alcohol ester 12 parts, 1, 2 benzisothiazole 3 ketone 0.5 1 parts, hydroxymethyl cellulose 12 parts, hollow glass micropearl 8 10 parts, the ammonia of 25% 34 parts, dehydrated alcohol 40 50 parts, tetraethyl orthosilicate 35 parts, hydroxy silicon oil 58 parts, white carbon 12 parts, dibutyl tin laurate 0.5 1 parts, deionized water is appropriate.The present invention is cheap, have good effect of heat insulation concurrently and daylighting degree and easy construction, has a good application prospect.

Description

A kind of Nano-meter SiO_22Modified heat-insulating waterproof coating of butadiene-styrene rubber and preparation method thereof
Technical field
The present invention relates to technical field of coatings, particularly a kind of Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber And preparation method thereof.
Technical background
Due to the irradiation of daylight, in making building, temperature raises, and will increase the energy consumption of air-conditioning.Additionally, industrial premises, work Dynamic room or temporary building etc. uses metal foil roof, and in the sun, indoor temperature can raise rapidly, in the case of many, Air conditioner refrigerating is used to reduce the poor effect of indoor temperature.Indoor temperature is reduced by reducing roof surface temperature, it is common that Practical ways.The approach preventing indoor temperature from raising mainly makes outdoor heat, and (mainly sunlight irradiates generation Heat) the most incoming indoor, and indoor heat the most outwards distributes.
The insulating moulding coating developed at present is broadly divided into 3 classes according to insulating mechanism: isolation-type insulating moulding coating, radiation type heat-insulation are coated with Material and reflection type thermal insulation coating.Wherein isolation-type insulating moulding coating is that the high thermal resistance by coating self realizes heat insulation a kind of painting Material.Being coated with during coating application and dress up certain thickness, generally 5-20mm, after abundant dry solidification, owing to material is dried to After film, thermal conductivity is the least, and therefore coating has the ability of certain hot-fluid transmission of slowing down.Present this kind of coating is experiencing one By industry heat-insulation and heat-preservation to the transformation of building heat insulation, but owing to there is the defect that own material structure is brought, such as dry week Phase dry contraction is big, and hydroscopicity is big, and dicoration on the low side to the adhesion strength of body of wall remains to be further improved, and limits this kind of The range of coating.
The patent No. 201510887384.8 discloses a kind of water proof rubber material, the raw material of following weight portion prepare system Become: polyethylene terephthalate 7-8, trioctyl lemon acid 3-4, Colophonium 1-2, polyacrylonitrile 24-27, sodium diacetate 1-2, Graphite 12-13, fly ash micro-sphere 3-4, sodium lauryl sulphate 0.7-1, LNBR 42-55, methacrylic acid 0.6- 1, nitrile rubber 52-60, butadiene-styrene rubber 20-25, Nano silica sol 5-6, tetramethylthiuram disulfide 3-4, diethylene glycol 2-3, VAE emulsion 6-8, active hargil 14-16, Barium metatitanate. 5-7, magnesium hydroxide 7-9, calcium propionate 0.2-0.3;The present invention uses above-mentioned joining Water proof rubber material obtained by side, although have good water resistance, but effect of heat insulation is poor, is not suitable for making the anti-of roof Water paint.
Summary of the invention
It is an object of the invention to provide a kind of Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber and preparation thereof Method.
To achieve these goals, the present invention adopts the following technical scheme that
A kind of Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is characterised in that it is by the raw material of following weight portion It is prepared from: between SBR emulsion 100 parts, neoprene latex 8-10 part, hydroxyethyl methylacrylate 15-20 part, alkyl Resorcinol formaldehyde resin 8-10 part, HMMM 1-2 part, titanium dioxide 3-5 part, Pulvis Talci 3-5 part, trimerization phosphorus Acid sodium 1-2 part, tributyl phosphate 2-3 part, alcohol ester 12 1-2 part, BIT 0.5-1 part, methylol fibre Dimension element 1-2 part, hollow glass micropearl 8-10 part, ammonia 3-4 part of 25%, dehydrated alcohol 40-50 part, tetraethyl orthosilicate 3-5 part, Hydroxy silicon oil 5-8 part, white carbon 1-2 part, dibutyl tin laurate 0.5-1 part, deionized water are appropriate.
Described Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is characterised in that it is by following steps system For forming:
(1) titanium dioxide, Pulvis Talci being put in ball mill and turn/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C, Carry out ball milling 30-40min, add glass microballoon, stir 20-30min, add sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 Continue stirring 10-20min, form the mixed powder of surface active;
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously Add the deionized water of 3-5 times amount, carry out microwave heating 10-20min with the frequency of 5000-20000MHz, then with liquid nitrogen rapidly It is cooled to 15-25 DEG C of prepared neoprene modification liquid;Neoprene modification liquid, mixed powder and neoprene latex are mixed Uniformly, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex;
(3) ammonia of 25% is added in dehydrated alcohol, high degree of agitation 30-40min at 60-65 DEG C, drips tetraethyl orthosilicate, Continue stirring 90-100min, stand 10-12h;Add hydroxy silicon oil and white carbon, with dibutyl tin laurate as catalyst, Reaction 8-10h is stirred at room temperature, obtains super-hydrophobic Nano-meter SiO_22
(4) BIT, hydroxymethyl cellulose are added to be equivalent to mixed powder weight portion 2-3 times In deionized water, stir, be then slowly added into acrylic acid modified neoprene latex and super-hydrophobic Nano-meter SiO_22, with 700-800 turns/the speed stirring 40-60min of min after, move to homogenizer, turn/the Rate Dispersion of min with 3500-4000 30-40min, it is thus achieved that mixed slurry;
(5) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration Heat-insulating waterproof coating coating.
The particle diameter of described hollow glass micropearl is 80-100 m.
The hydrogen content of described hydroxy silicon oil is 0.08-0.10%.
The excellent effect of the present invention is: the addition of neoprene latex, and butadiene-styrene rubber synergism, be in order to improve every The elongation at break of hot water-repellent paint and low temperature flexibility;First glass microballoon is carried out surface active, be redispersed in neoprene breast In liquid, increase its dispersibility in butadiene-styrene rubber, utilize the countless cavitys of tiny hollow glass micropearl to form thermal insulation layer resistance Only conduction of heat, improves the heat-proof quality of coating;Utilize acrylic acid modified neoprene latex, increase neoprene and butadiene-styrene rubber The compatibility, significantly improve the intensity of material and resistance to water and with concrete, the bonding force of cement mortar basic unit;By molten Glue-gel method prepares mono-dispersed nano silicon dioxide gel, and cross-links particle surface with the organosilicon of low-surface-energy Process with hydrophobization, obtain super-hydrophobic nano silicon;Super-hydrophobic silica not only increases the mechanical strength of emulsion, Also add the water resistance of emulsion;The heat-insulating waterproof coating that the present invention provides, cheap, have good effect of heat insulation concurrently simultaneously With daylighting degree and easy construction, have a good application prospect.
Detailed description of the invention
The Nano-meter SiO_2 of the present embodiment2The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is by the raw material system of following weight portion For forming: SBR emulsion 100 parts, neoprene latex 8 parts, hydroxyethyl methylacrylate 20 parts, alkyl-resorcin first Urea formaldehyde 10 parts, HMMM 2 parts, titanium dioxide 3 parts, Pulvis Talci 3 parts, sodium tripolyphosphate 2 parts, tricresyl phosphate fourth Ester 2 parts, alcohol ester 12 parts, BIT 0.5 part, hydroxymethyl cellulose 2 parts, hollow glass micropearl 8 parts, The ammonia of 25% 4 parts, dehydrated alcohol 40 parts, tetraethyl orthosilicate 4 parts, hydroxy silicon oil 8 parts, white carbon 2 parts, di lauric dibutyl 0.5 part of stannum, deionized water are appropriate.
The Nano-meter SiO_2 of the present embodiment2The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is prepared from by following steps:
(1) titanium dioxide, Pulvis Talci being put in ball mill with rotational speed of ball-mill is 2800 turns/min, and temperature is 90 DEG C, carries out ball milling 40min, adds glass microballoon, stirs 30min, adds sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 continuation stirring 20min, forms the mixed powder of surface active;
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously Add the deionized water of 5 times amount, carry out microwave heating 10min with the frequency of 20000MHz, then with liquid nitrogen rapid cooling to 25 DEG C The neoprene modification liquid prepared;By neoprene modification liquid, mixed powder and neoprene latex mix homogeneously, rise high-temperature To 60 DEG C, continuously stirred 8h, obtain acrylic acid modified neoprene latex;
(3) ammonia of 25% is added in dehydrated alcohol, high degree of agitation 40min at 60 DEG C, drips tetraethyl orthosilicate, continue to stir Mix 100min, stand 12h;Add hydroxy silicon oil and white carbon, with dibutyl tin laurate as catalyst, reaction is stirred at room temperature 10h, obtains super-hydrophobic Nano-meter SiO_22
(4) BIT, hydroxymethyl cellulose are added to be equivalent to going of mixed powder weight portion 3 times In ionized water, stir, be then slowly added into acrylic acid modified neoprene latex and super-hydrophobic Nano-meter SiO_22, with After the speed stirring 60min of 800 turns/min, move to homogenizer, with the Rate Dispersion 30min of 4000 turns/min, it is thus achieved that mixed Close slurry;
(5) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration Heat-insulating waterproof coating coating.
The coating appearance that the present invention produces is normal, without precipitation, without caking, by Water Resistance Test in 160 hours, 50 hours resistance to Alkalescence test, 10000 abrasion resistances are tested the most without exception;Artificial ageing resistance is tested: 2000 hours non-foaming, does not peels off, nothing Crackle.

Claims (4)

1. a Nano-meter SiO_22The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is characterised in that it is by the raw material of following weight portion It is prepared from: between SBR emulsion 100 parts, neoprene latex 8-10 part, hydroxyethyl methylacrylate 15-20 part, alkyl Resorcinol formaldehyde resin 8-10 part, HMMM 1-2 part, titanium dioxide 3-5 part, Pulvis Talci 3-5 part, trimerization phosphorus Acid sodium 1-2 part, tributyl phosphate 2-3 part, alcohol ester 12 1-2 part, BIT 0.5-1 part, methylol fibre Dimension element 1-2 part, hollow glass micropearl 8-10 part, ammonia 3-4 part of 25%, dehydrated alcohol 40-50 part, tetraethyl orthosilicate 3-5 part, Hydroxy silicon oil 5-8 part, white carbon 1-2 part, dibutyl tin laurate 0.5-1 part, deionized water are appropriate.
2. according to the Nano-meter SiO_2 described in claim 12The heat-insulating waterproof coating of modified butadiene-styrene rubber, it is characterised in that its It is prepared from by following steps:
(1) titanium dioxide, Pulvis Talci being put in ball mill and turn/min with rotational speed of ball-mill for 2400-2800, temperature is 80-90 DEG C, Carry out ball milling 30-40min, add glass microballoon, stir 20-30min, add sodium tripolyphosphate, tributyl phosphate, alcohol ester 12 Continue stirring 10-20min, form the mixed powder of surface active;
(2) by after hydroxyethyl methylacrylate, alkyl resorcinol formaldehyde resin, HMMM mix homogeneously Add the deionized water of 3-5 times amount, carry out microwave heating 10-20min with the frequency of 5000-20000MHz, then with liquid nitrogen rapidly It is cooled to 15-25 DEG C of prepared neoprene modification liquid;Neoprene modification liquid, mixed powder and neoprene latex are mixed Uniformly, rise high-temperature to 50-60 DEG C, continuously stirred 6-8h, obtain acrylic acid modified neoprene latex;
(3) ammonia of 25% is added in dehydrated alcohol, high degree of agitation 30-40min at 60-65 DEG C, drips tetraethyl orthosilicate, Continue stirring 90-100min, stand 10-12h;Add hydroxy silicon oil and white carbon, with dibutyl tin laurate as catalyst, Reaction 8-10h is stirred at room temperature, obtains super-hydrophobic Nano-meter SiO_22
(4) BIT, hydroxymethyl cellulose are added to be equivalent to mixed powder weight portion 2-3 times In deionized water, stir, be then slowly added into acrylic acid modified neoprene latex and super-hydrophobic Nano-meter SiO_22, with 700-800 turns/the speed stirring 40-60min of min after, move to homogenizer, turn/the Rate Dispersion of min with 3500-4000 30-40min, it is thus achieved that mixed slurry;
(5) mixed slurry, SBR emulsion are added together mix homogeneously in change-can mixer, adjusted viscosity, become after filtration Heat-insulating waterproof coating coating.
3. according to the Nano-meter SiO_2 described in claim 22The preparation method of the heat-insulating waterproof coating of modified butadiene-styrene rubber, it is special Levying and be, the particle diameter of described hollow glass micropearl is 80-100 m.
4. according to the Nano-meter SiO_2 described in claim 12The preparation method of the heat-insulating waterproof coating of modified butadiene-styrene rubber, it is special Levying and be, the hydrogen content of described hydroxy silicon oil is 0.08-0.10%.
CN201610559193.3A 2016-07-18 2016-07-18 A kind of Nano-meter SiO_22modified heat-insulating waterproof coating of butadiene-styrene rubber and preparation method thereof Withdrawn CN106118263A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410215A (en) * 2018-01-09 2018-08-17 浙江工业大学 A kind of surface hydrophobicity method of modifying of alumina powder
CN111851870A (en) * 2020-03-31 2020-10-30 同济大学 Building roof waterproof and heat insulation integrated super-hydrophobic particle, and preparation method and application thereof
CN112011202A (en) * 2020-08-20 2020-12-01 山东北方创信防水科技集团股份有限公司 SiO (silicon dioxide)2Preparation method of modified chloroprene rubber flame-retardant heat-insulation waterproof coating

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206445A (en) * 2011-05-23 2011-10-05 开平市日固力涂料有限公司 Heat insulating coating surface glue and heat insulating coating
CN103524815A (en) * 2013-08-26 2014-01-22 无锡市金盛助剂厂 Styrene butadiene rubber emulsion modifying agent
CN105199521A (en) * 2015-09-22 2015-12-30 天长市开林化工有限公司 Hydrophobic silica aerogel modified acrylate emulsion coating

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206445A (en) * 2011-05-23 2011-10-05 开平市日固力涂料有限公司 Heat insulating coating surface glue and heat insulating coating
CN103524815A (en) * 2013-08-26 2014-01-22 无锡市金盛助剂厂 Styrene butadiene rubber emulsion modifying agent
CN105199521A (en) * 2015-09-22 2015-12-30 天长市开林化工有限公司 Hydrophobic silica aerogel modified acrylate emulsion coating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108410215A (en) * 2018-01-09 2018-08-17 浙江工业大学 A kind of surface hydrophobicity method of modifying of alumina powder
CN111851870A (en) * 2020-03-31 2020-10-30 同济大学 Building roof waterproof and heat insulation integrated super-hydrophobic particle, and preparation method and application thereof
CN112011202A (en) * 2020-08-20 2020-12-01 山东北方创信防水科技集团股份有限公司 SiO (silicon dioxide)2Preparation method of modified chloroprene rubber flame-retardant heat-insulation waterproof coating

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Application publication date: 20161116