CN104277695A - Wear-resistant and scratch-resistant root-resistant waterproof coating and preparation method thereof - Google Patents
Wear-resistant and scratch-resistant root-resistant waterproof coating and preparation method thereof Download PDFInfo
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- CN104277695A CN104277695A CN201410590476.5A CN201410590476A CN104277695A CN 104277695 A CN104277695 A CN 104277695A CN 201410590476 A CN201410590476 A CN 201410590476A CN 104277695 A CN104277695 A CN 104277695A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a wear-resistant and scratch-resistant root-resistant waterproof coating which is characterized by being prepared from the following raw materials in parts by weight: 30-40 parts of polyurethane resin, 20-30 parts of PVDF (polyvinylidene fluoride) resin, 4-6 parts of partially etherified amino resin, 0.2-0.4 part of a dispersant EFKA6745, 0.3-0.4 part of a defoaming agent BYK-077, 0.1-0.3 part of dinonyl naphthalene sulfonic acid, 5-7 parts of barium metaborate, 3-5 parts of diamond powder, 6-9 parts of rosin maleic anhydride polyol ester, 1-2 parts of acetochlor, 1-2 parts of an antiager, 1-2 parts of 3,3-dichloro-4,4-methylene diphenylamine, 4-6 parts of zinc oxide, 5-6 parts of magnesium oxide, 5-7 parts of a root assisting auxiliary, 3-4 parts of methylpropanediol, 7-9 parts of acetic ether, 8-10 parts of n-butyl alcohol and 5-7 parts of ethylene glycol butyl ether. The barium metaborate and diamond powder added into the waterproof coating have the effect of enhancing the wear resistance and the scratch resistance of the coating; the added antiager has the effect of enhancing the weather resistance and aging resistance of the coating. By further adding the self-made root resisting auxiliary, the coating has a good root resisting effect and is less in damage to the plant root system. The coating disclosed by the invention is short in curing time, good in construction performance, convenient to manufacture and strong in practicality.
Description
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of root-resistant type waterproof paint and preparation method thereof of wear-resisting scratch resistant.
Background technology
Along with the fast development of economy and the raising gradually of people's living standard, energy dilemma and ecocrisis more and more severeer, very serious to environmental influence.Now people environmental consciousness also improves gradually, and for building residential quarter miscellaneous, people more and more value their green coverage and region, a direction of this Ye Shi China dwelling construction.Any planting technique engineering all can face the problem of water leakage, because the plant of plantation has flourishing root system, they can penetrate roof construction layer and cause serious percolating water phenomenon, therefore architecture greening planting engineering requires that waterproof paint has good resistance to roots of plants and wears performance, ensures plant normal growth simultaneously.The present invention is directed to root resistance auxiliary agent prepared by this situation, add in coating as auxiliary agent, there is production cost low, root system of plant is not almost affected, plays the effect of good anti-root system of plant puncture, and there is the performance of good wear-resisting scratch resistant, the work-ing life of paint film can be increased, reduce maintenance cost, substantially increase the performance of coating, reduce costs.
Summary of the invention
The object of this invention is to provide root-resistant type waterproof paint of a kind of wear-resisting scratch resistant and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of root-resistant type waterproof paint of wear-resisting scratch resistant, be made up of the raw material of following weight part: urethane resin 30-40, PVDF resin 20-30, partial ethers aminoresin 4-6, dispersion agent EFKA67450.2-0.4, defoamer BYK-0770.3-0.4, dinonylnaphthalene sulfonic acid 0.1-0.3, barium metaborate 5-7, bortz powder 3-5, Rosin Maleic polyol ester 6-9, acetochlor 1-2, antiaging agent 1-2, 3, 3-bis-chloro-4, 4-diphenylmethanediamiand 1-2, zinc oxide 4-6, magnesium oxide 5-6, root resistance auxiliary agent 5-7, methyl propanediol 3-4, vinyl acetic monomer 7-9, propyl carbinol 8-10, butyl glycol ether 5-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
The root-resistant type waterproof paint of a kind of wear-resisting scratch resistant of the present invention, comprises following concrete steps:
(1) by vinyl acetic monomer, propyl carbinol, butyl glycol ether mixing, add bortz powder, barium metaborate, zinc oxide, magnesium oxide ultrasonic disperse 10-20 minute, root resistance auxiliary agent, methyl propanediol and dispersion agent EFKA6745 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, defoamer BYK-077, dinonylnaphthalene sulfonic acid, urethane resin, PVDF resin, Rosin Maleic polyol ester, 3 is added under 2000-4000 rev/min, chloro-4, the 4-diphenylmethanediamiands of 3-bis-stir 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Advantage of the present invention is: the barium metaborate that waterproof paint of the present invention adds and bortz powder have the effect strengthening coating wear resistance and scratch resistant, the antiaging agent added has the weather resistance and ageing resistance that strengthen coating, the present invention also adds homemade root resistance auxiliary agent and has good root resistance effect, almost do not have the injury of root system of plant, the paint solidification time of the present invention is short, have good workability, easily manufactured, practical.
specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of root-resistant type waterproof paint of wear-resisting scratch resistant, be made up of the raw material of following weight part (kilogram): urethane resin 36, PVDF resin 26, partial ethers aminoresin 6, dispersion agent EFKA67450.4, defoamer BYK-0770.3, dinonylnaphthalene sulfonic acid 0.3, barium metaborate 6, bortz powder 4, Rosin Maleic polyol ester 8, acetochlor 1, antiaging agent 1,3, chloro-4, the 4-diphenylmethanediamiands 1 of 3-bis-, zinc oxide 5, magnesium oxide 6, root resistance auxiliary agent 6, methyl propanediol 3, vinyl acetic monomer 8, propyl carbinol 9, butyl glycol ether 6;
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part (kilogram): root resistance agent B24, petroleum pitch AH-8033, petroleum resin 14, gum resin 5, nano titanium oxide 3, turps 12, ethyl acetate 7, epoxy soybean oil 3, copper nanoparticle 7, calcined kaolin powder 16, calcining calcite in powder 15, silicon carbide whisker powder 7, sodium lauryl sulphate 1, silane coupling agent KH5600.9, Ethylene glycol dimethacrylate 1, dilaurate dibutyl tin 0.6, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
The root-resistant type waterproof paint of a kind of wear-resisting scratch resistant of the present invention, comprises following concrete steps:
(1) by vinyl acetic monomer, propyl carbinol, butyl glycol ether mixing, add bortz powder, barium metaborate, zinc oxide, magnesium oxide ultrasonic disperse 10-20 minute, root resistance auxiliary agent, methyl propanediol and dispersion agent EFKA6745 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, defoamer BYK-077, dinonylnaphthalene sulfonic acid, urethane resin, PVDF resin, Rosin Maleic polyol ester, 3 is added under 2000-4000 rev/min, chloro-4, the 4-diphenylmethanediamiands of 3-bis-stir 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Paint adhesion experiment (cross-hatching) of the present invention: 1 grade, experiment of hardness: 3H, T curved experiment: 2T, resistance to impact shock is tested: 7J, artificial ageing resistance experiment (2000H): film is unchanged, resistance to boiling water experiment (2H): unchanged, root puncture resistant capacity experimental: without penetration phenomenon.
Claims (2)
1. the root-resistant type waterproof paint of a wear-resisting scratch resistant, it is characterized in that, be made up of the raw material of following weight part: urethane resin 30-40, PVDF resin 20-30, partial ethers aminoresin 4-6, dispersion agent EFKA67450.2-0.4, defoamer BYK-0770.3-0.4, dinonylnaphthalene sulfonic acid 0.1-0.3, barium metaborate 5-7, bortz powder 3-5, Rosin Maleic polyol ester 6-9, acetochlor 1-2, antiaging agent 1-2, 3, 3-bis-chloro-4, 4-diphenylmethanediamiand 1-2, zinc oxide 4-6, magnesium oxide 5-6, root resistance auxiliary agent 5-7, methyl propanediol 3-4, vinyl acetic monomer 7-9, propyl carbinol 8-10, butyl glycol ether 5-7,
Described nanometer root resistance auxiliary agent is made up of the raw material of following weight part: root resistance agent B23-5, petroleum pitch AH-8030-34, petroleum resin 13-16, gum resin 4-6, nano titanium oxide 2-3, turps 12-14, ethyl acetate 6-8, epoxy soybean oil 2-3, copper nanoparticle 5-8, calcined kaolin powder 15-17, calcining calcite in powder 14-16, silicon carbide whisker powder 6-8, sodium lauryl sulphate 1-2, silane coupling agent KH5600.5-1.0, Ethylene glycol dimethacrylate 1-2, dilaurate dibutyl tin 0.4-0.8, preparation method is by silane coupling agent KH560, calcined kaolin powder, calcining calcite in powder, copper nanoparticle and silicon carbide whisker powder mixed grinding be uniformly dispersed formed mixed powder for subsequent use, again petroleum pitch AH-80 is heated to 120-130 ° of C, the solution making 0.5-1.5% that sodium lauryl sulphate is dissolved in water is heated to 60-80 ° of C formation emulsion, emulsion is added in petroleum pitch AH-80 and carries out high shear agitation 30-45 minute, temperature is controlled after 70-90 ° of C, add petroleum resin, gum resin, turps, ethyl acetate and epoxy soybean oil mixing and stirring, meanwhile add root resistance agent B2 again, mixed powder, dilaurate dibutyl tin and Ethylene glycol dimethacrylate stir.
2. a kind of ageing-resistant fade-proof root-resistant type coil coating according to claims 1, is characterized in that, comprise following concrete steps:
(1) by vinyl acetic monomer, propyl carbinol, butyl glycol ether mixing, add bortz powder, barium metaborate, zinc oxide, magnesium oxide ultrasonic disperse 10-20 minute, root resistance auxiliary agent, methyl propanediol and dispersion agent EFKA6745 are added to grinding in sand mill by control temperature when 20-50 ° of C even;
(2) material of step (1) is transferred in the reactor with stirring rake, defoamer BYK-077, dinonylnaphthalene sulfonic acid, urethane resin, PVDF resin, Rosin Maleic polyol ester, 3 is added under 2000-4000 rev/min, chloro-4, the 4-diphenylmethanediamiands of 3-bis-stir 1-2 hour;
(3) all the other surplus materialss are mixed, add the material in step (2), stir under 1200-1500 rev/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590476.5A CN104277695A (en) | 2014-10-29 | 2014-10-29 | Wear-resistant and scratch-resistant root-resistant waterproof coating and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410590476.5A CN104277695A (en) | 2014-10-29 | 2014-10-29 | Wear-resistant and scratch-resistant root-resistant waterproof coating and preparation method thereof |
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| CN104277695A true CN104277695A (en) | 2015-01-14 |
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| CN201410590476.5A Pending CN104277695A (en) | 2014-10-29 | 2014-10-29 | Wear-resistant and scratch-resistant root-resistant waterproof coating and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849322A (en) * | 2020-07-29 | 2020-10-30 | 深圳市奇信集团股份有限公司 | Toilet waterproof coating and construction method |
| CN111995946A (en) * | 2020-08-26 | 2020-11-27 | 成都新柯力化工科技有限公司 | Polyurethane root-resistant waterproof coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408822A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Polyurethane resin waterproof coating |
| CN103992731A (en) * | 2014-05-19 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | Expansive type polyurethane fire retardant coating |
| CN104073137A (en) * | 2013-03-28 | 2014-10-01 | 扬州豪扬新型建筑材料有限公司 | Aqueous polyurethane waterproof paint |
-
2014
- 2014-10-29 CN CN201410590476.5A patent/CN104277695A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102408822A (en) * | 2010-09-21 | 2012-04-11 | 苏州美亚美建筑涂料有限公司 | Polyurethane resin waterproof coating |
| CN104073137A (en) * | 2013-03-28 | 2014-10-01 | 扬州豪扬新型建筑材料有限公司 | Aqueous polyurethane waterproof paint |
| CN103992731A (en) * | 2014-05-19 | 2014-08-20 | 安徽嘉木橡塑工业有限公司 | Expansive type polyurethane fire retardant coating |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111849322A (en) * | 2020-07-29 | 2020-10-30 | 深圳市奇信集团股份有限公司 | Toilet waterproof coating and construction method |
| CN111995946A (en) * | 2020-08-26 | 2020-11-27 | 成都新柯力化工科技有限公司 | Polyurethane root-resistant waterproof coating and preparation method thereof |
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Application publication date: 20150114 |
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