CN106634707A - Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant - Google Patents
Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant Download PDFInfo
- Publication number
- CN106634707A CN106634707A CN201610968836.XA CN201610968836A CN106634707A CN 106634707 A CN106634707 A CN 106634707A CN 201610968836 A CN201610968836 A CN 201610968836A CN 106634707 A CN106634707 A CN 106634707A
- Authority
- CN
- China
- Prior art keywords
- retardant
- sealant
- fire
- flame
- tackifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000565 sealant Substances 0.000 title claims abstract description 48
- 239000003063 flame retardant Substances 0.000 title claims abstract description 43
- 239000011521 glass Substances 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 title claims description 10
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 22
- 229920005549 butyl rubber Polymers 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011347 resin Substances 0.000 claims abstract description 15
- 229920005989 resin Polymers 0.000 claims abstract description 15
- 229920002367 Polyisobutene Polymers 0.000 claims abstract description 13
- 239000006229 carbon black Substances 0.000 claims abstract description 13
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 8
- 229910052791 calcium Inorganic materials 0.000 claims abstract description 8
- 239000011575 calcium Substances 0.000 claims abstract description 8
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 8
- 150000003505 terpenes Chemical class 0.000 claims abstract description 8
- 235000007586 terpenes Nutrition 0.000 claims abstract description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002253 acid Substances 0.000 claims abstract 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 13
- 239000012530 fluid Substances 0.000 claims description 13
- 229910052750 molybdenum Inorganic materials 0.000 claims description 13
- 239000011733 molybdenum Substances 0.000 claims description 13
- 241000276489 Merlangius merlangus Species 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- 238000001125 extrusion Methods 0.000 claims description 6
- 230000001404 mediated effect Effects 0.000 claims description 6
- 238000007493 shaping process Methods 0.000 claims description 6
- 150000007513 acids Chemical class 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 15
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 6
- 239000006185 dispersion Substances 0.000 abstract description 4
- 239000012943 hotmelt Substances 0.000 abstract description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- 230000007797 corrosion Effects 0.000 abstract 2
- 238000005260 corrosion Methods 0.000 abstract 2
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 abstract 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 abstract 2
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- 239000002075 main ingredient Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000007789 sealing Methods 0.000 description 6
- 238000004134 energy conservation Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000008393 encapsulating agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C09J123/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C09J123/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefines
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
The invention provides a flame-retardant butyl sealant for hollow glass. The flame-retardant butyl sealant contains the following main ingredients, i.e., polyisobutylene, butyl rubber, molybdenum disulfide, a flame retardant, carbon black, a tackifier and heavy calcium carbonate. According to the flame-retardant butyl sealant for the hollow glass, the micron-scale flame retardant is added on the basis of the traditional hot-melt butyl sealant formula; on one hand, nano-scale silicon dioxide is uniformly dispersed in a system, so that the flame-retardant effect is good; on the other hand, calcium hexaluminate not only has a high-temperature property (above 1,000 DEG C), but also has very good acid/base corrosion resistance and metallic corrosion resistance; by adding the molybdenum disulfide, the dispersion effect of all substances can be greatly improved, particularly, the influence on the dispersion effect of the nano-scale flame retardant is very high, so that a better flame-retardant effect is achieved; and a mixture of rosin resin and terpene resin serves as the tackifier, and the tackifier not only has a good tackifying effect, but also has a skid-resisting effect, so that the cold flow property of the sealant is lowered, and the glass does not deform in long-term use after the glass is bonded.
Description
Technical field
The present invention relates to fluid sealant technical field, especially, is related to a kind of fire-retardant double glazing butyl sealant and its system
Preparation Method.
Background technology
With the progress of science and technology, growth in the living standard, requirement of the people to living environment also more and more higher, especially seven
Latter stage in the ten's, worldwide energy shortage, various countries to energy-saving and environmental protection type product promote the use of it is heavier regard, hollow glass
The development of glass product, production also progressively develop to energy-saving and environmental protection type direction.For it is current the country high energy consumption building large percentage,
Building energy conservation situation is not good enough, the application of national pay attention to day by day building energy conservation product and the formulation of relevant laws and regulations standard, 2005
National publication《Public building energy design standard》, the Ministry of Construction also issues therewith《With regard to developing housing and public buildings that use less energy and land
With the instruction of public building》, it is pointed out that, by 2010, national town building realized energy-conservation 50%, 2020,
The target of energy-conservation 65% is realized in the north and coastal economy developed regions and big city new building.To reach these targets, in
Empty glass production usage amount sharp increase, the production and application amount of 2003 more than 30,000,000 square metres, hollow glass in 2005
The year production and application amount of glass has reached 60,000,000 square metres, and estimated usage amount will be added to 1.5 hundred million square metres within 2010.
Due to the raising of double glazing yield, fluid sealant yield is also in sustainable growth necessary to double glazing.
On the make during empty glass, from suitable edge encapsulant and good peripheral frame material, in being raising
The key of empty glass performance.The sealing structure of double glazing is mainly double sealing, is sealed into interior road sealing first,
Play isolation steam and air effect；Second is sealed into outer course sealing, plays structure function.Therefore first of double glazing it is close
Envelope must use the extremely low hot melt butyl sealant of moisture-vapor transmission.If one fluid sealant moisture-vapor transmission is higher, water
First fluid sealant of vapor permeation is penetrated in double glazing, and double glazing is easy for dew point phenomenon occur, loses double glazing
Effect.Double glazing is used out of doors for a long time, and by direct sunlight, summer temperature may be up to 60 DEG C, and fluid sealant at high temperature can
Generation cold flow, affects using effect, therefore, apply the fluid sealant on double glazing there are too high cold flow properties, glue
Need Long-Time Service indeformable after knot glass.
Simultaneously at present the fire of China's skyscraper happens occasionally, and when there is fire of high-rise building, personnel are difficult to evacuate,
The time treated indoors is long, therefore the security requirement to construction material is higher, not only to heating the fire-retardant of butyl sealant
Performance proposes higher requirement, and requires that it, in fire, will not distribute toxic gas, so as to the peace of more preferable support personnel
Entirely.
The content of the invention
Present invention aim at providing a kind of fire-retardant double glazing butyl sealant and preparation method thereof, asked with solving technology
Topic.
A kind of fire-retardant double glazing butyl sealant, including the composition of following percentage by weight：
Polyisobutene 35-50%
Butyl rubber 10-20%
Molybdenum bisuphide 0.5-1%
Fire retardant 0.2-0.5%
Carbon black 5-8%
Tackifier 1-3%
Powdered whiting surplus.
Preferably, described tackifier are the mixture of rosin resin and terpene resin.
Preferably, described fire retardant is the mixture of calcium hexaluminate and nanometer grade silica.
Preferably, the molecular weight of described butyl rubber is 15000-25000.
A kind of preparation method of fire-retardant double glazing butyl sealant, comprises the following steps：
A, kneader is preheating to 80-90 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 110-130 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 140-150 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 50- in vacuum 0.08-0.1Mpa
80min, obtains fluid sealant kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant.
The invention has the advantages that：The fire-retardant double glazing butyl sealant of the present invention, in traditional hot melt fourth
Micron-sized fire retardant is added on the basis of the formula of based sealant, on the one hand, nano level silica is uniformly dispersed in
In system, good flame retardation effect, on the other hand, calcium hexaluminate not only has more than 1000 DEG C of high-temperature behavior, while it has very
Good acid-alkali-corrosive-resisting, the performance of resistance to metal erosion, is particularly suitable for double glazing and uses；2nd, addition molybdenum bisuphide can be significantly
The dispersion effect of each material is improved, particularly very big is affected on the dispersion effect of nano level fire retardant, so as to reach more preferably
Flame retardant effect；3rd, tackifier are done with the mixture of rosin resin and terpene resin, not only good antiskid effect, and has thickening
Effect, reduces the cold flow properties of fluid sealant, and Long-Time Service is indeformable after bonding glass.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages.
Below the present invention is further detailed explanation.
Specific embodiment
Embodiments of the invention are described in detail below, but the present invention can be limited according to claim and covered
Multitude of different ways implement.
Embodiment 1
A kind of fire-retardant double glazing butyl sealant, including the composition of following percentage by weight：
Polyisobutene 40%
Butyl rubber 15%
Molybdenum bisuphide 0.8%
Calcium hexaluminate 0.2%
Nanometer grade silica 0.1%
Carbon black 7.5%
Tackifier 2.5%
Powdered whiting surplus；
The molecular weight of described butyl rubber is 15000-25000；
Described tackifier are the mixture of rosin resin and terpene resin, and mass ratio is 1：1.
A kind of preparation method of fire-retardant double glazing butyl sealant, comprises the following steps：
A, kneader is preheating to 85 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 115 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 142 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 65min in vacuum 0.085Mpa, obtain
Fluid sealant kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant；
Embodiment 2
A kind of fire-retardant double glazing butyl sealant, including the composition of following percentage by weight：
Polyisobutene 50%
Butyl rubber 10%
Molybdenum bisuphide 1%
Calcium hexaluminate 0.18%
Nanometer grade silica 0.02%
Carbon black 8%
Tackifier 1%
Powdered whiting surplus.
Described tackifier are the mixture of rosin resin and terpene resin, and mass ratio is 1：4.
The molecular weight of described butyl rubber is 15000-25000.
A kind of preparation method of fire-retardant double glazing butyl sealant, comprises the following steps：
A, kneader is preheating to 80 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 130 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 140 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 50min in vacuum 0.1Mpa, obtain close
Sealing kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant.
Embodiment 3
A kind of fire-retardant double glazing butyl sealant, including the composition of following percentage by weight：
Polyisobutene 35%
Butyl rubber 20%
Molybdenum bisuphide 0.5%
Calcium hexaluminate 0.4%
Nanometer grade silica 0.1%
Carbon black 5%
Tackifier 3%
Powdered whiting surplus.
Described tackifier are the mixture of rosin resin and terpene resin, and mass ratio is 1：2.5.
The molecular weight of described butyl rubber is 15000-25000.
A kind of preparation method of fire-retardant double glazing butyl sealant, comprises the following steps：
A, kneader is preheating to 90 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 110 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 150 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 80min in vacuum 0.08Mpa, obtain close
Sealing kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant.
The fluid sealant of embodiment of the present invention 1-3 is detected, following data are obtained：
Table 1：The detection data of the fluid sealant of embodiment 1-3：
The preferred embodiments of the present invention are the foregoing is only, the present invention is not limited to, for those skilled in the art
For member, the present invention can have various modifications and variations.All any modifications within the spirit and principles in the present invention, made,
Equivalent, improvement etc., should be included within the scope of the present invention.
Claims (6)
1. a kind of fire-retardant double glazing butyl sealant, it is characterised in that including the composition of following percentage by weight：
Polyisobutene 35-50%
Butyl rubber 10-20%
Molybdenum bisuphide 0.5-1%
Fire retardant 0.2-0.5%
Carbon black 5-8%
Tackifier 1-3%
Powdered whiting surplus.
2. fire-retardant double glazing butyl sealant as claimed in claim 1, it is characterised in that described tackifier are rosin tree
The mixture of fat and terpene resin.
3. fire-retardant double glazing butyl sealant as claimed in claim 1, it is characterised in that described fire retardant is six aluminic acids
The mixture of calcium and nanometer grade silica.
4. fire-retardant double glazing butyl sealant as claimed in claim 1, it is characterised in that the molecule of described butyl rubber
Measure as 15000-25000.
5. a kind of preparation method of fire-retardant double glazing butyl sealant, comprises the following steps：
A, kneader is preheating to 80-90 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 110-130 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 140-150 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 50- in vacuum 0.08-0.1Mpa
80min, obtains fluid sealant kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant.
6. the preparation method of fire-retardant double glazing butyl sealant as claimed in claim 5, it is characterised in that including following step
Suddenly：
A, kneader is preheating to 85 DEG C, polyisobutene and butyl rubber is added in the kneader of preheating and is mediated;
B, reach 115 DEG C in temperature of charge, add carbon black, powdered whiting and tackifier；
C, continue to be increased to 142 DEG C and add molybdenum bisuphide and fire retardant, continue to mediate 65min in vacuum 0.085Mpa, obtain
Fluid sealant kneaded material；
D, extrusion, shaping, cooling obtain insulating glass sealant；
Described fire-retardant double glazing butyl sealant, including the composition of following percentage by weight：
Polyisobutene 40%
Butyl rubber 15%
Molybdenum bisuphide 0.8%
Calcium hexaluminate 0.2%
Nanometer grade silica 0.1%
Carbon black 7.5%
Tackifier 2.5%
Powdered whiting surplus；
The molecular weight of described butyl rubber is 15000-25000；
Described tackifier are the mixture of rosin resin and terpene resin, and mass ratio is 1：1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610968836.XA CN106634707A (en) | 2016-11-06 | 2016-11-06 | Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610968836.XA CN106634707A (en) | 2016-11-06 | 2016-11-06 | Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106634707A true CN106634707A (en) | 2017-05-10 |
Family
ID=58820737
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610968836.XA Pending CN106634707A (en) | 2016-11-06 | 2016-11-06 | Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106634707A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201196A (en) * | 2017-06-15 | 2017-09-26 | 湖北新海鸿化工有限公司 | A kind of double glazing butyl rubber sealant and preparation method thereof |
| CN109913151A (en) * | 2019-03-25 | 2019-06-21 | 河南连邦有机硅科技有限公司 | A kind of hollow glass special environment protection butyl rubber |
| CN110437773A (en) * | 2019-07-31 | 2019-11-12 | 南通市开泰高分子材料有限公司 | A kind of hot melt butyl sealant and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
| CN102850964A (en) * | 2011-07-01 | 2013-01-02 | 上海渊信建筑材料有限公司 | Butyl sealant for flame-retardant hollow glass, and its preparation method |
| CN105385388A (en) * | 2015-12-23 | 2016-03-09 | 成都硅宝科技股份有限公司 | Butyl hot melt adhesive and preparation method thereof |
-
2016
- 2016-11-06 CN CN201610968836.XA patent/CN106634707A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101805569A (en) * | 2009-10-23 | 2010-08-18 | 郑州中原应用技术研究开发有限公司 | Transparent butyl hot-melt sealant and preparation method thereof |
| CN102850964A (en) * | 2011-07-01 | 2013-01-02 | 上海渊信建筑材料有限公司 | Butyl sealant for flame-retardant hollow glass, and its preparation method |
| CN105385388A (en) * | 2015-12-23 | 2016-03-09 | 成都硅宝科技股份有限公司 | Butyl hot melt adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 纪楠 等: "中空玻璃用丁基热熔密封胶的研究", 《沈阳化工大学学报》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107201196A (en) * | 2017-06-15 | 2017-09-26 | 湖北新海鸿化工有限公司 | A kind of double glazing butyl rubber sealant and preparation method thereof |
| CN109913151A (en) * | 2019-03-25 | 2019-06-21 | 河南连邦有机硅科技有限公司 | A kind of hollow glass special environment protection butyl rubber |
| CN110437773A (en) * | 2019-07-31 | 2019-11-12 | 南通市开泰高分子材料有限公司 | A kind of hot melt butyl sealant and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107541179A (en) | A kind of compound silicone sealant of high-gas resistance performance and preparation method thereof | |
| CN102965020B (en) | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting | |
| CN102399521A (en) | Hot melt butyl sealant for hollow glass and manufacture method thereof | |
| CN106634707A (en) | Flame-retardant butyl sealant for hollow glass and preparation method for flame-retardant butyl sealant | |
| CN103173088B (en) | Reflective insulating fire-retardant coating for waterproof roll, and preparation method and use thereof | |
| CN100358966C (en) | Sealing silicone glue with low moisture permeability for hollow glass and its production process | |
| CN106588108A (en) | Building heat preservation material | |
| CN106554728A (en) | Pressure-sensitive Protection glue band of a kind of butyl rubber base and preparation method thereof | |
| CN104693339A (en) | Water-based dust depressor and preparation method thereof | |
| CN106883797B (en) | A kind of fireproof gum liquid-based matter and preparation method thereof and fire prevention glue and preparation method thereof | |
| CN103043983A (en) | Vitrified microbead heat-preserving mortar | |
| CN106243889A (en) | A kind of anti-temperature rise coating with compound heat-insulation effect and preparation method thereof | |
| CN106479402A (en) | Fire-retardant double glazing butyl sealant of a kind of permanent seal cooling and preparation method thereof | |
| KR102324860B1 (en) | Insulated Paint Composition | |
| CN106189941A (en) | A kind of waterproof freeze proof basement membrane and preparation method thereof | |
| CN103483950A (en) | Thermal-insulation exterior coating | |
| CN102964743A (en) | Energy-saving plastic composite door and window for buildings | |
| CN103467034A (en) | Inorganic wall heat insulation mortar | |
| CN103980412B (en) | A kind of preparation method of nano core-shell structure efficient molecular sieve drier | |
| CN206232610U (en) | It is a kind of it is new prevent condense frosting glass | |
| CN106010360A (en) | Wet glue for wallpaper and preparation method for wet glue | |
| CN109553990A (en) | Environment-friendly type is freeze proof to split color asphalt preparation method and application | |
| CN104860626A (en) | Flame-retardant building external wall heat-insulation material | |
| CN106520024A (en) | Antibacterial and flame retardant hot-melt butyl sealant for hollow glass and preparation method thereof | |
| CN108912775A (en) | A kind of novel environment friendly water-repellent paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170510 |