CN107760166A - A kind of double-component aqueous epoxide terrace paint of high-performance and preparation method thereof - Google Patents
A kind of double-component aqueous epoxide terrace paint of high-performance and preparation method thereof Download PDFInfo
- Publication number
- CN107760166A CN107760166A CN201711173966.5A CN201711173966A CN107760166A CN 107760166 A CN107760166 A CN 107760166A CN 201711173966 A CN201711173966 A CN 201711173966A CN 107760166 A CN107760166 A CN 107760166A
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- China
- Prior art keywords
- component
- double
- epoxide terrace
- terrace paint
- aqueous epoxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of double-component aqueous epoxide terrace paint of high-performance, and comprising two components of A, B, wherein component A includes following raw material by weight percentage：Curing agent 30 40%, defoamer 0.4 0.6%, auxiliary agent 0.2 4%, wax powder 1 2%, filler 4 40%, mill base 1 3%, surplus is water；B component is liquid-state epoxy resin；The invention also discloses the preparation method of the double-component aqueous epoxide terrace paint of the high-performance；The aqueous epoxy floor paint surface drying speed of the present invention is fast, possess excellent adhesive force, hardness, pliability, wearability, resistance to acids and bases and good water resistance, while preparation technology is simple, cost is low, it is convenient to construct, and be particularly suitable for use in the occasion higher to antiseptic property requirement.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of double-component aqueous epoxide terrace paint of high-performance and its preparation
Method.
Background technology
Floor paint product in the market contains substantial amounts of benzene,toluene,xylene, free TDI, again based on oiliness
The material harmful to human body and environment such as metal, the raising with living standards of the people and the more concern to environmental issue, are opened
The environmentally friendly floor paint for sending out new turns into a kind of trend.A type of no-solvent type epoxide terrace paint has without volatility
Machine thing (VOC), but the diluent used has certain toxicity and cost is higher.
Comparatively, aqueous epoxy floor paint using water as decentralized medium, without VOC, almost remains oiliness epoxide terrace
Paint and the advantages of no-solvent type epoxide terrace paint, and application property is good, accumulating and safe to use, cheap.Water-base epoxy
Level ground paint can construct in wet ground, in the absence of oiliness floor paint because steam rising and caused by paint film bubbling and scaling defects.Base
In above-mentioned excellent specific property, aqueous epoxy floor paint is just progressively favored by market, shows that great economic benefit and society imitate
Benefit.Chinese invention patent CN104559665A discloses a kind of preparation method of water-based epoxide terrace paint, comprises the following steps：
By 29.7% pure water and 0.6% dispersant, 0.2% wetting agent, 0.5% defoamer, 1% wax powder, 15%
Rutile titanium white powder, 3% glass dust and 10% silica flour stir, and obtain slurry, are eventually adding 40% water-based ring
Oxygen curing agent stirs evenly, and also can optionally add aqueous color paste toning, during use by foregoing aqueous epoxy floor paint with it is water-based
Epoxy resin latex presses 65：35 mass ratio stirs.For overcome epoxy resin viscosity is big, be not easy to mix the problem of,
Traditional aqueous epoxy floor paint or use diluent are pre-mixed with other components or directly use epoxy resin latex, to original
Material selection and follow-up use impact, in addition, its slow drying speed, repainting time are long, paint film weatherability is bad, even lack
The high-performance water-based epoxy floor paint that a kind of surface drying time and firm time are short, can use out of doors.
The content of the invention
For the above-mentioned deficiency of prior art, the present invention provides a kind of double-component aqueous epoxide terrace paint of high-performance and its system
Preparation Method.
The technical solution adopted in the present invention is as follows：
A kind of double-component aqueous epoxide terrace paint of high-performance, comprising two components of A, B, wherein component A is included below by weight
Measure the raw material of percentages：
Curing agent 30-40%,
Defoamer 0.4-0.6%,
Auxiliary agent 0.2-4%,
Wax powder 1-2%,
Filler 4-40%,
Mill base 1-3%,
Surplus is water；
The B component is liquid-state epoxy resin.
Preferably, the curing agent is nonionic amine curing agent.
Preferably, the liquid-state epoxy resin is bisphenol A type epoxy resin, molecular weight 300-400, and epoxide equivalent is
150-200, the epoxy molecule both ends respectively contain an epoxy radicals, can reacted with amine hardener, a small amount of hydroxyl contained in molecule
The compatibility of resin and amine curing agent can be improved, additionally containing fragrant ehter bond, it is possible to provide excellent resistance to acids and bases.
Preferably, the defoamer is mineral oil, and wax powder is 15-25 μm of polyethylene wax powder.
Preferably, the auxiliary agent is selected from least one of wetting agent, dispersant, levelling agent, thickener.
Preferably, the filler is at least one of talcum powder, mica powder, silica flour, titanium dioxide.
Preferably, yellow during the mill base uses, phthalocyanine blue compounding.
It is further preferred that component A includes following percentage by weight in the double-component aqueous epoxide terrace paint of high-performance
Than the raw material of meter：
Curing agent 30-40%,
Defoamer 0.4-0.6%,
Wetting agent 0.2-0.3%,
Dispersant 0.4-0.6%,
Levelling agent 0.2-0.5%,
Thickener 0.1-0.2%,
Wax powder 1-2%,
Talcum powder 8-9%,
Mica powder 5-7%,
Silica flour 15-17%,
Titanium dioxide 4-5%,
Middle yellow 1-2%,
Phthalocyanine blue 0.1-1%,
Surplus is water.
Preferably, the talcum powder, mica powder, silica flour, the particle diameter of titanium dioxide are 1000-1500 mesh.
It is further preferred that the titanium dioxide is rutile-type, produced by Sichuan's gold titanium titanium industry, model
778#。
Preferably, the dispersant is Sodium Polyacrylate, and wetting agent is nonionic surface active agent, levelling agent for it is non-from
Son association type polyurethane, thickener are that association type alkali activates acrylic emulsion.
It is further preferred that the wetting agent is APES class, model PE-100；Levelling agent is polyethers
Type polyurethane, model DH-206.
A kind of method for preparing the double-component aqueous epoxide terrace paint of above-mentioned high-performance, comprises the following steps：
(1) prepared by component A slurry：Raw material is weighed by weight, by water, curing agent, part defoamer, part of auxiliary, wax
Powder, filler are sequentially added in Scattered Kettle, are disperseed 10-20min with 400-800r/min, are obtained slurry；
(2) component A paint：Raw material is weighed by weight, and remaining auxiliary agent, mill base, remaining water and defoamer are added
It is mixed evenly into slurry made from step (1)；
(3) B component is directly packed.
A kind of application method of the double-component aqueous epoxide terrace paint of above-mentioned high-performance, it is specially：Above-mentioned A, B component are pressed into A:
B=4：1 quality proportioning stirs, and is then stirred by 15% plus water of A, B gross weight.
Beneficial effects of the present invention：
(1) the double-component aqueous epoxide terrace paint surface drying speed for preparing of the present invention is fast, possess excellent adhesive force, hardness,
Pliability, wearability, resistance to acids and bases and good water resistance, be particularly suitable for use in the occasion higher to antiseptic property requirement；
(2) present invention is directly using liquid-state epoxy resin as B component, and preparation technology is simple, and cost is low, and construction is convenient.
Embodiment
With reference to specific embodiment, the present invention is described in detail.
Embodiment 1
A kind of double-component aqueous epoxide terrace paint of high-performance, comprising two components of A, B, wherein component A is included below by weight
Measure the raw material of percentages：
Curing agent 35%,
Defoamer 0.4%,
Wetting agent 0.2%,
Dispersant 0.4%,
Levelling agent 0.2%,
Thickener 0.1%,
Wax powder 1%,
Talcum powder 9%,
Mica powder 6%,
Silica flour 16%,
Titanium dioxide 4%,
Middle yellow 1.69%,
Phthalocyanine blue 0.64%,
Water 25.4%；
The B component is liquid bisphenol A type epoxy resin, molecular weight 380, epoxide equivalent 190.
Wherein, curing agent, liquid bisphenol A types epoxide resin type number are respectively A2266, B2255, are purchased from Guangdong sea along new
Material Science and Technology Ltd..
Defoamer, wetting agent, levelling agent, thickener, wax powder are purchased from Chang Peng chemical companies of Foshan City, wherein, defoamer
For mineral oil, model NXZ；Wetting agent is APES class, model PE-100；Levelling agent is the poly- ammonia of polyether-type
Ester DH-206；Thickener is that association type alkali activates acrylic emulsion DH-939；Wax powder is 18 μm of polyethylene wax powder.
Dispersant is Sodium Polyacrylate, purchased from Rider company of Foshan Australia, model 5040.
Talcum powder, mica powder, silica flour, the particle diameter of titanium dioxide are 1250 mesh, wherein, talcum powder, mica powder, silica flour purchase
From the sail chemical company of Jiangmen one, titanium dioxide is rutile-type, is produced by Sichuan's gold titanium titanium industry, model 778#.
A kind of method for preparing the double-component aqueous epoxide terrace paint of above-mentioned high-performance, comprises the following steps：
(1) prepared by component A slurry：Weigh raw material by weight, by water 22%, curing agent, defoamer 0.2%, dispersant,
Levelling agent, wax powder, talcum powder, mica powder, silica flour, titanium dioxide are sequentially added in Scattered Kettle, are disperseed with 600r/min
15min, obtain slurry；
(2) component A paint：Raw material is weighed by weight, by wetting agent, thickener, middle Huang and phthalocyanine blue, water 3.4%, is disappeared
Infusion 0.2% is added in slurry made from step (1) and is mixed evenly；
(3) B component is directly packed.
A kind of application method of the double-component aqueous epoxide terrace paint of above-mentioned high-performance, it is specially：Above-mentioned A, B component are pressed into A:
B=4：1 quality proportioning stirs, and is then stirred by 15% plus water of A, B gross weight.
The performance test data of the aqueous epoxy floor paint of embodiment 1 is as shown in table 1：
Table 1
As can be seen from the above results, compared with prior art, aqueous epoxy floor paint surface drying speed of the invention is fast, tool
Standby excellent hardness, pliability, adhesive force, impact strength, wearability and good water resistance, and directly use liquid bisphenol
For A types epoxy resin as B component, acid-proof alkaline is excellent, and preparation technology is simple, easy for construction.
The preferred embodiment of the present invention described in detail above, still, the present invention are not limited in above-mentioned embodiment
Detail, those skilled in the art a variety of equivalent substitutes for carrying out or simple becomes in the range of the technology design of the present invention
Type mode, belongs to protection scope of the present invention.
Claims (10)
1. a kind of double-component aqueous epoxide terrace paint of high-performance, include two components of A, B, it is characterised in that the component A includes
Raw material by weight percentage below：
The B component is liquid-state epoxy resin.
2. the double-component aqueous epoxide terrace paint of high-performance according to claim 1, it is characterised in that the curing agent is non-
Ionic amine curing agent.
3. the double-component aqueous epoxide terrace paint of high-performance according to claim 1, it is characterised in that the liquid epoxy tree
Fat is bisphenol A type epoxy resin, molecular weight 300-400, epoxide equivalent 150-200.
4. the double-component aqueous epoxide terrace paint of high-performance according to claim 1, it is characterised in that the defoamer is ore deposit
Thing oil；The wax powder is 15-25 μm of polyethylene wax powder.
5. the double-component aqueous epoxide terrace paint of high-performance according to claim 1, it is characterised in that the auxiliary agent is selected from profit
At least one of humectant, dispersant, levelling agent, thickener.
6. the double-component aqueous epoxide terrace paint of high-performance according to claim 5, it is characterised in that the dispersant is poly-
PAA, wetting agent are nonionic surface active agent, and levelling agent is non-ionic associative type polyurethane, and thickener is association type
Alkali activates acrylic emulsion；The filler is at least one of talcum powder, mica powder, silica flour, titanium dioxide.
7. the double-component aqueous epoxide terrace paint of high-performance according to claim 6, it is characterised in that the talcum powder, cloud
Female powder, silica flour, the particle diameter of titanium dioxide are 1000-1500 mesh.
8. the double-component aqueous epoxide terrace paint of high-performance according to claim 1, it is characterised in that during the mill base uses
Yellow, phthalocyanine blue compounding.
9. a kind of method of the double-component aqueous epoxide terrace paint of high-performance prepared any one of claim 1-8, it is special
Sign is, comprises the following steps：
(1) prepared by component A slurry：Raw material is weighed by weight, by water, curing agent, part defoamer, part of auxiliary, wax powder, is filled out
Material is sequentially added in Scattered Kettle, is disperseed 10-20min with 400-800r/min, is obtained slurry；
(2) component A paint：Raw material is weighed by weight, and remaining auxiliary agent, mill base, remaining water and defoamer are added to step
Suddenly it is mixed evenly in slurry made from (1)；
(3) B component is directly packed.
10. the application method of the double-component aqueous epoxide terrace paint of high-performance described in a kind of claim 9, it is characterised in that make
Above-mentioned A, B component are pressed into A with preceding:B=4：1 quality proportioning stirs, then equal by 15% plus the water stirring of A, B gross weight
It is even.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711173966.5A CN107760166A (en) | 2017-11-22 | 2017-11-22 | A kind of double-component aqueous epoxide terrace paint of high-performance and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711173966.5A CN107760166A (en) | 2017-11-22 | 2017-11-22 | A kind of double-component aqueous epoxide terrace paint of high-performance and preparation method thereof |
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| CN107760166A true CN107760166A (en) | 2018-03-06 |
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| CN201711173966.5A Pending CN107760166A (en) | 2017-11-22 | 2017-11-22 | A kind of double-component aqueous epoxide terrace paint of high-performance and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181472A (en) * | 2018-08-04 | 2019-01-11 | 广州汤谱建筑装饰材料有限公司 | A kind of wear-resisting on-slip type epoxy resin is flat to apply floor coatings and preparation method thereof |
| CN109181478A (en) * | 2018-08-24 | 2019-01-11 | 河北晨阳工贸集团有限公司 | A kind of aqueous fluorescent epoxide terrace paint and preparation method thereof |
| CN109826395A (en) * | 2019-01-18 | 2019-05-31 | 东莞市天磊实业有限公司 | Floor paint construction method |
| CN112745736A (en) * | 2020-12-26 | 2021-05-04 | 上海汉中涂料有限公司 | Water-based epoxy matte floor varnish |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597812A (en) * | 2004-08-20 | 2005-03-23 | 广州秀珀化工有限公司 | Water epoxy paint for ground floor and its mfg. process and construction technology |
| CN1974701A (en) * | 2006-12-19 | 2007-06-06 | 盐城纺织职业技术学院 | Antiseptic and antistatic terrace paint and its prepn process |
| CN101368059A (en) * | 2008-09-04 | 2009-02-18 | 无锡市南雅化工有限公司 | Process for producing solvent-free epoxy matte paint for gravity flow flat ground |
| CN101818015A (en) * | 2010-05-24 | 2010-09-01 | 广州飞宇建材科技有限公司 | Aqueous antistatic epoxy floor paint and preparation method and application thereof |
| CN102190800A (en) * | 2010-03-06 | 2011-09-21 | 中国石油化工集团公司 | Preparation method of nonionic waterborne epoxy curing agent |
| CN106349884A (en) * | 2016-10-10 | 2017-01-25 | 深圳市前海福龙轩科技发展有限公司 | Double-component water-based epoxy floor paint |
-
2017
- 2017-11-22 CN CN201711173966.5A patent/CN107760166A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1597812A (en) * | 2004-08-20 | 2005-03-23 | 广州秀珀化工有限公司 | Water epoxy paint for ground floor and its mfg. process and construction technology |
| CN1974701A (en) * | 2006-12-19 | 2007-06-06 | 盐城纺织职业技术学院 | Antiseptic and antistatic terrace paint and its prepn process |
| CN101368059A (en) * | 2008-09-04 | 2009-02-18 | 无锡市南雅化工有限公司 | Process for producing solvent-free epoxy matte paint for gravity flow flat ground |
| CN102190800A (en) * | 2010-03-06 | 2011-09-21 | 中国石油化工集团公司 | Preparation method of nonionic waterborne epoxy curing agent |
| CN101818015A (en) * | 2010-05-24 | 2010-09-01 | 广州飞宇建材科技有限公司 | Aqueous antistatic epoxy floor paint and preparation method and application thereof |
| CN106349884A (en) * | 2016-10-10 | 2017-01-25 | 深圳市前海福龙轩科技发展有限公司 | Double-component water-based epoxy floor paint |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109181472A (en) * | 2018-08-04 | 2019-01-11 | 广州汤谱建筑装饰材料有限公司 | A kind of wear-resisting on-slip type epoxy resin is flat to apply floor coatings and preparation method thereof |
| CN109181478A (en) * | 2018-08-24 | 2019-01-11 | 河北晨阳工贸集团有限公司 | A kind of aqueous fluorescent epoxide terrace paint and preparation method thereof |
| CN109826395A (en) * | 2019-01-18 | 2019-05-31 | 东莞市天磊实业有限公司 | Floor paint construction method |
| CN112745736A (en) * | 2020-12-26 | 2021-05-04 | 上海汉中涂料有限公司 | Water-based epoxy matte floor varnish |
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Application publication date: 20180306 |
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