CN1597812A - Water epoxy paint for ground floor and its mfg. process and construction technology - Google Patents
Water epoxy paint for ground floor and its mfg. process and construction technology Download PDFInfo
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- CN1597812A CN1597812A CN 200410051180 CN200410051180A CN1597812A CN 1597812 A CN1597812 A CN 1597812A CN 200410051180 CN200410051180 CN 200410051180 CN 200410051180 A CN200410051180 A CN 200410051180A CN 1597812 A CN1597812 A CN 1597812A
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- water
- component
- floor coating
- agent
- aqueous epoxy
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- 239000003973 paint Substances 0.000 title claims abstract description 37
- 239000004593 Epoxy Substances 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title claims abstract description 22
- 238000010276 construction Methods 0.000 title claims description 6
- 238000005516 engineering process Methods 0.000 title description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 34
- 239000011248 coating agent Substances 0.000 claims abstract description 25
- 238000000576 coating method Methods 0.000 claims abstract description 25
- 239000003822 epoxy resin Substances 0.000 claims abstract description 20
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 20
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims description 16
- 239000012752 auxiliary agent Substances 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000000470 constituent Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 13
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 238000009736 wetting Methods 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 9
- 239000002270 dispersing agent Substances 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 230000004048 modification Effects 0.000 claims description 9
- 238000012986 modification Methods 0.000 claims description 9
- 230000008719 thickening Effects 0.000 claims description 7
- YSUQLAYJZDEMOT-UHFFFAOYSA-N 2-(butoxymethyl)oxirane Chemical compound CCCCOCC1CO1 YSUQLAYJZDEMOT-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- LSWYGACWGAICNM-UHFFFAOYSA-N 2-(prop-2-enoxymethyl)oxirane Chemical group C=CCOCC1CO1 LSWYGACWGAICNM-UHFFFAOYSA-N 0.000 claims description 5
- 150000002118 epoxides Chemical group 0.000 claims description 5
- 239000010445 mica Substances 0.000 claims description 5
- 229910052618 mica group Inorganic materials 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 230000009467 reduction Effects 0.000 claims description 5
- 239000004408 titanium dioxide Substances 0.000 claims description 5
- 239000004952 Polyamide Substances 0.000 claims description 4
- 229920002647 polyamide Polymers 0.000 claims description 4
- 230000037452 priming Effects 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 229920000768 polyamine Polymers 0.000 claims description 3
- 229930185605 Bisphenol Natural products 0.000 claims description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 2
- 239000004570 mortar (masonry) Substances 0.000 claims description 2
- 125000005375 organosiloxane group Chemical group 0.000 claims description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 239000002344 surface layer Substances 0.000 claims 1
- 239000002966 varnish Substances 0.000 claims 1
- 230000035699 permeability Effects 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 230000008859 change Effects 0.000 description 8
- 239000000049 pigment Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000699 topical effect Effects 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000009423 ventilation Methods 0.000 description 5
- 238000011161 development Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000005034 decoration Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 238000005273 aeration Methods 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000010687 lubricating oil Substances 0.000 description 2
- 239000010721 machine oil Substances 0.000 description 2
- 230000003204 osmotic effect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 229910002012 Aerosil® Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229920003656 Daiamid® Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000008098 Oxalis acetosella Nutrition 0.000 description 1
- 240000007930 Oxalis acetosella Species 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 235000013409 condiments Nutrition 0.000 description 1
- 235000019788 craving Nutrition 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- -1 siloxanes Chemical class 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to a water epoxy ground floor coating and its making method and constructing process, where one component is low-molecular weight liquid-state epoxy resin assorted with active diluter in a proper proportion, and the other component is a dispersoid with hydrophilic curing agent as the principal thing, containing water-borne curing agent, water, acid-resistant wearable color filler, various auxiliaries, etc. and its producing method is simple and mainly includes mechanical dispersing and mixing; it does need to clean paint-covered surface as used on humid basal surface; the paint film has excellent properties of oily products and unilateral permeability. It uses water as dispersing medium, has no VOC, safe and environmental-protection.
Description
Technical field
A kind of aqueous epoxy floor coating of the present invention and preparation method thereof and construction technology relate to a kind of development technology and operating technique of building coating.Particularly the development technology and the operating technique of terrace paint.
Technical background
Because the existence of solvent in the solvent-borne type terrace paint, health to people damages, environment is polluted, especially under the situation that petroleum resources are in short supply now, the solvent price increase is rapid, along with the strict day by day and people of coating products environmental requirement to the craving for of health, make the coating hydrotropismsization develop into inexorable trend.
Traditional solvent based coating since resin and solidifying agent all be in the solution with molecular form, system is a homogeneous system, therefore curing is very complete, and paint film is very fine and close, the ventilation property extreme difference, when being applied in the heavier basal plane of underground moisture, because the rising of underground steam produces osmotic pressure to paint film, when this osmotic pressure during greater than the sticking power between paint film and basic unit, paint film is by jack-up, show as the paint film bubbling, such example is of common occurrence.When with liquid-state epoxy resin and waterborne curing agent preparation terrace paint, under whipped state, the waterborne curing agent emulsion epoxy resin forms the emulsion dispersion body, curing reaction at first carries out at the interface, solidifying agent is diffused in the Resins, epoxy gradually simultaneously, further makes epoxy resin cure, along with the carrying out of curing reaction, system viscosity increases gradually, the activity of molecular chain becomes more and more difficult, and final curing reaction carries out not exclusively making paint film have ventilation property.Suitably adjust the resin-pigment ratio of system in addition again, obtain the paint film of different capillary pores rate, can obtain the paint film of corresponding different gas permeability, thereby can fundamentally solve because underground steam causes the problem of paint film bubbling.
The key of terrace paint Water-borne modification is to realize the Water-borne modification of solidifying agent, and United States Patent (USP) 5962629 discloses a kind of method for preparing w/o type daiamid epoxy resin curing agent, for the preparation of bi-component aqueous epoxy terrace paint provides strong technical support.United States Patent (USP) 6277928 discloses a kind of method for preparing water dispersible epoxide modified amine hardener, makes the performance of waterborne curing agent that further lifting arranged, and makes the aqueous epoxy floor coating of preparation performance excellence become possibility.
Summary of the invention
For avoid existing solvent based coating to environment pollute, to health of human body bring infringement and ventilation property poor, be not suitable for the deficiency on moist basal plane, used, the object of the present invention is to provide a kind of environmental protection breathable type bi-component epoxy terrace paint, to satisfy strict day by day environmental requirement and the application requiring on moist basal plane.
The present invention can reach by following measure:
A kind of bi-component aqueous epoxy terrace paint is prepared by following prescription:
Its composition of first component and mass percent are:
Constituent mass per-cent
Lower molecular weight liquid-state epoxy resin 85.0～95.0%
Reactive thinner 15.0～5.0%
First component manufacture method is: liquid-state epoxy resin is mixed 5～15min with dispersion machine or stirrer with reactive thinner under 200～600rpm speed, packing.Wherein liquid-state epoxy resin is meant bisphenol A-type lower molecular weight liquid-state epoxy resin.Its oxirane value is 0.48～0.54, organic chlorine number≤0.02, viscosity≤2.5Pas (40 ℃), volatile matter≤2%.Reactive thinner is meant any one or their mixture in glycidyl allyl ether (AGE), butylglycidyl ether (BGE) and the fatty clan elder's carbochain reactive thinner (as D-1214).
Its composition of second component and mass percent are:
Constituent mass per-cent
Waterborne curing agent 16.0～40.0%
Water 10.0～32.0%
Color stuffing 32.0～65.0%
Wetting dispersing agent 0.1～0.8%
Defoamer 0.1～0.7%
Flow agent 0.1～0.5%
Scratch resistance auxiliary agent 0～2.0%
Thickening material 0.1～0.8%
Mill base 0～3.0%
Second component manufacture method is: earlier with a part of water, auxiliary agent and whole color stuffing reduction of speed behind 1000～1800rpm high speed dispersion, 8～30min, add waterborne curing agent again and mix 3～10min at 600～900rpm, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.
The proportioning of first and second liang of components (ratio of the amount of substance of the amino reactive hydrogen that the amount of substance of the epoxide group that comprises by the first component and second component comprise) is the first component: second component=0.8～1.2: 1,
Wherein waterborne curing agent is to be selected from watersoluble modified amine, it specifically is the modified fatty amine that is selected from Water-borne modification, the 8537-wy-60 that comprises Shell company, ANQUAMINE701, the ANQUAMINE777 of U.S. aerification chemical product company limited, the HTW-208 of Jiangsu Sheng Jiete kind Resins, epoxy company limited, and the modified fatty amine of the WATERPOXY751 Water-borne modification of COGNIS company production; The modified polyamide of Water-borne modification comprises WH-900, the ANQUAMINE360 of U.S. aerification chemical product company limited; The epoxy of Water-borne modification-polyamines affixture, the WEC-402 that produces as Qingdao Haiyang chemical research institute etc. specifically can select wherein any one for use.Wherein, waterborne curing agent 8537-wy-60 is water miscible modified fatty amine, and non-volatile content is 59～61%, and reactive hydrogen equivalent (solid) is 174, and the amine value is 310～360mgKOH/g; ANQUAMINE777 is the water miscible liquid of modified fatty amine, and viscosity is 3～5Pas (25 ℃), and the reactive hydrogen equivalent is 200; HTW-208 is water miscible modified fatty amine, and non-volatile content is 58～62%, and reactive hydrogen equivalent (solid) is 174, and the amine value is 300～360; WATERPOXY 751 is water miscible modified fatty amine, and non-volatile part is 58.5～61.5%, and the reactive hydrogen equivalent is 225, and the amine value is 174～192mgKOH/g; WH-900 is water miscible modified polyamide, and resin part is 58～62%, and the reactive hydrogen equivalent is 210, and the amine value is 170～200mgKOH/g; ANQUAMINE360 is water miscible modified polyamide, and viscosity is 4.5Pas (25 ℃), and the reactive hydrogen equivalent is 280, and the amine value is 145mgKOH/g; WEC-402 is water miscible epoxy-polyamines affixture, is 59～61% admittedly contain, and the reactive hydrogen equivalent is 216, and the amine value is 170～185mgKOH/g.
Above-mentioned waterborne curing agent has two kinds of functions: one, can solidify with the epoxide group cross-linking reaction of Resins, epoxy; Its two, have emulsification function, can emulsion epoxy resin.After two components are mixed cooperation, under whipped state, the waterborne curing agent emulsion epoxy resin forms the emulsion dispersion body, curing reaction at first carries out at the interface, solidifying agent is diffused in the Resins, epoxy gradually simultaneously, further make epoxy resin cure, carrying out along with curing reaction, system viscosity increases gradually, and the activity of molecular chain becomes more and more difficult, and final curing reaction carries out not exclusively, make paint film have ventilation property, suitably adjust the resin-pigment ratio of system again, just can obtain the paint film of corresponding different gas permeability
Defoamer is to be selected among CF245 (England Blackburn chemical company), SN-DEFOAMER345 (Nippon Nopco Assistant Co., Ltd.), SN-DEFOAMER319 (Nippon Nopco Assistant Co., Ltd.), A10 (Shenzhen Hai Chuan chemical industry), A36 (Shenzhen Hai Chuan chemical industry), AGITAN760 (German bright icepro), AGITAN260 (German bright icepro), the EFKA2526 (Dutch EFKA auxiliary agent company) any one or a few.
Wetting dispersing agent is the surfactant of the following face condiment of the abundant wetting dispersion of energy; Color stuffing is some kinds that are selected from titanium dioxide, silica powder, barium sulfate, talcum powder, mica powder, the wollastonite.Flow agent is organically-modified siloxanes; The scratch resistance auxiliary agent is to be selected from organo-siloxane class, organic wax powder, the water-based wax slurry any one or a few; Thickening material is to be selected from cellulose family, acrylic acid or the like, polyurethanes, swelling great soil group, the aerosil any one or a few; This coating adopts the waterborne general color paste toning.
Construction technology is: at first use the aqueous priming paint bottoming according to above-mentioned first and second component formula adjustment resin-pigment ratios development, again the use epoxy putty and (or) the water-based mortar does the middle level, adopt then by the water-base epoxy colored paint of above-mentioned first and second component formula adjustment resin-pigment ratios development and do finish paint, when on the heavier basal plane of underground steam, using without clear finish.Above-mentioned paint vehicle can adopt during scumbling and brush or roller coat all with constructing in the suitable construction time limit behind the abundant mixing of hand electric stirrer, adopts trowel to be coated with during thick being coated with.
The present invention compares with existing epoxide terrace technology has outstanding advantage:
1, VOC content is extremely low.The first component adopts the active substance that can participate in curing reaction to make thinner, can suitably reduce system viscosity, helps the emulsification of Resins, epoxy; Can strengthen the snappiness of paint film again, avoid with an organic solvent, make that the VOC content of first component is extremely low.The second components system is a dispersion medium with water, selects low waterborne curing agent of solvent and defoamer for use, makes that whole system organic volatile content is extremely low, compliance with environmental protection requirements.
2, adopt silica powder, barium sulfate to do stopping composition, make that the paint film acid-fast alkali-proof is wear-resisting, an amount of wet method sericite in powder can reduce the consumption of thickening material, prevents to be coated with film rupture, increases snappiness, increases stability in storage.
3, this water-borne epoxy systems during as solidifying agent, all has good adhesive to numerous grounds at the water-based amine of selecting the epoxy addition modification for use, even excellent sticking power is also arranged on the abrasive aggregates terrace.
4, the resin-pigment ratio regulation range of system is bigger, can change the priming paint and the finish paint that require with the preparation different performance between 0.6～2.6.At basic unit's steam weight situation, adjust the system resin-pigment ratio, can be developed into the finishing system (paint film that resin-pigment ratio is higher, the capillary pore rate is higher, good permeability, price is lower) of different prices and ventilation property, satisfy different requirement of client easily.
Embodiment
Embodiment 1
The first component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Resins, epoxy CYD-128 90.0%
Reactive thinner butylglycidyl ether (BGE) 10.0%
First component manufacture method is: liquid-state epoxy resin is mixed 5～15min with dispersion machine or stirrer with reactive thinner under 200～600rpm speed, packing.
The second component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Waterborne curing agent THW-208 30.0%
Water 22.3%
Titanium dioxide 4.0%
Silica powder 16.0%
Barium sulfate 14.0%
Talcum powder 8.0%
Mica powder 4.0%
Wetting dispersing agent H-100 0.4%
Defoamer EFKA2526 0.3%
Flow agent BYK 346 0.3%
Thickening material TT 935 (50%) 0.7%
Second component method for manufacturing is: earlier with a part of water, wetting dispersing agent, a part of defoamer and whole color stuffing reduction of speed behind 1000～1800rpm high speed dispersion, 8～30min, add waterborne curing agent again at 600～900rpm mixing, 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.
Two constituent mass proportionings are first: second=1: 5 can be used as priming paint in the terrace coating decoration.The paint film fundamental property sees Table 1.
Table 1
| Project | Index | |
| Time of drying, h | Surface drying | 2 |
| Do solid work | 18 | |
| Hardness, H | 1 | |
| Sticking power, level | 0 | |
| Wear resistance (750g/300r, weightlessness, g) | 0.03 | |
| Shock-resistance, Kgcm | 50 | |
| Water tolerance, 48hs | Non-foaming, do not come off | |
| Anti-NaOH, 10% (topical application) | The 48hs no change | |
| Anti-Hcl, 10% (topical application) | The 48hs no change | |
Embodiment 2
The first component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Resins, epoxy Shell-828 92.0%
Reactive thinner AGE 8.0%
First component manufacture method is: liquid-state epoxy resin is mixed 5～15min with dispersion machine or stirrer with reactive thinner under 200～600rpm speed, packing.
The second component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Waterborne curing agent ANQUAMINE701 38.0%
Water 18.0%
Titanium dioxide 5.0%
Silica powder 17.0%
Barium sulfate 14.0%
Mica powder 4.0%
Wetting dispersing agent 188A 0.4%
Defoamer SN-DEFOAMER 319 0.4%
Scratch resistance auxiliary agent SER-AD DP-FS 444 0.2%
Flow agent EFKA 3,570 0.3%
Thickening material PUR45 (50%) 0.7%
Aqueous color paste 2.0%
Second component method for manufacturing is: earlier with a part of water, wetting dispersing agent, a part of defoamer and whole color stuffing reduction of speed behind 1000～1800rpm high speed dispersion, 8～30min, add waterborne curing agent again at 600～900rpm mixing, 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.
Two constituent mass proportionings are first: second=1: 4 can be used as finish paint in scumbling type terrace coating decoration.The paint film fundamental property sees Table 2.
Table 2
| Project | Index | |
| Time of drying, h | Surface drying | 2 |
| Do solid work | 18 | |
| Hardness, H | 2 | |
| Sticking power, level | 0 | |
| Wear resistance (750g/300r, weightlessness, g) | 0.02 | |
| Shock-resistance, Kgcm | 50 | |
| Abrasion resistance, inferior | ≥10000 | |
| Anti-NaOH, 10% (topical application) | The 48hs no change | |
| Anti-Hcl, 10% (topical application) | The 48hs no change | |
| Anti-lubricating oil (machine oil) | 30 days no changes | |
Embodiment 3
The first component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Resins, epoxy 618 88.0%
Reactive thinner AGE 12.0%
First component manufacture method is: liquid-state epoxy resin is mixed 5～15min with dispersion machine or stirrer with reactive thinner under 200～600rpm speed, packing.
The second component is got the raw materials ready by following material and mass percent thereof:
Constituent mass per-cent
Waterborne curing agent WATERPOXY751 21.0%
Water 13.0%
Titanium dioxide 3.0%
Silica powder 36.0%
Barium sulfate 20.0%
Mica powder 4.0%
Wetting dispersing agent SN-WET 991 0.4%
Defoamer SN-DEFOAMER A36 0.4%
Scratch resistance auxiliary agent SHAMROCK S-232 0.2%
Flow agent Wet KL245 0.3%
Thickening material D-105 (50%) 0.7%
Aqueous color paste 1.0%
Second component method for manufacturing is: earlier with a part of water, wetting dispersing agent, a part of defoamer and whole color stuffing reduction of speed behind 1000～1800rpm high speed dispersion, 8～30min, add waterborne curing agent again at 600～900rpm mixing, 3～10min, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.
Two constituent mass proportionings are first: second=1: 5 can be used as from plane of flow in the terrace coating decoration and coats with lacquer.The paint film fundamental property sees Table 3
Table 3
| Project | Index | |
| Time of drying, h | Surface drying | 2 |
| Do solid work | 18 | |
| Hardness, H | 3 | |
| Wear resistance (750g/300r, weightlessness, g) | 0.02 | |
| Ultimate compression strength, N/mm 2 | 35 | |
| Water tolerance | The 48hs no change | |
| Anti-NaOH, 10% (topical application) | The 48hs no change | |
| Anti-Hcl, 10% (topical application) | The 48hs no change | |
| Anti-lubricating oil (machine oil) | 30 days no changes | |
Claims (10)
1, a kind of aqueous epoxy floor coating, this coating is that first, second two components are formed, the first component is the reactive thinner that liquid-state epoxy resin is equipped with suitable proportion, the second component is made up of aqueous solidified agent dispersion, water, color stuffing and auxiliary agent etc., it is characterized in that its composition of first component and mass percent are:
Constituent mass per-cent
Lower molecular weight liquid-state epoxy resin 85.0～95.0%
Reactive thinner 5.0～15.0%
Its composition of second component and mass percent are:
Constituent mass per-cent
Waterborne curing agent 16.0～40.0%
Water 10.0～32.0%
Color stuffing 32.0～65.0%
Wetting dispersing agent 0.1～0.8%
Defoamer 0.1～0.7%
Flow agent 0.1～0.5%
Scratch resistance auxiliary agent 0～2.0%
Thickening material 0.1～0.8%
Mill base 0～3.0%
The proportioning of first and second liang of components (ratio of the amount of substance of the amino reactive hydrogen that the amount of substance of the epoxide group that comprises by the first component and second component comprise) is the first component: second component=0.8～1.2: 1,
2, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that selected liquid-state epoxy resin is a bisphenol A-type lower molecular weight liquid-state epoxy resin.
3, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that reactive thinner is any one or their mixture that is selected from glycidyl allyl ether (AGE), butylglycidyl ether (BGE) and the fatty clan elder's carbochain reactive thinner (D-1214).
4, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that waterborne curing agent is any one in the epoxy-polyamines affixture of modified polyamide, Water-borne modification of the modified fatty amine that is selected from Water-borne modification, Water-borne modification.
5, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that color stuffing is some kinds that are selected from titanium dioxide, silica powder, barium sulfate, talcum powder, the mica powder.
6, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that the scratch resistance auxiliary agent is to be selected from organo-siloxane class, organic wax powder, the water-based wax slurry any one or a few.
7, a kind of aqueous epoxy floor coating according to claim 1 is characterized in that this coating adopts the waterborne general color paste toning.
8, a kind of constructional method of aqueous epoxy floor coating as claimed in claim 1, it is characterized in that at first use priming paint bottoming, again the use epoxy putty and (or) the water-based mortar does the middle level, application water-base epoxy colored paint is made surface layer then, above-mentioned paint vehicle is all with constructing in the suitable construction time limit behind the abundant mixing of hand electric stirrer, can adopt during scumbling and brush or roller coat, adopt trowel to be coated with during thick being coated with.
9. according to the constructional method of aqueous epoxy floor coating as claimed in claim 8, it is characterized in that the body varnish cover.
10, a kind of making method of aqueous epoxy floor coating as claimed in claim 1, it is characterized in that first component manufacture method is: liquid-state epoxy resin is mixed 5～15min with dispersion machine or stirrer with reactive thinner under 200～600rpm speed, packing.
Second component manufacture method is: earlier with a part of water, auxiliary agent and whole color stuffing reduction of speed behind 1000～1800rpm high speed dispersion, 8～30min, add waterborne curing agent again and mix 3～10min at 600～900rpm, then add all the other auxiliary agents and mill base and disperse 8～20min, filter and package.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100511802A CN100519680C (en) | 2004-08-20 | 2004-08-20 | Water epoxy paint for ground floor and its mfg. process and construction technology |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2004100511802A CN100519680C (en) | 2004-08-20 | 2004-08-20 | Water epoxy paint for ground floor and its mfg. process and construction technology |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1597812A true CN1597812A (en) | 2005-03-23 |
| CN100519680C CN100519680C (en) | 2009-07-29 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2004100511802A Expired - Lifetime CN100519680C (en) | 2004-08-20 | 2004-08-20 | Water epoxy paint for ground floor and its mfg. process and construction technology |
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| CN (1) | CN100519680C (en) |
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Address after: Supe Industrial Park, No. 72 Panyu District Zhong villages of Guangzhou city in Guangdong province 511495 Xie Shi Lu Patentee after: GUANGZHOU SUPE CHEMICAL COATING CO.,LTD. Address before: Panyu District zhongcunzhen Guangzhou city in Guangdong province 511495 Xie Shi Road No. 72 Patentee before: GUANGZHOU SUPE CHEMICAL Co.,Ltd. |
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| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20090729 |