CN106010360A - Wet glue for wallpaper and preparation method for wet glue - Google Patents
Wet glue for wallpaper and preparation method for wet glue Download PDFInfo
- Publication number
- CN106010360A CN106010360A CN201610550551.4A CN201610550551A CN106010360A CN 106010360 A CN106010360 A CN 106010360A CN 201610550551 A CN201610550551 A CN 201610550551A CN 106010360 A CN106010360 A CN 106010360A
- Authority
- CN
- China
- Prior art keywords
- wallpaper
- wet glue
- titanium dioxide
- preservative
- pure cote
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J103/00—Adhesives based on starch, amylose or amylopectin or on their derivatives or degradation products
- C09J103/04—Starch derivatives
- C09J103/08—Ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides wet glue for wallpaper. The wet glue comprises the following components in percentage by mass: 15 to 25 percent of hydroxypropyl modified starch, 0.1 to 1 percent of VAE emulsion, 1 to 5 percent of titanium dioxide, 0.1 to 1 percent of a preservative and 70 to 82 percent of water. Correspondingly, the invention also provides a preparation method for the wet glue for the wallpaper. Compared with the prior art, the wet glue has the advantages that the prepared product is applied to adhesion of various kinds of wallpaper, and can be used for adhering various kinds of wallpaper and multiple adhered substrates, and after the product is used, pure white color, stable glue, strong adhesion force, high mildew resistance, convenience for construction and high applicability are ensured.
Description
Technical field
The present invention relates to chemical building material field, particularly relate to a kind of wallpaper wet glue and preparation method thereof, can extensively apply
Use when wallpaper is pasted in house decoration.
Background technology
Wallpaper powder, also known as adhesive powder for wall paper, is the adhesive specially prepared for putting up wallpaper, after adhesive powder for wall paper is made into glue
Wallpaper can be made to cement on the wall, if without " interior wall infiltration " or artificial destruction, after the construction of normal wallpaper is pasted, would not have de-
Fall phenomenon, is used alone wallpaper powder sticking wallpaper, can readily replaceable and less damage surface of wall, can be next time paste
There is provided convenient.Wallpaper powder is divided into cellulose and starch two class, makes with high-performance plant cellulose or potato starch for raw material,
Product is white plates powder, can be dissolved in cold water, and aqueous solution is milky thickness glue, is few in the gluing product of building decorating industry
Have is biodegradable, without formaldehyde, totally nontoxic, harmless, the healthy product of environmental protection.
At present, the wet glue of wallpaper is of a great variety on the market, and quality is uneven.Such as, have directly boils with dextrin, has
Making with common wheaten starch gelatinizing, viscosity index and viscosity intensity difference are away from the most remote.And the most former due to the wet glue of wallpaper
Material is the organic high molecular polymer of starch based, easily moldy metamorphism.The wet glue of some wallpapers the most on the market is the most all used
Organic mildew-resistant system carries out mildew-resistant, however organic mildew-resistant system during resisting the microbial attack such as antibacterial, mycete self
Can be gradually consumed, the wet glue of such wallpaper the most gradually loses self-protection performance, causes glued membrane to be easy to mouldy, causes wall
Paper large area is mouldy.
Summary of the invention
For the problem of above-mentioned existence, it is an object of the invention to provide a kind of wallpaper wet glue and preparation method thereof, suitable
For pasting various wallpaper, have after using that color and luster is pure white, rubber cement is stable, bonding force is strong, fungus resistance is good, easy construction, be suitable for
Property wide, can be used for various wallpaper and the multiple bonding by viscous substrate.
In order to realize the technical purpose of the present invention, the present invention adopts the following technical scheme that.
A kind of wet glue of wallpaper, by mass percentage, including following component: 15%-25% PURE COTE PURE COTE B790,
The VAE emulsion of 0.1%-1%, the titanium dioxide of 1%-5%, the preservative of 0.1%-1% and the water of 70%-82%.
Preferably, a kind of wet glue of wallpaper, by mass percentage, including following component: the hydroxypropyl modified shallow lake of 15%
Powder, the VAE emulsion of 0.1%-1%, the titanium dioxide of 1%-5%, the preservative of 0.1%-1% and the water of 70%-82%.
Preferably, a kind of wet glue of wallpaper, by mass percentage, including following component: the hydroxypropyl modified shallow lake of 15%
Powder, the VAE emulsion of 0.7%, the titanium dioxide of 3%, the preservative of 0.3% and the water of 81%.
Preferably, described PURE COTE PURE COTE B790 is hydroxypropyl PASELLI EASYGEL.
Preferably, described titanium dioxide be particle diameter be the titanium dioxide of 20-120nm.The particle diameter of titanium dioxide is to wet glue fungicidal properties
Having a significant impact, when titanium dioxide particle diameter is more than 500nm, the anti-mold effect of technical solution of the present invention disappears substantially, titanium white powder
Footpath is when 150nm-500nm, and product anti-mold effect is general, and therefore titanium dioxide particle diameter is preferably 20nm-120nm.
It is further preferred that rutile-type is 3:1 with the mol ratio of Detitanium-ore-type in described titanium dioxide.
Preferably, at least during described preservative is sodium benzoate, benzoic acid, sorbic acid, potassium sorbate, calcium propionate
Kind.
Accordingly, present invention also offers this wallpaper preparation method with wet glue, comprise the steps: by proportioning, instead
Answer in still addition pure water, be sequentially added into PURE COTE PURE COTE B790 under room temperature, nanometer titanium dioxide is warming up to 70 DEG C after stirring, protect
Temperature is continuously heating to 77-78 DEG C and reacts to plastic state after 20-25 minute, add VAE emulsion, stirring during cooling down to 60 DEG C
15 minutes, continue to be cooled to add preservative when 50 DEG C, cool down after stirring 30 minutes, obtain wet glue finished product.
The invention has the beneficial effects as follows: the invention provides a kind of wallpaper wet glue and preparation method thereof, with prior art
Compare, have the advantage that.
1. the present invention is by using PURE COTE PURE COTE B790, and reacts with VAE latex composite compounding, greatly improves wet gluing connect
Intensity.
2., by adding suitable nanometer titanium dioxide, compared with prior art, significantly improve the antimildew and antibacterial of wet glue
Ability, owing to using inorganic anti-bacterium mildewproof mechanism, relies on contact-type sterilization mechanism, by destroying microprotein and DNA
Means reach the purpose that sterilizes, and the nanoparticle after sterilization can depart from microorganism itself, follows in entering other microbial body
Ring sterilizes, therefore, it is possible to repeat, lasting sterilization, antibacterial, the mildew-resistant ability of Wall paper adhesive and wallpaper is greatly improved.
3. the product that the present invention provides, environmental protection, nontoxic, it is suitable for residential use.
Detailed description of the invention
In order to be better understood from the present invention, below in conjunction with specific embodiment, invention is described in detail.
Embodiment 1
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 15%, the VAE of 0.9%
Emulsion, titanium dioxide (particle diameter is 20nm), the preservative of 0.1% and the water of 81% of 3%.
Embodiment 2
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 25%, the VAE breast of 1%
Liquid, titanium dioxide (particle diameter is 50nm), the preservative of 1% and the water of 70% of 3%.
Embodiment 3
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 16%, the VAE of 0.1%
Emulsion, titanium dioxide (particle diameter is 80nm), the preservative of 0.9% and the water of 82% of 1%.
Embodiment 4
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 20%, the VAE breast of 1%
Liquid, titanium dioxide (particle diameter is 120nm), the preservative of 1% and the water of 73% of 5%.
Embodiment 5
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 15%, the VAE of 0.7%
Emulsion, titanium dioxide (particle diameter is 20nm), the preservative of 0.3% and the water of 81% of 3%.
Comparative example 1(common starch)
A kind of wet glue of wallpaper, by mass percentage, including following component: the starch of 15%, the VAE emulsion of 0.7%, the titanium of 3%
White lead (particle diameter is 20nm), the preservative of 0.3% and the water of 81%.
Comparative example 2(does not contains nanometer titanium dioxide)
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 18%, the VAE of 0.7%
Emulsion, the preservative of 0.3% and the water of 81%.
Comparative example 3(does not contains VAE emulsion)
A kind of wet glue of wallpaper, by mass percentage, including following component: the PURE COTE PURE COTE B790 of 15%, the titanium dioxide of 3%
(particle diameter is 20nm), the preservative of 1% and the water of 81%.
The preparation method of embodiment 1-5 and comparative example 1-3 is as follows, by proportioning, adds in a kettle. and depends under pure water, room temperature
Secondary addition PURE COTE PURE COTE B790, nanometer titanium dioxide are warming up to 70 DEG C after stirring, be continuously heating to after being incubated 20-25 minute
77-78 DEG C of reaction, to plastic state, adds VAE emulsion, stirs 15 minutes, when continuing to be cooled to 50 DEG C during cooling down to 60 DEG C
Add preservative, cool down after stirring 30 minutes, obtain wet glue finished product, be designated as A1-A5(embodiment respectively), B1-B3(comparative example).
A1-A5 sample and B1-B3 sample are carried out performance detection, and result is as shown in table 1.
Table 1 A1-A5 sample and B1-B3 properties of sample test result
| Sample | Mildew-resistant grade | Bonding force/N | Viscosity/mPa s | Stability |
| A1 | 0 grade | 43 | 178000 | Stable |
| A2 | 0 grade | 42 | 187000 | Stable |
| A3 | 0 grade | 40 | 177000 | Stable |
| A4 | 0 grade | 41 | 176000 | Stable |
| A5 | 0 grade | 40 | 178000 | Stable |
| B1 | 0 grade | 8.5 | 65000 | Unstable |
| B2 | 2 grades | 41 | 178000 | Unstable |
| B3 | 0 grade | 6.4 | 35000 | Unstable |
Note: viscosity test use the U.S. win Le fly (Brookfield RTV) viscosity tester detection.
According to upper table data it is apparent that the wet glue of a kind of wallpaper of present invention offer, changed by employing hydroxypropyl
Property starch, and react with VAE latex composite compounding, make wet glue obtain fabulous adhesive strength, have simultaneously preferable dispersibility with
Uniformity.Embodiment 1-5 understands with the result of comparative example 2, by adding suitable nanometer titanium dioxide, compared with prior art,
Significantly improve the antimildew and antibacterial ability of wet glue, owing to using inorganic anti-bacterium mildewproof mechanism, rely on contact-type sterilization mechanism, logical
The means crossing destruction microprotein and DNA reach the purpose that sterilizes, and the nanoparticle after sterilization can depart from microorganism itself,
Be circulated sterilization in entering other microbial body, therefore, it is possible to repeat, lasting sterilization, antibacterial, wallpaper is greatly improved
The mildew-resistant ability of glue and wallpaper.
Embodiment 1-5 understands with the result of comparative example 3, and the addition of VAE emulsion greatly improves the adhesive property of wet glue,
And compound with other component in the present invention, it is thus achieved that adhesive property is excellent, the wet glue product that fungicidal properties is excellent, the present invention simultaneously
The product provided, environmental protection, nontoxic, it is suitable for residential use.
The ultimate principle of the present invention, principal character and advantage have more than been shown and described.The technical staff of the industry should
Understanding, above-described embodiment limits the present invention the most in any form, and the mode of all employing equivalents or equivalent transformation is obtained
Technical scheme, all falls within protection scope of the present invention.
Claims (7)
1. the wet glue of wallpaper, it is characterised in that by mass percentage, the hydroxypropyl including following component: 15%-25% changes
Property starch, the VAE emulsion of 0.1%-1%, the titanium dioxide of 1%-5%, the preservative of 0.1%-1% and the water of 70%-82%.
A kind of wet glue of wallpaper the most according to claim 1, it is characterised in that by mass percentage, including following group
Point: the PURE COTE PURE COTE B790 of 15%, the VAE emulsion of 0.1%-1%, the titanium dioxide of 1%-5%, the preservative of 0.1%-1% and 70%-
The water of 82%.
A kind of wet glue of wallpaper the most according to claim 1, it is characterised in that by mass percentage, including following group
Point: the PURE COTE PURE COTE B790 of 15%, the VAE emulsion of 0.7%, the titanium dioxide of 3%, the preservative of 0.3% and the water of 81%.
4. according to the wet glue of a kind of wallpaper described in any one of claim 1-3, it is characterised in that: described titanium dioxide is that particle diameter is
The titanium dioxide of 20-120nm.
A kind of wet glue of wallpaper the most according to claim 4, it is characterised in that: rutile-type and sharp titanium in described titanium dioxide
The mol ratio of ore deposit type is 3:1.
A kind of wet glue of wallpaper the most according to claim 5, it is characterised in that: described preservative is sodium benzoate, benzene first
At least one in acid, sorbic acid, potassium sorbate, calcium propionate.
7. according to the preparation method of wet glue of a kind of wallpaper described in any one of claim 1-6, it is characterised in that include as follows
Step: by proportioning, adds in a kettle. and is sequentially added into PURE COTE PURE COTE B790, nanometer titanium dioxide stirring under pure water, room temperature all
It is warming up to 70 DEG C after even, is continuously heating to 77-78 DEG C of reaction after being incubated 20-25 minute to plastic state, cooling down to 60 DEG C
Time add VAE emulsion, stir 15 minutes, when continuing to be cooled to 50 DEG C, adds preservative, after stirring 30 minutes, cooling, obtains wet glue
Finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610550551.4A CN106010360B (en) | 2016-07-13 | 2016-07-13 | A kind of wallpaper wet glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610550551.4A CN106010360B (en) | 2016-07-13 | 2016-07-13 | A kind of wallpaper wet glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106010360A true CN106010360A (en) | 2016-10-12 |
| CN106010360B CN106010360B (en) | 2018-11-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610550551.4A Expired - Fee Related CN106010360B (en) | 2016-07-13 | 2016-07-13 | A kind of wallpaper wet glue and preparation method thereof |
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| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987219A (en) * | 2017-04-06 | 2017-07-28 | 合肥欧克斯新型建材有限公司 | A kind of high viscosity Wall paper adhesive and preparation method thereof |
| CN111647373A (en) * | 2020-05-21 | 2020-09-11 | 江门市蓝宝装饰材料有限公司 | Glutinous rice glue with formaldehyde removing and mildew preventing performances and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435461A (en) * | 2002-02-01 | 2003-08-13 | 张庆华 | Elastic emulsion adhesive |
| CN105567118A (en) * | 2015-12-16 | 2016-05-11 | 张树发 | Dehydrated wall paper wet glue and preparation method thereof |
-
2016
- 2016-07-13 CN CN201610550551.4A patent/CN106010360B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1435461A (en) * | 2002-02-01 | 2003-08-13 | 张庆华 | Elastic emulsion adhesive |
| CN105567118A (en) * | 2015-12-16 | 2016-05-11 | 张树发 | Dehydrated wall paper wet glue and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106987219A (en) * | 2017-04-06 | 2017-07-28 | 合肥欧克斯新型建材有限公司 | A kind of high viscosity Wall paper adhesive and preparation method thereof |
| CN111647373A (en) * | 2020-05-21 | 2020-09-11 | 江门市蓝宝装饰材料有限公司 | Glutinous rice glue with formaldehyde removing and mildew preventing performances and preparation method thereof |
| CN111647373B (en) * | 2020-05-21 | 2022-01-11 | 江门市蓝宝装饰材料有限公司 | Glutinous rice glue with formaldehyde removing and mildew preventing performances and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN106010360B (en) | 2018-11-30 |
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Granted publication date: 20181130 Termination date: 20190713 |