CN106431169A - Alkali-activated fly ash dry mixed adhesive for ceramic tiles and preparation method thereof - Google Patents
Alkali-activated fly ash dry mixed adhesive for ceramic tiles and preparation method thereof Download PDFInfo
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- CN106431169A CN106431169A CN201610662717.1A CN201610662717A CN106431169A CN 106431169 A CN106431169 A CN 106431169A CN 201610662717 A CN201610662717 A CN 201610662717A CN 106431169 A CN106431169 A CN 106431169A
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- tile adhesive
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/24—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing alkyl, ammonium or metal silicates; containing silica sols
- C04B28/26—Silicates of the alkali metals
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00637—Uses not provided for elsewhere in C04B2111/00 as glue or binder for uniting building or structural materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses an alkali-activated fly ash dry mixed adhesive for ceramic tiles and a preparation method thereof. The adhesive comprises the following components in parts by weight: 30-50 parts of fly ash, 0-10 parts of cement, 5-10 parts of slag, 50-70 parts of aggregates, 1.2-1.5 parts of redispersible latex powder, 0.03-0.06 part of water-retaining agent, 0.03-0.05 part of wood fibers, 8-15 parts of sodium silicate, 2-3 parts of sodium hydroxide and 0.6-1.0 part of plasticizer. The dry mixed adhesive for ceramic tiles, which is provided by the invention, has the beneficial effects that the problems of hollowing and falling of the ceramic tiles caused by deformation caused due to shrinkage of base materials and other factors can be solved by comprehensively applying the alkali activation principle and the polymer reinforcing and toughening mechanisms; the adhesive has high early strength, thus avoiding the phenomenon of ceramic tile slippage; the adhesive can utilize the fly ash resource in quantity, so utilization of the non-renewable resources, such as cement, is reduced and the adhesive has the advantages of energy saving and environmental protection.
Description
Technical field
The invention belongs to building material technical field, it is related to a kind of alkali-activated carbonatite flyash and ceramic tile adhesive and its preparation are dry mixed
Method.
Background technology
With the raising of people's living standard, ceramic tile usage amount gets more and more, and unit area is increasing.Although using poly-
Polymer modified ceramic tile adhesive and thin layer construction technique can increase substantially the efficiency of construction pasting engineering, improve ceramic tile
Adhesive strength, reduces the hollowing of tile paste and the risk that comes off, and improves the security of tile paste engineering.But recent years,
Media frequently report coming off due to ceramic tile, cause casualties and vehicle malicious event, find ceramic tile still occur in that hollowing with
Come off.Trace it to its cause and mainly have:(1) base course wall is dry-shrinkage deformed.The drying shrinkage of basic unit just can will complete in 1~3 year, and ceramic tile
Bonding be operated in major project after the completion of begin to carry out, this just be ceramic tile peeling provide possibility;(2) extraneous factor
As building settlement and creep.The displacement of fabric structure leads to the deformation of adhesive, cracking;(3) cataclysm of temperature is deformed.
The ceramic tile of exterior wall be exposed to sweltering heat sunlight under, surface temperature can exceed 50 DEG C, if now run into raining in torrents, temperature drastically under
Fall, the cataclysm of this temperature will produce larger shear stress in adhesive, leads to the destruction of ceramic tile and body of wall bonding;(4) many
Aqueous vapor in the ceramic tile of hole expands and produces shear stress;(5) when using ceramic tile, due to not having or almost there is no micropore, hollow and sky
Gap can anchor adhesive, ceramic tile surface smoother, and between adhesive and ceramic tile, mechanical anchoring force is very little, leads to other former
Bonding force is caused to destroy because producing very little profit.
As can be seen here, because ordinary cement is fragile material it is difficult to adapt to the change that the contraction of base material and other factorses cause
The requirement of shape, must pull against this weakness as ceramic tile adhesive.Alkali-activated carbonatite Binder Materials is a kind of new of new development in recent years
Type inorganic nonmetal gelled materials, the performance such as its pressure-proof and snap-resistent intensity, antiacid alkali erosiveness, freeze-thaw resistance, anti-carbonation is all excellent
In the performance of Portland cement, also quite excellent with the adaptability of base material body of wall and durability.In addition, alkali-activated carbonatite gelling material
Material preparation process is simple, need not fire, energy consumption is low, low cost, market are wide, is a kind of 21 century the most potential gelling material
Material.Prepare alkali-activated carbonatite flyash ceramic tile adhesive using flyash for primary raw material, ceramic tile hollowing and the wind coming off can be reduced
Danger, can also save the non-renewable resources such as cement simultaneously, meet the requirement of energy-saving and environmental protection.
The Han Chaohui of Beijing Dongfang Yuhong Waterproof Technology Co., Ltd discloses a kind of high-strength ceramic tile tackiness agent.This height
Strong type ceramic tile adhesive includes Portland cement, filler, cellulose ether, adhesive, lignin fibre, thixotropic agent, diminishing
Agent, in adhesive, each component weight percentage ranges are respectively:Portland cement 40.00%~50.00%;Filler
45.00%~55.00%;Cellulose ether 0.30%~0.60%;Adhesive 3.00%~8.00%;Lignin fibre 0.05%
~0.50%;Thixotropic agent 0.10%~0.30%;Water reducer 0.05%~0.20%.This ceramic tile adhesive adopts normal silicate
Cement, volume up to 40%~50%, the saving use for this kind of non-renewable resources of cement is then unfavorable, in adhesive strength
Rise relatively slow, the phenomenons such as ceramic tile sliding easily occur, the problem of accumulation of salt in the surface soil intensity decline easily in the later stage.
Zhang Jingfu of Meichao Group Stock Co., Ltd etc. discloses a kind of ceramic tile adhesive, including the component of following weight portion:
20~60 parts of portland cements;50~70 parts of quartz sands;1.5~5.5 parts of redispersable latex powders;0.2~0.4 part of cellulose
Ether;0.01~0.16 part of alcohol compound.In the invention, in alcohol compound, hydroxyl can form hydrogen bond with hydrone, rises
To water retention, and the workability of ceramic tile adhesive will not be reduced.Described alcohol compound is interacted with cellulose ether,
By the regulation of both ratios, so that ceramic tile adhesive dries in the air, the time processed is long, and the open hour are sufficient, thus being applied to stickup water absorption rate
Low quarry-tile or very thin ceramic tile, ceramic tile adhesive is firmly bonded, not hollowing, not sliding.But this ceramic tile adhesive adopts silicic acid
Salt cement, its volume is still up to 40%, is unfavorable for saving the renewable resources such as cement.Additionally use the water conservation of alcohol compound
Agent is although fine Water-saving effect can be reached, but this type organic can work the mischief to human body, can cause breathing system after suction
Eyes are had stimulation by the infringement of system.This formula no improves the composition of adhesive workability it is most likely that leading to slurry thicker
And cannot construct, add water and excessively cause intensity to drastically reduce.
Content of the invention
For above-mentioned technical problem, the invention provides a kind of alkali-activated carbonatite flyash is dry mixed ceramic tile adhesive and its preparation side
Method, can the pliability of high ceramic tile adhesive, adhesive strength and open hour, and improve doping quantity of fly ash, reducing cement etc. can not
The use of regenerated resources, reaches the requirement of energy-conserving and environment-protective.
For achieving the above object, technical scheme provided by the present invention is:
A kind of alkali-activated carbonatite flyash is dry mixed ceramic tile adhesive, counts by weight, including following components:
30~50 parts of flyash, 0~10 part of cement, 5~10 parts of slag, 50~70 parts of aggregate, redispersable latex powder 1.2
~1.5 parts, 0.03~0.06 part of water-loss reducer, 0.03~0.05 part of wood fibre, 8~15 parts of sodium metasilicate, 2~3 parts of NaOH,
0.6~1.0 part of plasticiser.
Preferably, described alkali-activated carbonatite flyash is dry mixed ceramic tile adhesive, counts by weight, including following components:
30 parts of flyash, 10 parts of cement, 5 parts of slag, 50 parts of aggregate, 1.2 parts of redispersable latex powder, water-loss reducer 0.03
Part, 0.03 part of wood fibre, 8 parts of sodium metasilicate, 2 parts of NaOH, 0.6 part of plasticiser.
Wherein, described flyash particle diameter is below 75 μm, SiO2、Al2O3、Fe2O3Three is total to account for more than 72%, calcium content
Less than 10%, its loss on ignition is less than 10%;
Wherein, described cement be Portland cement or white portland cement, ordinary portland cement strength grade be 42.5,
42.5R, 52.5 or 52.5R grade, white cement strength grade is 32.5,42.5 or 52.5 grades;
Wherein, described slag is residue after ore dressing or smelting for the iron ore;
Wherein, described aggregate is that 40~140 mesh dry river sands, at least one in 40~140 mesh quartz sands;
Wherein, described redispersable latex powder is vinylacetate and ethylene copolymer rubber powder (VAC/E), ethene and vinyl chloride
And vinyl laurate ternary polymerization rubber powder (E/VC/VL), vinylacetate and ethene and higher aliphatic vinyl acetate ternary are altogether
Poly- rubber powder (VACEVeoVa), vinylacetate and high-grade aliphatic ester (VACVeoVa), acrylate and styrene copolymerized rubber powder
(A/S), vinylacetate and acrylate and higher aliphatic vinyl acetate ternary polymerization rubber powder (VAC/AVeoVa), vinyl acetate
Ester homopolymerization rubber powder (PVAC), styrene and diene copolymerization rubber powder (SBR), other one of binary and ternary polymerization rubber powder;
Wherein, described water-loss reducer is one of cellulose ether and starch ether, and wherein cellulose ether is that hydroxypropyl methyl is fine
The plain ether of dimension or ethoxyl methyl cellulose ether, viscosity is between 40000mPa.s~70000mPa.s;
Wherein, described wood fibre is milky, and length is 200~500 μm;
Wherein, described sodium metasilicate and NaOH are commercially available technical grade product;
Wherein, described plasticiser is powder shaped cationic polycarboxylate water-reducer.
The preparation method of above-mentioned flyash base polymers grouting material, comprises the following steps:
By each component according to stoichiometry after, in dry mixing device mixing 3~5min obtain final product ceramic tile adhesive.During use,
The clear water mix and blend 2~3min of the 23~26% of addition ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed
Agent, you can construction.
By above technical scheme, beneficial effects of the present invention are as follows:
What the present invention provided is dry mixed ceramic tile adhesive, by the synthesis to alkali-activated carbonatite principle and enhancing by polymer toughening mechanism
With relying on alkali-activated carbonatite flyash and slag to provide primary intensity source, cement helps out, and can solve due to base material
Shrink and the deformation that causes of other factorses and cause ceramic tile hollowing, come off problem, early strength is high, no ceramic tile sliding phenomenon,
And fly ash can be utilized in a large number, reduce the utilization to non-renewable resources such as cement, there is the advantage of energy-conserving and environment-protective.
Specific embodiment
Following examples are used for the present invention is described, but are not limited to the scope of the present invention.Without departing substantially from present invention spirit
In the case of essence, the modification that the inventive method, step or condition are made or replacement, belong to the scope of the present invention.
Used in following examples, flyash particle diameter is below 75 μm, SiO2、Al2O3、Fe2O3Three add up to account for 72% with
On, calcium content is less than 10%, and its loss on ignition is less than 10%;
Embodiment 1
Prepare raw material by following components and weight:Flyash 30kg, strength grade is 42.5 Portland cement
10kg, residue 5kg after smelting for the iron ore, the drying river sand 50kg of 40 mesh, vinylacetate and ethene and higher aliphatic
Vinyl acetate ternary polymerization rubber powder 1.2kg, cellulose ether is hydroxypropyl methyl cellulose ether 0.03kg, and length is 300 μm of wood
Matter fiber 0.03kg, sodium metasilicate 8kg, NaOH 2kg, powder shaped cationic polycarboxylate water-reducer 0.6kg.
Prepare alkali-activated carbonatite flyash according to the following steps and ceramic tile adhesive is dry mixed:
By each component according to stoichiometry after, in dry mixing device mixing 4min obtain final product ceramic tile adhesive.During use, add
The clear water mix and blend 2.5min of the 25% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed, you can apply
Work.
The performance test results of this ceramic tile adhesive are as follows:
Embodiment 2
Prepare raw material by following components and weight:Flyash 40kg, strength grade is 52.5 Portland cement
5kg, residue 5kg after smelting for the iron ore, 100 mesh dry river sand 50kg, vinylacetate and acrylate and senior fat
Fat vinyl acetate ternary polymerization rubber powder 1.2kg, ethoxyl methyl cellulose ether 0.03kg, length is 200 μm of wood fibre
0.03kg, sodium metasilicate 8kg, NaOH 2kg, powder shaped cationic polycarboxylate water-reducer 0.6kg.
Prepare alkali-activated carbonatite flyash according to the following steps and ceramic tile adhesive is dry mixed:
By each component according to stoichiometry after, in dry mixing device mixing 3min obtain final product ceramic tile adhesive.During use, add
The clear water mix and blend 2min of the 23% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed, you can apply
Work.
The performance test results of this ceramic tile adhesive are as follows:
Embodiment 3
Prepare raw material by following components and weight:Flyash 50kg, strength grade is 32.5 white cement 10kg, iron ore
Residue 7kg after ore dressing, 140 mesh dry river sand 60kg, vinylacetate and ethylene copolymer rubber powder 1.3kg, starch ether
0.03kg, length is 500 μm of wood fibre 0.03kg, sodium metasilicate 8kg, NaOH 2kg, powder shaped cationic polycarboxylic acids
Water reducer 0.6kg.
Prepare alkali-activated carbonatite flyash according to the following steps and ceramic tile adhesive is dry mixed:
By each component according to stoichiometry after, in dry mixing device mixing 5min obtain final product ceramic tile adhesive.During use, add
The clear water mix and blend 3min of the 26% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed, you can apply
Work.
The performance test results of this ceramic tile adhesive are as follows:
Embodiment 4
Prepare raw material by following components and weight:Flyash 50kg, strength grade is 42.5 white cement 10kg, iron ore
Residue 10kg after ore dressing, 40 mesh quartz sand 70kg, acrylate and styrene copolymerized rubber powder 1.3kg, starch ether
0.05kg, length is 400 μm of wood fibre 0.04kg, sodium metasilicate 10kg, NaOH 3kg, powder shaped cationic poly carboxylic
Sour water reducer 0.8kg.
Prepare alkali-activated carbonatite flyash according to the following steps and ceramic tile adhesive is dry mixed:
By each component according to stoichiometry after, in dry mixing device mixing 4min obtain final product ceramic tile adhesive.During use, add
The clear water mix and blend 2.5min of the 25% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed, you can apply
Work.
The performance test results of this ceramic tile adhesive are as follows:
Embodiment 5
Prepare raw material by following components and weight:Flyash 50kg, residue 10kg after ore dressing for the iron ore, 140 mesh
Quartz sand 70kg, vinylacetate and acrylate and higher aliphatic vinyl acetate ternary polymerization rubber powder 1.5kg, hydroxypropyl methyl
Cellulose ether 0.06kg, length is 500 μm of wood fibre 0.05kg, sodium metasilicate 15kg, NaOH 2.5kg, powder shaped sun
Ionic polycarboxylate water-reducer 1.0kg.
Prepare alkali-activated carbonatite flyash according to the following steps and ceramic tile adhesive is dry mixed:
By each component according to stoichiometry after, in dry mixing device mixing 4min obtain final product ceramic tile adhesive.During use, add
The clear water mix and blend 2.5min of the 25% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed, you can apply
Work.
The performance test results of this ceramic tile adhesive are as follows:
Claims (8)
1. a kind of alkali-activated carbonatite flyash is dry mixed ceramic tile adhesive it is characterised in that counting by weight, including following components:
30~50 parts of flyash, 0~10 part of cement, 5~10 parts of slag, 50~70 parts of aggregate, redispersable latex powder 1.2~
1.5 parts, 0.03~0.06 part of water-loss reducer, 0.03~0.05 part of wood fibre, 8~15 parts of sodium metasilicate, 2~3 parts of NaOH, mould
0.6~1.0 part of agent.
2. ceramic tile adhesive is dry mixed it is characterised in that counting by weight according to the alkali-activated carbonatite flyash described in claim 1,
Including following components:
30 parts of flyash, 10 parts of cement, 5 parts of slag, 50 parts of aggregate, 1.2 parts of redispersable latex powder, 0.03 part of water-loss reducer, wood
0.03 part of matter fiber, 8 parts of sodium metasilicate, 2 parts of NaOH, 0.6 part of plasticiser.
3. ceramic tile adhesive is dry mixed according to the alkali-activated carbonatite flyash described in claim 1 it is characterised in that:Described flyash particle diameter
Below 75 μm, SiO2、Al2O3、Fe2O3Three is total to account for more than 72%, and calcium content is less than 10%, and its loss on ignition is less than
10%.
4. ceramic tile adhesive is dry mixed according to the alkali-activated carbonatite flyash described in claim 1 it is characterised in that:Described cement is common
Portland cement or white portland cement, ordinary portland cement strength grade is 42.5,42.5R, 52.5 or 52.5R grade, plain boiled water
Mud strength grade is 32.5,42.5 or 52.5 grades.
5. ceramic tile adhesive is dry mixed according to the alkali-activated carbonatite flyash described in claim 1 it is characterised in that:Described slag is iron ore
Residue after ore dressing or smelting for the stone;Described aggregate be 40~140 mesh dry river sands, in 40~140 mesh quartz sands at least
A kind of.
6. ceramic tile adhesive is dry mixed according to the alkali-activated carbonatite flyash described in claim 1 it is characterised in that:Wherein, described can be again
Dispersed latex powder is that vinylacetate is common with ethylene copolymer rubber powder (VAC/E), ethene and vinyl chloride and vinyl laurate ternary
Poly- rubber powder (E/VC/VL), vinylacetate and ethene and higher aliphatic vinyl acetate ternary polymerization rubber powder (VACEVeoVa), vinegar
Vinyl acetate and high-grade aliphatic ester (VACVeoVa), acrylate and styrene copolymerized rubber powder (A/S), vinylacetate and third
Olefin(e) acid ester and higher aliphatic vinyl acetate ternary polymerization rubber powder (VAC/AVeoVa), vinylacetate homopolymerization rubber powder (PVAC), benzene
Ethene and diene copolymerization rubber powder (SBR), other one of binary and ternary polymerization rubber powder;Described water-loss reducer be cellulose ether and
One of starch ether, wherein cellulose ether are hydroxypropyl methyl cellulose ether or ethoxyl methyl cellulose ether, and viscosity exists
40000mPa.s between~70000mPa.s.
7. ceramic tile adhesive is dry mixed according to the alkali-activated carbonatite flyash described in claim 1 it is characterised in that:Described wood fibre is
Milky, length is 200~500 μm;Described sodium metasilicate and NaOH are commercially available technical grade product;Described plasticiser is powder
Body shape cationic polycarboxylate water-reducer.
8. the alkali-activated carbonatite flyash described in claim 1 is dry mixed the preparation method of ceramic tile adhesive, comprises the following steps:
By each component according to stoichiometry after, in dry mixing device mixing 3~5min obtain final product ceramic tile adhesive;During use, add
The clear water mix and blend 2~3min of the 23~26% of ceramic tile adhesive quality obtains final product alkali-activated carbonatite flyash and ceramic tile adhesive is dry mixed,
Can construct.
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CN110372312A (en) * | 2019-07-18 | 2019-10-25 | 深圳工建科技有限公司 | A kind of water-proof back adhesive for stone and preparation method thereof |
CN110922082A (en) * | 2019-11-22 | 2020-03-27 | 东方雨虹民用建材有限责任公司 | Weather-resistant nano modified material of ceramic tile adhesive and application thereof |
CN112939530A (en) * | 2020-12-04 | 2021-06-11 | 绍兴精工绿筑集成建筑系统工业有限公司 | White high-performance cement-based material special for external wall tile reverse-hitting process |
CN115572113A (en) * | 2022-10-24 | 2023-01-06 | 崇左南方水泥有限公司 | Geopolymer tile back adhesive and preparation method and application thereof |
CN116082007A (en) * | 2022-12-07 | 2023-05-09 | 佛山市科顺建筑材料有限公司 | Two-component adhesive composition and article |
CN117510137A (en) * | 2023-10-31 | 2024-02-06 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
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CN112939530A (en) * | 2020-12-04 | 2021-06-11 | 绍兴精工绿筑集成建筑系统工业有限公司 | White high-performance cement-based material special for external wall tile reverse-hitting process |
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CN117510137A (en) * | 2023-10-31 | 2024-02-06 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
CN117510137B (en) * | 2023-10-31 | 2024-05-07 | 广东合睿智造新材料有限公司 | Adhesive for pasting large-size rock plate for alkali excitation system |
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Application publication date: 20170222 |