CN104073091A - Polyvinyl alcohol water-based architectural paint - Google Patents
Polyvinyl alcohol water-based architectural paint Download PDFInfo
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- CN104073091A CN104073091A CN201410284565.7A CN201410284565A CN104073091A CN 104073091 A CN104073091 A CN 104073091A CN 201410284565 A CN201410284565 A CN 201410284565A CN 104073091 A CN104073091 A CN 104073091A
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Abstract
The invention relates to a polyvinyl alcohol water-based architectural paint which is prepared from the following raw materials in parts by weight: 100 parts of polyvinyl alcohol, 10-20 parts of benzaldehyde, 5-15 parts of lithopone, 15-25 parts of hypnone, 1-10 parts of zinc oxide, 30-40 parts of paraffin, 50-60 parts of deionized water, 20-30 parts of benzoic acid, 15-25 parts of pigment, 30-40 parts of nitrocellulose, 25-35 parts of sodium hexametaphosphate, 35-45 parts of ethanol, 5-10 parts of plasticizer, 25-35 parts of ethyl acetate, 15-25 parts of talcum powder and 20-30 parts of triethanolamine. The product can not cake after being stored for 6-10 months, and the solid content is 35-45%. The surface drying time is 40-50 minutes, and the solid drying time is 20-22 hours. The paint does not have any abnormity after being immersed in saturated calcium carbonate for 10-20 days. The wiping resistance of the coated film is 2600-2800 times; and the paint can be widely produced and continuously substitute the existing materials.
Description
Technical field
The application belongs to paint field, relates in particular to a kind of polyvinyl alcohol aqueous architectural coating.
Background technology
Coating, is to be applied to body surface can form and have protection, decoration or property one class I liquid I of solid-state film of (as insulation, anticorrosion, mark etc.) or the general name of solid material, comprises oil (property) paint, water-miscible paint, powder coating.Paint is flowable liquid coating, comprises oil (property) paint and water-miscible paint.China's coating circle more authoritative " coating process " book is definition like this: " coating is a kind of material, and this material can be coated in article surface by different construction technologies, forms and adheres to firmly, has some strength, continuous solid film.The film common name film forming like this, claims again paint film or coating." paint finishing can and form the material of complete and tough and tensile protective membrane with the fine bonding of body material in body surface, is called coating.Coating and paint are identical concepts.Paint is people's custom titles used for a long time, introduces after China, just utilizes in building trade always.The effect of coating may be summarized to be three aspects: provide protection, decoration function, specific function effect.The general composition of coating: comprise filmogen, color stuffing, solvent, auxiliary agent.
Coating refers to the general name that is applied to body surface and can form the material of tough and tensile protective membrane, and building coating is an important class in coating, in China, generally will be used for inner wall of building, exterior wall, and ceiling, ground, the coating of toilet is called building coating.Building coating has decoration functions, defencive function and livability and improves function.The shared proportion of various functions is not quite similar because application target is different.Decoration functions is the function of beautifying the appearance value that improves it by buildings.Mainly comprise the design design of plane color, pattern and gloss aspect and the design of three-dimensional pattern design.But to match with the size and shape of the moulding of buildings itself and base material itself, just can fully play out.Defencive function refers to that protection buildings is not subject to the impact of environment and the function of destruction.The content that different types of protected body requires defencive function is also different.As indoor and outdoor application require the index difference that reaches just very large.Paint is taking organic solvent as medium or high solid, solvent-free oil-base paint.Water-miscible paint is used water dissolving or the coating with water-dispersion.
Coating is as one of main material of house decoration, and the large percentage accounting in decorations is bought the whether qualified environment that directly has influence on entirety finishing effect and room of coating, sometimes even can produce harm greatly to the health of human body.Building coating is mainly used in the coating products of house decoration as a class, its market development and real estate industry's development are closely related.Since " the tightest policy of real estate in history " put into effect, market of real estate development is absorbed in low ebb, and since especially entering 2012, the policy of expection is loosening before does not occur, is that firmly the portion of building clearly represents that in the short period of time, policy of regulation and control can not change on the contrary.Some buildingss to mildew-resistant, fire prevention, heat insulating, corrosion-resistant etc. have a particular requirement.It is mainly for indoor application that livability is improved function, contributes to exactly to improve the function of living environment, as sound-proofing, sound absorbing, antisweat etc.And universal along with humanity concept, and the formation of novel harmonious society, the polyvinyl alcohol aqueous architectural coating that designs a kind of good stability, fast drying, alkali resistance and resistance to wiping excellence is very important.
Summary of the invention
The technical problem solving:
The application, for above-mentioned technical problem, provides a kind of polyvinyl alcohol aqueous architectural coating, solves that existing polyvinyl alcohol aqueous architectural coating poor stability, time of drying are long, alkali resistance and the technical problem such as resistance to wiping is poor.
Technical scheme:
A kind of polyvinyl alcohol aqueous architectural coating, the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: 100 parts of polyvinyl alcohol; Phenyl aldehyde 10-20 part; Zinc sulfide white 5-15 part; Methyl phenyl ketone 15-25 part; Zinc oxide 1-10 part; Paraffin 30-40 part; Deionized water 50-60 part; Phenylformic acid 20-30 part; Pigment 15-25 part; Nitro-cotton 30-40 part; Sodium hexametaphosphate 99 25-35 part; Ethanol 35-45 part; Softening agent 5-10 part; Vinyl acetic monomer 25-35 part; Talcum powder 15-25 part; Trolamine 20-30 part.
As a preferred technical solution of the present invention: the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: 100 parts of polyvinyl alcohol; 15 parts of phenyl aldehydes; 10 parts, zinc sulfide white; 20 parts of methyl phenyl ketones; 5 parts, zinc oxide; 35 parts, paraffin; 55 parts of deionized waters; 25 parts, phenylformic acid; 20 parts of pigment; 35 parts of nitro-cottons; 30 parts of Sodium hexametaphosphate 99s; 40 parts of ethanol; 8 parts, softening agent; 30 parts of vinyl acetic monomers; 20 parts of talcum powder; 25 parts of trolamines.
As a preferred technical solution of the present invention: described pigment adopts light calcium carbonate.
As a preferred technical solution of the present invention: described softening agent adopts dibutyl phthalate.
Beneficial effect:
A kind of polyvinyl alcohol aqueous architectural coating of the present invention adopts above technical scheme compared with prior art, has following technique effect: 1, product storage is not lumpd for 6-10 month, solid content 35-45%; 2, surface drying 40-50min, does solid work 20-22h; 3, in unsaturated carbonate calcium, soak 10-20d after without abnormal; 4, the film 2600-2800 of resistance to wiping time, can the not division of history into periods of widespread production replace current material.
Embodiment
Embodiment 1:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 10 parts of phenyl aldehydes; 5 parts, zinc sulfide white; 15 parts of methyl phenyl ketones; 1 part, zinc oxide; 30 parts, paraffin; 50 parts of deionized waters; 20 parts, phenylformic acid; 15 parts of light calcium carbonates; 30 parts of nitro-cottons; 25 parts of Sodium hexametaphosphate 99s; 35 parts of ethanol; 5 parts of dibutyl phthalates; 25 parts of vinyl acetic monomers; 15 parts of talcum powder; 20 parts of trolamines.
After phenyl aldehyde is added in deionized water and to be dissolved, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min had both obtained finished product.
Product storage is not lumpd for 6 months, solid content 35%; Surface drying 50min, does solid work 22h; Soak 10d in unsaturated carbonate calcium after, nothing is abnormal; The resistance to wiping of film 2600 times.
Embodiment 2:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 20 parts of phenyl aldehydes; 15 parts, zinc sulfide white; 25 parts of methyl phenyl ketones; 10 parts, zinc oxide; 40 parts, paraffin; 60 parts of deionized waters; 30 parts, phenylformic acid; 25 parts of light calcium carbonates; 40 parts of nitro-cottons; 35 parts of Sodium hexametaphosphate 99s; 45 parts of ethanol; 10 parts of dibutyl phthalates; 35 parts of vinyl acetic monomers; 25 parts of talcum powder; 30 parts of trolamines.
After phenyl aldehyde is added in deionized water and to be dissolved, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min had both obtained finished product.
Product storage is not lumpd for 8 months, solid content 40%; Surface drying 45min, does solid work 21h; Soak 15d in unsaturated carbonate calcium after, nothing is abnormal; The resistance to wiping of film 2700 times.
Embodiment 3:
A kind of polyvinyl alcohol aqueous architectural coating, its raw materials by weight portion proportioning is as follows: 100 parts of polyvinyl alcohol; 15 parts of phenyl aldehydes; 10 parts, zinc sulfide white; 20 parts of methyl phenyl ketones; 5 parts, zinc oxide; 35 parts, paraffin; 55 parts of deionized waters; 25 parts, phenylformic acid; 20 parts of light calcium carbonates; 35 parts of nitro-cottons; 30 parts of Sodium hexametaphosphate 99s; 40 parts of ethanol; 8 parts of dibutyl phthalates; 30 parts of vinyl acetic monomers; 20 parts of talcum powder; 25 parts of trolamines.
After phenyl aldehyde is added in deionized water and to be dissolved, add polyvinyl alcohol, zinc sulfide white, zinc oxide, light calcium carbonate, dibutyl phthalate, Sodium hexametaphosphate 99, talcum powder, with ball mill ball milling 30min, then add methyl phenyl ketone, paraffin and surplus stock, ball milling 30min had both obtained finished product.
Product storage is not lumpd for 10 months, solid content 45%; Surface drying 40min, does solid work 20h; Soak 20d in unsaturated carbonate calcium after, nothing is abnormal; The resistance to wiping of film 2800 times.
Composition all components in above embodiment all can business be bought.
Above-described embodiment is just for content of the present invention is set forth, instead of restriction, and therefore any change in implication and the scope suitable with claims of the present invention, all should think to be included in the scope of claims.
Claims (4)
1. a polyvinyl alcohol aqueous architectural coating, is characterized in that the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: 100 parts of polyvinyl alcohol; Phenyl aldehyde 10-20 part; Zinc sulfide white 5-15 part; Methyl phenyl ketone 15-25 part; Zinc oxide 1-10 part; Paraffin 30-40 part; Deionized water 50-60 part; Phenylformic acid 20-30 part; Pigment 15-25 part; Nitro-cotton 30-40 part; Sodium hexametaphosphate 99 25-35 part; Ethanol 35-45 part; Softening agent 5-10 part; Vinyl acetic monomer 25-35 part; Talcum powder 15-25 part; Trolamine 20-30 part.
2. a kind of polyvinyl alcohol aqueous architectural coating according to claim 1, is characterized in that the raw materials by weight portion proportioning of described polyvinyl alcohol aqueous architectural coating is as follows: 100 parts of polyvinyl alcohol; 15 parts of phenyl aldehydes; 10 parts, zinc sulfide white; 20 parts of methyl phenyl ketones; 5 parts, zinc oxide; 35 parts, paraffin; 55 parts of deionized waters; 25 parts, phenylformic acid; 20 parts of pigment; 35 parts of nitro-cottons; 30 parts of Sodium hexametaphosphate 99s; 40 parts of ethanol; 8 parts, softening agent; 30 parts of vinyl acetic monomers; 20 parts of talcum powder; 25 parts of trolamines.
3. a kind of polyvinyl alcohol aqueous architectural coating according to claim 1, is characterized in that: described pigment adopts light calcium carbonate.
4. a kind of polyvinyl alcohol aqueous architectural coating according to claim 1, is characterized in that: described softening agent adopts dibutyl phthalate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410284565.7A CN104073091B (en) | 2014-06-23 | 2014-06-23 | A kind of polyvinyl alcohol aqueous architectural coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410284565.7A CN104073091B (en) | 2014-06-23 | 2014-06-23 | A kind of polyvinyl alcohol aqueous architectural coating |
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| Publication Number | Publication Date |
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| CN104073091A true CN104073091A (en) | 2014-10-01 |
| CN104073091B CN104073091B (en) | 2016-02-10 |
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| CN201410284565.7A Expired - Fee Related CN104073091B (en) | 2014-06-23 | 2014-06-23 | A kind of polyvinyl alcohol aqueous architectural coating |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086667A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Water-based multicolor coating |
| CN106833070A (en) * | 2016-12-30 | 2017-06-13 | 芜湖天鸿汽车零部件有限公司 | A kind of automobile sun paint and preparation method thereof |
| CN113278316A (en) * | 2021-06-03 | 2021-08-20 | 黑龙江佰嘉生物质材料有限公司 | Environment-friendly waterproof coating composition for indoor building decoration and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1182762A (en) * | 1997-11-03 | 1998-05-27 | 马新刚 | High hardness water-proof porcelain imitation paint |
| JP2000230144A (en) * | 1999-02-10 | 2000-08-22 | Asahi Chem Ind Co Ltd | Emulsion of cellulose nitric esters |
| CN101768398A (en) * | 2009-12-16 | 2010-07-07 | 上海维凯化学品有限公司 | Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof |
| CN102408793A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Polyvinyl alcohol waterproof coating |
-
2014
- 2014-06-23 CN CN201410284565.7A patent/CN104073091B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1182762A (en) * | 1997-11-03 | 1998-05-27 | 马新刚 | High hardness water-proof porcelain imitation paint |
| JP2000230144A (en) * | 1999-02-10 | 2000-08-22 | Asahi Chem Ind Co Ltd | Emulsion of cellulose nitric esters |
| CN101768398A (en) * | 2009-12-16 | 2010-07-07 | 上海维凯化学品有限公司 | Water-based temperature resistant single-coating transfer laser aluminizing paint and preparation method thereof |
| CN102408793A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Polyvinyl alcohol waterproof coating |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105086667A (en) * | 2015-08-03 | 2015-11-25 | 苏州舒而适纺织新材料科技有限公司 | Water-based multicolor coating |
| CN106833070A (en) * | 2016-12-30 | 2017-06-13 | 芜湖天鸿汽车零部件有限公司 | A kind of automobile sun paint and preparation method thereof |
| CN113278316A (en) * | 2021-06-03 | 2021-08-20 | 黑龙江佰嘉生物质材料有限公司 | Environment-friendly waterproof coating composition for indoor building decoration and preparation method thereof |
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| CN104073091B (en) | 2016-02-10 |
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| C06 | Publication | ||
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| C10 | Entry into substantive examination | ||
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| C14 | Grant of patent or utility model | ||
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| CB03 | Change of inventor or designer information |
Inventor after: Shen Xiaolong Inventor before: Qian Yuzhu |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170920 Address after: 215100 Hope Industrial Park, North Qiao Town, Suzhou, Jiangsu, Xiangcheng District Patentee after: Suzhou super coating Co., Ltd. Address before: Wujiang City, Suzhou City, 215299 Song Ling Zhen Wu in Jiangsu province with the side of the road Patentee before: Suzhou Jing Yu novel material company limited |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160210 Termination date: 20190623 |