CN101235252A - Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device - Google Patents
Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device Download PDFInfo
- Publication number
- CN101235252A CN101235252A CNA2008100100930A CN200810010093A CN101235252A CN 101235252 A CN101235252 A CN 101235252A CN A2008100100930 A CNA2008100100930 A CN A2008100100930A CN 200810010093 A CN200810010093 A CN 200810010093A CN 101235252 A CN101235252 A CN 101235252A
- Authority
- CN
- China
- Prior art keywords
- rubber
- component
- spray
- spraying
- carbon black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
Multifunctional liquid rubber spray coating comprises components of A, B, wherein A component comprises liquid rubber asphalt emulsion whose solid content is 50-75%, wherein 2-65% rubber elusion content, 30-97% asphalt elusion content, 0.0-5.0% carbon black, 0.0-6.0% ultra-fine powder, 0.025-2.50% anion dispersing agent and 0.025-3.00% anion surface activator, which is waterborne spray coating, and B component is water solution which comprises 3.0-18.0% concentration calcii chloridum (89.0-99.2%), sodium chloride (0.50-4.0%) and composite aluminum iron polymer (0.3-7.0%). The two components are sprayed on the same basal plane through adopting a double-component airless spraying device to form a gelatin film with 0.5-4mm after 3-5 seconds solidification, which has the characteristics of strong bonding, temperature resistance, weather resistance, and excellent chemical stability, heat insulation and puncture resistance. The A component can be individually sprayed, or can be combined with the double components.
Description
Technical field
The invention belongs to the spray material compositions field, relate to based on natural rubber, synthetic rubber and bituminous spray material composition; The coating composition that relates to water-based latex.Simultaneously, also relate to system device and using method coating liquid or other the fluidic technology of general surface with injection.
Background technology
The coating that multiple anti-corrosion function, water-proof function, protection function, adiabatic heat-insulation function, sqouynd absorption lowering noise function, anti-flaming function are arranged is the in demand material of engineering construction in the building trade.During the construction of prevention work of particularly underground, bridge, Tunnel Engineering, need to make as soon as possible tunnel face to apply one deck waterproof protective layer behind the excavation, and wish very fast curing.
US3785852 provides a kind of asphalt rubber emulsion and condensing agent mixes and the coagulum product of generation coagulative method of precipitation and generation.By using hydraulic pressure, solid injection equipment intersects chemical coagulation agent and bitumen emulsion by different pipelines and is sprayed onto on the basal plane of needs processing with the atomizing of rubber latex mixture, mixes when reaching treated side and forms concrement and solidify.Yet its technology realizes existing several big defectives: the one, contain that in the bitumen emulsion of 65%-98% 65%-75% to be arranged be solid matter; Contain the solid matter that contains 55%-65% in the rubber latex of 2%-35%, this raw material difficult with buy.The 2nd, the gun system design is very complicated.Condensing agent is easily destroyed its stability by emulsion besides.The technology that US4287242 then provides is: add anion surfactant in the rubber asphalt emulsion, use solid injection equipment, make emulsion and polyvalent metal salt brine solution at spraying equipment with need position between the surface of base of spraying to continue contact and mix, therefore form the rubber asphalt solid cladding at surface of base, and form characteristics such as waterproof, damp proof and gas-tight rapidly at surface of base; Yet also be the rubber asphalt anionic emulsion that need contain 70～80% solid matter, this raw material is difficult to obtain.
Summary of the invention
Defective at the prior art existence, the present invention be intended to according to commonly used rubber latex, bitumen emulsion resource provide a kind of can be with the spraying of fluid rubber pitch and the coating material of Airless spraying method, and can solidify rapidly and cured layer has functions such as superior elasticity, intensity, anticorrosion, waterproof, insulation.
Technical scheme of the present invention is: divide the A component fluids rubber asphalt latex solution and the B component condensing agent aqueous solution; And special-purpose Airless spraying system device and using method.
The A component: be the fluid rubber bitumen emulsion, its solid content is 50.00～75.00%.Wherein: rubber latex accounts for 2.00～65.00% in the fluid rubber bitumen emulsion, and the solids content of its rubber latex is 48.00～65.00%; Bitumen emulsion accounts for 30.00～97.00% of total amount, and the solids content of its bitumen emulsion is 50.00～75.00%; Carbon black is 0.00～5.00%; Fine powder material 0.00～6.00% (porcelain powder, dicalcium powder etc.); Anionic dispersing agents 0.025～2.500%; Anion surfactant is 0.025～3.000%, and the A component is the water-based spray material.
Rubber, pitch in the described A component fluids rubber asphalt emulsion can be rubber latex, bitumen emulsion or its commodity, also can be the bitumen emulsions that is mixed with pitch; Be equipped with the synthetic rubber latex by the free-radical emulsion polymerization legal system.
The compound method of bitumen emulsion is: add the 80-120 pitch of 100 weight fraction and remain on 130 ℃ in emulsified bitumen equipment; Add 20～45% water and 3.00～5.00% anion surfactant, temperature is 50～70 ℃, carries out high speed shear and stirs that to make solid content be 50～75% anionic emulsified bitumens.
Be lower than at 48～65% o'clock at the natural rubber latex of buying and its solid content of synthetic rubber latex, can pass through the extract at low temperature method, when temperature is controlled at 5～-3 ℃, extracts solid content and reach at 48～65% o'clock, standby when being warmed up to 20～40 ℃ in the reactor of again latex being packed into.
Described rubber latex is natural rubber latex or synthetic rubber latex, and the rubber that synthetic rubber latex is adopted is following kind: neoprene; Butadienestyrene copolymer rubber; Butadiene acrylonitrile copolymer rubber; Iso-butylene, isoprene copolymer rubber; In the polybutadiene rubber etc. 1～2 kind.Consider from applicability economy angle, preferably select the neoprene or the butadienestyrene copolymer rubber of neoprene, butadienestyrene copolymer rubber or improvement for use.
Described pitch is 80-120 number unfilled bitumen (petroleum pitch, kerites, shale tar pitch and transformation of the way pitch all can).
Described carbon black is 600 orders or thinner carbon powder or white carbon black powder.Be made into liquid carbon black (or liquid white carbon black) during use, or through the carbon powder (or white carbon black powder) of modification, its method for making is: 0.20～30.00% the anionic dispersing agents of getting carbon black mass, elder generation's water is transferred and is opened, add the carbon black powder then, it is abundant together to put into grinding in ball grinder, forms stable and flowability liquid carbon black dispersion preferably; Also can dry processing again, its technology can take the electrically heated oven dry to handle, and preferably adopts spray drying treatment.The carbon black that electrically heated oven dry is handled is again through the dry grinding powdering, and with the carbon powder that aforesaid method makes, the liquid carbon black dispersion takes wet method or dry method to store for future use.
Described fine powder material is that porcelain powder or dicalcium powder are 800 orders or thinner powder.Be made into liquid fine powder material dispersion during use or through modification oven dry and the fine powder material powder through grinding, its method for making is identical with carbon black with storage method.
Wherein used anionic dispersing agents is in the preparation of carbon black and fine powder material: sulfonate (R-SO
3Na), 1～5 kind in TH-904, CD-4, Acumer9400 polymkeric substance, naphthalene sulfonate salt polycondensate, the naphthalenesulfonate formaldehyde condensation compound dispersion agent.
The rubber asphalt emulsion is synthetic: under agitation add liquid carbon black or carbon powder, fine powder material or liquid fine powder material when emulsified bitumen is reduced to 20～40 ℃, then natural rubber latex or synthetic rubber latex are added slowly, stirring makes the multi-functional anion liquid body rubber bitumen emulsion of solid content 50～75%.
When making bitumen emulsion and be a high solid content, the rubber latex solid content is greater than 50% the time, according to the working conditions difference, can in the rubber asphalt emulsion is synthetic, not add liquid carbon black or carbon powder yet, fine powder material or liquid fine powder material, as long as with bitumen emulsion, rubber latex adds 1～5% anionic dispersing agents and anion surfactant in the said temperature scope and stirs and get final product; This names a person for a particular job and does concrete narration among the embodiment below.
The B component is that concentration 3～18% condensing agents are calcium chloride, sodium-chlor, compound ferro-aluminum polymerization polyvalent metal salt; Wherein contain calcium chloride 90.0～99.20% in the polyvalent metal salt condensing agent, sodium chloride-containing 0.50～3.0% contains compound ferro-aluminum polymkeric substance 0.3～7.0%; Also calcium chloride-compound its content of ferro-aluminum polymkeric substance composite salt is calcium chloride 93.0～99.70%, compound ferro-aluminum polymkeric substance 0.3～7.0%.Its method for making is: in proportion that above-mentioned polyvalent metal salt is soluble in water, mix evenly gets final product respectively.
The present invention is the preparation in proportion respectively of A component, B component in actually operating, and the present invention is water base spray material, adopts the Airless spraying method to carry out operation.Calcium chloride, sodium-chlor, compound ferro-aluminum polymerization polyvalent metal salt condensing agent and calcium chloride-compound ferro-aluminum polymkeric substance composite salt condensing agent is 1/15～1/3.5 with the spraying volume ratio of rubber asphalt emulsion all.
The present invention is through test in place and use, proof is solving waterproof construction antiseep problem, the protection of construction of large bridge water-tight corrosion-proof and large chemical equipment and pipeline is anticorrosion, the problem of aspects such as industry, automobile sqouynd absorption lowering noise sound insulation protection, and the quality technological effect is remarkable.
The lance driving device that a cover special spraying device system of the present invention can carry out two or more sets simultaneously carries out spraying application, is used for different basal planes such as roof, metope and ground simultaneously, has improved speed of application, the integrity of construction.The ratio of rubber asphalt latex A component of the present invention and condensing agent B component is to decide according to the environment of operation and their concentration, and best volume ratio is 1/15～1/4.The spraying volume ratio is 1/15～1/3.5.
The rubber asphalt emulsion of using in this invention all is anionic nature when carrying out the rapid hardening spraying operation, its tensio-active agent and dispersion agent also should be anionic, usually the add-on sum of tensio-active agent and dispersion agent is unsuitable too high, account for generally that 0.05～5.0% of total material is advisable or still less, if it is too much with anion surfactant bonded quantity, perhaps both total number are too much, the capital causes when the contact coagulant solution, condense not exclusively or rate of set slows down, therefore also can cause the solid cladding that on surface of base, forms incomplete.Particularly add materials such as carbon black, porcelain powder in the A component, its total amount and technology will be controlled well and generally account for 0.0～10.0% of total material and be advisable; Like this in the process of spraying, rubber asphalt emulsion and condensing agent are in joint mixing process, thorough mixing rapidly, the moment of (3～5 seconds) just forms glued membrane on matrix, and be unlikely to have part not solidify and influence the integrity of film body, use the present invention and can improve operation quality and working efficiency (seeing the spraying coating process schema for details).
Spendable rubber comprises natural rubber latex and synthetic rubber latex in the rubber asphalt emulsion, and the rubber clone that synthetic rubber latex is adopted is: neoprene; Butadienestyrene copolymer rubber; Butadiene acrylonitrile copolymer rubber; Iso-butylene, isoprene copolymer rubber; Polybutadiene rubber etc.Consider from applicability and economy angle, preferably select the neoprene and the butadienestyrene copolymer rubber of neoprene and butadienestyrene copolymer rubber or improvement for use.Pitch among the present invention in the applicable fluid rubber bitumen emulsion is that pitch or bitumen emulsion (petroleum pitch, kerites, shale tar pitch and transformation of the way pitch etc.) consider that for economy and domestic starting material solid content the always solid amount of rubber latex and bitumen emulsion all should not be lower than 48.0%.
B component: be coagulant solution.Because domestic rubber asphalt emulsion solids content is lower, can water ratio height, water molecules emanate from the rubber asphalt emulsion moment, and to come out be key in application point of the present invention.So quick solidifying agent that the present invention is used, on original villaumite bases such as calcium chloride of using, increased the compound ferro-aluminum polymeric coagulants blended aqueous solution, molecular structure is three-dimensional arrangement, contain a plurality of metal ions on the skin, can destroy the electronic shell of the molecular surface of multifunctional liquid rubber rapidly, reach rapid agglomerative electrochemical reaction process.The difference of the villaumites such as calcium chloride that the solidification process of the present invention and the U.S. provide, added content on the basis of calcium chloride salt and make the total content variation range still at 3～18% polyvalent metal ion salt brine solution using exactly at 0.3～7.0% compound ferro-aluminum polymeric coagulants (polymerize aluminum chloride, bodied ferric sulfate), but set time is rapid, (3～5 seconds) make the multifunctional liquid rubber surface cure in a short period of time, have improved operating efficiency and have reduced the cost that meets the tendency.
The process that material of the present invention sprays on the object basal plane is: A, the B component is being prepared burden in the proportion container respectively separately in proportion, under the promotion of power control system, the rubber asphalt emulsion of A component and the condensing agent aqueous solution of B component run to separately spray gun respectively by two pipelines, two spray guns intersect the same district of the object basal plane face that needs spray of aiming at simultaneously during spraying, the moment of material ejection forms atomization process, two components continue mixing fully before arriving basal plane and by basal plane the time, contact and reaction, make all mixing of materials more even, dispersive is more reasonable, react more complete, form more uniform rubber asphalt glued membrane.Because the rate of set of material is 3～5 seconds, so two components are very short at the joint that mixes arrival spraying basal plane, are generally 350～600mm.
For reaching above-mentioned effect, the present invention proposes a kind of two-pack Airless spraying device systems of special use, and as shown in drawings: spraying coating process is to be undertaken by specific equipment shown in the drawings system.Its technical process is the continuous spraying coating process of no gas.A material or B material add storage tank 1,10 separately respectively, and in storage tank 1, A expects under the effect of pump 5, by pump 5, through discharge nozzle 7, pressurization control valve 8A (or pressurization control valve 17A), arrives spray gun 9-A mouth (or spray gun 18-D mouth) from material sucking pipes 3; The A material has multinomial output pressure recycle control valve 6 through pump 5 outlets simultaneously, and the part A material is got back in the storage tank 1 through return line 4, also the material of the A in the storage tank 1 is carried out the effect of secondary blended when this process plays steady pressure and dominant discharge.In storage tank 10, B expects under the effect of B pump 14, by B pump 14, arrives spray gun 9-B mouth (or spray gun 18-C mouth) through discharge nozzle 16, pressurization control valve 8B (or pressurization control valve 17B) from material sucking pipes 12; Simultaneously the B material has multinomial output pressure recycle control valve 15 through pump 14 outlets, and part B material is got back in the storage tank 10 through return line 13, when this process plays steady pressure and dominant discharge also the B material to storage tank 10 carry out the effect of secondary blended.A component, B component arrive spray gun 9-A mouth, spray gun 9-B mouth or spray gun 18-D mouth, spray gun 18-C mouth respectively simultaneously, and the adjustable angle of Spray gun nozzle can be adjusted angle and the joint distance from the scope of operation according to the difference of the scope of operation; Angular dimension will be according to the practical situation adjustment but two rifles slope inwardly; Be sprayed on respectively on the different object basal plane on metope 19 or ground 20, form uniform rubber glued membrane 21,22; Also can adopt two groups of above spray guns to carry out spraying application; Metal filter screen 2,11 is housed respectively on the mouth of pipe of material sucking pipes 3 and material sucking pipes 12; Adjust pressurization control valve 8A, 8B (or adjusting pressurization control valve 17A, 17B) and multinomial output return pressure control valve 6, multinomial output return pressure control valve 15 and reach two-ways regulation control spraying flow, once make the spraying glued membrane reach the thickness (seeing embodiment and spraying coating process schema for details) of 0.2～4.0mm; The spraying equipment that uses among the present invention is a special-purpose two component Airless spraying system, and the A pump is 1/10～2/3 with the design capacity ratio of B pump; Spraying machine working pressure range: 0.1MPa～5.0MPa.
Use technology of the present invention, solidified rapidly in 3～5 seconds during spraying, the spraying material is determined and is not had trickling, behind the 24-48h, and the coating drying, the surface is evenly smooth, and 168h tests by standard the physical and chemical performance and the index of the rubber glued membrane of spraying, consequently:
Cohesiveness ... stripping strength: according to the ASTM903 standard, material is not peeled off from matrix.
Extensibility ... unit elongation has excellent unit elongation according to the GB/T16777-1997.7 standard.
Anti-pierceability test GB12952-91 does not seep water.
Compared with prior art, the outstanding advantage that the present invention has is: (1) raw material is easy to get: the rubber asphalt emulsion that contains 80% solid matter in the used injection rubber asphalt emulsion components of US 4287848 at least, this very harsh to basic raw material requirement condition, China market can't obtain.What the present invention used is the very common product-solid content of China market 48.0～60.0%, can make the bitumen emulsion solid content reach 70.0～75.0% under the laboratory condition, and the rubber latex solid content can reach 65%; The reduction of only this item expense of raw materials can make production cost significantly reduce.(2) prescription is advanced: can solidify main raw material (rubber latex in the content 2.0～65.0% rapidly in the very short time in order to make jetting material; Bitumen emulsion accounts for 30.0～98.0% of total amount, and solid content is 48.0～75.0% fluid rubber bitumen emulsion) particularly add carbon black, fine powder material etc. in the A component and further improved product performance; The condensing agent of B component is calcium chloride, sodium-chlor, compound ferro-aluminum polymerization polyvalent metal salt brine solution or calcium chloride-compound ferro-aluminum polymkeric substance composition metal salt brine solution, reach and shortened the setting time of prior art, the continuous site operation that more helps shortening stoppage time, even do not stop work.(3) the rubber glue film performance that forms of spraying is superior: its adhesive property, unit elongation, water resistance, corrosion-resistant, self-healing performance are all very good, and no matter being to use ASTM still be that Chinese Industrial Standards (CIS) is tested and is not always the case.(4) use range is wide: not only can obtain extraordinary effect in traditional waterproofing work, and the chemical anticorrosion that never sets foot in of prior art, reduce aspects such as noise protection effect remarkable.(5) equipment advanced person, easy to use: can big area construct simultaneously, shorten the engineering time, an Airless spraying specific equipment system during multiple gun construction, can be equipped with 3～4 of skilled operation skilled workers, and operation 8 hours can be finished waterproof homework 3000～5000m
2, be 10 times of traditional technology operating efficiency, shortened construction period, simultaneously also can the dexterous construction of small area, do not take big working-yard area.(6) when coating thickness during greater than 1mm, quantity for spray 1.5～2.5kg/m
2Whole production link and application process environmental protection do not have any obnoxious flavour (VOC) and constitute the material that directly people and animals is damaged, and operation field does not have waste and three waste discharge, and the working-yard environmental protection has improved existing application art level.
Be elaborated below in conjunction with concrete example:
Description of drawings
Embodiment
The preparation of embodiment 1, fluid rubber coating and application
One technology and preparation:
1, technology: the preparation of A component rubber asphalt emulsion;
(1), natural rubber latex and synthetic rubber latex are produced: the solid content that will buy rubber latex be lower than 48～65% when needing again by the extract at low temperature method, extract solid content greater than 48～65% natural rubber anionic latex and synthetic rubber anionic emulsion, standby when being warmed up to 20～40 ℃ in the reactor of again emulsion being packed into.
(2), producing of bitumen emulsion:
In emulsified bitumen equipment, add the 80-120 pitch of 100 weight fraction and remain on 130 ℃; Add 20～45% water and 3.0～5.0% anion surfactant, temperature is 40～70 ℃, carries out high speed shear and stirs that to make solid content be 50.0～75.0% anionic emulsified bitumens.
(3), carbon black is produced: get certain amount of dispersant naphthalene sulfonate salt polycondensate, naphthalenesulfonate formaldehyde condensation compound, sulfonate (R-SO
3Na), 1～5 kind among Acumer9400 polymkeric substance, CD-4, the TH-904.(consumption be about carbon black mass 0.20～30.0%), elder generation's water is transferred and is opened, add the carbon black powder then, disperse fully (it is abundant together to put into grinding in ball grinder) to form stable and flowability preferably carbon black dispersion make liquid carbon black, need dry again when handling, its technology can take the electrically heated oven dry to handle, and preferably adopts spray drying treatment.The carbon black that the electrically heated oven dry is handled needs with carbon powder and the liquid carbon black that aforesaid method makes, can take wet method or dry method to store for future use again through the dry grinding powdering.
(4) fine powder material (porcelain powder or dicalcium powder) is produced: processing method is the same.
(5) the rubber asphalt emulsion is synthetic:
When emulsified bitumen is reduced to 20～40 ℃ at the liquid carbon black that adds natural rubber or synthetic rubber latex and emulsified bitumen gross weight or through the carbon powder 0.0～5.0% of modification; Make the liquid fine powder material or through the fine powder material 0.0～6.0% (porcelain powder or dicalcium powder) of modification; Nature rubber latex or synthetic rubber latex are added slowly, and adding anionic dispersing agents is 0.025～2.50%; Anion surfactant 0.025～2.50% and stirring makes the multi-functional anion liquid body rubber bitumen emulsion of solid content 50.0～75.0%.
(6), the rubber latex selected for use of foregoing description: for natural rubber, synthon rubber are: neoprene; Butadienestyrene copolymer; Butadiene acrylonitrile copolymer rubber; Iso-butylene, isoprene copolymer rubber; Rubber such as polyhutadiene.Consider from applicability economy angle, preferably select the neoprene and the butadienestyrene copolymer rubber of neoprene and butadienestyrene copolymer rubber or improvement for use.From using and the consideration of solid cladding angle, the rubber latex content in the rubber asphalt is 2.0～65.0%.
(7), pitch is 80-120 number unfilled bitumen (petroleum pitch, kerites, shale tar pitch and transformation of the way pitch)
(8), anion surfactant is: in rosined soap, synthetic fatty acid soap, alkylsulfonate, alkylbenzene sulfonate, alkyl-sulphate, alkyl aryl sulfate, the α-Nai Huangsuan salt 1～5 kind.
(9), anionic dispersing agents is: sulfonate (R-SO
3Na), 1～5 kind in TH-904, CD-4, Acumer9400 polymkeric substance, naphthalene sulfonate salt polycondensate, the naphthalenesulfonate formaldehyde condensation compound dispersion agent.
(10), carbon black is 600 orders or the thinner black or white carbon black powder of black wood charcoal.
(11), porcelain powder, dicalcium powder are 800 orders or thinner powder.
2, prescription 1:
The preparation of A component: 100kg rubber asphalt emulsion needs neoprene latex 40kg (solid content 50%); Pitch 33.0kg; Carbon black 2.0kg; Fine porcelain powder 0.75kg; Tensio-active agent is rosined soap 1.0kg, synthetic fatty acid soap 0.5kg, alkylsulfonate 0.2kg; Dispersion agent is TH-904 0.25kg, naphthalenesulfonate formaldehyde condensation compound 0.15kg, CD-4 0.15kg, and water is surplus; Making the always solid amount of A component by above-mentioned technology is 58.0% neoprene bitumen emulsion; B component condensing agent is that 10% calcium chloride, sodium-chlor, compound ferro-aluminum polymkeric substance polyvalent metal salt are put into stirred vessel, 90% soft water or the tap water that add total amount in proportion mix fully (calcium chloride content 94.50%～98.50%, sodium-chlor 0.50～2.50%, ferro-aluminum polymer/metallic salt 1～3%), or in the B component condensing agent calcium chloride one compound ferro-aluminum aqueous solutions of polymers total mass greater than 10%, when metallize protection matrix, can not select for use sodium-chlor directly to choose total content calcium chloride, ferro-aluminum polymer/metallic salt 1～7% 93.0%～99.0%.
Two spraying equipment processing methodes: on cement wall surface, adopt (accompanying drawing one) two components not have the special-purpose paint finishing equipment of gas, (the design capacity ratio of A, B pump is 6.5: 1, adjusts multinomial output pressure recycle control valve 6,15); A, B pump work pressure ratio are 6: 1; Adjust spray gun bicker degree, open pressurization control valve 8A, 8B (or pressurization control valve 17A, 17B), it is 60.28% rubber asphalt emulsion that spraying simultaneously contains solids content, the calcium chloride of content 10%, sodium-chlor, the compound ferro-aluminum polymerization polyvalent metal salt condensing agent aqueous solution.The A material is exported with 6.5 liters/minute speed, and the B material is exported with 1 liter/minute speed, and the A of spray gun 9, B muzzle slope inwardly and simultaneously same target sprayed.The parallel speed for 400mm/ second with metope of spray gun moves.The spraying back just forms the thick rubber asphalt glued membrane of 4mm on the cement wall surface.Observe pollution condition by the light cardboard that distance spray gun 800mm is provided with, found that the stain that has only seldom.If change the coating thickness of glued membrane, can finish by suitably adjusting the slope inwardly distance and the translational speed of angle and basal plane of spray gun pressurization control valve 8A, 8B (or adjustment pressurization control valve 17A, 17B) or A, B (C, D) muzzle; A, the B material that multinomial output pressure recycle control valve 6,15 has simultaneously to storage tank 1,10 carries out the effect of secondary blended.
Three, test effect: there is a certain amount of moisture to separate out in the glued membrane of generation, behind the 24h, the coating drying, the surface is evenly smooth, thickness 2.3mm.Make adhesive test behind the 168h, according to the ASTM standard: material can't be peeled off from body of wall.Use the same method, coat remover before spraying, with the drawing machine test, tension set is 2000% behind the 168h that films that makes, anti-pierceability test GB12952-91 does not seep water, and utilization GB/T16777-1997.11 impermeability test standard 0.3MPa 30min is waterproof.
Material preparation: A component preparation: 100kg rubber asphalt emulsion needs the neoprene latex 19.30kg that improves; Pitch 45kg; Carbon black 2.0kg; Porcelain powder 1.0kg; Tensio-active agent is rosined soap 0.90kg, synthetic fatty acid soap 0.80kg, alkylsulfonate 0.50kg; Dispersion agent is TH-904 0.10kg, naphthalenesulfonate formaldehyde condensation compound 0.30kg, CD-4 0.10kg, and water is surplus; The always solid amount of neoprene pitch that makes the improvement of A component is 60.35% rubber asphalt emulsion; The preparation method is with embodiment 1.
B component condensing agent is 12% concentration calcium chloride-compound ferro-aluminum polymeric coagulant (calcium chloride content 94～97%, a ferro-aluminum polymer/metallic salt 3～6%), and the preparation method is with embodiment 1.
Spraying equipment processing method: with embodiment 1;
Test effect: the surface is evenly smooth, film thickness 2.0mm, glued membrane that generates behind the 168h and embodiment 1 do not have a considerable change, and the moisture that the glued membrane of generation is separated out is than embodiment 1 basically identical, unit elongation descends, and the test-results of other physical and chemical performance and embodiment 1 is basic identical.
Embodiment 3, be sprayed on the wooden boards basal plane
The material preparation: the preparation of A component: 100kg rubber asphalt emulsion needs neoprene latex 37.5kg; Pitch 35.0kg; Liquid carbon black 2.0kg; Tensio-active agent rosined soap 0.55kg, synthetic fatty acid soap 0.5kg, alkylsulfonate 0.2kg, alkyl aryl sulfate 0.2kg, α-Nai Huangsuan salt alkylsulfonate 0.30kg; Dispersion agent naphthalenesulfonate formaldehyde condensation compound 0.20kg, CD-4 0.20 water are surplus; Make the always solid amount of A component and be 57.9% neoprene bitumen emulsion, the preparation method is with embodiment 1.
B component condensing agent 6.0% concentration calcium chloride, sodium-chlor, compound ferro-aluminum polymkeric substance polyvalent metal salt condensing agent (calcium chloride content 91.0～95.0%, sodium-chlor 1.0～3.0%, ferro-aluminum polymer/metallic salt 2.0～6.0%).
The design capacity ratio of spraying equipment processing method: A, B pump is 2/3, adjust multinomial output pressure recycle control valve 6,15, the A pumping pressure is adjusted to 1.8MPa, the B pumping pressure is adjusted to 0.3MPa, adjust the two gun slots angle that slopes inwardly, open pressurization control valve 8A, 8B (or pressurization control valve 17A, 17B), it is 59.95% rubber asphalt emulsion that spraying simultaneously contains solids content, the calcium chloride of the content 6%-compound ferro-aluminum polymeric coagulants aqueous solution.The A material is exported with 6.0 liters/minute speed, and the B material is exported with 1 liter/minute speed, and the A of spray gun 9, B muzzle slope inwardly and simultaneously same target sprayed.The parallel speed for 600mm/1.2 second with sheet material of spray gun moves.The spraying back is the average thick rubber asphalt glued membrane of 2.5mm that forms on the wooden boards surface just.A, the B material that multinomial output pressure recycle control valve 6,15 has simultaneously to storage tank 1,10 carries out the effect of secondary blended.
Test effect: the surface is evenly smooth, film thickness 2.5mm, and the effusive moisture of speed and the embodiment 1 that generate glued membrane are basic identical, and it is smooth to observe glued membrane behind the 168h, and other physical and chemical performance is with embodiment 1.
Embodiment 4, be sprayed on the non-corroding iron plate basal plane
The material preparation: the preparation of A component: the 100kg rubber latex needs neoprene latex 97.45kg; Liquid white carbon black 2.5kg; Tensio-active agent is rosined soap 0.03kg; Dispersion agent is sulfonate (R-SO
3Na) 0.02kg makes the always solid amount of A component and is 56.15% neoprene emulsion; The preparation method simplifies the bitumen production composite part among the embodiment 1, as long as the method among the embodiment 1 is pressed in liquid white carbon black, surfactant-dispersed agent, once adding stirs and gets final product.
B component condensing agent is 8.0% calcium chloride-compound ferro-aluminum polymer/metallic salt, (calcium chloride is 95.0～98.5% ferro-aluminum polymer/metallic salt 1.5～5.0%), and the preparation method is with embodiment 1.
Spraying equipment processing method: with embodiment 1;
Test effect: the surface is evenly smooth, film thickness 0.8mm, quite embodiment 1 is fast slightly for the speed of generation glued membrane, effusive moisture is identical with embodiment 1, observe the glued membrane surfacing behind the 168h, tensile strength and extensibility height, the test-results of other physical and chemical performance and embodiment 1 is basic identical, but cost improves.
The material preparation: the preparation of A component: 100kg rubber asphalt emulsion needs butadienestyrene copolymer rubber latex 19.8kg (50%); Pitch 45kg (60%); Carbon black 2.0kg; Dicalcium powder 0.45kg; Tensio-active agent is rosined soap 0.65kg, synthetic fatty acid soap 0.65kg, alkylsulfonate 0.50kg, alkyl aryl sulfate 0.25kg, α-Nai Huangsuan salt alkylbenzene sulfonate 0.20kg; Dispersion agent is Acumer 9400 polymkeric substance 0.25kg, naphthalenesulfonate formaldehyde condensation compound 0.25kg, and water is surplus; Making the always solid amount of A component is 60.1% rubber asphalt emulsion, and the preparation method is with embodiment 1.
B component condensing agent is 12.0% calcium chloride, sodium-chlor, the compound ferro-aluminum polymerization polyvalent metal salt of content, (calcium chloride is 95.0～97.0%, ferro-aluminum polymer/metallic salt 3.0～5.0%), and the preparation method is with embodiment 1.
Spraying equipment processing method: with embodiment 1;
Test effect: the surface is evenly smooth, film thickness 1.5mm, the speed of generation glued membrane quite embodiment 1 does not have considerable change, moisture of separating out and embodiment 1 basically identical, observe the glued membrane surfacing behind the 168h, unit elongation descends, and other physical and chemical performance is more identical than embodiment 1, and comprehensive cost and embodiment 2 relatively show slightly low.
Material preparation: A component preparation: 100kg rubber asphalt emulsion needs the butadienestyrene copolymer rubber latex 15.8kg that improves; Pitch 45kg; Carbon black 3.0kg; Liquid porcelain powder 3.5kg; Tensio-active agent is rosined soap 0.8kg, synthetic fatty acid soap 0.8kg, alkylsulfonate 0.65kg; Dispersion agent is TH-9040.2kg, naphthalenesulfonate formaldehyde condensation compound 0.1kg, CD-4 0.15kg, and water is surplus; Make the always solid amount of A component and be the butadienestyrene copolymer rubber asphalt emulsion of 62.10% improvement; B component condensing agent is that the concentration of calcium chloride-compound ferro-aluminum polymeric coagulants is increased to 10.0% (calcium chloride content 96.5～98.5%, sodium-chlor 0.50～2.0%, ferro-aluminum polymer/metallic salt 1.5～2.5%), and the preparation method is with embodiment 1.
Spraying equipment processing method: with embodiment 1;
Test effect: the surface is evenly smooth, film thickness 2.0mm, and the effusive moisture of the glued membrane of generation is implemented
Example 1 a little, 168h observes the glued membrane surfacing, extensibility descends obviously, other physical and chemical performance is with example 2.
The material preparation: the preparation of A component: 100kg rubber asphalt emulsion needs butadienestyrene copolymer rubber latex 44kg; Pitch 27.0kg; Carbon black 3.0kg; Liquid porcelain powder 6.0kg; Tensio-active agent is rosined soap 0.33kg, synthetic fatty acid soap 0.32kg, alkylsulfonate 0.35kg, α-Nai Huangsuan sodium 0.35kg; Dispersion agent is TH-904 0.25kg, naphthalenesulfonate formaldehyde condensation compound 0.15kg, sulfonate (R-SO
3Na) 0.25kg, water are surplus.Make the always solid amount of A component and be 60.0% butadienestyrene copolymer rubber asphalt emulsion; B component: calcium chloride, sodium-chlor, the compound ferro-aluminum polymerization polyvalent metal salt condensing agent aqueous solution 10.0% (calcium chloride is 94.0～99.0%, sodium-chlor 0.5～3.0%, ferro-aluminum polymer/metallic salt 0.50～3.0%); Reparation technology is with embodiment 1.
The spraying equipment processing method: according to the method for embodiment 1 to spraying on the wooden columnar material.
Test effect: the surface is evenly smooth, film thickness 1.8mm, dissociate the moisture that than embodiment 1 a little, 168h observes the glued membrane surfacing, tensile strength as a result and the extensibility of doing physical test have raising, other is basic identical with embodiment 1, unit cost improves.
Preparation technology and prescription: the preparation of A component: 100kg rubber asphalt emulsion needs butadienestyrene copolymer rubber latex 55kg (48%); Pitch 23.0kg; Liquid carbon black 5.0kg; Tensio-active agent is rosined soap 0.65kg, α-Nai Huangsuan sodium 0.35kg, alkylsulfonate 0.15kg; Dispersion agent is Acumer9400 polymkeric substance 0.37kg, naphthalene sulfonate salt polycondensate 0.15kg, and water is surplus; Make the always solid amount of A component and be 56.07% butadienestyrene copolymer rubber asphalt emulsion; B component: the calcium chloride-compound ferro-aluminum polymeric coagulants aqueous solution 15.0% (calcium chloride is 98.0～99.0% ferro-aluminum polymer/metallic salt 1.0～2.0%).Reparation technology is with embodiment 1.
Use and effect
The spraying equipment processing method: spraying is that spray gun rolls from bottom to top and carries out, spray gun other with embodiment 1.
Detect effect: film thickness 1.5mm, cross section 5m
2The surface is evenly smooth, and the moisture that on-the-spot glued membrane is separated out is identical with embodiment 1, observes the glued membrane drying behind the 24h, and 168h observes the glued membrane surfacing, and according to the ASTM standard: make the stripping test glued membrane and do not peel off from basic unit, extensibility, tensile strength have raising, the cost height.
One. the material preparation: A component preparation under laboratory condition: 10kg rubber asphalt emulsion needs negatively charged ion natural rubber latex 3.0kg (solid content 65%); Anionic emulsified bitumen 96.7kg (solid content 75%); Dispersion agent is that TH-904 0.1kg, naphthalenesulfonate formaldehyde condensation compound 0.05kg, tensio-active agent are rosined soap 0.05kg, synthetic fatty acid soap 0.05kg, alkylsulfonate 0.03kg, α-Nai Huangsuan salt 0.02kg.Make the always solid amount of A component and be 74.78% natural rubber bitumen emulsion, reparation technology is synthetic with (5) rubber asphalt emulsion among the embodiment 1, and other is with embodiment 1; B component: the calcium chloride-compound ferro-aluminum polymeric coagulants aqueous solution 10.0% (calcium chloride is 95.0～97.0%, sodium-chlor 1.0～2.0%, ferro-aluminum polymer/metallic salt 2.0～3.0%).
Spraying equipment processing method: with embodiment 1.
Detect effect: the surface is evenly smooth, film thickness 1.8mm, cross section 1.8m
2According to the method test of embodiment 1, do the good film-forming property as a result of physical and chemical performance test, isolated moisture is less, and unit elongation is very low, and stripping strength is with embodiment 1.
The preparation of A component: 100kg rubber asphalt emulsion needs (co) polychloroprene rubber emulsion 16.0kg, the (co) polychloroprene rubber emulsion 12.0kg of improvement; Negatively charged ion bitumen emulsion 69.6kg (solid content 48%); Carbon black 1.5kg; Tensio-active agent is rosined soap 0.30kg, synthetic fatty acid soap 0.15kg, alkylsulfonate 0.15kg; Dispersion agent is sulfonate (R-SO
3Na) 0.1kg, TH-904 0.1kg, naphthalenesulfonate formaldehyde condensation compound 0.1kg, reparation technology be with embodiment 1, makes the always solid amount of A component and be 49.8% rubber asphalt emulsion; B component: the calcium chloride-compound ferro-aluminum polymeric coagulants aqueous solution 12.0% (calcium chloride is 97.0～99.0% ferro-aluminum polymer/metallic salt 1.0～3.0%).
Spraying equipment processing method: with embodiment 1.
Detect effect: the surface is evenly smooth, film thickness 2.5mm, cross section 1.0m
2Isolated moisture is than wanting many among the embodiment 1, and 168h observes the glued membrane surfacing, and other is substantially the same manner as Example 3.
A component preparation under laboratory condition: 10kg rubber asphalt emulsion, processing method is with example 1; Make negatively charged ion (co) polychloroprene rubber emulsion 3300g, (solid content 65%); Negatively charged ion bitumen emulsion 5500g (solid content 75%); Liquid carbon black 400g; Liquid porcelain powder 500g; Tensio-active agent is rosined soap 80g, synthetic fatty acid soap 85g, alkylsulfonate 55g, α-Nai Huangsuan salt 50g; Dispersion agent is sulfonate (R-SO
3Na) 5g, naphthalene sulfonate salt polycondensate 8g, TH-904 10g, naphthalenesulfonate formaldehyde condensation compound 7g make the always solid amount of A component and are 74.70% rubber asphalt emulsion; B component condensing agent is 8.0% calcium chloride, sodium-chlor, the compound ferro-aluminum polymerization polyvalent metal salt of content, (calcium chloride is 93.0～96.50%, sodium-chlor 0.50～2.0%, ferro-aluminum polymer/metallic salt 3.0～5.0%), and the preparation method is with embodiment 1.
Spraying equipment processing method: with embodiment 3.
Detect effect: the surface is evenly smooth, film thickness 2.3mm, cross section 1.0m
2Isolated moisture be than will reduce a lot among the embodiment 1, and 168h observes the glued membrane surfacing, and intensity increases that other is substantially the same manner as Example 3.
A component preparation under laboratory condition: 10kg rubber asphalt emulsion, processing method is with example 1; Make butadienestyrene copolymer negatively charged ion rubber latex 2000g, iso-butylene, isoprene copolymer rubber latex 1500g, (solid content is 65%) method for making two latex in the time of 20～40 ℃ add reactor and stir stand-by; Negatively charged ion bitumen emulsion 6220g (solid content 75%); Liquid carbon black 250g; Tensio-active agent is that rosined soap 15g, dispersion agent are sulfonate (R-SO
3Na) 15g makes the always solid amount of A component and is 72.20% rubber asphalt emulsion; B component: the calcium chloride-compound ferro-aluminum polymeric coagulants aqueous solution 12.0% (calcium chloride is 97.0～99.0% ferro-aluminum polymer/metallic salt 1.0～3.0%).
Spraying equipment processing method: the same.
Detect effect: the surface is evenly smooth, film thickness 2.3mm, cross section 1.0m
2Isolated moisture is identical than embodiment 12, and 168h observes the glued membrane surfacing, and intensity is better than embodiment 1, and flexible and recovery rate is better than embodiment 12, and other is the same.
The gas tank formula buffering strap fly-ash separator equipment of certain ammonia chloride production plant is taked traditional hand brush rubber coating technology, because the internal structure complexity is difficult to satisfy the condition of construction technology.Select rapid hardening handicraft product of the present invention for use, to ventilation installation, carried out interior anticorrosion process and handled (scope of operation is near 100 square metres), in pipeline and the gas tank is ferric oxide rust-inhibiting paint metal basal plane, directly spraying, the fluid rubber of thickness 1.8～2.0mm, and interconnecting piece has all been carried out spraying protected, there is not corrosion phenomenon in the whole plant, the glued membrane surface is evenly smooth.
Spraying equipment processing method: with embodiment 1.
Detect effect: 168h and observe surfacing, through delivery receiving acceptance according to the ASTM standard: detecting glued membrane can't peel off from basic unit.Fine by effect.The running period of prolongation equipment, save the maintenance and the fund cost of exchange device more.Chemical stability: glued membrane surface layer no change; Alkali resistance, acid resistance are according to GB/T9274; Salt fog resistance is according to GB/T1771; Humidity resistance is according to GB/T1740; Resistance to salt water is according to GB/T1763.3.1, and is all qualified.
Adopt this process materials, played certain sound insulation and noise reduction effect.Detect with sqouynd absorption lowering noise detecting instrument-RTA840 system through on-the-spot, descended before noise quite sprays 1.5 decibels (dB).
The manufacture craft spraying method is with embodiment 10.
Construction prescription: with embodiment 10.
Certain indoor swimming pool maintenance engineering adopts fluid rubber spray film rapid hardening technology, and thickness is greater than 2mm, surplus the construction area 500 square metre since at that time in the indoor swimming pool the higher basal plane of temperature and room temperature, between 25～30 ℃, very suitablely spray film and construct near consistent.
Spraying equipment processing method: with embodiment 3.At these special environments for use of swimming pool, in order to satisfy the swimming pool particular requirement, the uncertainty of considering the various chemical materialss of basic unit as: the resin waterproof layer of renovation swimming pool and the cement basic layer alkaline substance too high levels of overhauling are wet excessively, clean and other impurity of base treatment is to the influence of rapid hardening technology etc., can be before the spraying of rapid hardening technology, thin bilge construction to swimming pool is taked artificial brushing, also can directly use special-purpose two group Airless spraying system devices to carry out A group single component spraying operation, or other spraying media processes, this operation is to adopt the A component of embodiment 10 to carry out the list group to use.As long as close pressurization control valve 8B or 17B switch the pressurization control valve 8A of special-purpose paint finishing equipment of the present invention or 17A switch opens this moment, aims at the basal plane that will spray as stated above and carry out operation; At this moment also to note adjusting pressurization control valve 8A, or 17A and multinomial output pressure recycle control valve 6, or 15 carry out two-ways regulation control and reach suitable spraying flow/pressure, can once make the spraying film thickness is below 0.15～0.30mm, note avoiding the materials flow of A group to hang phenomenon, cut the waste and guarantee the glued membrane quality, this swimming pool facade once sprays mean thickness less than 0.2mm, slightly shift to an earlier date time of drying than artificial brushing paint the time of drying of glued membrane, but the quality of spraying is far above artificial brushing technique, and performance after the film forming and two-component spraying rapid hardening technology are without any difference.The glued membrane surface drying can adopt the spray coating constructing technique of embodiment 3 to carry out normal spraying operation in 8 hours.
Test effect: the surface is evenly smooth, once single group sprays and the bonding one of the two group spraying glued membranes of secondary, total thickness 2.0mm, and the effusive moisture of speed of two groups of spraying generation glued membranes is identical with embodiment 3, it is smooth to observe glued membrane behind the 168h, and other physical and chemical performance is with embodiment 10.
Detect effect: with embodiment 10.
Claims (11)
1. a multifunctional liquid rubber spray-coating material is divided into A, B two components, and the A component is an anion liquid body rubber bitumen emulsion, and the B component is a coagulant solution, during use two components is sprayed on simultaneously and is frozen into the rubber asphalt glued membrane on the same basal plane immediately; It is characterized in that two components are made up of following raw material:
A component: be the fluid rubber bitumen emulsion, solid content 50～75%; Wherein: rubber latex 3～65%, bitumen emulsion 30.0～97.0%, carbon black are 0.00～5.0%, superfine powder 0.0～6.0%, anionic dispersing agents 0.025～2.5%, anion surfactant 0.025～3.0% is the water-based spray material;
Wherein said: the solid content of rubber latex is 48～65%; The solid content of bitumen emulsion is 50.0～75.0%;
Rubber in the rubber latex in the described A component is selected from natural rubber or synthetic rubber; Synthetic rubber is selected from: (co) polychloroprene rubber; Butadienestyrene copolymer rubber; Butadiene acrylonitrile copolymer rubber; Iso-butylene, isoprene copolymer rubber; Polybutadiene rubber; Pitch in the bitumen emulsion is selected from: petroleum pitch, coal-tar pitch, shale tar pitch or transformation of the way pitch; Carbon black is fineness 600 orders or thinner carbon powder or white carbon black powder; Fine powder material is fineness 800 orders or thinner porcelain powder or dicalcium powder; Anionic dispersing agents is selected from sulfonate, 1～5 kind of combination in TH-904, Acumer9400 polymkeric substance, CD-4, naphthalene sulfonate salt polycondensate, the naphthalenesulfonate formaldehyde condensation compound; Anion surfactant is selected from 1～5 kind of combination in rosined soap, synthetic fatty acid soap, alkylsulfonate, sodium alkyl benzene sulfonate, alkyl-sulphate, alkyl aryl sulfate, the α-Nai Huangsuan sodium;
B component: be condensing agent, by the aqueous solution of the concentration 3.0～18.0% of calcium chloride, sodium-chlor, the preparation of compound ferro-aluminum polymkeric substance polyvalent metal salt; Wherein contain calcium chloride 90.0～99.2%, sodium chloride-containing 0.50～3.0%, contain compound ferro-aluminum polymkeric substance 0.3～7.0%; Compound ferro-aluminum polymkeric substance is polymerize aluminum chloride and bodied ferric sulfate;
Adopt two component Airless spraying system devices, the spraying volume ratio of B component, A component is 1/15～1/3.5;
Rubber glued membrane coating thickness: a 0.50～4.0mm, unit elongation is good, cohesiveness-stripping strength: material is not peeled off from matrix, has temperature tolerance, weathering resistance, chemical stability and adiabatic noise reduction and anti-flaming function, anti-pierceability test is not seeped water.
2. multifunctional liquid rubber spray-coating material according to claim 1 is characterized in that rubber clone in the fluid rubber bitumen emulsion of A component is 1～2 kind that selects for use in the neoprene of neoprene, butadienestyrene copolymer rubber or improvement or the butadienestyrene copolymer rubber.
3. multifunctional liquid rubber spray-coating material according to claim 1, the fluid rubber bitumen emulsion medium pitch that it is characterized in that the A component are 80～No. 120 petroleum pitch and emulsion thereof.
4. the synthetic method for making of multifunctional liquid rubber emulsion according to claim 1, the preparation method who it is characterized in that A component rubber asphalt emulsion in the liquid rubber spray-coating material adds carbon black, fine powder material under stirring during at 20～40 ℃ in the emulsified bitumen temperature, then nature rubber latex or synthetic rubber latex are added slowly, stirring makes; The method for making of B component is: in proportion that calcium chloride and compound ferro-aluminum polymkeric substance is soluble in water, stir.
5. the method for making of multifunctional liquid rubber spray-coating material according to claim 1, it is characterized in that in the liquid rubber spray-coating material A component, natural rubber latex and its solid content of synthetic rubber latex are lower than at 48～65% o'clock, can pass through the extract at low temperature method, when temperature is controlled at 5～-3 ℃, extract solid content and reach at 48～65% o'clock, standby when being warmed up to 20～40 ℃ in the reactor of again latex being packed into.
6. the method for making of multifunctional liquid rubber spray-coating material according to claim 1 is characterized in that in the liquid rubber spray-coating material A component that described carbon black, fine powder material are liquid carbon black, liquid fine powder material dispersion; Its preparation method is: the amount of taking is 0.20～30.00% a anionic dispersing agents of carbon black or fine powder material quality, elder generation's water is transferred and is opened, add carbon powder or fine powder material then, it is abundant together to put into grinding in ball grinder, forms stable and flowability liquid carbon black or liquid fine powder material dispersion preferably;
7. the method for making of multifunctional liquid rubber spray-coating material according to claim 1, it is characterized in that in the liquid rubber spray-coating material A component that described carbon black, fine powder material are the dry powder of liquid carbon black, liquid fine powder material dispersion: its preparation method is: liquid carbon black, liquid fine powder material dispersion are handled or the spray-drying process processing through electric heating drying; Carbon black or fine powder material that the electrically heated oven dry is handled need once more through the dry grinding powdering.
8. the method for making of multifunctional liquid rubber spray-coating material according to claim 1, it is characterized in that B component condensing agent is that concentration is calcium chloride-compound ferro-aluminum polymeric composite metal-salt of 3.0～18.0%, in calcium chloride-compound ferro-aluminum polymeric composite metal-salt: calcium chloride 93.0～99.7%, compound ferro-aluminum polymer/metallic salt 0.3～7.0%.
9. the using method of multifunctional liquid rubber spray-coating material according to claim 1, it is characterized in that the A that to prepare, the B component is respectively charged into separately in the proportion container, under the promotion of power system, the rubber asphalt emulsion of A component and the condensing agent aqueous solution of B component run to separately spray gun respectively by two pipelines, two muzzle slope inwardly during spraying, spray angle is adjustable aims at the same district of the object basal plane face that needs spraying simultaneously, the moment of material ejection forms atomization process, two components are mixed before arriving basal plane and when arriving basal plane fully, film thereby form more uniform rubber asphalt, two components are 350～600mm in the distance of the joint that mixes the spraying face of arrival; The spraying volume ratio of calcium chloride, sodium-chlor, compound ferro-aluminum polymerization polyvalent metal salt condensing agent and rubber asphalt emulsion is 1/15～1/3.5; The promotion of described power system is the continuous spraying coating process of no gas, promptly there is not the special-purpose paint finishing device of a cover that the atmospheric pressure pump promotes spraying, the lance driving device that can be equipped with two or more sets simultaneously carries out spraying application, can carry out the spraying application of different basal planes such as roof, metope and ground simultaneously.
10. multifunctional liquid rubber spray-coating material is to adopt two-pack Airless spraying system device according to claim 1, it is characterized in that forming by following unit equipment, its function mode is: A material or B material add storage tank 1,10 separately respectively, in storage tank 1, the A material is under the effect of pump 5, from material sucking pipes 3 by pump 5, through discharge nozzle 7, pressurization control valve 8A or/and pressurization control valve 17A, to spray gun 9-A mouth or/and spray gun 18-D mouth; The A material has multinomial output pressure recycle control valve 6 through pump 5 outlets simultaneously, and the part A material is got back in the storage tank 1 through return line 4; Equally, in storage tank 10, B expects under the effect of B pump 14, from material sucking pipes 12 by B pump 14, through discharge nozzle 16, pressurization control valve 8B or/and pressurization control valve 17B to spray gun 9-B mouth or/and spray gun 18-C mouth; The B material has multinomial output pressure recycle control valve 15 through pump 14 outlets simultaneously, and part B material is got back in the storage tank 10 through return line 13; A, B component arrive spray gun 9-A mouth, spray gun 18-D mouth and spray gun 9-B mouth, spray gun 18-C mouth respectively simultaneously, and the adjustable angle of Spray gun nozzle is sprayed on respectively on the different object basal plane on metope 19 or ground 20, forms uniform rubber asphalt glued membrane 21,22; Metal filter screen 2,11 is housed respectively on the mouth of pipe of material sucking pipes 3 and material sucking pipes 12; Control and adjust pressurization control valve 8A, 8B or/pressurization control valve 17A, 17B and multinomial output pressure recycle control valve 6 and 15 reach required spraying flow by two-ways regulation and control; Can once make the spraying glued membrane reach the thickness of 0.5～4.0mm.A, the B material that multinomial output pressure recycle control valve 6,15 has simultaneously to storage tank 1,10 carries out the effect of secondary blended.
11. the equipment as multifunctional liquid rubber spray-coating material as described in the claim 10 is characterized in that the A pump 5 and the design capacity ratio of B pump 14 are 1/10～2/3; The spraying machine operating pressure is: 0.1MPa～5.0Mpa; The output capacity ratio is 1/15～1/4.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100100930A CN101235252B (en) | 2008-01-15 | 2008-01-15 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100100930A CN101235252B (en) | 2008-01-15 | 2008-01-15 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010580327 Division CN102009019B (en) | 2008-01-15 | 2008-01-15 | Special equipment for multi-functional liquid rubber coating |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101235252A true CN101235252A (en) | 2008-08-06 |
| CN101235252B CN101235252B (en) | 2011-04-20 |
Family
ID=39919167
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100100930A Expired - Fee Related CN101235252B (en) | 2008-01-15 | 2008-01-15 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101235252B (en) |
Cited By (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102287032A (en) * | 2011-07-15 | 2011-12-21 | 大连美宸特科技有限公司 | Waterproof heat insulating roof with coating |
| CN102330487A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Waterproof heat insulation roof with coating |
| CN102329564A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing zinc borate |
| CN102329570A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing antimony oxide compounds |
| CN102329569A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Rock wool-containing liquid rubber spray coating |
| CN102330473A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Gable sealing structure with coating |
| CN102329566A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | High-permeability liquid rubber spray coating |
| CN102329565A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Flyash floating bead-containing liquid rubber spray coating |
| CN102330476A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Waterproof thermal insulation wall body with coating |
| CN102329568A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing triaryl phosphate |
| CN102329567A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing hydrotalcite |
| CN102329562A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Superfine needle-shaped wollastonite powder-containing liquid rubber spray coating |
| CN102330409A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Concrete column with coating |
| CN102329563A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Aluminum hydroxide-containing liquid rubber spray coating |
| CN102337076A (en) * | 2011-07-13 | 2012-02-01 | 大连美宸特科技有限公司 | Liquid rubber spray coating containing phosphotriester |
| CN102345286A (en) * | 2011-07-14 | 2012-02-08 | 大连美宸特科技有限公司 | Waterproof anti-corrosive prestressing force solid pile with coating |
| CN102345411A (en) * | 2011-07-14 | 2012-02-08 | 大连美宸特科技有限公司 | Rust-proof anti-corrosive guardrail with coatings |
| CN102351085A (en) * | 2011-07-14 | 2012-02-15 | 大连美宸特科技有限公司 | Garbage can with coating |
| CN102372034A (en) * | 2011-07-14 | 2012-03-14 | 大连美宸特科技有限公司 | Corrosion-preventing and shock-absorbing vehicle chassis guard board with coating |
| CN102505679A (en) * | 2011-07-14 | 2012-06-20 | 大连美宸特科技有限公司 | Waterproof and anti-corrosion prestressed hollow pile with coating |
| CN102503555A (en) * | 2011-11-17 | 2012-06-20 | 大连美宸特科技有限公司 | Sewage treatment pool with coating |
| CN102518910A (en) * | 2011-07-14 | 2012-06-27 | 大连美宸特科技有限公司 | Pipeline with coating |
| CN102910878A (en) * | 2012-09-26 | 2013-02-06 | 成都嘉新科技集团有限公司 | Dry powder for cement asphalt mortar |
| CN102965018A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Nano spraying quick-setting rubber asphalt waterproof coating for metro tunnels |
| CN102965020A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting |
| CN102965014A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water-proofing material for pitched roof |
| CN102965017A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Saline-alkaline resistant spray fast-setting rubber asphalt waterproof material |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
| CN102965019A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Flame-retardant spraying quick-settling rubber asphalt waterproof paint |
| CN102965016A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | High-temperature resistant spray fast-setting rubber asphalt waterproof coating |
| CN102965015A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Anticorrosion type spraying quick-setting rubber asphalt waterproof coating |
| CN102993968A (en) * | 2012-11-30 | 2013-03-27 | 山东北方创信防水技术有限公司 | Special spraying and quick-setting rubber waterproof coating for sewage treatment plant |
| CN103003314A (en) * | 2010-08-06 | 2013-03-27 | 电气化学工业株式会社 | Polychloroprene latex, rubber-asphalt composition and construction method thereof, sheet, and waterproof coating film |
| CN103289572A (en) * | 2012-12-06 | 2013-09-11 | 侯保荣 | Dustproof waterproof protective film-forming agent |
| CN103360933A (en) * | 2013-07-22 | 2013-10-23 | 广东科顺化工实业有限公司 | Non-asphaltic waterborne spraying rapid hardening rubber waterproof paint and its manufacturing method |
| CN103396707A (en) * | 2013-07-09 | 2013-11-20 | 贵州省复合改性聚合物材料工程技术研究中心 | Color-adjusting spraying rapid-hardening liquid rubber waterproof material and using method thereof |
| CN103627258A (en) * | 2012-08-23 | 2014-03-12 | 山东北方创信防水技术有限公司 | Spraying quick-setting rubber asphalt waterproof coating material |
| CN103666260A (en) * | 2013-09-12 | 2014-03-26 | 宁波镭纳涂层技术有限公司 | Color polymer modified emulsion asphalt-base waterproof paint and preparation method thereof |
| CN103897595A (en) * | 2014-04-09 | 2014-07-02 | 苏州中材非金属矿工业设计研究院有限公司 | Spraying quickly-hardening rubber asphalt waterproof paint |
| CN104140761A (en) * | 2014-08-06 | 2014-11-12 | 苏州卓越工程塑料有限公司 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
| CN104342029A (en) * | 2013-07-31 | 2015-02-11 | 大禹伟业(北京)国际科技有限公司 | Method for preparing and applying coating waterproof material, and coating waterproof material |
| CN104403566A (en) * | 2014-11-05 | 2015-03-11 | 大禹伟业(北京)国际科技有限公司 | Electrically isolated aqueous rubber asphalt coating waterproof material and preparation and construction method |
| CN104449380A (en) * | 2014-11-05 | 2015-03-25 | 大禹伟业(北京)国际科技有限公司 | Electric insulating water-based rubber asphalt coating waterproof material and preparation and construction methods thereof |
| CN104673094A (en) * | 2013-11-28 | 2015-06-03 | 北京奥泰利新技术有限公司 | Quick-setting waterproof paint |
| CN104761970A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Radiative heat-insulation aqueous coating being good in waterproof effect and preparation method thereof |
| CN105062106A (en) * | 2015-09-11 | 2015-11-18 | 苏交科集团股份有限公司 | Asphalt-based material, preparation method and application of asphalt-based material |
| CN105888702A (en) * | 2016-05-09 | 2016-08-24 | 中国建筑第五工程局有限公司 | Waterproof construction method in underground engineering |
| CN106836683A (en) * | 2016-12-28 | 2017-06-13 | 淮北矿业(集团)工程建设有限责任公司 | A kind of construction method of Machine-made Sand aggregate dry-mixed mortar coated building metope |
| CN107476505A (en) * | 2016-02-24 | 2017-12-15 | 张日龙 | A kind of heat-insulating sound-insulating log cabin roof |
| CN107927929A (en) * | 2017-11-22 | 2018-04-20 | 宁波凯信服饰股份有限公司 | A kind of trousers |
| CN108913823A (en) * | 2018-08-31 | 2018-11-30 | 西安远方航空技术发展有限公司 | A kind of painting apparatus for ash of fur depilation |
| CN108979083A (en) * | 2018-07-30 | 2018-12-11 | 广东宏穗晶科技服务有限公司 | A kind of multi-angle indoor spraying robot |
| CN109401624A (en) * | 2018-10-22 | 2019-03-01 | 广州市鲁班建筑科技集团股份有限公司 | A kind of watersoluble modified asphalt waterproofing paint of thixotropic and preparation method thereof |
| CN109675686A (en) * | 2018-11-29 | 2019-04-26 | 刘永 | A kind of material filling method improving ball mill grinding efficiency |
| US10814643B2 (en) | 2008-10-24 | 2020-10-27 | Dürr Systems Ag | Coating device and associated coating method |
| CN111944423A (en) * | 2020-07-13 | 2020-11-17 | 大禹伟业(北京)国际科技有限公司 | Flame-retardant water-based non-cured rubber asphalt waterproof coating and preparation and construction methods thereof |
| CN114149747A (en) * | 2021-12-20 | 2022-03-08 | 重庆中防德邦防水技术有限公司 | Self-heating double-component emulsified asphalt coating, preparation method and use method thereof |
| CN114213908A (en) * | 2022-01-04 | 2022-03-22 | 青岛新华友建工集团股份有限公司 | Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof |
| CN114737780A (en) * | 2022-04-12 | 2022-07-12 | 湖南教建集团有限公司 | Premixed mortar thin plastering construction method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3785852A (en) * | 1972-05-10 | 1974-01-15 | Tremco Mfg Co | Bituminous emulsion-rubber latex compositions and method of depositing coagula therefrom |
| DE10245708A1 (en) * | 2002-10-01 | 2004-04-15 | Remmers Baustofftechnik Gmbh | spray-On waterproofing |
| CN1962782A (en) * | 2005-11-10 | 2007-05-16 | 沈阳蓝光新型防水材料有限公司 | Aqueous asphalt-based root-protecting waterproof coating and method for preparing same |
-
2008
- 2008-01-15 CN CN2008100100930A patent/CN101235252B/en not_active Expired - Fee Related
Cited By (73)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US10814643B2 (en) | 2008-10-24 | 2020-10-27 | Dürr Systems Ag | Coating device and associated coating method |
| US11241889B2 (en) | 2008-10-24 | 2022-02-08 | Dürr Systems GmbH | Coating device and associated coating method |
| CN103003314B (en) * | 2010-08-06 | 2016-06-01 | 电化株式会社 | Polychloroprene latex, rubber-containing bituminous composition and construction method, thin slice and waterproof coating |
| US9321937B2 (en) | 2010-08-06 | 2016-04-26 | Denka Company Limited | Polychloroprene latex, rubber-asphalt composition and utilization method thereof, sheet, and waterproof coating film |
| CN103003314A (en) * | 2010-08-06 | 2013-03-27 | 电气化学工业株式会社 | Polychloroprene latex, rubber-asphalt composition and construction method thereof, sheet, and waterproof coating film |
| CN102329566A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | High-permeability liquid rubber spray coating |
| CN102329569A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Rock wool-containing liquid rubber spray coating |
| CN102329565A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Flyash floating bead-containing liquid rubber spray coating |
| CN102329570A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing antimony oxide compounds |
| CN102329568A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing triaryl phosphate |
| CN102329567A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing hydrotalcite |
| CN102329562A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Superfine needle-shaped wollastonite powder-containing liquid rubber spray coating |
| CN102329564A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Liquid rubber spray paint containing zinc borate |
| CN102329563A (en) * | 2011-07-13 | 2012-01-25 | 大连美宸特科技有限公司 | Aluminum hydroxide-containing liquid rubber spray coating |
| CN102337076A (en) * | 2011-07-13 | 2012-02-01 | 大连美宸特科技有限公司 | Liquid rubber spray coating containing phosphotriester |
| CN102330476A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Waterproof thermal insulation wall body with coating |
| CN102518910B (en) * | 2011-07-14 | 2015-09-30 | 大连美宸特环保节能产品有限公司 | A kind of pipeline of coating |
| CN102351085A (en) * | 2011-07-14 | 2012-02-15 | 大连美宸特科技有限公司 | Garbage can with coating |
| CN102372034A (en) * | 2011-07-14 | 2012-03-14 | 大连美宸特科技有限公司 | Corrosion-preventing and shock-absorbing vehicle chassis guard board with coating |
| CN102505679A (en) * | 2011-07-14 | 2012-06-20 | 大连美宸特科技有限公司 | Waterproof and anti-corrosion prestressed hollow pile with coating |
| CN102345411A (en) * | 2011-07-14 | 2012-02-08 | 大连美宸特科技有限公司 | Rust-proof anti-corrosive guardrail with coatings |
| CN102518910A (en) * | 2011-07-14 | 2012-06-27 | 大连美宸特科技有限公司 | Pipeline with coating |
| CN102330487A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Waterproof heat insulation roof with coating |
| CN102345286A (en) * | 2011-07-14 | 2012-02-08 | 大连美宸特科技有限公司 | Waterproof anti-corrosive prestressing force solid pile with coating |
| CN102330409A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Concrete column with coating |
| CN102330473A (en) * | 2011-07-14 | 2012-01-25 | 大连美宸特科技有限公司 | Gable sealing structure with coating |
| CN102287032A (en) * | 2011-07-15 | 2011-12-21 | 大连美宸特科技有限公司 | Waterproof heat insulating roof with coating |
| CN102503555A (en) * | 2011-11-17 | 2012-06-20 | 大连美宸特科技有限公司 | Sewage treatment pool with coating |
| CN103627258B (en) * | 2012-08-23 | 2015-01-07 | 山东北方创信防水技术有限公司 | Spraying quick-setting rubber asphalt waterproof coating material |
| CN103627258A (en) * | 2012-08-23 | 2014-03-12 | 山东北方创信防水技术有限公司 | Spraying quick-setting rubber asphalt waterproof coating material |
| CN102910878A (en) * | 2012-09-26 | 2013-02-06 | 成都嘉新科技集团有限公司 | Dry powder for cement asphalt mortar |
| CN102910878B (en) * | 2012-09-26 | 2014-05-21 | 成都嘉新科技集团有限公司 | Dry powder for cement asphalt mortar |
| CN102965017B (en) * | 2012-11-30 | 2016-01-20 | 山东北方创信防水技术有限公司 | Salt tolerant alkaline spraying rapid hardening rubber-asphalt waterproof material |
| CN102965020A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
| CN102965016B (en) * | 2012-11-30 | 2016-01-20 | 山东北方创信防水技术有限公司 | High temperature resistant type spraying rapid hardening rubber asphalt waterproof coating |
| CN102993968A (en) * | 2012-11-30 | 2013-03-27 | 山东北方创信防水技术有限公司 | Special spraying and quick-setting rubber waterproof coating for sewage treatment plant |
| CN102965019A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Flame-retardant spraying quick-settling rubber asphalt waterproof paint |
| CN102965015A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Anticorrosion type spraying quick-setting rubber asphalt waterproof coating |
| CN102965019B (en) * | 2012-11-30 | 2015-09-09 | 山东北方创信防水技术有限公司 | Flame retardant type spraying rapid hardening rubber asphalt waterproof coating |
| CN102965017A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Saline-alkaline resistant spray fast-setting rubber asphalt waterproof material |
| CN102965016A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | High-temperature resistant spray fast-setting rubber asphalt waterproof coating |
| CN102965020B (en) * | 2012-11-30 | 2015-06-17 | 山东北方创信防水技术有限公司 | Root-resistance spraying rapid-hardening rubber asphalt water-proofing material for planting |
| CN102965014A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water-proofing material for pitched roof |
| CN102965018A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Nano spraying quick-setting rubber asphalt waterproof coating for metro tunnels |
| CN103289572A (en) * | 2012-12-06 | 2013-09-11 | 侯保荣 | Dustproof waterproof protective film-forming agent |
| CN103396707B (en) * | 2013-07-09 | 2015-07-08 | 贵州省复合改性聚合物材料工程技术研究中心 | Color-adjusting spraying rapid-hardening liquid rubber waterproof material and using method thereof |
| CN103396707A (en) * | 2013-07-09 | 2013-11-20 | 贵州省复合改性聚合物材料工程技术研究中心 | Color-adjusting spraying rapid-hardening liquid rubber waterproof material and using method thereof |
| CN103360933B (en) * | 2013-07-22 | 2016-01-20 | 广东科顺化工实业有限公司 | Non-bituminous water-based spraying rapid hardening rubber water-proof paint and preparation method thereof |
| CN103360933A (en) * | 2013-07-22 | 2013-10-23 | 广东科顺化工实业有限公司 | Non-asphaltic waterborne spraying rapid hardening rubber waterproof paint and its manufacturing method |
| CN104342029A (en) * | 2013-07-31 | 2015-02-11 | 大禹伟业(北京)国际科技有限公司 | Method for preparing and applying coating waterproof material, and coating waterproof material |
| CN104342029B (en) * | 2013-07-31 | 2017-12-05 | 大禹伟业(北京)国际科技有限公司 | Method and coating film waterproof material for the coating film waterproof material for preparing and construct |
| CN103666260B (en) * | 2013-09-12 | 2016-05-11 | 宁波镭纳涂层技术有限公司 | Colored modified-high polymer emulsion type asphaltic base water-repellent paint and preparation method thereof |
| CN103666260A (en) * | 2013-09-12 | 2014-03-26 | 宁波镭纳涂层技术有限公司 | Color polymer modified emulsion asphalt-base waterproof paint and preparation method thereof |
| CN104673094A (en) * | 2013-11-28 | 2015-06-03 | 北京奥泰利新技术有限公司 | Quick-setting waterproof paint |
| CN103897595A (en) * | 2014-04-09 | 2014-07-02 | 苏州中材非金属矿工业设计研究院有限公司 | Spraying quickly-hardening rubber asphalt waterproof paint |
| CN104140761A (en) * | 2014-08-06 | 2014-11-12 | 苏州卓越工程塑料有限公司 | Sprayed rapid hardening rubber asphalt water-proof material used in severe cold areas |
| CN104403566A (en) * | 2014-11-05 | 2015-03-11 | 大禹伟业(北京)国际科技有限公司 | Electrically isolated aqueous rubber asphalt coating waterproof material and preparation and construction method |
| CN104449380A (en) * | 2014-11-05 | 2015-03-25 | 大禹伟业(北京)国际科技有限公司 | Electric insulating water-based rubber asphalt coating waterproof material and preparation and construction methods thereof |
| CN104761970A (en) * | 2015-03-18 | 2015-07-08 | 蚌埠市高华电子有限公司 | Radiative heat-insulation aqueous coating being good in waterproof effect and preparation method thereof |
| CN105062106A (en) * | 2015-09-11 | 2015-11-18 | 苏交科集团股份有限公司 | Asphalt-based material, preparation method and application of asphalt-based material |
| CN107476505A (en) * | 2016-02-24 | 2017-12-15 | 张日龙 | A kind of heat-insulating sound-insulating log cabin roof |
| CN105888702A (en) * | 2016-05-09 | 2016-08-24 | 中国建筑第五工程局有限公司 | Waterproof construction method in underground engineering |
| CN106836683A (en) * | 2016-12-28 | 2017-06-13 | 淮北矿业(集团)工程建设有限责任公司 | A kind of construction method of Machine-made Sand aggregate dry-mixed mortar coated building metope |
| CN107927929A (en) * | 2017-11-22 | 2018-04-20 | 宁波凯信服饰股份有限公司 | A kind of trousers |
| CN108979083A (en) * | 2018-07-30 | 2018-12-11 | 广东宏穗晶科技服务有限公司 | A kind of multi-angle indoor spraying robot |
| CN108913823A (en) * | 2018-08-31 | 2018-11-30 | 西安远方航空技术发展有限公司 | A kind of painting apparatus for ash of fur depilation |
| CN109401624A (en) * | 2018-10-22 | 2019-03-01 | 广州市鲁班建筑科技集团股份有限公司 | A kind of watersoluble modified asphalt waterproofing paint of thixotropic and preparation method thereof |
| CN109675686A (en) * | 2018-11-29 | 2019-04-26 | 刘永 | A kind of material filling method improving ball mill grinding efficiency |
| CN111944423A (en) * | 2020-07-13 | 2020-11-17 | 大禹伟业(北京)国际科技有限公司 | Flame-retardant water-based non-cured rubber asphalt waterproof coating and preparation and construction methods thereof |
| CN114149747A (en) * | 2021-12-20 | 2022-03-08 | 重庆中防德邦防水技术有限公司 | Self-heating double-component emulsified asphalt coating, preparation method and use method thereof |
| CN114213908A (en) * | 2022-01-04 | 2022-03-22 | 青岛新华友建工集团股份有限公司 | Ultralow-temperature flame-retardant quick-setting spraying rubber asphalt waterproof paint and construction method thereof |
| CN114737780A (en) * | 2022-04-12 | 2022-07-12 | 湖南教建集团有限公司 | Premixed mortar thin plastering construction method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101235252B (en) | 2011-04-20 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101235252B (en) | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device | |
| CN102009019B (en) | Special equipment for multi-functional liquid rubber coating | |
| CN102329566A (en) | High-permeability liquid rubber spray coating | |
| CN105948617B (en) | A kind of cracking resistance, impervious mortar and preparation method thereof | |
| CN101407687B (en) | Quick-drying type composite water-proof paint and preparation thereof | |
| CN107868616A (en) | One kind spraying rapid hardening rubber asphalt waterproof coating and preparation method thereof | |
| CN1753960A (en) | Coating, its purposes and the method that applies this coating | |
| CN102329562A (en) | Superfine needle-shaped wollastonite powder-containing liquid rubber spray coating | |
| CN103508709B (en) | The autoclaved aerated concrete slab preparation method of reinforced steel bar rust preventing coating | |
| CN1931952A (en) | Waterproof adhesive powder composition and its prepn process | |
| CN104529526A (en) | Emulsion type concrete curing agent and prepration method thereof | |
| CN101880495A (en) | Method for preparing water-based natural rubber waterproofing coating | |
| CN105735546A (en) | Construction method for constructing light-steel house roof with industrial by-product gypsum as binding material | |
| CN102329568A (en) | Liquid rubber spray paint containing triaryl phosphate | |
| CN104404502A (en) | Phosphate based steel rebar anticorrosive coating | |
| CN107973565B (en) | Anti-corrosion and anti-freezing mortar and preparation method thereof | |
| CN107955536A (en) | A kind of liquid rubber spray-coating material | |
| CN109386149A (en) | A kind of construction method of gymnasium grandstand | |
| CN102337076A (en) | Liquid rubber spray coating containing phosphotriester | |
| CN108252260B (en) | A kind of anti-maintenance construction method degraded | |
| CN102796432A (en) | High-molecular nanometer elastic mud | |
| CN105199585A (en) | Novel polyurethane waterproof coating | |
| CN112831205A (en) | Toilet waterproof coating and preparation method and application thereof | |
| CN107964364A (en) | A kind of liquid rubber spray-coating material | |
| CN105131620A (en) | Manufacturing process of building environment-friendly waterproof material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110420 Termination date: 20220115 |