CN1955241A - Calcium sulfate whisker modified ceramic tile adhesive - Google Patents
Calcium sulfate whisker modified ceramic tile adhesive Download PDFInfo
- Publication number
- CN1955241A CN1955241A CN 200510047435 CN200510047435A CN1955241A CN 1955241 A CN1955241 A CN 1955241A CN 200510047435 CN200510047435 CN 200510047435 CN 200510047435 A CN200510047435 A CN 200510047435A CN 1955241 A CN1955241 A CN 1955241A
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- CN
- China
- Prior art keywords
- calcium sulfate
- water
- ceramic tile
- tile adhesive
- sulfate whisker
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Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention is a chemical building materials and technology, involving a calcium sulfate whisker modified tile adhesive, include the following components (weight percentage) : white cement 35%~65%; quartz sand 20%-30%, filling materials 10%~35%; latex powder 2.0%~3.0%; aquasorb 0.1%~0.4%; lignocellulose 0.5%~1.0%; high alumina cement 0.5%-0.8%,crystal whiskers 0.3%~0.5%,water reducer 0.2%~1.0%, coloring agent fraction 0-0.6%. The invention of waterproof and heat proof, frost resistance, impermeability and can be used for outdoor cold, damp places engineering operations.
Description
Technical field
The invention belongs to the chemical building material technical field, particularly a kind of calcium sulfate whisker modified ceramic tile adhesive.
Background technology
Decorative craft of building development at present is very fast, it is good to press for a kind of performance, easy construction, the ceramic tile of reasonable price, decorating and renovating materials such as marble binding agent, and existing this class binding agent uses inconvenience, cohesive strength is low, and especially the waterproof weathering resistance is very poor, comes off easily, be used in particular for exterior wall, effect is poorer.Still the ceramic tile, the marble binding agent that do not have at present a kind of easy construction and excellent property.
Summary of the invention
The object of the present invention is to provide a kind of waterproof heat resistant, freeze proof, anti-permeability performance good, can be used for outdoor cold, the calcium sulfate whisker modified ceramic tile adhesive on humid area and the place engineering.
Technical solution of the present invention can realize according to following mode:
Calcium sulfate whisker modified ceramic tile adhesive, it comprises following component (weight percentage):
White cement 35%～65%
Quartz sand 20%～30%
Filler 10%～35%
Latex powder 2.0%～3.0%
Water-holding agent 0.1%～0.4%
Lignocellulose 0.5%～1.0%
High-alumina cement 0.5%～0.8%
Whisker 0.3%～0.5%
Water reducer 0.2%～1.0%
Tinting material 0～0.6%
Its optimum formula scope is:
White cement 45%～65%
Quartz sand 20%～25%
Filler 10%～25%
Latex powder 2.5%～3.0%
Water-holding agent 0.1%～0.3%
Lignocellulose 0.7%～1.0%
High-alumina cement 0.65%～0.8%
Whisker 0.4%～0.5%
Water reducer 0.5%～1.0%
Tinting material 0.3～0.6%
Wherein, the white cement label is 52.5, whiteness 〉=80 °; Filler is a water-ground limestone;
Quartz sand and filler fineness are all greater than 200 orders;
Water-holding agent: methylhydroxypropylcellulose;
The high-alumina cement label is 42.5;
Described water reducer is Melment F10;
Tinting material can select for use pigment dyestuff and mineral dye collocation to use.
During preparation,, take by weighing the adding whisker, mix and get final product in above ratio with cement, inert filler, finished product is a powdery, and single-component adds water by water cement ratio 0.25 during use and is stirred to required denseness, be coated in scraper on the basis of desire stickup, stick ceramic tile or marble then, compacting gets final product.
No. 525 cement of employed white cement in the composition, inert filler is with 200 purpose quartz sands, used whisker is as softening agent, guarantee that moisture content is difficult for being absorbed by base mateiral in the binding agent, water can be converted into the active mineral in the cement complexing hydrate, makes the abundant aquation of cement, brings into play its inherent cohesive action to greatest extent, improve cohesive strength, and make binding agent have certain plasticity-.Add Mierocrystalline cellulose and improved workability, particularly blocked original kapillary, make moisture content be difficult for being penetrated into binding agent inside, reduced that because climate change causes expanding with heat and contract with cold of planar water or freezes ceramic tile is come off.In general, these additives can both play the binding agent effect, increase cohesive strength.
The present invention adds various additives based on white cement, and wherein whisker has the fixed cross-sectional area, complete profile, and perfect internal structure, length-to-diameter ratio is up to 5～1000 fibrous single crystal.Because its diameter is little, atomic arrangement high-sequential when crystallization has changed the space that conventional material has and the defective of dislocation.Therefore, calcium sulfate crystal whiskers has unique premium properties.The weighting agent that can be used as medium tenacity, the reinforcing effect of the reinforcing effect of small diameter fiber and other high-performance fiber strongthener is approaching.With its enhanced plastics, tensile strength, flexural strength, crooked elastic rate and heat-drawn wire are improved.Being used of various additives makes it play bonding, water conservation, heat resistanceheat resistant, cold-resistant, effects such as bleed make fully aquation of cement, and form even bubble, block original kapillary, reduce infiltration, improve waterproof, cold-resistant, resistance toheat, can be used for outdoor cold, on the engineering in humid area and place, prolongedly do not come off.
With the ceramic tile marble binding agent that above proportioning is produced, every performance index particularly waterproof heat resistant, anti-freezing property are far superior to domestic and international regulation (advanced person) standard, also are better than the domestic like product performance of being grasped at present.When the bonding ceramic tile, not only can do operation, basic unit needn't sprinkle water and soak, and face brick needn't soak and dry in the shade, and has good water-retentivity.New design finalization, single component is pressed manufacturing technique requirent by factory, the proportioning of strict control effective constituent.Can not tell white by the accumulation of salt in the surface soil.4～5 hours initial condensation time, at this moment operator have ample time and carry out large-area levelling adjustment.About 6 hours of final setting time is compared with other rigid materials and have been accelerated speed of application, has shortened the whole duration.The process of bonding applique surface brick is exactly the operation process of waterproof layer because this invention anti-permeability performance is good, at the position that needs are done facing tile, go to toilet bathe between, wall face etc., can not do waterproof layer in addition, promptly finished the operation of waterproof layer with this tackiness agent taping process.Add different tinting materials and can make the powder of different colours, and be applicable to do colored rigid roofing and colour ground concrete, ornamentally whitewash, navigation mark, the building in the seawater and other colored, water-repellent decorative engineerings in Haihe River.
Embodiment
Processing step of the present invention is described by the following examples, but not limited by embodiment.
Embodiment 1: present embodiment is an example to prepare 1000 kilograms of Dry Powder Shaped Tile Adhesives:
(label is 52.5 to get 350 kilograms of white cements, whiteness 〉=80 °), add in the specific stirring tank, add 255 kilograms of quartz sands (〉=200 order), 340 kilograms of fillers (〉=200 order), 30 kilograms of latex powder, 2 kilograms of water-holding agents, 5 kilograms of lignocelluloses, 6 kilograms of high-alumina cements (label is 42.5), 4 kilograms of whiskers, 4 kilograms of water reducers, 4 kilograms of tinting materials again, in stirring tank, stir half an hour, after making uniform mixing, can obtain Dry Powder Shaped Tile Adhesive.
Detected result is as follows through Liaoning Province material of construction supervision and inspection institute:
| Sequence number | Interventions Requested | Measure unit | Assay |
| 1 | Outward appearance | * | Even matter, dry powder, nothing caking |
| 2 | Ultimate compression strength (3d) | MPa | 10.0 |
| 3 | Impervious (thick coating 3mm, 7d) | MPa | 0.8 |
| 4 | Time of coagulation | Presetting period | Min | 353 |
| Final setting time | Min | 605 | ||
| 5 | Cohesive strength (7d) | MPa | 1.4 | |
| 6 | Folding strength (7d) | MPa | 4.2 | |
| 7 | Water tolerance | ％ | 80 | |
| 8 | Alkali resistance (10%NaOH solution soaking 48h) | * | There is not phenomenons such as ftractureing, flake, peel off | |
Embodiment 2: chemical ingredients such as the white cement that present embodiment utilizes and index are same as the previously described embodiments, to produce 1000 kilograms of Dry Powder Shaped Tile Adhesives is example: get 590 kilograms of white cement (model WP, label is 52.5, whiteness 〉=80 °), add in the specific stirring tank, add 180 kilograms of quartz sands (〉=200 order) again, 180 kilograms of fillers (〉=200 order), 30 kilograms of latex powder, 1 kilogram of water-holding agent, 4 kilograms of lignocelluloses, 6 kilograms of high-alumina cements (label is 42.5), 5 kilograms of whiskers, 2 kilograms of water reducers, 2 kilograms of tinting materials, in stirring tank, stir half an hour, after making uniform mixing, promptly obtain Dry Powder Shaped Tile Adhesive.
Detected result is as follows through Liaoning Province material of construction supervision and inspection institute:
| Sequence number | Interventions Requested | Measure unit | Assay | |
| 1 | Outward appearance | * | Even matter, dry powder, nothing caking | |
| 2 | Ultimate compression strength (3d) | MPa | 18.5 | |
| 3 | Impervious (thick coating 3mm, 7d) | MPa | 1.2 | |
| 4 | Time of coagulation | Presetting period | Min | 282 |
| Final setting time | Min | 355 | ||
| 5 | Cohesive strength (7d) | MPa | 2.0 | |
| 6 | Folding strength (7d) | MPa | 6.1 | |
| 7 | Water tolerance | ％ | 95 | |
| 8 | Alkali resistance (10%NaOH solution soaking 48h) | * | There is not phenomenons such as ftractureing, flake, peel off | |
By above two examples as can be seen, according to different construction requirements at white cement 35%～60%, quartz sand 20%～30%, filler 18%～35%, water-holding agent 0.1%～0.4%, whisker 0.4%～0.5%, water reducer 0.2%～1.0%, the addition of tinting material 0～0.6% (more than be mass percent) is mediated, and can obtain the colored Dry Powder Shaped Tile Adhesive of different mechanical properties.
Claims (5)
1, calcium sulfate whisker modified ceramic tile adhesive is characterized in that, comprises following component (weight percentage):
White cement 35%～65%
Quartz sand 20%～30%
Filler 10%～35%
Latex powder 2.0%～3.0%
Water-holding agent 0.1%～0.4%
Lignocellulose 0.5%～1.0%
High-alumina cement 0.5%～0.8%
Whisker 0.3%～0.5%
Water reducer 0.2%～1.0%
Tinting material 0～0.6%.
2, calcium sulfate whisker modified ceramic tile adhesive according to claim 1 is characterized in that: the weight percentage of described component is:
White cement 45%～65%
Quartz sand 20%～25%
Filler 10%～25%
Latex powder 2.5%～3.0%
Water-holding agent 0.1%～0.3%
Lignocellulose 0.7%～1.0%
High-alumina cement 0.65%～0.8%
Whisker 0.4%～0.5%
Water reducer 0.5%～1.0%
Tinting material 0.3～0.6%.
3, calcium sulfate whisker modified ceramic tile adhesive according to claim 1 and 2 is characterized in that: described white cement label is 52.5, whiteness 〉=80 °; Described filler is a water-ground limestone, the fineness of quartz sand and filler all 〉=200 orders.
4, calcium sulfate whisker modified ceramic tile adhesive according to claim 1 and 2 is characterized in that: described water-holding agent is a methylhydroxypropylcellulose; Described water reducer is Melment F10; Described high-alumina cement label is 42.5; Tinting material can select for use pigment dyestuff and mineral dye collocation to use.
5, calcium sulfate whisker modified ceramic tile adhesive according to claim 3 is characterized in that: described water-holding agent is a methylhydroxypropylcellulose; Described high-alumina cement label is 42.5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510047435 CN100554356C (en) | 2005-10-19 | 2005-10-19 | Calcium sulfate whisker modified ceramic tile adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200510047435 CN100554356C (en) | 2005-10-19 | 2005-10-19 | Calcium sulfate whisker modified ceramic tile adhesive |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1955241A true CN1955241A (en) | 2007-05-02 |
| CN100554356C CN100554356C (en) | 2009-10-28 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200510047435 Expired - Fee Related CN100554356C (en) | 2005-10-19 | 2005-10-19 | Calcium sulfate whisker modified ceramic tile adhesive |
Country Status (1)
| Country | Link |
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| CN (1) | CN100554356C (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153323A (en) * | 2010-12-30 | 2011-08-17 | 李角 | Adhesive for porcelain walls and floor tiles |
| CN102173688A (en) * | 2011-02-28 | 2011-09-07 | 李德川 | Water-proof mucilage glue for ceramic product |
| CN102229486A (en) * | 2011-04-20 | 2011-11-02 | 厦门力嘉诚防水工程有限公司 | Marble glue |
| CN103467054A (en) * | 2013-09-12 | 2013-12-25 | 德高（广州）建材有限公司 | Early-strength type mosaic binding agent |
| CN105086874A (en) * | 2015-08-09 | 2015-11-25 | 严雪琦 | Concentrated ceramic tile adhesive |
| CN106431169A (en) * | 2016-08-12 | 2017-02-22 | 卓达新材料科技集团威海股份有限公司 | Alkali-activated fly ash dry mixed adhesive for ceramic tiles and preparation method thereof |
| CN108264270A (en) * | 2016-12-30 | 2018-07-10 | 上海华仕科技工程有限公司 | A kind of Floor tile made of steel plate paving environment-friendly type slurry |
| CN109369120A (en) * | 2018-11-14 | 2019-02-22 | 江苏贝尔诺新能源科技有限公司 | A kind of construction tile bonding agent rubber powder preparation method |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000096274A (en) * | 1998-09-25 | 2000-04-04 | Yoshiyuki Ogushi | Method for modifying iron surface |
-
2005
- 2005-10-19 CN CN 200510047435 patent/CN100554356C/en not_active Expired - Fee Related
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102153323A (en) * | 2010-12-30 | 2011-08-17 | 李角 | Adhesive for porcelain walls and floor tiles |
| CN102173688A (en) * | 2011-02-28 | 2011-09-07 | 李德川 | Water-proof mucilage glue for ceramic product |
| CN102229486A (en) * | 2011-04-20 | 2011-11-02 | 厦门力嘉诚防水工程有限公司 | Marble glue |
| CN103467054A (en) * | 2013-09-12 | 2013-12-25 | 德高（广州）建材有限公司 | Early-strength type mosaic binding agent |
| CN105086874A (en) * | 2015-08-09 | 2015-11-25 | 严雪琦 | Concentrated ceramic tile adhesive |
| CN106431169A (en) * | 2016-08-12 | 2017-02-22 | 卓达新材料科技集团威海股份有限公司 | Alkali-activated fly ash dry mixed adhesive for ceramic tiles and preparation method thereof |
| CN108264270A (en) * | 2016-12-30 | 2018-07-10 | 上海华仕科技工程有限公司 | A kind of Floor tile made of steel plate paving environment-friendly type slurry |
| CN108264270B (en) * | 2016-12-30 | 2021-02-05 | 上海华仕科技工程有限公司 | Environment-friendly slurry for paving metal floor tiles |
| CN109369120A (en) * | 2018-11-14 | 2019-02-22 | 江苏贝尔诺新能源科技有限公司 | A kind of construction tile bonding agent rubber powder preparation method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100554356C (en) | 2009-10-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: DAVCO (GUANGZHOU) BUILDING MATERIAL CO., LTD. Assignor: Liaoming Petrochemical Univ. Contract record no.: 2011440000155 Denomination of invention: Calcium sulfate whisker modified ceramic tile adhesive Granted publication date: 20091028 License type: Exclusive License Open date: 20070502 Record date: 20110311 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20091028 Termination date: 20181019 |