CN102965020A - Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting - Google Patents
Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting Download PDFInfo
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- CN102965020A CN102965020A CN2012105003492A CN201210500349A CN102965020A CN 102965020 A CN102965020 A CN 102965020A CN 2012105003492 A CN2012105003492 A CN 2012105003492A CN 201210500349 A CN201210500349 A CN 201210500349A CN 102965020 A CN102965020 A CN 102965020A
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- rubber
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- rubber asphalt
- latex
- emulsion
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- 239000010426 asphalt Substances 0.000 title claims abstract description 77
- 229920001971 elastomer Polymers 0.000 title claims abstract description 52
- 239000005060 rubber Substances 0.000 title claims abstract description 52
- 239000000463 material Substances 0.000 title claims abstract description 32
- 238000005507 spraying Methods 0.000 title claims abstract description 9
- 238000004078 waterproofing Methods 0.000 title abstract 5
- 239000000839 emulsion Substances 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229920000126 latex Polymers 0.000 claims abstract description 25
- 239000007788 liquid Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920000642 polymer Polymers 0.000 claims abstract description 3
- 239000007787 solid Substances 0.000 claims description 39
- 239000000843 powder Substances 0.000 claims description 30
- 239000012530 fluid Substances 0.000 claims description 17
- 238000002360 preparation method Methods 0.000 claims description 17
- 125000000129 anionic group Chemical group 0.000 claims description 14
- 239000003945 anionic surfactant Substances 0.000 claims description 14
- 239000002270 dispersing agent Substances 0.000 claims description 14
- 239000007921 spray Substances 0.000 claims description 14
- 239000011248 coating agent Substances 0.000 claims description 13
- 238000000576 coating method Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000011295 pitch Substances 0.000 claims description 11
- 229920006174 synthetic rubber latex Polymers 0.000 claims description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 10
- 239000000853 adhesive Substances 0.000 claims description 10
- 230000001070 adhesive effect Effects 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 10
- 239000001110 calcium chloride Substances 0.000 claims description 10
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 10
- 239000006229 carbon black Substances 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 229920006173 natural rubber latex Polymers 0.000 claims description 6
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 5
- 238000013019 agitation Methods 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000004816 latex Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 4
- 229910052573 porcelain Inorganic materials 0.000 claims description 4
- 239000011294 coal tar pitch Substances 0.000 claims description 3
- 238000000605 extraction Methods 0.000 claims description 3
- 239000011301 petroleum pitch Substances 0.000 claims description 3
- 239000011435 rock Substances 0.000 claims description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 2
- 229920000459 Nitrile rubber Polymers 0.000 claims description 2
- 229920013649 Paracril Polymers 0.000 claims description 2
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 claims description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 claims description 2
- 229920002857 polybutadiene Polymers 0.000 claims description 2
- 229920001195 polyisoprene Polymers 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000011271 tar pitch Substances 0.000 claims description 2
- 230000009466 transformation Effects 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract 2
- 230000032683 aging Effects 0.000 abstract 1
- 239000000701 coagulant Substances 0.000 abstract 1
- 231100000252 nontoxic Toxicity 0.000 abstract 1
- 230000003000 nontoxic effect Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 239000012874 anionic emulsifier Substances 0.000 description 4
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 230000005068 transpiration Effects 0.000 description 1
Abstract
The invention provides a root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting. According to the spraying rapid-hardening rubber asphalt water-proofing material, emulsified asphalt and high-molecular polymer rubber latex are prepared into liquid rubber asphalt emulsion component in the ratio by the latest technology, and a root resisting agent is added to the liquid rubber asphalt emulsion component, and then the liquid rubber asphalt emulsion component is mixed with a coagulating agent in the ratio so as to obtain a water-based spraying material. According to the root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting, a cold-constructing technology is adopted; a water-proofing film which is quickly formed after the spraying is high in breaking elongation (more than 1000%), high in bonding strength, outstanding in ageing resistance, ultraviolet ray resistance and low-temperature resistance, environment-friendly, nontoxic, and outstanding in root resistance, and can be widely applied to water prevention of various planted roofs.
Description
Technical field
The present invention relates to a kind of waterproof paint, especially a kind of plantation sprays the rapid hardening rubber asphalt waterproof coating with anti-.
Technical background
Along with the raising that the growth of Chinese national economy and people require living environment, architecture greening becomes the new problem of building trade.Building roof realizes that greening can more effectively stop the sunlight direct projection, and the transpiration by vegetation effectively reduces ambient, reduces the energy consumption alleviating urban heat island effect.And easily being pierced through the formation crack by plant roots and stems by the roofing that vegetation covers, traditional water-proof material does not possess the puncture performance and is easy to be penetrated the effect of discharging water that loses by root.Along with architecture greening universal conventional waterproof material at home can not meet the demands.
Summary of the invention
The present invention provides a kind of elongation height, cohesive strength plantation large, root-resistant puncturing to spray the rapid hardening rubber asphalt waterproof coating with anti-in order to remedy the deficiencies in the prior art.
The present invention is achieved through the following technical solutions:
A kind of plantation sprays the rapid hardening rubber asphalt waterproof coating with anti-, its feature exists: be the respectively water base spray material of preparation in proportion of 50～65% fluid rubber asphalt adhesive emulsion components, concentration 1～20% condensing agent component by solid content, the spraying volume ratio of condensing agent component and fluid rubber asphalt adhesive emulsion components is 1/15～1/3.5;
Described fluid rubber bitumen emulsion component formula rate by weight is: the bitumen emulsion 52～78% of solid content 55～65%, the rubber latex 18～43% of solid content 45～50%, root resistance agent 0.5～1%, carbon black 0～2%, fine powder material 0～2%, anionic dispersing agents 0.5～1%, anion surfactant 0.997～0.999%, stablizer 0.001～0.003%; Wherein said fine powder material is porcelain powder, dicalcium powder or light calcium carbonate powder;
Described condensing agent component formula rate by weight is: calcium chloride 95～99.6%, sodium-chlor 0.2～2%, compound ferro-aluminum polymkeric substance 0.2～3% or formula rate are: calcium chloride 92～99.9%, compound ferro-aluminum polymkeric substance 0.1～8%; In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 1～20%.
Described rubber latex is by the standby synthetic rubber latex of free-radical emulsion polymerization legal system or the commodity of directly buying; Described bitumen emulsion is bitumen emulsion or the direct commodity of buying that are mixed with pitch.
Described rubber latex is natural rubber latex or synthetic rubber latex, and synthetic rubber latex is 2～4 kinds of latex of making of styrene-butadiene rubber(SBR), cis-1,4-polybutadiene rubber, paracril, ethylene-propylene rubber(EPR), polyisoprene rubber, chloroprene rubber, neoprene, butadienestyrene copolymer rubber, butadiene acrylonitrile copolymer rubber, isobutene polymer rubber, isoprene copolymer rubber or polybutadiene rubber.
When described natural rubber latex and its solid content of synthetic rubber latex are lower than 45～50%, can pass through the extract at low temperature method, when temperature is controlled at 7～-4 ℃, when the extraction solid content reaches 45～50%, for subsequent use when being warmed up to 30～50 ℃ in the reactor of again latex being packed into.
The compound method of described bitumen emulsion is: add weight part and be 100 parts pitch and remain on 120 ℃ in equipment for production of emulsified bitumen; The concentration that adds weight part and be 100～122 parts is 0.5～1.5% the anionic emulsifier aqueous solution, and temperature is 40～80 ℃, carries out high speed shear and stirs that to make solid content be 55～65% bitumen emulsions.
Described pitch is petroleum pitch, coal tar pitch, rock asphalt, shale tar pitch or the transformation of the way pitch of 70-90#.
The preparation method of described fluid rubber asphalt adhesive emulsion components: when bitumen emulsion is down to 20～40 ℃, under agitation add liquid carbon black or carbon powder, fine powder material or liquid fine powder material, root resistance agent, anionic dispersing agents, anion surfactant, stablizer, then rubber latex is added slowly, stir, make the fluid rubber bitumen emulsion of solid content 50～65%.
When make the bitumen emulsion solid content greater than 60% or the rubber latex solid content greater than 47% the time, different according to working conditions, can in the rubber asphalt emulsion is synthetic, not add liquid carbon black or carbon powder, fine powder material or liquid fine powder material yet, stir as long as bitumen emulsion, rubber latex are added root resistance agent, anionic dispersing agents, anion surfactant and stablizer 20～40 ℃ of temperature ranges.
The invention has the beneficial effects as follows: plantation of the present invention is compared with normal waterproof material except the characteristics that elongation at break is high, cohesive strength is large, material compatibility is good with anti-spraying rapid hardening rubber asphalt waterproof coating, and its outstanding feature is exactly its good root-resistant puncturing.The present invention carries out the root-resistant puncturing experiment according to the test method of JC/T 1075-2008 " planted roof root resistant waterproof roll " to it, and experimental result shows that wheat root all do not scurry into three circular prints, and the illustrative material root resistance is functional.The present invention has the advantages such as film forming is rapid, operating efficiency is high, excellent low-temperature performance, root resistance performance be good, can be widely used in the waterproof that various needs carry out the building roof of greening vegetation.
Embodiment
Embodiment 1: the preparation of condensing agent component
Prescription: calcium chloride 99.6%, sodium-chlor 0.2%, compound ferro-aluminum polymkeric substance 0.2%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 20%.
Embodiment 2: the preparation of condensing agent component
Prescription: calcium chloride 95%, sodium-chlor 2%, compound ferro-aluminum polymkeric substance 3%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 1%.
Embodiment 3:The preparation of condensing agent component
Prescription: calcium chloride 97%, sodium-chlor 1%, compound ferro-aluminum polymkeric substance 2%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 10%.
Embodiment 4:The preparation of condensing agent component
Prescription: calcium chloride 99.9%, compound ferro-aluminum polymkeric substance 0.1%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 20%.
Embodiment 5: the preparation of condensing agent component
Prescription: calcium chloride 92%, compound ferro-aluminum polymkeric substance 8%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 10%.
Embodiment 6: the preparation of condensing agent component
Prescription: calcium chloride 96%, compound ferro-aluminum polymkeric substance 4%.In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 1%.
Embodiment 7: the processing of rubber latex
When natural rubber latex and its solid content of synthetic rubber latex are lower than 45～50%, can pass through the extract at low temperature method, when temperature is controlled at 7～-4 ℃, when the extraction solid content reaches 45～50%, for subsequent use when being warmed up to 30～50 ℃ in the reactor of again latex being packed into.
Embodiment 8:The preparation of bitumen emulsion
In equipment for production of emulsified bitumen, add weight part and be 100 parts 80# rock asphalt and remain on 120 ℃; Add weight part and be 122 parts the anionic emulsifier aqueous solution (carboxylic acid type metallic soap, concentration are 0.5%), temperature is 60～80 ℃, carries out high speed shear and stirs that to make solid content be 55% bitumen emulsion.
Embodiment 9:The preparation of bitumen emulsion
In equipment for production of emulsified bitumen, add weight part and be 100 parts 90# petroleum pitch and remain on 120 ℃; Add weight part and be 100 parts the anionic emulsifier aqueous solution (carboxylic acid type metallic soap, concentration are 1%), temperature is 40～60 ℃, carries out high speed shear and stirs that to make solid content be 65% bitumen emulsion.
Embodiment 10:The preparation of bitumen emulsion
In equipment for production of emulsified bitumen, add weight part and be 100 parts 70# coal tar pitch and remain on 120 ℃; Add weight part and be 108 parts the anionic emulsifier aqueous solution (carboxylic acid type metallic soap, concentration are 1.5%), temperature is 40～80 ℃, carries out high speed shear and stirs that to make solid content be 60% bitumen emulsion.
Embodiment 11:The preparation of fluid rubber asphalt adhesive emulsion components
When being down to 20～40 ℃, embodiment 8 medium pitch emulsions under agitation add root resistance agent, carbon powder, liquid fine powder material, anionic dispersing agents, anion surfactant, stablizer, then solid content 45% is added the fluid rubber bitumen emulsion that stirs and make solid content 50% slowly for natural rubber latex.
Concrete prescription is: the bitumen emulsion of solid content 55% (embodiment 8) 52%, the rubber latex 43% of solid content 45%, root resistance agent 1%, carbon powder 0.5%, liquid fine powder material 2%, anionic dispersing agents 0.5%, anion surfactant 0.998%, stablizer 0.002% by weight percentage.
Embodiment 12:The preparation of fluid rubber asphalt adhesive emulsion components
When being down to 20～40 ℃, embodiment 9 medium pitch emulsions under agitation add root resistance agent, liquid carbon black, dicalcium powder fine powder material, anionic dispersing agents, anion surfactant, stablizer, then solid content 50% is added the fluid rubber bitumen emulsion that stirs and make solid content 55% slowly for synthetic rubber latex.
Concrete prescription is: the bitumen emulsion of solid content 65% (embodiment 9) 78%, the rubber latex 18% of solid content 50%, root resistance agent 0.5%, liquid carbon black 0.5%, dicalcium powder fine powder material 1.5%, anionic dispersing agents 0.5%, anion surfactant 0.997%, stablizer 0.003% by weight percentage.
Embodiment 13:The preparation of fluid rubber asphalt adhesive emulsion components
When being down to 20～40 ℃, embodiment 10 medium pitch emulsions under agitation add carbon powder, porcelain powder and fine powder material, anionic dispersing agents, anion surfactant, stablizer, then solid content 45% is added the fluid rubber bitumen emulsion that stirs and make solid content 65% slowly for synthetic rubber latex.
Concrete prescription is: the bitumen emulsion of solid content 60% (embodiment 10) 63%, the rubber latex 30% of solid content 45%, root resistance agent 1%, carbon black 2%, fine powder material 2%, anionic dispersing agents 1%, anion surfactant 0.999%, stablizer 0.001% by weight percentage.
Embodiment 14:The preparation of fluid rubber asphalt adhesive emulsion components
When make the bitumen emulsion solid content greater than 60% or the rubber latex solid content greater than 47% the time, different according to working conditions, can in the rubber asphalt emulsion is synthetic, not add liquid carbon black or carbon powder yet, porcelain powder and fine powder material or liquid fine powder material, as long as with bitumen emulsion, rubber latex stirs and gets final product at the agent of temperature 20-40 ℃ of scope adding root resistance, anionic dispersing agents anion surfactant, stablizer.
Concrete prescription is: the bitumen emulsion 65% of solid content 60～65%, the rubber latex 32% of solid content 47～50%, root resistance agent 1%, anionic dispersing agents 1%, anion surfactant 0.997%, stablizer 0.003% by weight percentage.
Claims (8)
1. a plantation sprays the rapid hardening rubber asphalt waterproof coating with anti-, its feature exists: be the respectively water base spray material of preparation in proportion of 50～65% fluid rubber asphalt adhesive emulsion components, concentration 1～20% condensing agent component by solid content, the spraying volume ratio of condensing agent component and fluid rubber asphalt adhesive emulsion components is 1/15～1/3.5;
Described fluid rubber bitumen emulsion component formula rate by weight is: the bitumen emulsion 52～78% of solid content 55～65%, the rubber latex 18～43% of solid content 45～50%, root resistance agent 0.5～1%, carbon black 0～2%, fine powder material 0～2%, anionic dispersing agents 0.5～1%, anion surfactant 0.997～0.999%, stablizer 0.001～0.003%; Wherein said fine powder material is porcelain powder, dicalcium powder or light calcium carbonate powder;
Described condensing agent component formula rate by weight is: calcium chloride 95～99.6%, sodium-chlor 0.2～2%, compound ferro-aluminum polymkeric substance 0.2～3% or formula rate are: calcium chloride 92～99.9%, compound ferro-aluminum polymkeric substance 0.1～8%; In proportion that above-mentioned metal-salt is soluble in water, mix is even respectively, is formulated as concentration 1～20%.
2. plantation according to claim 1 sprays the rapid hardening rubber asphalt waterproof coating with anti-, it is characterized in that: described rubber latex is by the standby synthetic rubber latex of free-radical emulsion polymerization legal system or the commodity of directly buying; Described bitumen emulsion is bitumen emulsion or the direct commodity of buying that are mixed with pitch.
3. plantation according to claim 2 sprays the rapid hardening rubber asphalt waterproof coating with anti-, it is characterized in that: described rubber latex is natural rubber latex or synthetic rubber latex, and synthetic rubber latex is 2～4 kinds of latex of making of styrene-butadiene rubber(SBR), cis-1,4-polybutadiene rubber, paracril, ethylene-propylene rubber(EPR), polyisoprene rubber, chloroprene rubber, neoprene, butadienestyrene copolymer rubber, butadiene acrylonitrile copolymer rubber, isobutene polymer rubber, isoprene copolymer rubber or polybutadiene rubber.
4. plantation according to claim 3 sprays the rapid hardening rubber asphalt waterproof coating with anti-, it is characterized in that: when described natural rubber latex and its solid content of synthetic rubber latex are lower than 55～65%, can pass through the extract at low temperature method, when temperature is controlled at 7～-4 ℃, when the extraction solid content reaches 55～65%, for subsequent use when being warmed up to 30～50 ℃ in the reactor of again latex being packed into.
5. plantation according to claim 1 sprays the rapid hardening rubber asphalt waterproof coating with anti-, and it is characterized in that: the compound method of described bitumen emulsion is: add weight part and be 100 parts pitch and remain on 120 ℃ in equipment for production of emulsified bitumen; The concentration that adds weight part and be 100～122 parts is 0.5～1.5% emulsifier aqueous solution, and temperature is 40～80 ℃, carries out high speed shear and stirs that to make solid content be 45～50% bitumen emulsions.
6. plantation according to claim 5 sprays the rapid hardening rubber asphalt waterproof coating with anti-, it is characterized in that: described pitch is petroleum pitch, coal tar pitch, rock asphalt, shale tar pitch or the transformation of the way pitch of 70-90#.
7. plantation according to claim 1 sprays the rapid hardening rubber asphalt waterproof coating with anti-, the preparation method who it is characterized in that described fluid rubber asphalt adhesive emulsion components: when bitumen emulsion is down to 20～40 ℃, under agitation add liquid carbon black or carbon powder, fine powder material or liquid fine powder material, root resistance agent, anionic dispersing agents, anion surfactant, stablizer, then rubber latex is added slowly, stir, make the fluid rubber bitumen emulsion of solid content 50～65%.
8. plantation according to claim 7 sprays the rapid hardening rubber asphalt waterproof coating with anti-, it is characterized in that: when make the bitumen emulsion solid content greater than 47% or the rubber latex solid content greater than 60% the time, different according to working conditions, can in the rubber asphalt emulsion is synthetic, not add liquid carbon black or carbon powder yet, fine powder material or liquid fine powder material stir as long as bitumen emulsion, rubber latex are added root resistance agent, anionic dispersing agents, anion surfactant and stablizer 20～40 ℃ of temperature ranges.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201210500349.2A CN102965020B (en) | 2012-11-30 | 2012-11-30 | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210500349.2A CN102965020B (en) | 2012-11-30 | 2012-11-30 | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting |
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| CN102965020A true CN102965020A (en) | 2013-03-13 |
| CN102965020B CN102965020B (en) | 2015-06-17 |
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| CN103525307A (en) * | 2013-10-14 | 2014-01-22 | 浙江鲁班建筑防水有限公司 | Machine-spraying quick-demulsifying solidification film formation creep waterproof coating and preparation method thereof |
| CN103897635A (en) * | 2014-04-23 | 2014-07-02 | 衡水中铁建土工材料制造有限公司 | Waterproof material prepared from fluid rubber and preparation method thereof |
| CN104277666A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Root-blocking type epoxy amino waterproof paint and preparation method thereof |
| CN104277669A (en) * | 2014-10-29 | 2015-01-14 | 安徽朗凯奇建材有限公司 | Heat-insulation corrosion-resistant rooting-resistant type waterproof paint for planted roof and preparation method thereof |
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| CN104387781A (en) * | 2014-12-02 | 2015-03-04 | 天津海泰环保科技发展有限公司 | Fluid rubber modified emulsified asphalt and preparation method thereof |
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| CN114369413A (en) * | 2021-12-29 | 2022-04-19 | 大禹伟业(北京)国际科技有限公司 | Root-puncture-resistant quick-setting spray rubber asphalt waterproof coating, and preparation method and application thereof |
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| CN114369413B (en) * | 2021-12-29 | 2022-11-08 | 大禹伟业(北京)国际科技有限公司 | Root-puncture-resistant quick-setting spray rubber asphalt waterproof coating, and preparation method and application thereof |
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