CN104277669A - Heat-insulation corrosion-resistant rooting-resistant type waterproof paint for planted roof and preparation method thereof - Google Patents

Heat-insulation corrosion-resistant rooting-resistant type waterproof paint for planted roof and preparation method thereof Download PDF

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Publication number
CN104277669A
CN104277669A CN201410590712.3A CN201410590712A CN104277669A CN 104277669 A CN104277669 A CN 104277669A CN 201410590712 A CN201410590712 A CN 201410590712A CN 104277669 A CN104277669 A CN 104277669A
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parts
rooting
powder
resistant
resin
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CN201410590712.3A
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Inventor
朱厚信
张军
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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ANHUI LANGKAIQI BUILDING MATERIALS Co Ltd
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Priority to CN201410590712.3A priority Critical patent/CN104277669A/en
Publication of CN104277669A publication Critical patent/CN104277669A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses heat-insulation corrosion-resistant rooting-resistant type waterproof paint for a planted roof. The heat-insulation corrosion-resistant rooting-resistant type waterproof paint is characterized by being prepared from the following raw materials in parts by weight: 0.3-0.4 part of a dispersing agent EFKA015, 0.05-0.15 part of a defoaming agent EFKA-20220, 20-30 parts of urea resin, 30-40 parts of epoxy resin, 6-9 parts of phenylated amino resin, 0.2-0.3 part of aminobenzene sulfonic acid, 1-2 parts of 1,6-hexylene glycol diacrylate, 1-2 parts of 2-methyl-4-cholopentyloxy propionic acid, 1-2 parts of vacuum glass beads, 2-3 parts of coal ash hollow beads, 4-6 parts of aluminum silicate powder, 3-4 parts of borax, 1-2 parts of 3,3-dicholo-4,4-diphenyl methane diamine, 5-7 parts of rooting-resisting auxiliaries, 1-2 parts of polyethylene wax emulsion, 2-4 parts of turpentine, 4-6 parts of dimethyl benzene, 7-9 parts of butyl acetate and 5-7 parts of S-100. The heat-insulation corrosion-resistant rooting-resistant type waterproof paint disclosed by the invention has excellent heat insulation performance, rooting resistance and corrosion resistance; the added coal ash hollow beads and the vacuum glass beads have good heat insulation and are low in cost, the added rooting-resisting auxiliaries have excellent rooting resistance and are free of harms on plants; and the added borax has effects of strengthening the corrosion resistance, the sterilization and the like of the paint.

Description

A kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof and preparation method thereof
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof and preparation method thereof.
Background technology
Along with the fast development of economy and the raising gradually of people's living standard, energy dilemma and ecocrisis more and more severeer, very serious to environmental influence.Ecological planting system for roof is a developing direction of China's dwelling construction, is also the important content carrying out energy saving building, green building and establishment " ecology botanical garden city ".Planted roof improves afforestation coverage in the city, slows down " tropical island effect ", reduces topsoil, saves the energy, retains rainwater, extends waterproof layer work-ing life, improves the ecological environment and the effective way of beautifying city view.Planting technique roofing is generally made up of planted plant, waterproof stopping area, water draining and accumulating device, heat insulation layer etc., and wherein waterproof stopping area is particularly important.Any planting technique engineering all can face the problem of water leakage, because the plant of plantation has flourishing root system, they can penetrate roof construction layer and cause serious percolating water phenomenon, therefore architecture greening planting engineering requires that waterproof paint has good resistance to roots of plants and wears performance, ensures plant normal growth simultaneously.
Now day by day warming along with weather, and along with the irradiation of sunlight, the accumulation due to heat can make air and body surface temperature constantly raise, and heat enters internal medium by thermal conduction.This can increase the use of electrical equipment and cause many pollutions and waste to environment and society.The present invention is directed to root resistance auxiliary agent prepared by this situation, add in coating as auxiliary agent, there is production cost low, root system of plant is not almost affected, play the effect of good anti-root system of plant puncture, and add the material with heat-blocking action, the transmission of heat can be reduced, make inner envrionment temperature not increase, avoid the waste of Energy resources.
Summary of the invention
The object of this invention is to provide a kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof, be made up of the raw material of following weight part: dispersion agent EFKA0150.3-0.4, defoamer EFKA-202200.05-0.15, urea-formaldehyde resin 20-30, epoxy resin 30-40, benzene is for aminoresin 6-9, aniline sulfonic acid 0.2-0.3, 1, 6-hexanediyl ester 1-2, 2-methyl-4-chlorine pentyloxy propionic acid 1-2, vacuum glass microballon 1-2, coal fly ash hollow micro bead 2-3, aluminium silicate powder 4-6, borax 3-4, 3, 3-bis-chloro-4, 4-diphenylmethanediamiand 1-2, root resistance auxiliary agent 5-7, polythene wax emulsion 1-2, turps 2-4, dimethylbenzene 4-6, N-BUTYL ACETATE 7-9, S-1005-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
A kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof of the present invention, comprises following concrete steps:
(1) by N-BUTYL ACETATE, turps, dimethylbenzene, S-100 mixing, add vacuum glass microballon, coal fly ash hollow micro bead, aluminium silicate powder, polythene wax emulsion ultrasonic disperse 10-20 minute, root resistance auxiliary agent, 2-methyl-4-chlorine pentyloxy propionic acid, borax and dispersion agent EFKA015 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer EFKA-20220, urea-formaldehyde resin, epoxy resin, aniline sulfonic acid, 1,6 hexanediol diacrylate stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Advantage of the present invention is: coating of the present invention has excellent heat-proof quality, root-resistant type energy and non-corrosibility, the coal fly ash hollow micro bead added and vacuum glass microballon have good heat-proof quality, and cost is low, the root resistance auxiliary agent added has excellent root resistance effect, and to plant fanout free region, the borax of interpolation has the effect strengthening the aspects such as anticorrosion with coat erosion, sterilization.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof, be made up of the raw material of following weight part (kilogram): dispersion agent EFKA0150.3, defoamer EFKA-202200.08, urea-formaldehyde resin 25, epoxy resin 37, benzene is for aminoresin 8.3, aniline sulfonic acid 0.2, 1, 6-hexanediyl ester 1, 2-methyl-4-chlorine pentyloxy propionic acid 2, vacuum glass microballon 1, coal fly ash hollow micro bead 3, aluminium silicate powder 5, borax 3, 3, 3-bis-chloro-4, 4-diphenylmethanediamiand 1, root resistance auxiliary agent 6, polythene wax emulsion 2, turps 4, dimethylbenzene 5, N-BUTYL ACETATE 8, S-1006,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part (kilogram): root resistance agent B24, petroleum pitch AH-8033, petroleum resin 14, gum resin 5, nano titanium oxide 3, turps 12, ethyl acetate 7, epoxy soybean oil 3, copper nanoparticle 7, calcined kaolin powder 16, calcining calcite in powder 15, silicon carbide whisker powder 7, sodium lauryl sulphate 1, silane coupling agent KH5600.9, Ethylene glycol dimethacrylate 1, dilaurate dibutyl tin 0.6, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
A kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof of the present invention, comprises following concrete steps:
(1) by N-BUTYL ACETATE, turps, dimethylbenzene, S-100 mixing, add vacuum glass microballon, coal fly ash hollow micro bead, aluminium silicate powder, polythene wax emulsion ultrasonic disperse 10-20 minute, root resistance auxiliary agent, 2-methyl-4-chlorine pentyloxy propionic acid, borax and dispersion agent EFKA015 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer EFKA-20220, urea-formaldehyde resin, epoxy resin, aniline sulfonic acid, 1,6 hexanediol diacrylate stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Paint adhesion experiment (cross-hatching) of the present invention: 0 grade, experiment of hardness: 3H, T curved experiment: 2T, resistance to impact shock is tested: 9J, artificial ageing resistance experiment (2000H): film is unchanged, resistance to boiling water experiment (2H): unchanged, root puncture resistant capacity experimental: without penetration phenomenon.

Claims (2)

1. the heat insulating and corrosion root-resistant type waterproof paint for planted roof, it is characterized in that, be made up of the raw material of following weight part: dispersion agent EFKA0150.3-0.4, defoamer EFKA-202200.05-0.15, urea-formaldehyde resin 20-30, epoxy resin 30-40, benzene is for aminoresin 6-9, aniline sulfonic acid 0.2-0.3, 1, 6-hexanediyl ester 1-2, 2-methyl-4-chlorine pentyloxy propionic acid 1-2, vacuum glass microballon 1-2, coal fly ash hollow micro bead 2-3, aluminium silicate powder 4-6, borax 3-4, 3, 3-bis-chloro-4, 4-diphenylmethanediamiand 1-2, root resistance auxiliary agent 5-7, polythene wax emulsion 1-2, turps 2-4, dimethylbenzene 4-6, N-BUTYL ACETATE 7-9, S-1005-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
2. a kind of heat insulating and corrosion root-resistant type waterproof paint for planted roof according to claims 1, is characterized in that, comprise following concrete steps:
(1) by N-BUTYL ACETATE, turps, dimethylbenzene, S-100 mixing, add vacuum glass microballon, coal fly ash hollow micro bead, aluminium silicate powder, polythene wax emulsion ultrasonic disperse 10-20 minute, root resistance auxiliary agent, 2-methyl-4-chlorine pentyloxy propionic acid, borax and dispersion agent EFKA015 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, under 2000-4000 rev/min, add defoamer EFKA-20220, urea-formaldehyde resin, epoxy resin, aniline sulfonic acid, 1,6 hexanediol diacrylate stirring 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
CN201410590712.3A 2014-10-29 2014-10-29 Heat-insulation corrosion-resistant rooting-resistant type waterproof paint for planted roof and preparation method thereof Pending CN104277669A (en)

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Application Number Priority Date Filing Date Title
CN201410590712.3A CN104277669A (en) 2014-10-29 2014-10-29 Heat-insulation corrosion-resistant rooting-resistant type waterproof paint for planted roof and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318113A (en) * 2016-08-18 2017-01-11 柳州市亿廷贸易有限责任公司 Thermal insulation coating

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101935488A (en) * 2010-09-30 2011-01-05 北京立高科技股份有限公司 Plant root resistant waterproof coating and preparation method thereof
CN102863891A (en) * 2012-09-12 2013-01-09 常熟市三恒建材有限责任公司 Plant-root-piercing-resistant waterproof coating
CN102965020A (en) * 2012-11-30 2013-03-13 山东北方创信防水技术有限公司 Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting
CN103275611A (en) * 2013-04-28 2013-09-04 北京立高防水工程有限公司 Environmentally-friendly root-resistant waterproof polyurethane paint and preparation method thereof
CN103468124A (en) * 2013-09-06 2013-12-25 安徽朗凯奇建材有限公司 Waterproof and root-resistant polyurethane coating for planting roof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101935488A (en) * 2010-09-30 2011-01-05 北京立高科技股份有限公司 Plant root resistant waterproof coating and preparation method thereof
CN102863891A (en) * 2012-09-12 2013-01-09 常熟市三恒建材有限责任公司 Plant-root-piercing-resistant waterproof coating
CN102965020A (en) * 2012-11-30 2013-03-13 山东北方创信防水技术有限公司 Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting
CN103275611A (en) * 2013-04-28 2013-09-04 北京立高防水工程有限公司 Environmentally-friendly root-resistant waterproof polyurethane paint and preparation method thereof
CN103468124A (en) * 2013-09-06 2013-12-25 安徽朗凯奇建材有限公司 Waterproof and root-resistant polyurethane coating for planting roof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106318113A (en) * 2016-08-18 2017-01-11 柳州市亿廷贸易有限责任公司 Thermal insulation coating

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