CN102337076A - Liquid rubber spray coating containing phosphotriester - Google Patents
Liquid rubber spray coating containing phosphotriester Download PDFInfo
- Publication number
- CN102337076A CN102337076A CN2011101958279A CN201110195827A CN102337076A CN 102337076 A CN102337076 A CN 102337076A CN 2011101958279 A CN2011101958279 A CN 2011101958279A CN 201110195827 A CN201110195827 A CN 201110195827A CN 102337076 A CN102337076 A CN 102337076A
- Authority
- CN
- China
- Prior art keywords
- component
- phosphotriester
- rubber
- spray
- liquid rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 103
- 239000005060 rubber Substances 0.000 title claims abstract description 101
- 239000007788 liquid Substances 0.000 title claims abstract description 80
- 238000005507 spraying Methods 0.000 title claims abstract description 79
- 239000000839 emulsion Substances 0.000 claims abstract description 48
- 239000010426 asphalt Substances 0.000 claims abstract description 41
- 150000001450 anions Chemical class 0.000 claims abstract description 26
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 20
- 239000001110 calcium chloride Substances 0.000 claims abstract description 20
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 20
- 239000002270 dispersing agent Substances 0.000 claims abstract description 12
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 10
- 239000000701 coagulant Substances 0.000 claims abstract description 9
- 239000007787 solid Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 77
- 150000001875 compounds Chemical class 0.000 claims description 33
- 229910052782 aluminium Inorganic materials 0.000 claims description 27
- 239000000843 powder Substances 0.000 claims description 22
- 239000006229 carbon black Substances 0.000 claims description 19
- 239000007864 aqueous solution Substances 0.000 claims description 18
- 239000000126 substance Substances 0.000 claims description 15
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 14
- 125000000129 anionic group Chemical group 0.000 claims description 13
- 229920000126 latex Polymers 0.000 claims description 12
- 229920001577 copolymer Polymers 0.000 claims description 11
- 239000000344 soap Substances 0.000 claims description 11
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims description 10
- 239000000243 solution Substances 0.000 claims description 8
- 238000009833 condensation Methods 0.000 claims description 7
- 230000005494 condensation Effects 0.000 claims description 7
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000011301 petroleum pitch Substances 0.000 claims description 7
- 239000011295 pitch Substances 0.000 claims description 7
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 6
- 239000000194 fatty acid Substances 0.000 claims description 6
- 229930195729 fatty acid Natural products 0.000 claims description 6
- 150000004665 fatty acids Chemical class 0.000 claims description 6
- 229910052573 porcelain Inorganic materials 0.000 claims description 6
- 239000012530 fluid Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229920002449 FKM Polymers 0.000 claims description 4
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 4
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 4
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 4
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 4
- 229920002857 polybutadiene Polymers 0.000 claims description 4
- RUKCSZJSODAPHD-UHFFFAOYSA-N 3-ethenylpenta-1,3-diene Chemical group CC=C(C=C)C=C RUKCSZJSODAPHD-UHFFFAOYSA-N 0.000 claims description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 3
- 239000011294 coal tar pitch Substances 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- -1 sodium alkyl benzene Chemical class 0.000 claims description 3
- 239000011271 tar pitch Substances 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 239000000806 elastomer Substances 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 238000002156 mixing Methods 0.000 abstract description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract 1
- CYUOWZRAOZFACA-UHFFFAOYSA-N aluminum iron Chemical compound [Al].[Fe] CYUOWZRAOZFACA-UHFFFAOYSA-N 0.000 abstract 1
- 239000003945 anionic surfactant Substances 0.000 abstract 1
- 239000002131 composite material Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 238000000576 coating method Methods 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 239000007921 spray Substances 0.000 description 13
- 239000012528 membrane Substances 0.000 description 12
- 238000000034 method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 6
- 230000001070 adhesive effect Effects 0.000 description 6
- 238000010276 construction Methods 0.000 description 4
- 229920006174 synthetic rubber latex Polymers 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 238000005272 metallurgy Methods 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010073 coating (rubber) Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- AICOOMRHRUFYCM-ZRRPKQBOSA-N oxazine, 1 Chemical compound C([C@@H]1[C@H](C(C[C@]2(C)[C@@H]([C@H](C)N(C)C)[C@H](O)C[C@]21C)=O)CC1=CC2)C[C@H]1[C@@]1(C)[C@H]2N=C(C(C)C)OC1 AICOOMRHRUFYCM-ZRRPKQBOSA-N 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a liquid rubber spray coating containing phosphotriester, which relates to the technical field of spray coatings. The liquid rubber spray coating containing phosphotriester comprises component A and component B, wherein, the component A is anion liquid rubber asphalt emulsion, and the component B is a solution of a coagulant. The weight of solid content of the anion liquid rubber asphalt emulsion of the component A is 50 to 75% by mass, wherein, the weight of ingredients in the anion liquid rubber asphalt emulsion is as follows: rubber emulsion 1 to 35%, asphalt emulsion 10 to 50%, an anion dispersant 0.01 to 2%, an anionic surfactant 0.01 to 2%, phosphotriester 1 to 60%, aluminum hydroxide 1 to 20% and a silane coupling agent 0.1 to 10%. The component B is a solution with a concentration of 3 to 18% by mass prepared by mixing calcium chloride and composite aluminum-iron polymer. According to the invention, phosphotriester is added into the spray coating, and the spray coating has the properties of self-extinguishment, weatherability and antistatic performance.
Description
Technical field
The present invention relates to the spray material technical field, specifically be meant a kind of liquid rubber spray-coating material that contains phosphotriester.
Background technology
Spray material is used and extensively, is not only related to building field, also relates to each technical fields such as chemical industry, daily life.People hope to provide and multi-functional novel spraying material such as a kind of anticorrosion, waterproof, protection, adiabatic heat-insulation, thin sound noise reduction occur.Though CN101235252 discloses a kind of spray material, solved some technical barriers among the US4287242, its side or performance do not reach the ideal effect, have brought very big resistance to practical application, make the scope of application of its spray material seriously limited.
Summary of the invention
The present invention is in order to solve above-mentioned technical barrier; Providing a kind of can solidify rapidly; And the coating after solidifying not only has the effect of certain elasticity, intensity, anticorrosion, waterproof, insulation; And have a self-extinguishing, the liquid rubber spray-coating material that contains phosphotriester of weathering resistance, winter hardiness, static resistance.
The present invention to achieve these goals, the technical scheme that is adopted does, a kind of liquid rubber spray-coating material that contains phosphotriester is provided, the said liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; Said A component is an anion liquid body rubber bitumen emulsion; Said B component is a coagulant solution;
Said A component is represented with mass percent, and fluid rubber bitumen emulsion weight solid content is 50-75%; Wherein, rubber latex 1-35%, bitumen emulsion 10-50%; Anionic dispersing agents 0.01-2%, AS 0.01-2%, phosphotriester 1-60%; White lake 1-20%, silane coupling agent 0.1-10%;
Said B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
Saidly contain the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
Rubber in the rubber latex of said A component is tree elastomer or viton; Said viton is selected from (co) polychloroprene rubber, butadienestyrene copolymer rubber, the fine copolymer rubber of divinyl propylene, iso-butylene, isoprene copolymer rubber, one or more in the polybutadiene rubber;
Pitch in the bitumen emulsion of said A component is selected from petroleum pitch, coal-tar pitch, shale tar pitch, one or more in the transformation of the way pitch;
The anionic dispersing agents of said A component is selected from vitriol, TH-904, Acumer940 polymkeric substance, CD-4, naphthalene sulfonate salt polycondensate, one or more in the naphthalenesulfonate formaldehyde condensation compound;
The AS of said A component is selected from rosined soap, synthetic fatty acid soap, AS, sodium alkyl benzene sulfonate, alkyl-sulphate, alkyl aryl sulfate, one or more in α-sodium naphthalene sulfonate.
Said B component is preferably, and representes with mass percent, is 3-18% the aqueous solution by 93-99.7% calcium chloride, the formulated concentration of 0.3-7% compound ferro-aluminum mixed with polymers.
Said B component also contains sodium-chlor, representes with mass percent, is 3-18% the aqueous solution by 90-99.2% calcium chloride, 0.5-3% sodium-chlor, the formulated concentration of 0.3-7% compound ferro-aluminum mixed with polymers.
Said compound ferro-aluminum polymkeric substance is one or both in Poly aluminum Chloride (PAC), the bodied ferric sulfate.
Said A component is represented with mass percent, also contains carbon black 0-3%, fine powder material 0-3%.
Pitch in the bitumen emulsion of said A component is preferably 60-120 petroleum pitch and emulsion thereof.
Rubber in the rubber latex of said A component is preferably one or both in (co) polychloroprene rubber, the butadienestyrene copolymer rubber.
The carbon black of said A component is that fineness is not less than 600 purpose carbon powders or WHITE CARBON BLACK powder;
The fine powder material of said A component is that fineness is not less than 800 purpose porcelain powder or dicalcium powders.
A kind of its beneficial effect of liquid rubber spray-coating material that contains phosphotriester of the present invention is: it is that main raising fluid rubber material has self-extinguishing, weathering resistance, winter hardiness, static resistance etc. that the present invention adds phosphotriester at its spray material.In order to improve the weather resistance of this kind fluid rubber coating, the spy takes to add the method that phosphotriester is master's a raising fluid rubber material property.Can make this kind material as having certain anticorrosion, antiseepage to require and being exposed under the sunlight or the weatherable occasion of needs, be applicable to steelwork and the antiseepage of skeleton construction, anticorrosion mask and repairing works such as ocean, roof, boat deck, port engineering, highway, bridge, metallurgy, chemical industry, industry ground slab and covil construction.The body rubber bitumen emulsion coating of taking to add phosphotriester and be main liquid has flame retardant resistance, self-extinguishing, weathering resistance, winter hardiness, antistatic etc.; Cracking resistance, freeze proof, antiseepage, anticorrosion, chloride-penetration resistance, ageing-resistant and corrosion resisting property are applicable to steelwork and the antiseepage of skeleton construction, anticorrosion mask and repairing works such as ocean, roof, boat deck, port engineering, highway, bridge, metallurgy, chemical industry, industry ground slab and covil construction.
Embodiment
Below in conjunction with embodiment a kind of liquid rubber spray-coating material that contains phosphotriester of the present invention is described.
1 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and (co) polychloroprene rubber emulsion 10kg; No. 80 petroleum pitch emulsion 30kg; Anionic dispersing agents TH-904 is that 0.15kg, naphthalenesulfonate formaldehyde condensation compound 0.15kg, CD-4 are 0.15kg, AS rosined soap 1kg, synthetic fatty acid soap 0.5kg, AS 0.2kg, phosphotriester 40kg; White lake 2kg, silane coupling agent 2kg; Carbon black 1.5kg, fineness is not less than 800 purpose porcelain powder 0.75kg, and water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 95% calcium chloride, 1.5% sodium-chlor, the formulated concentration of 5% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is a Poly aluminum Chloride (PAC).
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion:
(1) producing of nature rubber latex or synthetic rubber latex: with the rubber latex of buying if solid content is lower than 48-60%; Need pass through extract at low temperature; Extract solid content at 48-60% nature rubber latex or synthetic rubber latex, with its be warming up to 20--40 ℃ subsequent use.
(2) bitumen emulsion produces
In emulsified bitumen equipment, add the pitch of 1000 weight parts, and remain on 130 ℃, add 20-45% water and anionic part tensio-active agent, temperature will be 40-70 ℃, and carrying out high speed shear, to stir worth solid content be 50-75% anionic emulsified bitumen.
(3) carbon black is produced
Get a certain amount of dispersion agent (consumption be carbon black mass 0.2-30%); Elder generation's water is transferred and is opened; Add the carbon black powder then, disperse fully (it is abundant together to put into grinding in ball grinder) to form stable and flowability carbon black dispersion preferably, it is subsequent use to make liquid carbon black.It is subsequent use that liquid carbon black also can be processed carbon powder.The system carbon powder takes the electrically heated oven dry to handle, and preferably adopts spray drying treatment, and the carbon black that the electrically heated oven dry is handled also need carry out the dry grinding powdering.
(4) fine powder material is produced preparation method and is produced with carbon black.
(5) phosphotriester is processed fineness and is not less than 800 purpose powders.
(6) produce anion liquid body rubber bitumen emulsion
The emulsified bitumen that (2) make is reduced to 20--40 ℃; Add the carbon black of (3) producing, the fine powder material that produce (4), the phosphotriester powder that produce (5) therein; Nature rubber latex or the synthetic rubber latex (1) produced slowly add again; Stir at adding anionic dispersing agents, remaining AS, white lake (powder), silane coupling agent, make anion liquid body rubber bitumen emulsion.
The preparation of B component condensing agent:
90% (mass ratio) water that is accounted for 10% (mass ratio) and the B component total amount of B component by calcium chloride, compound ferro-aluminum polymkeric substance, sodium-chlor mixes fully, produces the B component.
A kind of spraying coating process that contains the liquid rubber spray-coating material of phosphotriester: the A for preparing, B component are respectively charged in the proportion container separately; Under the promotion of power system; A component and B component run to spray gun separately respectively through two pipelines; Two muzzle slope inwardly during spraying, and spray angle is aimed at the same district of the object basal plane face that needs spraying simultaneously, and the moment of material ejection forms atomization process; Two components are carried out thorough mixing before arriving basal plane or when arriving basal plane, film thereby form more uniformly rubber asphalt.Two components are 350-600mm in the joint distance of mixing the spraying face of arrival.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 2.3mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
2 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and butadienestyrene copolymer rubber 10kg; No. 90 petroleum pitch emulsion 15kg; Anionic dispersing agents vitriol is that 0.5kg, naphthalenesulfonate formaldehyde condensation compound 0.15kg, CD-4 are 0.15kg, AS rosined soap 0.5kg, synthetic fatty acid soap 1kg, α-sodium naphthalene sulfonate 0.2kg, phosphotriester 55kg; White lake 2kg, silane coupling agent 5kg; Water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 95% calcium chloride, the formulated concentration of 5% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is a Poly aluminum Chloride (PAC).
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion, the preparation of B component condensing agent and to contain the spraying coating process of liquid rubber spray-coating material of phosphotriester identical with embodiment 1.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 2.0mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
3 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and the fine copolymer rubber emulsion of divinyl propylene 15kg; No. 100 petroleum pitch emulsion 30kg; Anionic dispersing agents TH-904 is that 0.25kg, naphthalenesulfonate formaldehyde condensation compound 0.25kg, Acumer940 polymkeric substance are 0.15kg, AS AS 2.2kg, phosphotriester 40kg; White lake 2kg, silane coupling agent 5kg; Carbon black 0.3kg, fineness is not less than 800 purpose porcelain powder 0.75kg, and water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 97% calcium chloride, 2% sodium-chlor, the formulated concentration of 5% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is a bodied ferric sulfate.
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion, the preparation of B component condensing agent and to contain the spraying coating process of liquid rubber spray-coating material of phosphotriester identical with embodiment 1.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 1.8mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
4 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and isoprene copolymer rubber latex 20kg; Coal-tar pitch emulsion 15kg; Anionic dispersing agents naphthalene sulfonate salt polycondensate is that 0.25kg, naphthalenesulfonate formaldehyde condensation compound 0.55kg, CD-4 are 0.15kg, AS rosined soap 1kg, sodium alkyl benzene sulfonate 1.2kg, phosphotriester 45kg; White lake 2kg, silane coupling agent 4kg; Water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 95% calcium chloride, 2% sodium-chlor, the formulated concentration of 5% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is Poly aluminum Chloride (PAC) and bodied ferric sulfate.
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion, the preparation of B component condensing agent and to contain the spraying coating process of liquid rubber spray-coating material of phosphotriester identical with embodiment 1.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 2.8mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
5 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and polybutadiene rubber emulsion 20kg; Transformation of the way bitumen emulsion 30kg; Anionic dispersing agents TH-904 is 0.25kg, naphthalenesulfonate formaldehyde condensation compound 1.5kg, AS synthetic fatty acid soap 1.5kg, AS 0.2kg, phosphotriester 35kg; White lake 2kg, silane coupling agent 5kg; Carbon black.1kg, fineness is not less than 800 purpose porcelain powder 2.5kg, and water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 95% calcium chloride, 1.5% sodium-chlor, the formulated concentration of 5% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is a Poly aluminum Chloride (PAC).
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion, the preparation of B component condensing agent and to contain the spraying coating process of liquid rubber spray-coating material of phosphotriester identical with embodiment 1.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 3.3mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
6 one kinds of liquid rubber spray-coating materials that contain phosphotriester of embodiment.
A kind of prescription that contains the liquid rubber spray-coating material of phosphotriester is:
A kind of liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; The A component is an anion liquid body rubber bitumen emulsion, the water-based spray material; The B component is a coagulant solution;
A component anion liquid body rubber bitumen emulsion adds up to 100kg, wherein, and isobutene polymer rubber latex 5kg; Shale tar pitch emulsion 50kg; Anionic dispersing agents vitriol 2kg, AS synthetic fatty acid soap 2.5kg, phosphotriester 10kg; White lake 0.5kg, silane coupling agent 2kg; Carbon black 2kg, fineness is not less than 800 purpose porcelain powder 0.75kg, and water is surplus.
The B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
The B component is represented with mass percent, is 10% the aqueous solution by 95% calcium chloride, 2% sodium-chlor, the formulated concentration of 3% compound ferro-aluminum mixed with polymers, and compound ferro-aluminum polymkeric substance is a Poly aluminum Chloride (PAC).
Containing the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
The preparation of A component anion liquid body rubber bitumen emulsion, the preparation of B component condensing agent and to contain the spraying coating process of liquid rubber spray-coating material of phosphotriester identical with embodiment 1.
The glued membrane checking.
Have a certain amount of moisture that gets to separate out in the glued membrane that generates, behind the 24h, coating is dry, and the surface is evenly smooth, thickness 2.5mm.Do adhesive test behind the 168h, according to the ASTM standard, material can't be peeled off from body of wall.Use the same method, coat releasing agent at spraying money, with the drawing machine test, tension set is 200% behind the 168h that films that makes.Detect anti-pierceability test, do not seep water, detect impermeability test, waterproof.
The above; Be merely the preferable embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any technician who is familiar with the present technique field is equal to replacement or change according to technical scheme of the present invention and inventive concept thereof in the technical scope that the present invention discloses, all should be encompassed within protection scope of the present invention.
Claims (9)
1. liquid rubber spray-coating material that contains phosphotriester, it is characterized in that: the said liquid rubber spray-coating material that contains phosphotriester is divided into A, two kinds of components of B; Said A component is an anion liquid body rubber bitumen emulsion; Said B component is a coagulant solution;
Said A component is represented with mass percent, and fluid rubber bitumen emulsion weight solid content is 50-75%; Wherein, rubber latex 1-35%, bitumen emulsion 10-50%; Anionic dispersing agents 0.01-2%, AS 0.01-2%, phosphotriester 1-60%; White lake 1-20%, silane coupling agent 0.1-10%;
Said B component is represented with mass percent, is 3-18% the aqueous solution by calcium chloride, the formulated concentration of compound ferro-aluminum mixed with polymers;
Saidly contain the liquid rubber spray-coating material B component of phosphotriester and the spraying volume ratio of A component is 1/15-1/3.5.
2. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 1 is characterized in that:
Rubber in the rubber latex of said A component is tree elastomer or viton; Said viton is selected from the chlorine polybutadiene rubber, butadienestyrene copolymer rubber, the fine copolymer rubber of divinyl propylene, iso-butylene, isoprene copolymer rubber, one or more in the polybutadiene rubber;
Pitch in the bitumen emulsion of said A component is selected from petroleum pitch, coal-tar pitch, shale tar pitch, one or more in the transformation of the way pitch;
The anionic dispersing agents of said A component is selected from vitriol, TH-904, Acumer940 polymkeric substance, CD-4, naphthalene sulfonate salt polycondensate, one or more in the naphthalenesulfonate formaldehyde condensation compound;
The AS of said A component is selected from rosined soap, synthetic fatty acid soap, AS, sodium alkyl benzene sulfonate, alkyl-sulphate, alkyl aryl sulfate, one or more in α-sodium naphthalene sulfonate.
3. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 1; It is characterized in that: said B component is preferably; Representing with mass percent, is 3-18% the aqueous solution by 93-99.7% calcium chloride, the formulated concentration of 0.3-7% compound ferro-aluminum mixed with polymers.
4. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 1; It is characterized in that: said B component also contains sodium-chlor; Representing with mass percent, is 3-18% the aqueous solution by 90-99.2% calcium chloride, 0.5-3% sodium-chlor, the formulated concentration of 0.3-7% compound ferro-aluminum mixed with polymers.
5. according to claim 1 or 3 or 4 described a kind of liquid rubber spray-coating materials that contain phosphotriester, it is characterized in that: said compound ferro-aluminum polymkeric substance is one or both in Poly aluminum Chloride (PAC), the bodied ferric sulfate.
6. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 1 is characterized in that: it is characterized in that: said A component, represent with mass percent, and also contain carbon black 0-3%, fine powder material 0-3%.
7. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 2, it is characterized in that: the pitch in the bitumen emulsion of said A component is preferably 60-120 petroleum pitch and emulsion thereof.
8. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 1 is characterized in that: the rubber in the rubber latex of said A component is preferably one or both in (co) polychloroprene rubber, the butadienestyrene copolymer rubber.
9. a kind of liquid rubber spray-coating material that contains phosphotriester according to claim 6 is characterized in that: the carbon black of said A component is that fineness is not less than 600 purpose carbon powders or WHITE CARBON BLACK powder; The fine powder material of said A component is that fineness is not less than 800 purpose porcelain powder or dicalcium powders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101958279A CN102337076A (en) | 2011-07-13 | 2011-07-13 | Liquid rubber spray coating containing phosphotriester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011101958279A CN102337076A (en) | 2011-07-13 | 2011-07-13 | Liquid rubber spray coating containing phosphotriester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102337076A true CN102337076A (en) | 2012-02-01 |
Family
ID=45513037
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011101958279A Pending CN102337076A (en) | 2011-07-13 | 2011-07-13 | Liquid rubber spray coating containing phosphotriester |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102337076A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834244A (en) * | 2013-12-25 | 2014-06-04 | 杨昌富 | Emulsion paint for exterior wall |
| CN106085018A (en) * | 2016-06-12 | 2016-11-09 | 安徽快来防水防腐有限公司 | A kind of flame-retardant double-component neoprene polymer cement-base waterproof coating and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876740A (en) * | 2006-07-12 | 2006-12-13 | 海洋化工研究院 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
| US20080125504A1 (en) * | 2006-11-29 | 2008-05-29 | Hilti Aktiengesellscahft | Multicomponent polyurethane/vinyl ester hybrid foam system and its use |
| CN101235252A (en) * | 2008-01-15 | 2008-08-06 | 大连美宸特环保节能产品有限公司 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
-
2011
- 2011-07-13 CN CN2011101958279A patent/CN102337076A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1876740A (en) * | 2006-07-12 | 2006-12-13 | 海洋化工研究院 | Solvent-free expansion type fire-proof epoxy coating and its preparation method |
| US20080125504A1 (en) * | 2006-11-29 | 2008-05-29 | Hilti Aktiengesellscahft | Multicomponent polyurethane/vinyl ester hybrid foam system and its use |
| CN101235252A (en) * | 2008-01-15 | 2008-08-06 | 大连美宸特环保节能产品有限公司 | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device |
| CN101440249A (en) * | 2008-05-23 | 2009-05-27 | 海洋化工研究院 | Ultrathin section steel structure fire-resisting paint and preparation thereof |
| CN101358028A (en) * | 2008-09-02 | 2009-02-04 | 宁波一舟塑胶有限公司 | Halogen-free flame-retardant thermoplastic elastomer electrical cable material using polyphenylene ether as base material and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103834244A (en) * | 2013-12-25 | 2014-06-04 | 杨昌富 | Emulsion paint for exterior wall |
| CN106085018A (en) * | 2016-06-12 | 2016-11-09 | 安徽快来防水防腐有限公司 | A kind of flame-retardant double-component neoprene polymer cement-base waterproof coating and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102329566A (en) | High-permeability liquid rubber spray coating | |
| CN101235252B (en) | Multifunctional liquid rubber spray-coating material, preparation method, using method and special-purpose device | |
| CN102329562A (en) | Superfine needle-shaped wollastonite powder-containing liquid rubber spray coating | |
| CN103666201B (en) | Long-acting acid and alkali-resistance, solvent-free anticorrosive paint and preparation method thereof and application | |
| CN105838195A (en) | Waterborne epoxy anti-corrosion paint containing graphene oxide and preparing method of waterborne epoxy anti-corrosion paint | |
| CN102329112B (en) | Colored polymer cement underwater paint | |
| CN101597454A (en) | The environment-friendly cable fire-refractory coating of high-weatherability and preparation technology | |
| CN105176172A (en) | Water-based anticorrosive paint and preparation method thereof | |
| CN104877402A (en) | Compound water-based inorganic anticorrosive paint and preparation method | |
| CN102009019B (en) | Special equipment for multi-functional liquid rubber coating | |
| CN104725969B (en) | Water-based anti-corrosion floating type aluminium powder paint and preparation method thereof | |
| CN102702899A (en) | Water-based modified pure acrylic acid anticorrosive paint | |
| CN102329568A (en) | Liquid rubber spray paint containing triaryl phosphate | |
| CN104194534A (en) | Waterproof heat preservation coating for building external wall and preparation method of waterproof heat preservation coating | |
| CN105907240B (en) | A kind of water corrosion-resistant epoxy paint and preparation method thereof containing anti-flash rusting agent | |
| CN105086770A (en) | Iron oxide red water-based epoxy rust-proof primer and preparing method thereof | |
| CN106519890A (en) | Economical aqueous epoxy scumbled floor paint and preparation method therefor | |
| CN102337076A (en) | Liquid rubber spray coating containing phosphotriester | |
| CN109880479A (en) | A kind of double-component aqueous graphene epoxy zinc-enriched paint and preparation method thereof | |
| CN102329567A (en) | Liquid rubber spray paint containing hydrotalcite | |
| CN105419571A (en) | Heavy anti-corrosion coating material | |
| CN107955536A (en) | A kind of liquid rubber spray-coating material | |
| CN102702867B (en) | Modified high chlorinated polythene long-acting anti-corrosive paint and preparation method thereof | |
| CN1544557A (en) | Fireproof paint for expanding super-thin steel structure and its preparation method | |
| CN102329569A (en) | Rock wool-containing liquid rubber spray coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| ASS | Succession or assignment of patent right |
Owner name: DALIAN MEICHENTE ENVIRONMENTAL PROTECTION AND ENER Free format text: FORMER OWNER: DALIAN MEICHENTE TECHNOLOGY CO., LTD. Effective date: 20130522 |
|
| C10 | Entry into substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 116021 DALIAN, LIAONING PROVINCE TO: 116023 DALIAN, LIAONING PROVINCE |
|
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20130522 Address after: Dalian high tech Industrial Park in Liaoning province wide road 116023 room No. 97 201A Applicant after: Dalian meichente environmental protection and energy saving products Co.,Ltd. Address before: 116021 No. 139, Shenyang Road, Xigang District, Liaoning, Dalian Applicant before: DALIAN MEICHENTE TECHNOLOGY Co.,Ltd. |
|
| C12 | Rejection of a patent application after its publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20120201 |